Lab recent news

iWMK2024

Together with M. Shih-Hong Liu, we attended the international Workshop on Membranes at Kobe University (iWMK2024) organized by Professor Hideto Matsuyama and his group. This two-day event provided a unique platform to exchange ideas with researchers sharing similar research interests such as green membranes, desalination membranes, and membranes for sustainable development.

New publication (accepted November 2024)

Congratulations to Ms. Trisha Nicole Lazo for getting her study published in the Journal of Membrane Science. Ms. Lazo interned in our team for 6 months. During her stay, she fabricated green microfiltration membranes before applying a surface modification by spray-coating, with the aim to impart the membranes with antifouling properties. Her results highlight the potential of γ-valerolactone and the spray-coating technique as environmentally friendly solvents and modification techniques for producing green antifouling PVDF membranes, aligning with sustainable practices. The article is available here. 

2024TwIChE

The MEL members presented our group's studies at the Taiwan Institute of Chemical Engineering conference 2024 (2024TwIChE) hosted by our university, CYCU.

As a highlight, M.  Ting-Wei Chen was honored for his oral presentation titled, "Optimizing Wettability and Performance of Superhydrophobic Poly(vinylidene difluoride) Membranes via Vapor-Induced Phase Separation for Enhanced DCMD Applications" and was ranked 2 in the oral competition for students. In addition, M. Shih-Hong Liu and Yuan-Chen Huang received honorable mentions.

Congratulations to them and all the members of the team who took part in the event!

New publication (accepted August 2024)

Our latest work on the development of green antifouling membranes, using a green solvent for the membrane casting, and a green solvent for the antifouling coating, has been published in the Journal of the Taiwan Institute of Chemical Engineers (SCI, Q1).  This work focusses on the development of porous membranes specically resisting bacterial fouling in static and dynamic conditions. 

This is the second work published by Ms. Wu in the frame of her master's thesis work. This publication can be read at this link.

New publication (accepted August 2024)

We have developed antifouling green membranes using gamma-valerolactone (GVL) as the solvent for the casting solution containing poly(vinylidene fluoride) (PVDF) and a zwitterionic copolymer (based on sulfobetaine methacrylate). While GVL is not listed among the good solvents for PVDF, homogeneous and visually transparent casting solutions could still be obtained by raising the temperature. Membranes, prepared by a dual-bath procedure, were homogeneous and presented a highly porous structure. They were challenged against bacteria and proteins, and used for the bacterial removal from water.

The paper has been published in the Journal of Membrane Science (SCI, Q1) and can be viewed at here

New publication (accepted July 2024)

We have investigate, in the frame of a project with a team from Toulouse University (France) the possibility for using forward osmosis (FO) process to concentrate platelets. The membrane design consisted of a non-woven support made of polyethylene terephthalate onto which was created a polyacrylonitrile (PAN) by vapor-induced phase separation. A polyamide layer was formed by interfacial polymerization on the PAN interface, and an antifouling coating then applied. Significant platelet and growth factor enrichment were measured during the FO tests, which could be valuable to the field of regenerative medicine.

The paper has been published in Separation and Purification Technology (SCI, Q1) and can be viewed at this link

New publication (accepted July 2024)

In our recent publication, we explored the possibility of using a commercial copolymer containing styrene groups (anchoring functions) and maleic anhydride (MA) for the zwitterionic modification of PVDF-based membranes. The MA groups can readily react with amine groups. Thus, it provides a platform for diverse modifications. Here, we grafted zwitterionic functions based on sulfobetaine methacrylate and investigated the effect of the modification on the hydration properties of the membranes,  and then on their antifouling properties. As we prepared microfiltration membranes, a potential application would be the pre-treatment of bacteria-containing wastewater.

The paper has been published in the Journal of Membrane Science (SCI, Q1) and can be viewed at this link

Graduation!

Congratulations to Ms. Huang, Ms. Wu, Mr. Lai and Mr. Liou (left to right) who successfully defended their Master's thesis.

New publication (accepted May 2024)

Being set to graduate in June 2024, Ms. Yi-Ling Wu has just published her Master's research work, focussing on the development of antifouling membranes by spray-coating modification, in Separation and Purification Technology (SCI, Q1).

