The oxidation and reduction reactions always occur simultaneously in redox or oxidation-reduction reactions. The substance getting reduced in a chemical reaction is known as the oxidizing agent, while a substance that is getting oxidized is known as the reducing agent.

A redox reaction can be defined as a chemical reaction in which electrons are transferred between two reactants participating in it. This transfer of electrons can be identified by observing the changes in the oxidation states of the reacting species.


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In the illustration provided below, it can be observed that the reactant, an electron, was removed from reactant A, and this reactant is oxidized. Similarly, reactant B was handed an electron and was, therefore, reduced.

The loss of electrons and the corresponding increase in the oxidation state of a given reactant is called oxidation. The gain of electrons and the corresponding decrease in the oxidation state of a reactant is called reduction.

Electron-accepting species which tend to undergo a reduction in redox reactions are called oxidizing agents. An electron-donating species which tends to hand over electrons can be referred to as a reducing agent. These species tend to undergo oxidation. It can be noted that any redox reaction can be broken down into two half-reactions, namely, the oxidation half-reaction and the reduction half-reaction.

In this type of reaction, a metal present in the compound is displaced by another metal. These types of reactions find their application in metallurgical processes where pure metals are obtained from their ores.

Oxidation may be defined as the loss of electrons from a substance; the other definition of oxidation reactions states that the addition of oxygen or the more electronegative element or removal of hydrogen or the more electropositive element from a substance is called an oxidation reaction.

The reaction in which FeCl3 is getting reduced as electronegative element chlorine is being removed from it. At the same time, hydrogen is getting oxidized due to the addition of chlorine, an electronegative element, in the same reaction.

Lithium is the strongest reducing agent in the solution, and caesium is the strongest reducing agent in the absence of water. The substances which act as oxidizing as well as reducing agents are H2O2, SO2, H2SO3, HNO2 and NaNO2

Each half-reaction that makes up a redox reaction has a standard electrode potential. This potential equals the voltage produced by an electrochemical cell in which the cathode reaction is the half-reaction considered, whereas the anode is a standard hydrogen electrode.

This voltage produced by the half-reactions is called their reduction potentials (denoted by E0red). The value of the reduction potential of a half-reaction is positive for the oxidizing agents that are stronger than H+ and negative for the weaker ones.

There are two ways of balancing the redox reaction. One method is by using the change in oxidation number of oxidizing agent and the reducing agent, and the other method is based on dividing the redox reaction into two half reactions-one of reduction and another of oxidation.

Fe2+ is oxidised to Fe3+ oxidation: \(\begin{array}{l}2F{{e}^{2+}}\to Fe_{2}^{+3}+2{{e}^{-}}\left[oxidation \right]\end{array} \)Reduction: \(\begin{array}{l}M{{n}^{+7}}+5{{e}^{-}}\to M{{n}^{+2}}\left[ {Re}duciton \right]\end{array} \)Multiply the oxidation reaction by 5 and the reduction reaction by 2.

Combustion is a type of oxidation-reduction reaction, and hence, it is a redox reaction. An explosion is a fast form of combustion; hence, the explosion can be treated as a redox reaction. Even the space shuttle uses redox reactions. The combination of ammonium perchlorate and powdered aluminium inside the rocket boosters gives rise to an oxidation-reduction reaction.

In the above reaction, we can see that carbon dioxide is reduced to carbohydrates while the water gets oxidized to oxygen; hence, it is a redox reaction. The energy is provided by the sunlight for this reaction. This reaction is a source of food for animals and plants.


Frequently Asked Questions on Redox ReactionsQ1 What are oxidation-reduction reactions?Oxidation-reduction reactions are chemical reactions that involve the transfer of electrons between the reacting species. These electron transfers are accompanied by a change in the oxidation state of the reactants.Q2 What are oxidizing agents?An oxidizing agent is an electron-accepting species that is readily reduced in an oxidation-reduction reaction. The oxidation numbers of these species tend to decrease in redox reactions. Examples: nitric acid (HNO3) and hydrogen peroxide (H2O2).Q3 What are reducing agents?Reducing agents are the electron-donating species that readily undergo oxidation in oxidation-reduction reactions. These species tend to lose electrons in redox reactions, and their oxidation number increases. Examples: zinc and lithium.Q4 How do you determine if a redox reaction has occurred?1. Assign the oxidation numbers to all the atoms.

