Laboratory for Optoelectronic Semiconductors and Energy Conversion
Cheng-Ying Chen Group 陳政營研究團隊
Laboratory for Optoelectronic Semiconductors and Energy Conversion
Cheng-Ying Chen Group 陳政營研究團隊
本實驗室專注於光電半導體材料的成長設計與機制研究,結合光電特性、載子動力學與界面化學反應,致力於開發高效率且穩定的光電與光電化學能量轉換技術。
Our lab focuses on the growth design and mechanistic study of optoelectronic semiconductor materials, integrating optoelectronic properties, carrier dynamics, and interfacial chemical reactions to develop high-efficiency and stable optoelectronic and photoelectrochemical energy conversion technologies.
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🎉 Congratulations to our five Master’s students, who successfully passed their thesis defenses under the supervision of Prof. Cheng-Ying (Gary) Chen!
Their thesis titles are as follows:
Hung-Yu Chen
Enhancing Photoelectrochemical Hydrogen Production and Related Applications Using Sb₂(S,Se)₃ Thin Films Synthesized via Hydrothermal Method with Post-Annealing Optimization
Yu-Hsiang Tsai
Fabrication of Cuprous Oxide Semiconductor Thin Films by Reactive Sputtering for Photoelectrochemical Water Splitting Applications
Tsan-Hsuan Yang
Antimony-Doped Cuprous Oxide Thin Films Grown by Chemical Bath Deposition for Photoelectrochemical Water Splitting Applications
Juan-Xuan Li
Preparation of Gallium-Doped Cuprous Oxide Semiconductor Films via Sputtering for Photoelectrochemical Water Splitting Applications
Ching-Yung Tseng
Atom Probe Study on Gallium-Doped Cuprous Oxide Thin Film
🎉 恭喜 五位碩士班同學 在陳政營老師的指導下,順利通過碩士學位口試!
以下為同學們的論文題目:
陳泓瑜
《透過退火優化水熱法合成之 Sb₂(S,Se)₃ 薄膜並用於增強光電化學產氫及相關應用》
蔡宇翔
《使用反應式濺鍍法製備氧化亞銅半導體薄膜用於光電化學水分解應用》
楊璨瑄
《透過化學水浴法成長氧化亞銅薄膜摻雜銻之光陰極應用於光電水分解》
李卷軒
《濺鍍法製備鎵摻雜氧化亞銅半導體薄膜用於光電化學水分解應用》
曾慶永
《鎵摻雜氧化亞銅薄膜之原子針尖斷層影像分析研究》
🎉 Congratulations to Mr. Yuan-Chi Lin, graduate student of our lab, for receiving the NSTC Graduate Student Travel Grant to attend the International Conference on Materials for Advanced Technologies (ICMAT 2025) in Singapore, and for delivering an oral presentation! 👏
📄 Presentation Title:
Sb₂(S,Se)₃ Thin Films Synthesized by Hydrothermal Method for Photoelectrochemical Water Splitting and Solar Cell Applications
🗓 Conference Date: June 30 – July 4, 2025
📍 Venue: Suntec Convention Centre, Singapore
🎉 恭喜本實驗室 林垣圻同學 榮獲 國科會補助國內研究生出席國際學術會議費用補助,於 新加坡 參加 2025 先進技術材料國際會議 (ICMAT 2025),並進行口頭發表!👏
📄 發表論文題目:
《水熱法合成 Sb₂(S,Se)₃ 薄膜用於光電化學水分解及太陽能電池應用》
🗓 會議日期:2025 年 6 月 30 日-7 月 4 日
📍 地點:新加坡 Suntec Convention Centre
🎉 Congratulations to Prof. Cheng-Ying (Gary) Chen for being recognized as an Elsevier Reviewer for the first half of 2025!
This honor highlights his valuable contributions to the peer-review process and academic service in the Elsevier publishing community. 👏
🎉 恭喜 陳政營老師 榮獲 Elsevier 出版社 2025 上半年同儕審查者 (Reviewer Recognition) 的肯定!
