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The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, solid state, and quantum chemistry to draw inferences about the properties of atoms, molecules and solids. The effect has found use in electronic devices specialized for light detection and precisely timed electron emission.

Even though photoemission can occur from any material, it is most readily observed from metals and other conductors. This is because the process produces a charge imbalance which, if not neutralized by current flow, results in the increasing potential barrier until the emission completely ceases. The energy barrier to photoemission is usually increased by nonconductive oxide layers on metal surfaces, so most practical experiments and devices based on the photoelectric effect use clean metal surfaces in evacuated tubes. Vacuum also helps observing the electrons since it prevents gases from impeding their flow between the electrodes.[citation needed]

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The classical setup to observe the photoelectric effect includes a light source, a set of filters to monochromatize the light, a vacuum tube transparent to ultraviolet light, an emitting electrode (E) exposed to the light, and a collector (C) whose voltage VC can be externally controlled.[citation needed]

A positive external voltage is used to direct the photoemitted electrons onto the collector. If the frequency and the intensity of the incident radiation are fixed, the photoelectric current I increases with an increase in the positive voltage, as more and more electrons are directed onto the electrode. When no additional photoelectrons can be collected, the photoelectric current attains a saturation value. This current can only increase with the increase of the intensity of light.[citation needed]

There are cases where the three-step model fails to explain peculiarities of the photoelectron intensity distributions. The more elaborate one-step model[21] treats the effect as a coherent process of photoexcitation into the final state of a finite crystal for which the wave function is free-electron-like outside of the crystal, but has a decaying envelope inside.[20]

In 1839, Alexandre Edmond Becquerel discovered the photovoltaic effect while studying the effect of light on electrolytic cells.[22] Though not equivalent to the photoelectric effect, his work on photovoltaics was instrumental in showing a strong relationship between light and electronic properties of materials. In 1873, Willoughby Smith discovered photoconductivity in selenium while testing the metal for its high resistance properties in conjunction with his work involving submarine telegraph cables.[23]

In 1887, Heinrich Hertz observed the photoelectric effect[26] and reported on the production and reception[27] of electromagnetic waves.[28] The receiver in his apparatus consisted of a coil with a spark gap, where a spark would be seen upon detection of electromagnetic waves. He placed the apparatus in a darkened box to see the spark better. However, he noticed that the maximum spark length was reduced when inside the box. A glass panel placed between the source of electromagnetic waves and the receiver absorbed ultraviolet radiation that assisted the electrons in jumping across the gap. When removed, the spark length would increase. He observed no decrease in spark length when he replaced the glass with quartz, as quartz does not absorb UV radiation.[citation needed]

The discoveries by Hertz led to a series of investigations by Wilhelm Hallwachs,[29][30] Hoor,[31] Augusto Righi[32] and Aleksander Stoletov[33][34] on the effect of light, and especially of ultraviolet light, on charged bodies. Hallwachs connected a zinc plate to an electroscope. He allowed ultraviolet light to fall on a freshly cleaned zinc plate and observed that the zinc plate became uncharged if initially negatively charged, positively charged if initially uncharged, and more positively charged if initially positively charged. From these observations he concluded that some negatively charged particles were emitted by the zinc plate when exposed to ultraviolet light.

In the period from 1888 until 1891, a detailed analysis of the photoeffect was performed by Aleksandr Stoletov with results reported in six publications.[34] Stoletov invented a new experimental setup which was more suitable for a quantitative analysis of the photoeffect. He discovered a direct proportionality between the intensity of light and the induced photoelectric current (the first law of photoeffect or Stoletov's law). He measured the dependence of the intensity of the photo electric current on the gas pressure, where he found the existence of an optimal gas pressure corresponding to a maximum photocurrent; this property was used for the creation of solar cells.[citation needed]

Initial investigation of the photoelectric effect in gasses by Lenard[41] were followed up by J. J. Thomson[42] and then more decisively by Frederic Palmer Jr.[43][44] The gas photoemission was studied and showed very different characteristics than those at first attributed to it by Lenard.[28]

