If you have a burning desire to know the origins of caustic, you're already well on your way to figuring it out. Caustic was formed in Middle English as an adjective describing chemical substances, such as lime and lye, that are capable of destroying or eating away at something. The word is based on the Latin adjective causticus, which itself comes ultimately from the Greek verb kaiein, meaning "to burn." In time, caustic was baked into the English language as an adjective describing people or things (such as wit or remarks) that are bitingly sarcastic. Other kaiein descendants in English include cautery and cauterize, causalgia (a burning pain caused by nerve damage), and encaustic (a kind of paint that is heated after it's applied).

People most susceptible to medical complications are those who inhale caustic fumes in an enclosed area for a long time and those with a pre-existing airway disease, such as asthma, bronchitis or chronic obstructive pulmonary disease (COPD).


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The paper presents an analysis of a variety of laboratory experiments substantiating the fact that caustic waterflooding can significantly improve waterflood recovery of certain low-gravity viscous crude oils. Success of the process depends on the presence of naturally occurring organic acids. Experiments show that caustic waterflooding can significantly increase oil recovery obtained before water breakthrough.

Caustic injection as a method for improving waterflood oil recovery is not a new idea. U. S. Patent 1,651,311, covering waterflooding with sodium Patent 1,651,311, covering waterflooding with sodium hydroxide, was issued to H. Atkinson in Nov. 1927. There is no record of successful field application of the method described, however. In 1962 Leach et al. showed that caustic injection water could alter wettability and improve oil recovery in laboratory experiments, but the results of a small field trial were somewhat inconclusive. In 1970 Emery et al. showed that caustic injection could cause wettability reversal and improve the waterflood recovery of crude oil from the Singleton field, Nebraska, in laboratory experiments. A field trial of the process proved to be disappointing, however. The experiments described here show that there is an alternative to the wettability reversal mechanism by which caustic injection can significantly improve the recovery of certain crude oils. The mechanism involves the drastic reduction of oil-water interfacial tension by the caustic activation of potentially surface-active organic acids naturally occurring in the crude oil. The reduction of interfacial tension causes emulsification of crude oil in situ that tends to lower injected water mobility, damp the tendency toward viscous fingering, slow water channeling caused by reservoir stratification, and improve volumetric conformance or sweep efficiency. The laboratory caustic floods of viscous, lowgravity crude oils containing sufficient natural organic acids are characterized by improved recovery at water breakthrough and lower producing water-oil ratios (WOR). The mechanism involving lowered interfacial tension, in-situ emulsification, and water mobility reduction is supported by correlation of interfacial tension with recovery efficiency, observation of in-situ emulsification in thin, transparent glass bead packs accompanied by changes in areal sweep efficiency, and evidence that ultimate residual oil saturation or microscopic conformance in reservoir core material is not significantly affected by caustic injection. The process appears to have good economic potential for suitable crude oils. Sodium hydroxide is potential for suitable crude oils. Sodium hydroxide is an inexpensive material and most required concentrations for in-situ emusification range between 0.05 and 0.50 weight percent, about one-fifth the concentration usually specified for wettability reversal. Furthermore, slug injection of about 0.15 PV can sometimes be as effective as continuous injection in laboratory tests.

For regulations relating to invoices, entry, and assessment of duties, see 19 CFR parts 141, 142, 143, 151, 152. For regulations regarding the examination, classification, and disposition of foods, drugs, devices, cosmetics, insecticides, fungicides, and caustic or corrosive substances, see 19 CFR part 12. For regulations relating to consular invoices, and documentation of merchandise, see 22 CFR parts 91 and 92.

In lieu of a particular guaranty for each lot of dangerous caustic or corrosive substances, a general continuing guaranty may be furnished by the guarantor to actual or prospective purchasers. The following are forms of continuing guaranties:

The undersigned guarantees that the retail parcels, packages, or containers of the dangerous caustic or corrosive substance or substances to be sold to _____ are not misbranded within the meaning of the Federal Caustic Poison Act.

The dangerous caustic or corrosive substance or substances in retail parcels, packages, or containers suitable for household use to be sold to _____ are for other than household use, and guaranteed not to be misbranded within the meaning of the Federal Caustic Poison Act.

If a guaranty in respect to any specific lot of dangerous caustic or corrosive substances be given, it shall be incorporated in or attached to the bill of sale, invoice, or other schedule bearing the date and the name and quantity of the substance sold, and shall not appear on the label or package. The following are forms of specific guaranties:

The undersigned guarantees that the retail parcels, packages, or containers of the dangerous caustic or corrosive substance or substances listed herein (or specifying the substances) are not misbranded within the meaning of the Federal Caustic Poison Act.

