112) Droghetti F., Natali M. Design Principles for Tuning Selectivity in CO2 Reduction by Fe and Co Polypyridine Complexes. Chem. Commun. 2026. DOI: 10.1039/d6cc04834j.
111) Rosso C., Barison G., Droghetti F., Michelazzo N., Sartorel A., Pelosi G., Bortolus M., Bonacchi S., Visentini S., Marrese A., Bistoni G., Lerda S., Burigana V., Collini E., Costa P., Natali M., Dell'Amico L. Bimodal Multiphoton Catalysis via Structural Regeneration. Nat. Catal. 2026. DOI: 10.1038/s41929-026-01593-w.
110) Uipanit S., Schreyer T., Zhiliaev K., Kaup J. H., Natali M., Mateos J. Selenoxanthylium Salts - Organic Photocatalysts for Low-Energy Photoredox Catalysis. J. Am. Chem. Soc. 2026, 148, 35139-35146. DOI: 10.1021/jacs.6c13607.
109) Wu T., Gentilin A., Droghetti F., Morhart L., Ðorđević L., Natali M., Sartorel A. Coupled Light-Driven p-Xylene Oxidation and H2O2 Production with Organic Photocatalysts in Propylene Carbonate. Photocatalysis 2026, 2, 7. DOI: 10.53941/photocatalysis.2026.100007.
108) Mantovani A., Droghetti F., Tortajada A., Rulíšek L., Lemken F., Ruggi A., Natali M. Green Ammonia Generation with a Polypyridine Cobalt Complex and Visible Light. J. Am. Chem. Soc. 2026, 148, 31621-31626. DOI: 10.1021/jacs.6c01477.
107) Droghetti F., Lemken F., Castellani F., Rulíšek L., Ruggi A., Natali M. Electronic Effects Drive Selectivity in CO2 Reduction Catalysis by Heptacoordinated Cobalt Complexes. Inorg. Chem. 2026, 65, 12678-12692. DOI: 10.1021/acs.inorgchem.6c01633.
106) Riina F., Chiarello G., Poletti L., Ragno D., De Risi C., Natali M., Droghetti F., Massi A., Di Carmine G. Synthesis of a-C-Glycoside Conjugates via Giese-like Reaction Triggered by Photoactivated Electron-Donor-Acceptor (EDA) Complexes and In-Situ Photocatalytic Species. Org. Chem. Front., 2026, 13, 2867-2874. DOI: 10.1039/d6qo00174b.
105) Rodriguez R.I., Paut J., Armellin G., Visentini S., Cormier G., Droghetti F., Natali M., Bortolus M., Pelosi G., Dell'Amico L. Photochemical Thiocarbonyl Difluoride Generation Enables Azetidine Synthesis. Nat. Commun., 2026, 17, 2631. DOI: 10.1038/s41467-026-69464-3.
104) Raulin M., Droghetti F., Zeppilli D., Begato F., Kumar Mondal P., Rancan M., Licini G., Orian L., Natali M., Zonta C. Confined Metal Centres in a Symmetric Cage: Mono- and Heterodinuclear Complexes for Photocatalytic Hydrogen Evolution. Inorg. Chem. Front., 2026, 13, 2470 - 2477. DOI: 10.1039/d5qi02424b
103) Bianco A., Natali M., Bergamini G. When Better Quenching Means Lower Yields: Electrostatic Control of Cage Escape. ACS Phys. Chem. Au, 2026, 6, 185 - 195. DOI: 10.1021/acsphyschemau. 5c00103
102) Corti V., Simionato G., Rizzo L., Serapian S.A., Pelosi G., Natali, M., Dell'Amico L. Triplet state reactivity of iminium ions in organocatalytic asymmetric [2+2] photocycloadditions. Nat. Chem., 2026, 18, 189 - 197. DOI: 10.1038/s41557-025-01960-3
101) Sanhueza L., Luco S., Salas F., Gonzalez I., Robles S., Natali M., Khodr A., Margeat O., Ruiz C.M., Cortés-Arriagada D., Dreyse P. Iridium Complexes Based on 1H-imidazo[4,5-f][1,10]Phenantroline Ligand: Photophysical Properties and Light-Emitting Electrochemical Cells Characterization. Chem. Eur. J. 2026, 32, e02588. DOI: 10.1002/chem.202502588
