Metallic glasses (MG's) and nanoglasses (NG's) exhibit fundamentally different deformation behavior compared to crystalline metals because they lack long-range atomic order. Instead of dislocation motion, these amorphous materials deform through localized shear transformations that combine to form shear bands. Understanding how and why these shear bands initiate is crucial for improving the ductility and reliability of metallic glasses. Using instrumented nanoindentation, I studied how structural relaxation, free-volume distribution, and nanoscale interfaces influence shear localization in Pd–Si and Cu-Zr based amorphous alloys. This work is important for designing next-generation amorphous materials with improved mechanical stability, resistance to shear banding, and enhanced performance under extreme conditions. Nanoindentation provides a powerful means to probe hardness, modulus, time-dependent deformation, and localized plasticity using only microscopic volumes of material.
Materials used in fusion reactors must withstand high temperatures, cyclic stresses, and irradiation over long service lifetimes. Time-dependent deformation (creep) plays a critical role in determining the structural integrity of these components. My research focuses on understanding creep mechanisms in spark plasma sintered (SPS) ferritic–martensitic steels and Cu-based high-conductivity alloys designed for high-heat-flux applications. Through high-temperature nanoindentation and bulk creep testing, I examine how thermally stable MX and M₂₃C₆ precipitates formed during optimized heat treatments stabilize lath boundaries and slow microstructural coarsening. These studies help reveal how microstructural design can significantly improve the creep resistance of fusion-relevant alloys, contributing to safer and more efficient reactor components.
Ultra-high-temperature ceramics (UHTCs) such as WC-based systems are widely used in extreme environments including aerospace, cutting tools, and thermal-protection systems but their inherently low fracture toughness limits broader applications. Understanding how cracks initiate and propagate in these brittle materials is essential for improving their reliability. Through indentation fracture studies, I investigate crack opening, crack deflection, and microstructural toughening in monolithic carbides such as WC, VC and their composites (WC-SiC, VC-SiC). The addition of SiC is known to refine microstructure and enhance toughening via mechanisms such as crack bridging and grain-boundary deflection. These insights are important for designing tougher, more damage-resistant ceramics suitable for high-temperature and high-wear environments.