By adjusting the spray-coating parameters, Ms. Wu was able to attain full wettability of highly hydrophobic membranes, from the top surface to the bottom one, despite solely spraying an amphiphilic copolymer on the top surface. It implies that the coating penetrates the entire bulk of the membrane. It is not solely a surface modification, but a bulk modification and it is achieved in just a few seconds. Thus, it competes with common blending modification for which common issues are (1) the compatibility of the main polymer and the antifouling copolymer, and (2) surface segregation that results in low density of the antifouling material in the deeper layers. It resulted in excellent antifouling performances against various bacteria, and as such, the membranes could be utilized in wastewater treatment. 

2024中華民國高分子學會年會 

The group members recently showcased their research work at the Annual Meeting of the Polymer Society in Tainan, held on January 24th and 25th. The conference provided a platform for them to present their work both orally and through poster presentations.

As a highlight, M.  Ting-Wei Chen and Ms. Yi-Ling Wu were honored for their presentations titled, "Manipulating VIPS parameters for wettability optimization and enhancement of the DCMD performances of PVDF membranes" and "Leveraging amphiphilic copolymers of sulfobetaine methacrylamide for the construction of sterilization-tolerant and fouling-resistant poly(vinylidene fluoride) membranes", respectively. Their dedication to their research work stood out, earning them well-deserved recognition. Congratulations to them and all the members of our lab who took part in the event!

Congratulations to Dr. Maggay!

In a significant development for our research community, we are thrilled to announce that Dr. Irish Maggay, a key member of our lab, is set to embark on a new academic journey as Assistant Professor. Dr. Maggay will be joining the R&D Center for Membrane Technology and the Department of Chemical Engineering at CYCU as a faculty member, starting February 2024.

During her time in our lab, Dr. Maggay has made invaluable contributions to the development of advanced membranes for photocatalytic reactors and wastewater treatment, and made some significant contributions to the field of membrane formation, showcasing exceptional dedication and expertise in her field. Her innovative research and passion for advancing membrane technology have not only enriched our lab but have also paved the way for this remarkable career progression.

While we bid farewell to Dr. Maggay as she concludes her postdoctoral studies with us, we couldn't be prouder of her achievements and the recognition she has earned. We have full confidence that she will continue to excel in her new role, shaping the future of research and education at CYCU.

New publication (accepted Sept 2023)

Thank you to Dr. Maggay for writing and publishing a study on the development of PTFE-based membranes able to kill bacteria during filtration. The membranes were modified with amine functional groups via dielectric barrier discharge plasma in order to endow them with antibacterial properties. In addition, the surface properties of the membranes can be regenerated by salt washing and the membranes can then be reused. 

The findings of this work can be read in the ACS Applied Materials & Interfaces (SCI, Q1) here.

New publication (accepted July 2023)

We have recently collaborated on designing an innovative antifouling microfiltration membrane. 

Through spray-coating a zwitterionic copolymer onto activated polytetrafluoroethylene membranes, our aim was to apply these membranes to accelerate the wound healing process for diabetic wounds. 

The research work specifically highlights the potential of zwitterionic-modified membranes to create an optimal wound environment that reduces inflammation and promotes faster healing.

The findings of this work can be read in the Journal of Membrane Science (SCI, Q1) here.

New publication (accepted July 2023)

We have developed thermostable VIPS membranes using a blend of PVDF and a copolymer called P(S-r-EGMA-r-4VPPS). This copolymer contains styrene units, poly(ethylene glycol) methyl ether methacrylate units, and zwitterionic units derived from 4-vinylpyridine.

One interesting feature of these membranes is the presence of 4VPPS units, which enable high hydration and water retention. This results in improved resistance to fouling by various common biofoulants such as bacteria and cells from whole blood. Moreover, the copolymer retains its antifouling properties even after being exposed to steam sterilization, making it suitable for biomedical applications.

The results of our work have been accepted for publication in the journal Separation and Purification Technology (SCI, Q1). This paper can be read here.

Visit of Kobe University

Currently visiting the Membrane Engineering  at Kobe University (link here ) in Japan, led and founded by Professor Hideto Matsuyama, where my primary focus is to deepen my understanding of the process of forming hollow fibers through temperature-induced phase separation, a major phase-inversion process employed in industry to fabricate microfiltration membranes.

I am also testing one of our team's materials for coating these hollow fibers, with the goal of enhancing their performance and bestowing them with antifouling properties.

Lastly, this presents a great opportunity for me to engage in meaningful discussions, share ideas, and collaborate with students, postdoctoral researchers, and professors involved in the research and projects within this center.

ICOM 2023

Some of us are present at ICOM 2023 (International Conference on Membranes and Membrane Processes), held in Chiba (Japan).

Dr. Maggay, a postdoctoral researcher in our laboratory, delivered a captivating talk on the formation of macrovoids-free and skin-free polysulfone membranes in one step.

