Overview: Environmental regulations and sustainability demands require alternatives to conventional lead-based ceramics (like PZT). Our lab focuses on developing compositionally engineered lead-free ferroelectric and piezoelectric systems.
Focus Areas:
Bismuth-based, and titanate perovskite solid solutions.
Strain engineering and phase boundary optimization for enhanced electromechanical response.
Energy harvesting and high-temperature applications.
Overview: Defect structures strongly govern the macroscopic electrical, dielectric, and piezoelectric responses of functional ceramics. We investigate point defect behavior, oxygen vacancy dynamics, and domain wall pinning.
Focus Areas:
Characterization of acceptor/donor defect dipoles and polarization fatigue.
Tailoring dielectric breakdown strength and insulation resistance.
Electrical degradation mechanisms under high-temperature/high-field conditions.
Overview: Incorporating multi-component equimolar/near-equimolar cations into single-phase ceramic lattices unlocks unique entropy-stabilized structures with tailored dielectric and functional capabilities.
Focus Areas:
Synthesis and phase stability of high-entropy perovskites and oxides.
Local structure disorder and its influence on permittivity, energy storage density, and loss mechanisms.
Discovering novel composition spaces for multi-functional applications.
Overview: Additive manufacturing (3D printing) breaks traditional geometric constraints, enabling complex, architected structures that enhance functional performance. Our research focuses on tailoring feedstock chemistry, printing parameters, and sintering strategies to fabricate high-density functional ceramics and flexible ceramic–polymer composites.
Focus Areas:
Feedstock & Rheology Optimization: Formulating high-solid-loading ceramic slurries and composite inks with tailored rheological behavior for high-resolution printing.
Complex Dielectric & Piezoelectric Architectures: Designing structured composites and porous lattices to optimize dielectric constant, piezoelectric response, and mechanical flexibility.
Structure–Property Relationships: Investigating the interplay between printing-induced microstructural anisotropy, interfacial compatibility between phases, and resulting functional properties.
Target Applications: Flexible energy harvesters, custom-shaped sensors, high-temperature dielectric capacitors, and architected acoustic transducers.
Highlight 1: Defect-Driven Phase Transition and Enhanced Electromechanical Strain in Alkali-Doped BaTiO3-Bi(Zn1/2Ti1/2)O3 Relaxor Ceramics
Journal: Journal of Alloys and Compounds
Authors: Ketkaeo Bunpang, Puripat Kantha, Jialuo Wang, Pathit Premwichit, Sasipohn Prasertpalichat, Xiaoxu Zhao, Natthaphon Raengthon
Highlight 2: Enhanced temperature stability and reduced tan δ in B‐site modified titanate‐based high‐entropy perovskite oxides
Journal: Journal of the American Ceramic Society
Authors: Ketkaeo Bunpang, Widchaya Somsri, David P Cann, Natthaphon Raengthon
Ferroelectric / Piezoelectric Test Unit
Polarization & Strain vs Electric Field : Poling : Fatigue (At room and high temperatures)
Raman Spectroscopy
Phase Transitions : Soft Phonon Modes : Local Distortion and Disorder Mapping
AFM/PFM
Surface topography and roughness : Local ferroelectric domains and electromechanical properties
High-Temperature Furnaces
Up to 1500 C
Microwave Oven
Use with silicon carbide microwave kiln for rapid synthesis and sintering
Ball Milling & Chemical Processing
Solid-State and Wet-chemical synthesis (Sol-Gel & Hydro/Solvothermal)