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Patents and Patent Applications
Patents and Patent Applications
1. Dan Zhao, Anthony K. Cheetham, and Rajesh Das, Hydrophobic Metal-Organic Framework Composites for Carbon Capture, 2024, Singapore Patent Application No. 10202402004Q.
Research Articles
Research Articles
16. Das, R.; Li, H.; Evans, H. A.; Deng, Z.; Zhao, D.; Cheetham, A. K. Hydrophobic Metal-Formate Composites for Efficient CO2 Capture. J. Am. Chem. Soc. 2025, 147, 8377−8385.
Link: https://doi.org/10.1021/jacs.4c16131
Link: https://doi.org/10.1021/jacs.4c16131
15. Rani, P.; Das, R.; Nagaraja, C. M. A review on framework (MOF/COF/POP)-based materials for efficient conversion of CO2 to bio-active oxazolidinones. Inorg. Chem. Front. 2025, 12, 430-478.
This article is part of the themed collection: 2024 Inorganic Chemistry Frontiers Review-type Articles
Link: https://doi.org/10.1039/D4QI02101K
Link: https://doi.org/10.1039/D4QI02101K
14. Das, R.; Kishan, R.; Muthukumar, D.; Pillai, R. S.; Nagaraja, C. M. Engineering the Functionality of Porous Organic Polymers (POPs) for Metal/Cocatalyst-Free CO2 Fixation at Atmospheric Conditions. J. Environ. Chem. Eng. 2024, 12, 113777.
Link: https://doi.org/10.1016/j.jece.2024.113777
13. Das, R.; Verma, P. K.; Nagaraja, C. M. Design of Porphyrin-based Frameworks for Artificial Photosynthesis and Environmental Remediation: Recent Progress and Future Prospects. Coord. Chem. Rev. 2024, 514, 215944.
Link: https://doi.org/10.1016/j.ccr.2024.215944
12. R. Das, R. Belgamwar, S. S. Manna, B. Pathak, V. Polshettiwar and C. M. Nagaraja, Design of porphyrin-based frameworks for efficient visible light-promoted reduction of CO2 from dilute gas: Combined experimental and theoretical investigation. J. Colloid Interface Sci. 2023, 652, 480-489.
Link: https://doi.org/10.1016/j.jcis.2023.08.093
11. Das, R.; Kamra, S.; Nagaraja, C. M. Ionic Fe(III)-porphyrin frameworks for the one-pot synthesis of cyclic carbonates from olefins and CO2. Inorg. Chem. Front. 2023, 10, 2088–2099. (Hot article / Highlights from India)
Link: https://doi.org/10.1039/d2qi02599j
Hot Article: https://pubs.rsc.org/en/journals/articlecollectionlandingsercode=qi&themeid=9c767cb4-c807-4d99-a9c7-36046ae7bd4b
Highlights from India: https://click.rsc.org/rsps/m/6GKVW7e0Rr3nQh2qUPMALnLa-hBEqdo-82vL2puhuN8
10. Nagaraj, A.; Das, R.; Nagaraja, C. M. Rational construction of noble metal-free Cu(I) anchored Zr-MOF for efficient fixation of CO2 from diluted gas at ambient conditions. Micropor. Mesopor. Mater. 2023, 351, 112494.
Link: https://doi.org/10.1016/j.micromeso.2023.112494
9. Das, R.; Manna, S. S.; Pathak, B.; Nagaraja, C. M. Strategic Design of Mg-Centered Porphyrin MOF for Efficient Visible Light-Promoted Fixation of CO2 at Ambient Conditions: Combined Experimental and Theoretical Investigation. ACS Appl. Mater. Interfaces 2022, 14, 33285-33296.
9. Das, R.; Manna, S. S.; Pathak, B.; Nagaraja, C. M. Strategic Design of Mg-Centered Porphyrin MOF for Efficient Visible Light-Promoted Fixation of CO2 at Ambient Conditions: Combined Experimental and Theoretical Investigation. ACS Appl. Mater. Interfaces 2022, 14, 33285-33296.
Link: https://doi.org/10.1021/acsami.2c07969
8. Das, R.; Ezhil, T.; Nagaraja, C. M. Design of Bifunctional Zinc(II)-Organic Framework for Efficient Coupling of CO2 with Terminal/Internal Epoxides under Mild Conditions. Crystal Growth & Design, 2022, 22, 598-607.
8. Das, R.; Ezhil, T.; Nagaraja, C. M. Design of Bifunctional Zinc(II)-Organic Framework for Efficient Coupling of CO2 with Terminal/Internal Epoxides under Mild Conditions. Crystal Growth & Design, 2022, 22, 598-607.