The chemical reactions which involve the transfer of electrons from one chemical substance to another. These electron-transfer reactions are termed as oxidation-reduction reactions or redox reactions. These reactions are accompanied by energy changes in the form of heat, light, and electricity etc. The oxidation and reduction reaction also involve the addition of oxygen or hydrogen to different substances.

Note:(i) In the reactions taking place in acidic medium, balance the O atom by adding the required number of H2O molecules to the side deficient in O atoms. Then balance the H atoms by adding H+ to the side deficient in H atoms.

It is based on the Principle that the electrons lost during oxidation half reaction in a particular redox reactions is equal to the electrons gained in the reduction half reaction. The method is called half reaction method. The balancing is completed in the following steps:

When a reactant loses electrons during a reaction, it is called oxidation. When a reactant accumulates electrons during a reaction, it is called reduction. When metals react with acid, this is a common occurrence. When a reactant loses electrons during a reaction, it is called oxidation. When a reactant accumulates electrons during a reaction, it is called reduction. When metals react with acid, this is a common occurrence.

A reduction-oxidation or redox reaction is a type of chemical reaction in which reduction and oxidation occur at the same time. The reduced species receives electrons whereas the oxidised species loses them. An oxidation process does not need the presence of oxygen, despite its name.

Due to the changes in oxidation states that occur without the independent transfer of electrons, many reactions in organic chemistry can be classified as redox reactions. For instance, the oxidation state of carbon atoms in the wood increases during the combustion of wood with molecular oxygen, and that of oxygen atoms decreases as carbon dioxide and water are produced. The oxygen atoms are reduced, formally receiving electrons, while the carbon atoms are oxidised, losing electrons. Therefore, oxygen is the oxidising agent and the reducing agent in this reaction is carbon.

It loses electrons in a reaction in chemistry if a substance is oxidized. It gains electrons in a reaction if a substance is reduced. A reaction within which there is both oxidation and reduction is called a REDOX reaction.

Oxidation-reduction (redox) reactions are significant because they are the main natural or biological and artificial energy sources on this planet. Oxidation of molecules usually releases large amounts of energy by removing hydrogen and replacing it with oxygen.

It oxidizes the material that gives electrons. It forms a chemical called rust when iron reacts with oxygen because it has been oxidized (the iron has lost some electrons) and the oxygen has been reduced (the oxygen has gained some electrons). The cause of reduction is oxidation.

Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds. In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer.[1] Instead the relevant criterion for organic oxidation is gain of oxygen and/or loss of hydrogen.[2] Simple functional groups can be arranged in order of increasing oxidation state. The oxidation numbers are only an approximation:[1]

Many reactions classified as reductions also appear in other classes. For instance, conversion of the ketone to an alcohol by lithium aluminium hydride can be considered a reduction but the hydride is also a good nucleophile in nucleophilic substitution. Many redox reactions in organic chemistry have coupling reaction reaction mechanism involving free radical intermediates. True organic redox chemistry can be found in electrochemical organic synthesis or electrosynthesis. Examples of organic reactions that can take place in an electrochemical cell are the Kolbe electrolysis.[3]

Most oxidations are conducted with air or oxygen, especially in industry. These oxidation include routes to chemical compounds, remediation of pollutants, and combustion. Some commercially important oxidations are listed:

In organic chemistry, reduction is equivalent to the addition of hydrogen atoms, usually in pairs. The reaction of unsaturated organic compounds with hydrogen gas is called hydrogenation. The reaction of saturated organic compounds with hydrogen gas is called hydrogenolysis. Hydrogenolyses necessarily cleaves C-X bonds (X = C, O, N, etc.). Reductions can also be effected by adding hydride and proton sources, the so-called heterolytic pathway. Such reactions are often effected using stoichiometric hydride reagents such as sodium borohydride or lithium aluminium hydride.[5]

In the example above, the reactants C and O2 have an oxidation state of zero because they are in their molecular forms. On the product side, the oxidation state of carbon is changed to +4, and for oxygen, it is -2. We can see that simultaneous oxidation and reduction occur in one reaction. Hence, it is a combination redox reaction. 152ee80cbc

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