這項榮譽表彰了陳老師在國際學術期刊審稿服務上的專業貢獻。👏
🎉 Congratulations to Prof. Cheng-Ying (Gary) Chen and his graduate student Yu-Hsiang Tsai, who received the Best Poster Award in the category of Novel Material Characterization and Analysis Techniques at the 5th Symposium on Nano Devices, Circuits, and Technology (SNDCT 2025)! 👏 (May 28, 2025 )
🎉 恭喜 陳政營老師 指導之碩士生 蔡宇翔同學,於 第5屆奈米元件電路與技術研討會 (SNDCT 2025) 榮獲 「新穎材料檢測分析技術」優良海報獎 (Best Poster Award)!👏 (2025年5月28日)
🎉 Congratulations to Prof. Cheng-Ying (Gary) Chen for the Invited Talk at NTU Physics
Prof. Cheng-Ying (Gary) Chen was invited to give a talk at the Department of Physics, National Taiwan University on the topic:
“Advancing Kesterite-Based Solar Cells: Structural, Defect, and Interface Engineering Strategies for Enhanced Efficiency.”
The seminar will be held on April 23, 2025 (Wednesday) at 2:20 PM, in Rm. 104, Chin-Pao Yang Lecture Hall, NTU Physics.
This talk will highlight our group’s recent advances in kesterite-based thin-film solar cells (CZTSSe), with a focus on structural control, defect engineering, and interface design to overcome voltage deficits and enhance photovoltaic performance.
🎉 恭喜 陳政營老師受邀至台大物理系演講
陳政營教授受邀至 國立臺灣大學物理系 演講,主題為:
「Advancing Kesterite-Based Solar Cells: Structural, Defect, and Interface Engineering Strategies for Enhanced Efficiency」。
演講時間為 2025年4月23日 (星期三) 下午2:20,地點在 台大物理系 楊金豹講堂 (104室)。
本次演講將分享實驗室在 硫屬化物基薄膜太陽能電池 (CZTSSe) 的最新研究進展,重點聚焦於 結構調控、缺陷工程與界面設計,以突破電壓缺陷並提升光電轉換效率。
🎉 Congratulations to our lab for the successful publication in ACS Applied Materials & Interfaces!
📄 Title: Ultrathin Bi₂O₂Se/Si Heterojunction Photodetector with Tunneling Oxide Passivation for Enhanced Optoelectronic Performance
ACS Appl. Mater. Interfaces 2025, 17, 18, 26931–26939 https://doi.org/10.1021/acsami.5c03477
This work reports a high-performance Bi₂O₂Se/Si heterojunction photodetector fabricated by a transfer-free pulsed laser deposition approach, integrated with a thin tunneling SiO₂ passivation layer. The device demonstrates ultralow dark current (~22.3 nA/cm²), high on/off ratio (~8 × 10⁶), and remarkable responsivity (23.0 A/W) under zero bias, together with sub-millisecond response time. These results highlight Bi₂O₂Se’s great potential for next-generation optoelectronic and photonic applications. (November 15, 2024)
🎉 恭喜本實驗室研究成果發表於 ACS Applied Materials & Interfaces!
📄 論文題目:《超薄 Bi₂O₂Se/Si 異質接面光偵測器:利用穿隧氧化層鈍化提升光電性能》
本研究首次以 無轉移脈衝雷射沉積法 (PLD) 直接成長 Bi₂O₂Se/Si 異質接面,並引入 超薄 SiO₂ 穿隧氧化層 進行界面鈍化。器件展現出 極低暗電流 (~22.3 nA/cm²)、高開關比 (~8 × 10⁶)、高響應度 (23.0 A/W),且在零偏壓下具備次毫秒級快速響應。此成果顯示 Bi₂O₂Se 在新世代高性能光電與光子元件上的應用潛力。
🏆✨ Excited to share that Prof. Cheng-Ying (Gary) Chen’s paper
“Visualizing Vacancy Annihilation in CZTSe Solar Cells by Hydrogen-Assisted Selenization with In Operando X-ray Nanoprobe Studies”
presented at the 2025 Materials Research Society (MRS) Spring Meeting, Symposium EN05: Thin-Film Compound Semiconductor Photovoltaics (Seattle, USA), has been selected as a finalist for the Best Paper Award (CONTROL ID: 4207310).
