(I won't cover full sets until later time, I'll just name the set and talk about it)
Backrooms: Very useful for the journey, maybe too powerful. Can't be burned
Amethyst: Decent and easy to get like iron. Tools give effects on right click (Only axe, sword and pickaxe)
Nytranium: Can't be burned, durable like diamond, strong like iron.
Dirt: Maybe a little weak, but if you need some real starter tools, take these.