Bases

Just as with acids, there are three definitions of a base.

Bases: The Definitions

According to the Arrhenius definition, a base produces OH- when in aqueous solutions. An example is sodium hydroxide (NaOH).

When you add NaOH to water, NaOH dissociates:

NaOH (aq)---> Na+(aq) + OH-(aq)

As you can see, NaOH dissociates and produces OH-, which is how Arrhenius defined a base.

Under Bronsted-Lowry, bases are as substances that accept H+ (protons). Ammonia (NH3) provides a good example of this definition:

NH3 (aq) + H2O(l) ---> (NH4)+ (aq) + OH- (aq)

In this reaction, ammonia (NH3) abstracted (took) a proton from water to form ammonium (NH4 +) and hydroxide (OH-). Thus, ammonia accepted a proton and is a base under the Bronsted-Lowry. We can also see that ammonia produced OH- and would therefore qualify as a base under the Arrhenius definition as well.

The Lewis definition says that bases are electron pair donors. By this definition, a given base must have at least one lone pair of electrons. Using the ammonia example again, ammonia is donating the electron pair on nitrogen to a hydrogen atom on water in order to form ammonia. The following figure may help you picture this. The red arrows indicate the movement of a pair of electrons.

Another example of ammonia as a Lewis base:

Here, ammonia is donating an electron pair to the electron-deficient boron in boron trichloride, which accepts a pair of electrons (making it a Lewis acid!).

Other Properties of Bases

  • Bases have pH>7 (by definition) or pH>8 (commonly).

  • Bases are also known as "alkali"

  • IF tasted, based would be "bitter" (though I strong advise against tasting a base!!)

  • Bases also feel slippery to the touch. Just think of how soap feels when you use it!

Examples of bases

Bases can be found in substances such as:

  • sea water

  • baking soda

  • milk of magnesia( Mg(OH)2)

  • ammonia solution

  • soap water

  • bleach

  • anti-acids

  • drain cleaner,

  • toothpaste

  • laundry detergent/washing powder

  • quick lime

Chemical formulas of bases include:

Strong Bases:

  • NaOH (sodium hydroxide)

  • LiOH (lithium hydroxide)

  • Ba(OH)2 (barium hydroxide)

  • KOH (potassium hydroxide)

  • Sr(OH)2 (strontium hydroxide)

  • Ca(OH)2 (calcium hydroxide)

Weak bases:

  • NH3 (ammonia)

  • anions (of strong acids) like Cl- (chloride), F- (fluoride), NO3- (nitrate), C2H3O2 - (acetate)

  • CO3 2- (carbonate ion)

  • CH3NH2 (methylamine)

  • C5H5N (pyridine)

  • HCO3 - (bicarbonate/hydrogen carbonate)

  • C6H5NH2 (aniline)