Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen.[1]Coal is a type of fossil fuel, formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years.[2] Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous (Pennsylvanian) and Permian times.[3][4]

Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased.[citation needed] In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity.[5] Some iron and steel-making and other industrial processes burn coal.


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The extraction and use of coal causes premature death and illness.[6] The use of coal damages the environment, and it is the largest anthropogenic source of carbon dioxide contributing to climate change. Fourteen billion tonnes of carbon dioxide were emitted by burning coal in 2020,[7] which is 40% of the total fossil fuel emissions[8] and over 25% of total global greenhouse gas emissions.[9] As part of worldwide energy transition, many countries have reduced or eliminated their use of coal power.[10][11] The United Nations Secretary General asked governments to stop building new coal plants by 2020.[12] Global coal use was 8.3 billion tonnes in 2022.[13] Global coal demand is set to remain at record levels in 2023.[14] To meet the Paris Agreement target of keeping global warming below 2 C (3.6 F) coal use needs to halve from 2020 to 2030,[15] and "phasing down" coal was agreed upon in the Glasgow Climate Pact.

The largest consumer and importer of coal in 2020 was China, which accounts for almost half the world's annual coal production, followed by India with about a tenth. Indonesia and Australia export the most, followed by Russia.[16][17]

The word originally took the form col in Old English, from Proto-Germanic *kula(n), which in turn is hypothesized to come from the Proto-Indo-European root *g(e)u-lo- "live coal".[18] Germanic cognates include the Old Frisian kole, Middle Dutch cole, Dutch kool, Old High German chol, German Kohle and Old Norse kol, and the Irish word gual is also a cognate via the Indo-European root.[18]

The conversion of dead vegetation into coal is called coalification. At various times in the geologic past, the Earth had dense forests[21] in low-lying wetland areas. In these wetlands, the process of coalification began when dead plant matter was protected from biodegradation and oxidation, usually by mud or acidic water, and was converted into peat. This trapped the carbon in immense peat bogs that were eventually deeply buried by sediments. Then, over millions of years, the heat and pressure of deep burial caused the loss of water, methane and carbon dioxide and increased the proportion of carbon.[19] The grade of coal produced depended on the maximum pressure and temperature reached, with lignite (also called "brown coal") produced under relatively mild conditions, and sub-bituminous coal, bituminous coal, or anthracite coal (also called "hard coal" or "black coal") produced in turn with increasing temperature and pressure.[2][22]

Of the factors involved in coalification, temperature is much more important than either pressure or time of burial.[23] Subbituminous coal can form at temperatures as low as 35 to 80 C (95 to 176 F) while anthracite requires a temperature of at least 180 to 245 C (356 to 473 F).[24]

Favorable geography alone does not explain the extensive Carboniferous coal beds.[28] Other factors contributing to rapid coal deposition were high oxygen levels, above 30%, that promoted intense wildfires and formation of charcoal that was all but indigestible by decomposing organisms; high carbon dioxide levels that promoted plant growth; and the nature of Carboniferous forests, which included lycophyte trees whose determinate growth meant that carbon was not tied up in heartwood of living trees for long periods.[29]

One theory suggested that about 360 million years ago, some plants evolved the ability to produce lignin, a complex polymer that made their cellulose stems much harder and more woody. The ability to produce lignin led to the evolution of the first trees. But bacteria and fungi did not immediately evolve the ability to decompose lignin, so the wood did not fully decay but became buried under sediment, eventually turning into coal. About 300 million years ago, mushrooms and other fungi developed this ability, ending the main coal-formation period of earth's history.[30][31] Although some authors pointed at some evidence of lignin degradation during the Carboniferous, and suggested that climatic and tectonic factors were a more plausible explanation,[32] reconstruction of ancestral enzymes by phylogenetic analysis corroborated a hypothesis that lignin degrading enzymes appeared in fungi approximately 200 MYa.[33]

