Our research group is developing new synthetic protocols to design Coordination Networks (Metal-organic frameworks/Coordination Polymers)-based Crystal-Glass Composites toward the application of atmospheric water harvesting (AWH), Li/Na-ion conducting solid-state electrolytes, photoactive materials, gas separating membranes, and heterogeneous catalysts for the transformation of gaseous molecules into industrially important liquid fuels. The strategy to achieve these fascinating materials involves phase transition and dynamicity of the molecules in different states of matter.