Photo Effect

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Photo Effect

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The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, solid state, and quantum chemistry to draw inferences about the properties of atoms, molecules and solids. The effect has found use in electronic devices specialized for light detection and precisely timed electron emission.

The photons of a light beam have a characteristic energy, called photon energy, which is proportional to the frequency of the light. In the photoemission process, when an electron within some material absorbs the energy of a photon and acquires more energy than its binding energy, it is likely to be ejected. If the photon energy is too low, the electron is unable to escape the material. Since an increase in the intensity of low-frequency light will only increase the number of low-energy photons, this change in intensity will not create any single photon with enough energy to dislodge an electron. Moreover, the energy of the emitted electrons will not depend on the intensity of the incoming light of a given frequency, but only on the energy of the individual photons.[citation needed]

When the photoelectron is emitted into a solid rather than into a vacuum, the term internal photoemission is often used, and emission into a vacuum is distinguished as external photoemission.

Even though photoemission can occur from any material, it is most readily observed from metals and other conductors. This is because the process produces a charge imbalance which, if not neutralized by current flow, results in the increasing potential barrier until the emission completely ceases. The energy barrier to photoemission is usually increased by nonconductive oxide layers on metal surfaces, so most practical experiments and devices based on the photoelectric effect use clean metal surfaces in evacuated tubes. Vacuum also helps observing the electrons since it prevents gases from impeding their flow between the electrodes.[citation needed]

The classical setup to observe the photoelectric effect includes a light source, a set of filters to monochromatize the light, a vacuum tube transparent to ultraviolet light, an emitting electrode (E) exposed to the light, and a collector (C) whose voltage VC can be externally controlled.[citation needed]

A positive external voltage is used to direct the photoemitted electrons onto the collector. If the frequency and the intensity of the incident radiation are fixed, the photoelectric current I increases with an increase in the positive voltage, as more and more electrons are directed onto the electrode. When no additional photoelectrons can be collected, the photoelectric current attains a saturation value. This current can only increase with the increase of the intensity of light.[citation needed]

An increasing negative voltage prevents all but the highest-energy electrons from reaching the collector. When no current is observed through the tube, the negative voltage has reached the value that is high enough to slow down and stop the most energetic photoelectrons of kinetic energy Kmax. This value of the retarding voltage is called the stopping potential or cut off potential Vo.[12] Since the work done by the retarding potential in stopping the electron of charge e is eVo, the following must hold eVo = Kmax.

For a given metal surface, there exists a certain minimum frequency of incident radiation below which no photoelectrons are emitted. This frequency is called the threshold frequency. Increasing the frequency of the incident beam increases the maximum kinetic energy of the emitted photoelectrons, and the stopping voltage has to increase. The number of emitted electrons may also change because the probability that each photon results in an emitted electron is a function of photon energy.

There are cases where the three-step model fails to explain peculiarities of the photoelectron intensity distributions. The more elaborate one-step model[21] treats the effect as a coherent process of photoexcitation into the final state of a finite crystal for which the wave function is free-electron-like outside of the crystal, but has a decaying envelope inside.[20]

In 1839, Alexandre Edmond Becquerel discovered the photovoltaic effect while studying the effect of light on electrolytic cells.[22] Though not equivalent to the photoelectric effect, his work on photovoltaics was instrumental in showing a strong relationship between light and electronic properties of materials. In 1873, Willoughby Smith discovered photoconductivity in selenium while testing the metal for its high resistance properties in conjunction with his work involving submarine telegraph cables.[23]

In 1887, Heinrich Hertz observed the photoelectric effect[26] and reported on the production and reception[27] of electromagnetic waves.[28] The receiver in his apparatus consisted of a coil with a spark gap, where a spark would be seen upon detection of electromagnetic waves. He placed the apparatus in a darkened box to see the spark better. However, he noticed that the maximum spark length was reduced when inside the box. A glass panel placed between the source of electromagnetic waves and the receiver absorbed ultraviolet radiation that assisted the electrons in jumping across the gap. When removed, the spark length would increase. He observed no decrease in spark length when he replaced the glass with quartz, as quartz does not absorb UV radiation.[citation needed]

The discoveries by Hertz led to a series of investigations by Wilhelm Hallwachs,[29][30] Hoor,[31] Augusto Righi[32] and Aleksander Stoletov[33][34] on the effect of light, and especially of ultraviolet light, on charged bodies. Hallwachs connected a zinc plate to an electroscope. He allowed ultraviolet light to fall on a freshly cleaned zinc plate and observed that the zinc plate became uncharged if initially negatively charged, positively charged if initially uncharged, and more positively charged if initially positively charged. From these observations he concluded that some negatively charged particles were emitted by the zinc plate when exposed to ultraviolet light. ff782bc1db