One likely tectonic factor was the Central Pangean Mountains, an enormous range running along the equator that reached its greatest elevation near this time. Climate modeling suggests that the Central Pangean Mountains contributed to the deposition of vast quantities of coal in the late Carboniferous. The mountains created an area of year-round heavy precipitation, with no dry season typical of a monsoon climate. This is necessary for the preservation of peat in coal swamps.[34]

Sometimes coal seams (also known as coal beds) are interbedded with other sediments in a cyclothem. Cyclothems are thought to have their origin in glacial cycles that produced fluctuations in sea level, which alternately exposed and then flooded large areas of continental shelf.[37]

The woody tissue of plants is composed mainly of cellulose, hemicellulose, and lignin. Modern peat is mostly lignin, with a content of cellulose and hemicellulose ranging from 5% to 40%. Various other organic compounds, such as waxes and nitrogen- and sulfur-containing compounds, are also present.[38] Lignin has a weight composition of about 54% carbon, 6% hydrogen, and 30% oxygen, while cellulose has a weight composition of about 44% carbon, 6% hydrogen, and 49% oxygen. Bituminous coal has a composition of about 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis.[39] This implies that chemical processes during coalification must remove most of the oxygen and much of the hydrogen, leaving carbon, a process called carbonization.[40]

Dehydration and decarboxylation take place early in coalification, while demethanation begins only after the coal has already reached bituminous rank.[42] The effect of decarboxylation is to reduce the percentage of oxygen, while demethanation reduces the percentage of hydrogen. Dehydration does both, and (together with demethanation) reduces the saturation of the carbon backbone (increasing the number of double bonds between carbon).

Chemical changes are accompanied by physical changes, such as decrease in average pore size.[44] The macerals (organic particles) of lignite are composed of huminite, which is earthy in appearance. As the coal matures to sub-bituminous coal, huminite begins to be replaced by vitreous (shiny) vitrinite.[45] Maturation of bituminous coal is characterized by bitumenization, in which part of the coal is converted to bitumen, a hydrocarbon-rich gel.[46] Maturation to anthracite is characterized by debitumenization (from demethanation) and the increasing tendency of the anthracite to break with a conchoidal fracture, similar to the way thick glass breaks.[47]

There are several international standards for coal.[48] The classification of coal is generally based on the content of volatiles. However the most important distinction is between thermal coal (also known as steam coal), which is burnt to generate electricity via steam; and metallurgical coal (also known as coking coal), which is burnt at high temperature to make steel.

Hilt's law is a geological observation that (within a small area) the deeper the coal is found, the higher its rank (or grade). It applies if the thermal gradient is entirely vertical; however, metamorphism may cause lateral changes of rank, irrespective of depth. For example, some of the coal seams of the Madrid, New Mexico coal field were partially converted to anthracite by contact metamorphism from an igneous sill while the remainder of the seams remained as bituminous coal.[49]

Among the materials that are dug because they are useful, those known as anthrakes [coals] are made of earth, and, once set on fire, they burn like charcoal [anthrakes]. They are found in Liguria ... and in Elis as one approaches Olympia by the mountain road; and they are used by those who work in metals.

These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground extraction by shaft mining or adits was developed.[56] The alternative name was "pitcoal", because it came from mines.

The development of the Industrial Revolution led to the large-scale use of coal, as the steam engine took over from the water wheel. In 1700, five-sixths of the world's coal was mined in Britain. Britain would have run out of suitable sites for watermills by the 1830s if coal had not been available as a source of energy.[67] In 1947 there were some 750,000 miners in Britain,[68] but the last deep coal mine in the UK closed in 2015.[69]

A grade between bituminous coal and anthracite was once known as "steam coal" as it was widely used as a fuel for steam locomotives. In this specialized use, it is sometimes known as "sea coal" in the United States.[70] Small "steam coal", also called dry small steam nuts (DSSN), was used as a fuel for domestic water heating. 2351a5e196

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