100) Martì G., Alique M., Lopez I., Francas L., Bofill R., Schott O., Hanan G.S., Lozano-Roche A., Romero N., Philippot K., Llobet A., Natali M., Garcia-Anton J., Sala, X. Dyadic Ru-based nanomaterials for visible light-driven photocatalytic hydrogen evolution. Appl. Surf. Sci. 2026, 716, 164621. DOI: 10.1016/j.apsusc.2025.164621
99) Mantovani A., Mastrolorenzo A., Marchini E., Manini P., Natali M. Exploring the Boundaries of Cyclometalated Iridium(III) Sensitizers in Photoelectrochemical Organic Transformations. ACS Appl. Mater. Interfaces, 2025, 17, 69519 - 69529. DOI: 10.1021/acsami.5c20212
98) Mantovani A., Marchini E., Ianniello A., Amati A., Caramori S., Natali M. Photoelectrochemical Generation of Value-Added Organics via C-H Bond Activation at WO3 Photoelectrodes. ACS Appl. Energy Mater. 2025, 8, 18335 - 18362. DOI: 10.1021/acsaem.5c03321
97) Natali M., Ruggi A. Eart-abundant molecular catalysts with polypyridyl redox-active ligands in artificial photosynthesis: From leaf to lab. Advances in Catalysis, 2025, 77, 1 - 27. DOI: 10.1016/bs.acat.2025.10.004
96) Droghetti F., Mantovani A., Natali M. Light-Driven CO2 Reduction Catalysis with Organic Thermally Activated Delayed Fluorescence (TADF) Sensitizers. ChemCatChem, 2025, 17, e202500247. DOI: 10.1002/cctc.202500247
95) Droghetti F., Villa L., Sartorel A., Dell'Amico L., Ruggi A., Natali M. Boosting Light-Driven CO2 Conversion into CO by a Polypyridine Iron(II) Catalyst Using an Organic Sensitizer. ChemSusChem, 2025, 18, e202402627. DOI: 10.1002/cssc.202402627
94) Bonetto R., Romero N., Sabuzi F., Forchetta M., Natali M., Signorini R., Bofill R., Francàs L., Gil-Sepulcre M., Rüdiger O., DeBeer S., García-Antón J., Philippot K., Galloni P., Sartorel A., Sala X. KuQuinone-sensitized cobalt oxide nanoparticles for photoelectrocatalytic oxygen evolution with visible light. Green Chem., 2025, 27, 4352 – 4368. DOI: 10.1039/d4gc06606e
93) Tacchi E., Rossi G., Natali M., Ðorđević L., Sartorel A. Aqueous Photocatalytic Glycerol Oxidation to Formic Acid Coupled to H2O2 Production with an Anthraquinone Dye. Adv. Sustain. Syst., 2025, 9, 2400538. DOI: 10.1002/adsu.202400538
92) Toro P.M., Henriquez M., Erazo I., Levin P., Villaman D., Natali M., Barrientos C. Cabrera A.R. Rhenium(I) complexes based on iminopyridyl ligands: Structural, Photophysical, and CO2 electrocatalytic reduction studies. Inorg. Chim. Acta, 2025, 587, 122827. DOI: 10.1016/j.ica.2025.122827
91) Villegas-Menares A., Hansmann Y.S., Bayas M., Verdugo C., Erazo I., Zuñiga C., Gonzalez I., Galdámez A., Villa L., Natali M., Cabrera A.R. Exploring catalytic activity modulations: photoredox catalysis with substituted copper(i)-dipyridylamine derivatives. Dalton Trans., 2025, 54, 7306 - 7314. DOI: 10.1039/d4dt03337j
90) Droghetti F., Begato F., Raulin M., Musiu G., Licini G., Natali M., Zonta C. Strong Enhancement in Cobalt(II)-TPMA Aqueous Hydrogen Photosynthesis through Intramolecular Proton Relay. Angew. Chem. Int. Ed., 2024, 63, e202408316. DOI: 10.1002/anie.202408316
89) Droghetti F., Lemken F., Rulíšek L., Ruggi A., Natali M. Selective and Efficient Light-Driven CO2 Reduction to CO with a Heptacoordinated Polypyridine Iron(II) Catalyst. ACS Catal., 2024, 14, 16920 – 16935. DOI: 10.1021/acscatal.4c04290