This recognition highlights his team’s cutting-edge research on anion vacancy defect elimination in CZTSe solar cells through advanced in-operando X-ray nanoprobe analysis. 👏
🏆✨ 恭喜 陳政營老師 的論文
「Anion Vacancy Defect Elimination in CZTSe Solar Cells via Hydrogen-Assisted Selenization—In Operando X-Ray Nanoprobe Analysis」
在 2025 美國材料研究學會春季會議 (MRS Spring Meeting),EN05: Thin-Film Compound Semiconductor Photovoltaics 專題 (西雅圖,美國) 中,榮獲 最佳論文獎入選!👏
此殊榮肯定了陳老師團隊在 CZTSe 太陽能電池陰離子空缺缺陷消除 與 操作中同步輻射奈米探針分析 的前瞻研究成果。
📢 Congratulations to Prof. Cheng-Ying (Gary) Chen for being recognized as an ACS Reviewer for 2024! This honor highlights his valuable contributions to the peer-review process and academic service in the ACS publishing community. 👏
📢 恭喜 陳政營老師 榮獲 2024 ACS 同儕審查者(ACS Reviewer Recognition 2024) 的肯定!這項榮譽表彰了陳老師在國際期刊審稿工作中的專業貢獻與學術服務。👏
🎉 Congratulations to our group member Hong-Yu Chen for receiving the NSTC Graduate Student Travel Grant to attend LASE 2025 (SPIE Conference) in San Francisco, USA, and deliver an oral presentation! 👏
📄 Paper Title:
Optical properties of hydrothermally synthesized Sb₂(S,Se)₃ and their application in water splitting
📚 Proceedings: Volume PC13352, Nanoscale and Quantum Materials: From Synthesis and Laser Processing to Applications 2025; Paper No. PC1335201 (2025)
🔗 DOI: 10.1117/12.3042515
🎉 恭喜本實驗室 陳泓瑜同學 獲得 國科會補助國內研究生出席國際學術會議費用補助,前往美國舊金山參加 LASE 2025 (SPIE Conference),並進行口頭發表!👏
📄 發表論文題目:
《Optical properties of hydrothermally synthesized Sb₂(S,Se)₃ and their application in water splitting》
📚 收錄於:Proceedings Volume PC13352, Nanoscale and Quantum Materials: From Synthesis and Laser Processing to Applications 2025; Paper No. PC1335201 (2025)
🔗 DOI: 10.1117/12.3042515
📢 Congratulations to Prof. Cheng-Ying (Gary) Chen and his graduate student Yu-Hsiang Tsai, for receiving the Student Poster Paper Award at OPTIC 2024! (November 29, 2024)
📢 恭喜陳政營老師 指導之碩士生 蔡宇翔 於 OPTIC 2024 榮獲 學生海報論文獎!(2024年11月29日)
📢 Congratulations to our lab for the successful publication in ACS Applied Materials & Interfaces!
📄 Title: Visualization of Anion Vacancy Defect Annihilation in CZTSe Solar Cells by Hydrogen-Assisted Selenization with In Operando X-ray Nanoprobe Studies
ACS Appl. Mater. Interfaces 2024, 16, 47, 64656–64663 https://doi.org/10.1021/acsami.4c11127
This work demonstrates how hydrogen-assisted selenization (HAS) effectively reduces selenium vacancies in CZTSe thin-film solar cells, leading to enhanced photocurrent and improved device efficiency (up to 10.36%). Using synchrotron-based nano-XRF and nano-XBIC, we directly visualized the correlation between defect annihilation and charge collection, providing new insights into defect engineering for next-generation kesterite photovoltaics. (November 15, 2024)
📢 恭喜本實驗室研究成果發表於 ACS Applied Materials & Interfaces!