Link: https://doi.org/10.1021/acs.cgd.1c01148
Link: https://doi.org/10.1021/acs.cgd.1c01148
7. Das, R.; Parihar, V.; Nagaraja, C. M. Strategic design of a bifunctional Ag(I)-grafted NHC-MOF for efficient chemical fixation of CO2 from dilute gas at ambient conditions. Inorg. Chem. Front. 2022, 9, 2583-2593.
7. Das, R.; Parihar, V.; Nagaraja, C. M. Strategic design of a bifunctional Ag(I)-grafted NHC-MOF for efficient chemical fixation of CO2 from dilute gas at ambient conditions. Inorg. Chem. Front. 2022, 9, 2583-2593.
Link: https://doi.org/10.1039/D2QI00479H
Link: https://doi.org/10.1039/D2QI00479H
6. Das, R.; Ezhil, T.; Palakkal, A. S.; Muthukumar, D.; Pillai, R. S.; Nagaraja, C. M. Efficient chemical fixation of CO2 from direct air under environment-friendly co-catalyst and solvent-free ambient conditions. J. Mater. Chem. A 2021, 9, 23127-23139.
6. Das, R.; Ezhil, T.; Palakkal, A. S.; Muthukumar, D.; Pillai, R. S.; Nagaraja, C. M. Efficient chemical fixation of CO2 from direct air under environment-friendly co-catalyst and solvent-free ambient conditions. J. Mater. Chem. A 2021, 9, 23127-23139.
Link: https://doi.org/10.1039/D1TA05138E
Link: https://doi.org/10.1039/D1TA05138E
5. Das, R.; Nagaraja, C. M. Noble metal-free Cu(I)-anchored NHC-based MOF for highly recyclable fixation of CO2 under RT and atmospheric pressure conditions. Green Chem. 2021, 23, 5195-5204.
5. Das, R.; Nagaraja, C. M. Noble metal-free Cu(I)-anchored NHC-based MOF for highly recyclable fixation of CO2 under RT and atmospheric pressure conditions. Green Chem. 2021, 23, 5195-5204.
Link: https://doi.org/10.1039/D1GC01312B
Link: https://doi.org/10.1039/D1GC01312B
4. Dhankhar, S. S.; Das, R.; Ugale, B.; Pillai, R. S.; Nagaraja, C. M. Chemical Fixation of CO2 Under Solvent and Co-Catalyst-free Conditions Using a Highly Porous Two-fold Interpenetrated Cu(II)-Metal–Organic Framework. Cryst. Growth Des. 2021, 21, 1233-1241.
Link: https://doi.org/10.1021/acs.cgd.0c01530
Link: https://doi.org/10.1021/acs.cgd.0c01530
3. Das, R.; Nagaraja, C. M. Highly Efficient Fixation of Carbon Dioxide at RT and Atmospheric Pressure Conditions: Influence of Polar Functionality on Selective Capture and Conversion of CO2. Inorg. Chem. 2020, 59, 9765-9773. (A unique CAS number has been registered for the compound reported in this work).
3. Das, R.; Nagaraja, C. M. Highly Efficient Fixation of Carbon Dioxide at RT and Atmospheric Pressure Conditions: Influence of Polar Functionality on Selective Capture and Conversion of CO2. Inorg. Chem. 2020, 59, 9765-9773. (A unique CAS number has been registered for the compound reported in this work).
Link: https://doi.org/10.1021/acs.inorgchem.0c00987
Link: https://doi.org/10.1021/acs.inorgchem.0c00987
2. Das, R.; Muthukumar, D.; Pillai, R. S.; Nagaraja, C. M. Rational design of a Zn(II)-MOF with multiple functional sites for highly efficient fixation of CO2 at mild conditions: combined experimental and theoretical investigation. Chem. Eur. J. 2020, 26, 17445-17454
2. Das, R.; Muthukumar, D.; Pillai, R. S.; Nagaraja, C. M. Rational design of a Zn(II)-MOF with multiple functional sites for highly efficient fixation of CO2 at mild conditions: combined experimental and theoretical investigation. Chem. Eur. J. 2020, 26, 17445-17454
Link: https://doi.org/10.1002/chem.202002688
Link: https://doi.org/10.1002/chem.202002688
1. Das, R.; Dhankhar, S. S.; Nagaraja, C. M. Construction of a bifunctional Zn(II)-organic framework containing basic amine functionality for selective capture and room temperature fixation of CO2. Inorg. Chem. Front. 2020, 7, 72-81. (Featured on the front cover of the issue).
1. Das, R.; Dhankhar, S. S.; Nagaraja, C. M. Construction of a bifunctional Zn(II)-organic framework containing basic amine functionality for selective capture and room temperature fixation of CO2. Inorg. Chem. Front. 2020, 7, 72-81. (Featured on the front cover of the issue).
Link: https://doi.org/10.1039/C9QI01058K
Link: https://doi.org/10.1039/C9QI01058K
If we knew what we were doing, it wouldn’t be called research, would it?
If we knew what we were doing, it wouldn’t be called research, would it?
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