88) Droghetti F., Amati A., Ruggi A., Natali M. Bioinspired motifs in proton and CO2 reduction with 3d-metal polypyridine complexes. Chem. Commun., 2024, 60, 658 – 673. DOI: 10.1039/d3cc05156k
87) Rossin E., Bonchio M., Natali M., Sartorel A. Sequential proton coupled electron transfer events from a tetraruthenium polyoxometalate in photochemical water oxidation. Sustain. Energy Fuels, 2024, 8, 1944 – 1952. DOI: 10.1039/d4se00146j
86) Natali M., Sartorel A. Mechanistic Investigation of Light-Driven Catalysis for Solar Fuel Formation. Photochemistry, 2024, 52, 373-396. DOI: 10.1039/9781837676552-00373
85) Rodríguez R.I., Corti V., Rizzo L., Visentini S., Bortolus M., Amati A., Natali M., Pelosi G., Costa P., Dell’Amico L. Radical strain-release photocatalysis for the synthesis of azetidines. Nat. Catal., 2024, 7, 1223 – 1231. DOI: 10.1038/s41929-024-01206-4
84) Zardi P., Piękoś J., Bravin C., Wurst K., Droghetti F., Natali M., Licini G., Zambon A., Zonta C. Novel ligands from direct benzylic functionalisation of tris(2-pyridylmethyl)amine. Dalton Trans., 2024, 53, 13831 – 13836. DOI: 10.1039/d4dt02022g
83) Droghetti F., Amati A., Pascale F., Crochet A., Pastore M., Ruggi A., Natali M. Catalytic CO2 Reduction with Heptacoordinated Polypyridine Complexes: Switching the Selectivity via Metal Replacement. ChemSusChem, 2024, 17, e202300737. DOI: 10.1002/cssc.202300737
82) Vásquez B., Bayas M., Dreyse P., Palma J.L., Cabrera A.R., Rossin E., Natali M., Saldias C., González-Pavez I. Synthesis and Characterization of Iridium(III) Complexes with Substituted Phenylimidazo(4,5-f)1,10-phenanthroline Ancillary Ligands and Their Application in LEC Devices. Molecules, 2024, 29, 53. DOI: 10.3390/molecules29010053
81) Moreno-da Costa D., Zúñiga-Loyola C., Droghetti F., Robles S., Villegas-Menares A., Villegas-Escobar N., Gonzalez-Pavez I., Molins E., Natali M., Cabrera A.R. Air- and Water-Stable Heteroleptic Copper (I) Complexes Bearing Bis(indazol-1-yl)methane Ligands: Synthesis, Characterisation, and Computational Studies. Molecules, 2024, 29, 47. DOI: 10.3390/molecules29010047
80) Mateos J., Rigodanza F., Costa P., Natali M., Vega-Peñaloza A., Fresch E., Collini E., Bonchio M., Sartorel A., Dell’Amico L. Unveiling the impact of the light source and steric factors on [2+2] heterocycloaddition reactions. Nat. Synth., 2023, 2, 26 – 36. DOI: 10.1038/s44160-022-00191-5
79) Poletti L., Massi A., Ragno D., Droghetti F., Natali M., De Risi C., Bortolini O., Di Carmine G. Modulable Photocatalyzed Strategies for the Synthesis of α-C-Glycosyl Alanine Analogues via the Giese Reaction with Dehydroalanine Derivates. Org. Lett., 2023, 25, 4862 – 4867. DOI: 10.1021/acs.orglett.3c01660
78) Lucarini F., Fize J., Morozan A., Droghetti F., Solari E., Scopelliti R., Marazzi M., Natali M., Pastore M., Artero V., Ruggi A. Electro- and photochemical H2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines. Sustain. Energy Fuels, 2023, 7, 3384 – 3394. DOI: 10.1039/d3se00295k
