The chemical structure of Denatonium Benzoate.
Denatonium Benzoate in its powder form.
What is denatonium benzoate? It's a fair question to ask. It is a chemical compound that belongs to a class of bitters, and is most commonly used as a bittering agent powder in industrial and commercial products.
Studies have shown that the addition of bittering agents to solutions or consumable items decrease the amount of time an individual spends interacting with or ingesting said item. The idea here is that adding denatonium benzoate to antifreeze would cause the solution to change from its deceptively sweet flavor to a bitter and unsavory one, and become less favorable or ingestible, which in turn would decrease the amount of toxic substance consumed.
This is not a new argument. 17 of the 50 states have passed legislation requiring the addition of denatonium benzoate, or some other bittering agent, to antifreeze, starting with Oregon in 1991. There have even been voluntary movements amongst antifreeze manufacturers and some members of Congress, most recently dating back to 2013, for the addition as well. However, as antifreeze can still be sold legally without the addition of a bittering agent, and as its toxicity continues to harm more Americans and animals, it is as critical as ever for the US to adopt this as national law.
Now, when advocating for a change that requires extra additives or expenses to be incurred, it is important to provide a cost-benefit analysis. While the value of a human life transcends all tangible and monetary means, and as such, demands the change regardless of cost, providing physical numbers also aids in debate. The interesting thing to note though, is that the addition of a bittering agent virtually seems to come at no additional cost. PEAK Long Life Prediluted Antifreeze and Coolant retails at $9.04, while Prestone Extended Life Prediluted Antifreeze and Coolant retails at $8.88. According to the Safety Data Sheets for both mixtures, which include relevant information regarding safety, health, and handling processes, both antifreezes contain either the same ingredients, or chemical substitutes, except in the case of a bittering agent, in which PEAK antifreeze has denatonium benzoate, and Prestone has none. While not representative of all antifreeze mixtures, the minute $0.16 price difference between the two solutions could be the pivotal difference in thousands of more human and animal lives lost, a pressing yet logical reason for why a bittering agent must be required in all antifreeze mixtures.
The chemical structure of Propylene Glycol.
The chemical structure of Ethylene Glycol.
What is propylene glycol? Another great question to ask. It is an alcohol incredibly similar to ethylene glycol, with the main difference being that it has three carbon atoms instead of two. This slight difference in chemical structure though is what gives rise to its viability as a substitute for ethylene glycol in antifreeze.
The extra carbon atom in propylene glycol serves to stabilize the chemical; it causes the alcohol to oxidize differently in the body, in a much more safe manner than ethylene glycol does, as seen on the Effects of Consumption page. In fact, not only is it safe to ingest, but US and European food authorities have declared it safe for being used as an additive in food, as well as for hygienic and cosmetic products.
It specifically applies to the automotive industry though, as the Environmental Protection Agency has found that by adding tiny metal oxide particles to a propylene glycol antifreeze mixture, by thinning the mixture, the antifreeze becomes more efficient at dispersing or transferring heat, which in turn increases the fuel economy in cars, and cuts emissions. Therefore, as propylene glycol is not only a safer alternative to ethylene glycol in terms of ingestion and interaction, but also is better for consumer products and the environment overall, if the addition of denatonium benzoate to normal ethylene glycol antifreeze does not gain national support, then the switch to propylene glycol antifreeze must instead.