Our society is undergoing a pivotal shift from a fossil-fuel-based economy to a clean and sustainable energy future. Over the past decade, lithium-ion batteries (LIBs) have achieved remarkable progress as energy storage solutions, powering everything from portable electronics to large-scale applications such as electric vehicles and grid storage systems. However, the theoretical energy density of conventional LIBs—typically employing a graphite anode and a lithium transition metal oxide cathode—is becoming insufficient to meet the growing demands of emerging markets, especially in electric mobility.
Next-generation LIBs are broadly defined as systems that deliver substantially higher energy densities than current technologies or offer cost-effective and environmentally sustainable alternatives. In line with this vision, our research focuses on several core areas to drive the next wave of innovation in battery science.
Topic 1 : centers on elucidating the reaction mechanisms of inorganic materials through advanced electrochemical and structural analysis techniques. These insights are critical to the rational design of high-performance battery components.
Topic 2 : explores intercalation batteries based on emerging mono- and multivalent ion chemistries—such as Na⁺, K⁺, Mg²⁺, Zn²⁺, Ca²⁺, and Al³⁺—which hold promise for achieving greater energy density, lower cost, and improved sustainability.
Topic 3 : involves the continued development and optimization of cathode materials for LIBs, with a focus on understanding their reaction mechanisms to enable more stable and efficient energy storage systems.
Topic 4 : targets the development of all-solid-state lithium-ion batteries, which offer inherent safety advantages and the potential for significantly enhanced energy densities.
A fundamental understanding of electrochemical intercalation chemistry—including intercalation mechanisms, diffusion kinetics, migration barriers, and structural evolution during charge/discharge—is crucial for the development of high-performance battery materials. A core strength of our group lies in the application of advanced powder X-ray crystallographic techniques to investigate these processes in depth. Our approach incorporates 3D electron density mapping, bond valence sum analysis, and ab initio structure determination. These structural insights are complemented by comprehensive electrochemical analyses, which allow us to elucidate interfacial reactions, intercalation behavior, migration barriers, and the intrinsic resistances of inorganic materials.
Our research is dedicated to uncovering the fundamental reaction mechanisms of inorganic and ceramic systems, providing new scientific insights that inform the rational design of next-generation electrode materials for advanced energy storage technologies.
Adv. Energy Mater., 2002205, (2020), Adv. Energy Mater., 2002077, (2020), Adv. Energy Mater., 2000564, (2020)
Topic 2 : Mono/Multivalent-Ion Electrode Materials for Next-Generation Battery Systems
Although lithium-ion batteries have long dominated the energy storage landscape thanks to their high energy and power densities, growing concerns persist regarding their safety, limited energy density, high cost, and environmental impact. As potential post-LIB alternatives, multivalent-ion batteries—based on Mg²⁺, Ca²⁺, Zn²⁺, and Al³⁺—are particularly attractive due to the high volumetric energy densities of their metal anodes and their natural abundance. Likewise, Na⁺ and K⁺-ion batteries offer promising prospects as cost-effective, earth-abundant, and durable options, especially for large-scale energy storage applications.
Our research is focused on discovering and developing novel inorganic electrode materials that can outperform conventional LIBs in capacity, cost-efficiency, or scalability. By integrating advanced electrochemical techniques with state-of-the-art crystallographic analysis, we aim to gain a deep understanding of the fundamental reaction mechanisms that govern the behavior of these next-generation materials.
ACS Catalysis, 10(14), 7773-7784, (2020), ACS Energy Lett., 6, 2659-2665, (2021), ACS Energy Lett., 7(12), 4161-4167, (2022), Chem. Eng. J., 474, 145596, (2023), Small Struct., 5(1), 2300228, (2024), Adv. Sci., 2406642. (2024), Energy & Environ. Mater., e12823, (2025)
Layered cathode materials for lithium-ion batteries have attracted considerable attention due to their high energy density. Our lab conducts in-depth studies using crystallographic analysis to explore the effects of elemental substitution and doping aimed at enhancing the performance of these materials. In parallel, there is increasing interest in cost-effective alternatives such as lithium iron phosphate (LFP) and lithium manganese iron phosphate (LMFP). Despite their advantages in safety and affordability, improving their electrochemical performance remains a key challenge. To address this, our research focuses on structural characterization, reaction mechanism studies in olivine-type materials, surface modification, elemental doping and substitution, as well as thermal stability analysis.
The overarching goal of this work is to develop high-performance cathode materials for next-generation LIBs that offer both enhanced energy density and improved safety compared to existing technologies.
Adv. Sci., 9, 33, 2202627, (2022), J. Power Sources, 626, 2357555, (2025)
Conventional lithium-ion batteries utilize flammable liquid electrolytes, which are susceptible to performance degradation and pose significant safety risks, including fire and explosion under extreme or abnormal conditions. All-solid-state batteries (ASSBs) have emerged as a promising next-generation alternative, offering improved safety, higher theoretical energy densities, and the potential to reduce both material usage and manufacturing costs by eliminating separators and liquid components. However, the widespread commercialization of ASSBs is currently limited by the low ionic conductivity of solid electrolytes. To overcome this bottleneck, our research focuses on the structural design and engineering of inorganic solid electrolyte materials to enhance their ionic transport properties.
The central objective of this work is to discover and develop novel, high-performance inorganic solid electrolytes that enable ASSBs with superior energy density, safety, and scalability compared to current LIB technologies.
J. Solid State Chem., 320, 123861, (2023), J. Solid State Chem., 337, 124788, (2024), Energy Mater., 5, 500061, (2025), Small, 2406200, (2025)