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Intimate Interaction of TFSI− Anions with MoO3−x Oxygen Vacancies Boost Ionic Conductivity of Cathode-Supported Solid Polymer Electrolyte
Actual operation of SSB
ToF-SIMS Mapping
Schematic illustration of ion dissociation in the presence of MNBs.
MoO3−x nanobelts (MNBs) were used a passive nanofillers in a PEO/LiTFSI matrix to enhance the ionic conductivity of solid polymer electrolyte.
The O2 vacancies on the MNBs surface act as Lewis acid sites and dissociate the LiTFSI salt into Li+ cation and TFSI- anions. This phenomenon help to increase the ionic conductivity of the polymer matrix.
Capillary-Induced Self-Crumpled and Sulfur-Deficient MoS2 Nanosheets Inhibit Polysulfide Cycling in Lithium-Sulfur Batteries
Published as: R. Paste et.al Capillary-induced self-crumpled and sulfur-deficient MoS2 nanosheets inhibit polysulfide cycling in lithium-sulfur batteries" J. Mater. Chem. A, 2023,11, 8265-8276
Specially designed 3D crumpled MoS2 was utilized as a shielding layer to suppress the migration of Li-Polysulfides.
The strained sulfur vacancies on the MoS2 surface initiate the adsorption and reutilization of LiPSs during battery cycling.
Li Dendrite Growth
Ball Milling Method
Spray Coating Technique
Oxygen-Enriched α-MoO3–x Nanobelts (MNBs) were utilized to suppress the formation of Li dendrites on Li metal anode.
MNBs can shorten the diffusion length of Li with a large surface area and a high number of edges and corners.
The MNBs provide sufficient diffusion pathways for the Li+ ions to diffuse during cycling, which decreases the electrode's interfacial resistance.