📄 論文題目:《透過氫氣輔助硒化與操作中 X 光奈米探針研究,觀察 CZTSe 太陽能電池中陰離子空缺缺陷的消除》
本研究提出 氫氣輔助硒化 (HAS) 技術,有效降低 CZTSe 薄膜太陽能電池中的硒空缺缺陷,提升載子收集效率並改善光電轉換效率(最高達 10.36%)。藉由 同步輻射奈米 X 光螢光 (nano-XRF) 與 X 光誘發電流 (nano-XBIC),首次在操作條件下直接觀察到缺陷消除與光電流收集的關聯,為下一代硫銅鋅錫硒太陽能電池的缺陷工程提供重要新見解。(2024年11月15日)
📢 Congratulations to Ching-Yung Tseng and Yu-Hsiang Tsai from our lab for winning the Poster Excellent Award in the category Optoelectronic and Optical Materials at the 2024 Annual Meeting of the Materials Research Society-Taiwan (MRST 2024)! 👏
📑 Ching-Yung Tseng — Atom Probe Study on the Atomic Distribution of Sb/Ga-Doped Cu₂O Thin Films
📑 Yu-Hsiang Tsai — Reactive Sputtering Fabrication of Cu₂O Thin Films for Photoelectrochemical Water Splitting
This award recognizes their outstanding contributions to research in materials science and optoelectronics. (November 1, 2024)
📢 恭喜本實驗室 曾慶永 與 蔡宇翔 同學,於 113 年材料年會 (MRST 2024)「光電與光學材料 (Optoelectronic and Optical Materials)」領域海報競賽中,榮獲 優等獎!👏
📑 曾慶永 — 以原子針尖斷層影像儀分析銻鎵摻雜氧化亞銅薄膜之原子分布
📑 蔡宇翔 — Reactive Sputtering Fabrication of Cu₂O Thin Films for Photoelectrochemical Water Splitting
此殊榮肯定了兩位同學在材料與光電研究上的優秀成果與貢獻。(2024年11月1日)
📢 Congratulations to Prof. Cheng-Ying (Gary) Chen for receiving the 11th Young Scholar Award of the Taiwan Vacuum Society (TVS)(October 28, 2022)!
This award recognizes his outstanding contributions to semiconductor thin films, defect/interface engineering, and advanced characterization for energy and optoelectronic applications.
📢恭喜 陳政營老師 獲得 台灣真空學會第十一屆年輕學者獎!(2022年10月28日)
這是對其在光電半導體材料研究與創新成果的高度肯定。
🎉 Congratulations to our lab for the publication in Sustainability (IF 3.9, 2022)!
📄 Title: Back Contact Engineering to Improve CZTSSe Solar Cell Performance by Inserting MoO₃ Sacrificial Nanolayers
Sustainability 2022, 14(15), 9511; https://doi.org/10.3390/su14159511
This study introduces an ultrathin MoO₃ sacrificial nanolayer to optimize the Mo/CZTSSe back-contact interface in thin-film solar cells. The MoO₃ layer promotes grain growth, suppresses harmful MoS(e)₂ formation, and improves absorber quality. Key results include:
Defect energy level reduced from 228 meV to 148 meV
Series resistance decreased from 1.83 Ω·cm² to 1.54 Ω·cm²
Fill factor (FF) increased to 52.12%
Efficiency improved by ~26%, achieving a maximum 7.78% PCE
First-principles (VASP) calculations further revealed that sulfoselenized MoO₃ nanolayers act as p-type hole-selective contacts, contributing to enhanced device performance. (August 3, 2022)
🎉 恭喜本實驗室研究成果發表於 Sustainability (IF 3.9, 2022)!
📄 論文題目:《Back Contact Engineering to Improve CZTSSe Solar Cell Performance by Inserting MoO₃ Sacrificial Nanolayers》
本研究提出於 CZTSSe 薄膜太陽能電池中導入 超薄 MoO₃ 犧牲層,能有效改善 Mo/CZTSSe 背接觸界面,促進晶粒成長並抑制 MoS(e)₂ 等有害相的生成。實驗結果顯示:
缺陷能階由 228 meV 降低至 148 meV
串聯電阻由 1.83 Ω·cm² 降至 1.54 Ω·cm²
填充因子 (FF) 提升至 52.12%
效率提升 約 26%,最高達 7.78%
研究同時透過 第一原理計算 (VASP) 證實,MoO₃ 在硫硒化後可轉化為 具 p 型導電性的 MoS(e)₂₋ₓOₓ,充當有效的空穴選擇性接觸層,進一步提升電池效能。(2022年8月3日)
Contact 聯絡資訊 :chen.chengying.cyc@gmail.com
Department of Optoelectronics and Materials Technology, National Taiwan Ocean University
Address:No.2, Beining Rd., Zhongzheng Dist.,Keelung City 202301, Taiwan