Calcium carbonate is an inorganic compound ubiquitous in nature present as minerals and biominerals (produced by organisms), with great environmental importance and extensive industrial applications. Carbonates are important biominerals building blocks of biological bodies, making up the skeletal structure of invertebrate organisms in the marine, freshwater, and terrestrial realm. Calcium carbonate is also a key compound for atmospheric CO2 sequestration through mineral trapping regulating CO2 emission levels. Therefore, understanding the mechanisms of the CaCO3 formation and its governing parameters is of great importance.
Recently, many studies have revealed that calcification, the process of CaCO3 formation, involves the precipitation of an amorphous precursor, which acts as an intermediate in the formation of the final CaCO3 crystalline mineral (e.g., calcite, vaterite or aragonite). Therefore, the main goal of this project is to understand the role of the amorphous calcium carbonate (ACC) in the (bio)mineralization process. With this aim, in this project we characterize the amorphous precursor phase and the crystalline mineral and investigate which factors (e.g., water, presence of organic molecules) affect the transformation kinetics of the amorphous precursor into the crystalline phase (Fig. 1).
The innovative character of this project is the use of advanced synchrotron and neutron techniques, such as X-ray Photon Correlation Spectroscopy (XPCS) and Incoherent Inelastic Neutron Scattering (INS) that are more sensitive to small structural changes than other traditional characterization techniques.