The dangerous caustic or corrosive substance or substances listed herein (or specifying the substances) in retail parcels, packages, or containers suitable for household use are for other than household use and are guaranteed not to be misbranded within the meaning of the Federal Caustic Poison Act.

Authorized agents in the employ of the Department of Health and Human Services may make investigations, including the inspection of premises where dangerous caustic and corrosive substances subject to the act are manufactured, packed, stored, or held for sale or distribution, and make examinations of freight and other transportation records.

Caustic soda, also known as sodium hydroxide (NaOH), caustic, and lye, is a strong metallic base. It is used in a wide variety of industries and by consumers for cleaning. Caustic soda is highly corrosive and reactive. In its pure form it is a white solid, however it is sold in the form of flakes, pellets and in a 50% liquid solution with water. It is highly hygroscopic so readily attracts water molecules from the air through absorption and adsorption. If not stored in an air tight container, it will begin to dissolve in the water it attracts. Caustic soda also readily dissolves in ethanol and methanol, though it is less soluble in these than in water. The largest application of caustic soda world-wide is in the paper and pulp industry where it is used to de-ink paper, for bleaching and so on. Other industrial applications include processing of textiles, bleach manufacture, petroleum production and products, aluminum production, chemical processing, water treatment and in detergents. In detergents, caustic is used in soaponification reactions and for anionic surfactants. Caustic soda is a common base in laboratories and used for cleaning in homes. The industrial manufacture of caustic soda involves a chlor-alkali process. Electrolysis is used to separate chlorine and sodium hydorxide. The overall reaction is as follows;

with chlorine at the anode and sodium hydroxide and hydrogen at the cathode. It is imperative that the chlorine and sodium hydroxide are kept separate so that they do not react. This is done in a variety of ways. The three most common are the membrane cell process, the diaphragm cell process, and the mercury cell process. The latter is more controversial in its use due to the environmental and health problems associated with mercury. The largest producer of caustic soda is the Dow Chemical Company which employs the use of the former two in the production of caustic. Due to its high reactivity and corrosiveness, caustic soda must be used carefully by people as it will burn skin and damage eyes. When using caustic soda, individuals need to use safety precautions, such as gloves and glasses.

In the wine industry, caustic soda is used as a cleaning and sanitation agent and in laboratories. In laboratories and wine testing, sodium hydroxide is used as a base for various tests such as titrations. In wineries, it is used to clean and sanitize surfaces. One application is to clean winery floors, or other surfaces, to prevent corrosion by organic acids from wine. Wine spilled on the winery floor can corrode the floor. Caustic soda, in liquid or flake form, can be put on the floor to neutralize the acid. This is mostly commonly employed on concrete and other porous surfaces. Caustic soda is used to clean and sanitize tank exteriors, usually in a 5% liquid solution. It is also used to remove cells and biofilms from winery surfaces. One study found that of the commonly used detergents tested, caustic soda was the most effective in the removal of cells and biofilms from plastic and metal surfaces. While effective for plastic and metal, caustic soda cannot be used for some winery surfaces, such as oak barrels.

On an average trip to the supermarket, shoppers may stock up on detergent, purchase a bottle of aspirin and take a look at the latest headlines on newspapers and magazines. At first glance, it may not seem like these items have much in common. However, for each of them, caustic soda plays a key role in their ingredient lists or manufacturing processes.

Current modulations, current spikes, and current horns, are observed in a range of accelerator physics applications including strong bunch compression in Free Electron Lasers and linear colliders, trains of microbunching for terahertz radiation, microbunching instability and many others. This paper considers the fundamental mechanism that drives intense current modulations in dispersive regions, beyond the common explanation of nonlinear and higher-order effects. Under certain conditions, neighboring electron trajectories merge to form caustics, and often result in characteristic current spikes. Caustic lines and surfaces are regions of maximum electron density, and are witnessed in accelerator physics as folds in phase space of accelerated bunches. We identify the caustic phenomenon resulting in cusplike current profiles and derive an expression which describes the conditions needed for particle-bunch caustic formation in dispersive regions. The caustic expression not only reveals the conditions necessary for caustics to form but also where in longitudinal space the caustics will form. Particle-tracking simulations are used to verify these findings. We discuss the broader implications of this work including how to utilize the caustic expression for manipulation of the longitudinal phase space to achieve a desired current profile shape. ff782bc1db

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