Photoinduced Charge Carrier Dynamics based on Time-Resolved Spectroscopy
We employ advanced time-resolved spectroscopic techniques to investigate photoinduced charge carrier dynamics in molecular semiconductor systems across femtosecond-to-second timescales. Our research focuses on probing exciton dissociation, charge transfer, carrier transport, and recombination processes in photovoltaic, photocatalytic, and photoelectrochemical materials and devices. By combining transient absorption spectroscopy, time-resolved photoluminescence, transient photovoltage/current, and operando spectroscopic analyses, we reveal the fundamental mechanisms governing non-equilibrium carrier dynamics and long-lived charge generation for efficient light-energy conversion. - Read moreÂ
TAS is a spectroscopic technique that measures the absorption spectra and lifetimes of excited states in sample molecules following excitation by a short light pulse.
TRPL is a spectroscopic technique that measures the fluorescence lifetime of sample molecules by statistically accumulating the detection times of single photons emitted from excited states following excitation by a short light pulse. In general, highly sensitive lifetime measurements are performed using time-correlated single photon counting (TCSPC).
TPV is a technique that measures the temporal evolution of photovoltage after light excitation under open-circuit conditions.
TPC is a technique that measures the temporal evolution of photocurrent after light excitation under short-circuit conditions.
CE is a technique in which a solar cell operating under illumination is simultaneously switched to short-circuit conditions while the light is turned off, and the amount of remaining extracted charge is analyzed by integrating the extracted current.
CELIV is a technique in which a linearly increasing voltage is applied to a material to forcibly extract trapped charges, and the resulting current transient is analyzed to determine the charge carrier mobility and charge density.