We demonstrate quantum mechanically how to resolve enantiomers from an oriented racemic mixture taking advantage of photodissociation. Our approach employs a femtosecond ultraviolet (UV) laser pulse with specific linear polarization achieving selective photodissociation of one enantiomer from a mixture of L and D enantiomers. As a result, the selected enantiomer is destroyed in the electronic excited state while the opposite counter enantiomer is left intact in the ground state. As an example we use H₂POSD which presents axial chirality. A UV pulse excites the lowest singlet excited state which has nσ* character and is, therefore, strongly repulsive along the P-S bond. The model simulations are performed using wavepackets which propagate on two dimensional potential energy surfaces, calculated along the chirality and dissociation reaction coordinates using CASSCF level of theory.