The sixth generation (6G) networks are expected to support a hyperconnected world with unprecedented wireless connectivity and network capabilities. Realizing this vision requires embracing Artificial Intelligence (AI) and Machine Learning (ML) techniques across the entire network to enable sustainable, reliable, and trustworthy 6G systems. 6G represents a significant leap forward in the digital age. Its impact will be to make changes across various sectors, from revolutionizing industries to transforming how we interact with the world. By embracing innovation and addressing the challenges, 6G has the potential to create a more connected, intelligent, and personalized digital experience for everyone. Integrating AI and ML holds the key to unlocking the full potential of 6G. The objective of the workshop is to promote the harvest of the benefits of pervasive network intelligence for 6G by considering the aforementioned challenges. This workshop can serve as a platform for researchers from academia, government, and industries to exchange ideas on 6G and AI.