Dr. Maggay's compelling presentation showcased the team's rigorous methodology and intersting findings with the promise of enhanced membrane mechanical properties without sacrificing the membrane performances (such as their permeability).

Stay tuned for further updates as we delve deeper into the world of membrane research, guided by Dr. Maggay's pioneering contributions!

IMCT 2023

Congratulations to Shih-Hong Liou on his well-deserved award at the students' poster contest at the International Membrane Conference in Taiwan (IMCT 2023)! His achievement is a testament to his very good attitude,  commitment,  determination, and resilience which genuinely sets him apart from the rest of the lab.

It was truly inspiring to witness Shih-Hong Liou's exceptional dedication during the students' poster contest at the International Membrane Conference in Taiwan (IMCT 2023). Despite being tired, he exhibited an unwavering commitment and stayed until the very end, giving his maximum effort. In stark contrast, it was disheartening to see that others merely showed up without fully engaging, leaving promptly after their presentations as if they already knew that they stood no chance since they did not give their best effort. Such behavior not only showed a lack of respect for the lab, but also for the organizers and more importantly, for the other students who were awarded. 

May Shih-Hong's remarkable display of dedication and perseverance serve as a shining example for others, and may his attitude continue to bring him success in his future endeavors. Congratulations once again on a well-deserved award!

 
"Do the job well, or don't do it at all"

(= it's not about winning or losing but giving your maximum effort. If you don't want to do the job well, don't show up at the event) 

New publication (accepted June 2023)

We have recently contributed to the writing of an experimental study on the surface modification of polypropylene (PP) membranes by dielectric barrier discharge (DBD) plasma. DBD permitted to graft and polymerize zwitterionic sulfobetaine methacrylate and the goal was to develop leukoreduction filters. Promising results were obtained as the membrane could reject more leukocytes than different commercial alternatives, still permitting a high recovery rate of erythrocytes. The work has been published in the Journal of Membrane Science (SCI, Q1, IF 10.53) and can be viewed here

New publication (accepted May 2023)

Ms. Kuo-Yun Chang's work has been recently accepted for publication in Desalination (SCI, Q1 IF 11.211). During her Master's research work which she is set to present at the end of next June, Ms. Chang has been working on the adjustment of the morphology of VIPS membranes in order to make them suitable for desalination applications. She managed to develop superhydrophobic membranes in one single step (the vast majority of recent studies report multi-step processes), that could deliver high transmembrane flux (about 35 LMH) and rejection (99.99%) under a relatively low gradient of temperature (35°). Her membranes outperform state-of-the-art membranes in terms of flux and rejection.

New publication (accepted April 2023)

We recently contributed to a study on the design of glass interfaces able to resist fog, frost and biofouling, and endowed with blood compatibility. This study has been published in the Journal of the Taiwan Institute of Chemical Engineers (SCI, Q1 IF 5.477)

The system is based on two distinct moieties: dopamine and sulfobetaine methacrylate.  The synthesis (Michael addition) and grafting to the glass material were done simultaneously, which is an unconventional way to graft polymers/copolymers. Nevertheless,  this method was proven efficient and led to the maintaining of the optical properties of the glass in various situations (fog, frost tests-) while biofouling was mitigating.

The paper can be viewed here 

New publication (accepted Jan. 2023)

We have recently investigated the possibility of preparing 3 antifouling membranes with distinct pore size range from 1 single dope solution (i.e one formulation), using different phase-inversion processes: the VIPS process, the LIPS process and a combination of the EIPS and LIPS processes. Then we used these 3 membranes in a wastewater treatment process. This invesitgation was led by Dr. Maggay and Ms. Hsin-Pei Lin and has been recently accepted for publication in Separation and Purification Technology (SCI, Q1 IF 9.136).

The paper can be viewed here 

Award

The team's PI was awarded the CYCU Outstanding Research Award for the second time! This award is mostly based on research outcomes (SCI publications, project grants, etc.) obtained over a period of 4-5 years, and is delivered to 2 to 3 researchers in the university each year. 

It rewards the efforts of the team, and somehow, validates its consistency.

New publication (accepted Dec. 2022)

Our review paper on the development of antifouling membranes by blending has just been published in the open-access journal Membranes (SCI, Q1 IF 4.562)

In this paper, the focus lies on the work carried out by the research teams worldwide during the period 2012-2022 on the development of antifouling membranes by blending using polymeric additives, but also ceramic materials and carbon derivatives.

The paper can be viewed here