In 1900, while studying black-body radiation, the German physicist Max Planck suggested in his "On the Law of Distribution of Energy in the Normal Spectrum"[45] paper that the energy carried by electromagnetic waves could only be released in packets of energy. In 1905, Albert Einstein published a paper advancing the hypothesis that light energy is carried in discrete quantized packets to explain experimental data from the photoelectric effect. Einstein theorized that the energy in each quantum of light was equal to the frequency of light multiplied by a constant, later called the Planck constant. A photon above a threshold frequency has the required energy to eject a single electron, creating the observed effect. This was a step in the development of quantum mechanics. In 1914, Robert A. Millikan's highly accurate measurements of the Planck constant from the photoelectric effect supported Einstein's model, even though a corpuscular theory of light was for Millikan, at the time, "quite unthinkable".[46] Einstein was awarded the 1921 Nobel Prize in Physics for "his discovery of the law of the photoelectric effect",[47] and Millikan was awarded the Nobel Prize in 1923 for "his work on the elementary charge of electricity and on the photoelectric effect".[48] In quantum perturbation theory of atoms and solids acted upon by electromagnetic radiation, the photoelectric effect is still commonly analyzed in terms of waves; the two approaches are equivalent because photon or wave absorption can only happen between quantized energy levels whose energy difference is that of the energy of photon.[49][18]

Albert Einstein's mathematical description of how the photoelectric effect was caused by absorption of quanta of light was in one of his Annus Mirabilis papers, named "On a Heuristic Viewpoint Concerning the Production and Transformation of Light".[50] The paper proposed a simple description of energy quanta, and showed how they explained the blackbody radiation spectrum. His explanation in terms of absorption of discrete quanta of light agreed with experimental results. It explained why the energy of photoelectrons was not dependent on incident light intensity. This was a theoretical leap, but the concept was strongly resisted at first because it contradicted the wave theory of light that followed naturally from James Clerk Maxwell's equations of electromagnetism, and more generally, the assumption of infinite divisibility of energy in physical systems.

Video camera tubes in the early days of television used the photoelectric effect, for example, Philo Farnsworth's "Image dissector" used a screen charged by the photoelectric effect to transform an optical image into a scanned electronic signal.[56]

Photons hitting a thin film of alkali metal or semiconductor material such as gallium arsenide in an image intensifier tube cause the ejection of photoelectrons due to the photoelectric effect. These are accelerated by an electrostatic field where they strike a phosphor coated screen, converting the electrons back into photons. Intensification of the signal is achieved either through acceleration of the electrons or by increasing the number of electrons through secondary emissions, such as with a micro-channel plate. Sometimes a combination of both methods is used. Additional kinetic energy is required to move an electron out of the conduction band and into the vacuum level. This is known as the electron affinity of the photocathode and is another barrier to photoemission other than the forbidden band, explained by the band gap model. Some materials such as gallium arsenide have an effective electron affinity that is below the level of the conduction band. In these materials, electrons that move to the conduction band all have sufficient energy to be emitted from the material, so the film that absorbs photons can be quite thick. These materials are known as negative electron affinity materials.[citation needed]

The photoelectric effect will cause spacecraft exposed to sunlight to develop a positive charge. This can be a major problem, as other parts of the spacecraft are in shadow which will result in the spacecraft developing a negative charge from nearby plasmas. The imbalance can discharge through delicate electrical components. The static charge created by the photoelectric effect is self-limiting, because a higher charged object does not give up its electrons as easily as a lower charged object does.[58][59]

Light from the Sun hitting lunar dust causes it to become positively charged from the photoelectric effect. The charged dust then repels itself and lifts off the surface of the Moon by electrostatic levitation.[60][61] This manifests itself almost like an "atmosphere of dust", visible as a thin haze and blurring of distant features, and visible as a dim glow after the sun has set. This was first photographed by the Surveyor program probes in the 1960s,[62] and most recently the Chang'e 3 rover observed dust deposition on lunar rocks as high as about 28 cm.[63] It is thought that the smallest particles are repelled kilometers from the surface and that the particles move in "fountains" as they charge and discharge.[64] e24fc04721