77) Gryszel M., Schlossarek T., Würthner F., Natali M., Głowacki E.D. Water-Soluble Cationic Perylene Diimide Dyes as Stable Photocatalysts for H2O2 Evolution. ChemPhotoChem, 2023, 7, e202300070. DOI: 10.1002/cptc.202300070
76) Adorinni S., Goti G., Rizzo L., Grassi F., Kralj S., Matroodi F., Natali M., De Zorzi R., Marchesan S., Dell’Amico L. Self-assembly of benzophenone-diphenylalanine conjugate into a nanostructured photocatalyst. Chem. Commun., 2023, 59, 7619 – 7622. DOI: 10.1039/d3cc01673k
75) Franceschi P., Rossin E., Goti G., Scopano A., Vega-Peñaloza A., Natali M., Singh D., Sartorel A., Dell’Amico L. A Proton-Coupled Electron Transfer Strategy to the Redox-Neutral Photocatalytic CO2 Fixation. J. Org. Chem., 2023, 88, 6454 – 6464. DOI: 10.1021/acs.joc.2c02952
74) Santander-Nelli M., Sanhueza L., Navas D., Rossin E., Natali M., Dreyse P. Unusual fluorescence behaviour of a heteroleptic Cu(i) complex featuring strong electron donating groups on a diimine ligand. New J. Chem., 2022, 46, 1693 – 1703. DOI: 10.1039/d1nj04811b
73) Droghetti F., Benazzi E., Boaretto R., Natali M. Evaluation of Pt Deposition onto Dye‐Sensitized NiO Photocathodes for Light‐Driven Hydrogen Production. Appl. Sci., 2022, 12, 4955. DOI: 10.3390/app12104955
72) Álvarez-Prada I., Nguyen A.D., Romero N., Hou H., Benazzi E., Escriche L., Acharjya A., Thomas A., Schwarze M., Schomäcker R., Sala X., Natali M., García-Anto J., Tasbihi M. Insights into the light-driven hydrogen evolution reaction of mesoporous graphitic carbon nitride decorated with Pt or Ru nanoparticles. Dalton Trans., 2022, 51, 731 – 740. DOI: 10.1039/d1dt03006j
71) Orlando A., Lucarini F., Benazzi E., Droghetti F., Ruggi A., Natali M. Rethinking Electronic Effects in Photochemical Hydrogen Evolution Using CuInS2@ZnS Quantum Dots Sensitizers. Molecules, 2022, 27, 8277. DOI: 10.3390/molecules27238277
70) Droghetti F., Lucarini F., Molinari A., Ruggi A., Natali M. Recent findings and future directions in photosynthetic hydrogen evolution using polypyridine cobalt complexes. Dalton Trans., 2022, 51, 10658 – 10673. DOI: 10.1039/d2dt00476c
69) Natali M., Sala X., Roy S., Pannwitz A., Ruggi A. Editorial: Light-Assisted Molecular and Hybrid Systems for Artificial Photosynthesis. Front. Chem., 2022, 10, 868373. DOI: 10.3389/fchem.2022.868373
68) Natali M., Sartorel A., Ruggi A. Beyond Water Oxidation: Hybrid, Molecular-Based Photoanodes for the Production of Value-Added Organics. Front. Chem., 2022, 10, 907510. DOI: 10.3389/fchem.2022.907510
67) Benazzi E., Begato F., Niorettini A., Destro L., Wurst K., Licini G., Agnoli S., Zonta C., Natali M. Electrocatalytic hydrogen evolution using hybrid electrodes based on single-walled carbon nanohorns and cobalt(ii) polypyridine complexes. J. Mater. Chem. A, 2021, 9, 20032 – 20039. DOI: 10.1039/d1ta03645a
66) La Ganga G., Puntoriero F., Fazio E., Natali M., Nastasi F., Santoro A., Galletta M., Campagna S. Photoinduced Water Oxidation in Chitosan Nanostructures Containing Covalently Linked RuII Chromophores and Encapsulated Iridium Oxide Nanoparticles. Chem. Eur. J., 2021, 27, 16904 – 16911. DOI: 10.1002/chem.202102032
65) Benazzi E., Cristino V., Boaretto R., Caramori S., Natali M. Photoelectrochemical hydrogen evolution using CdTex S1- x quantum dots as sensitizers on NiO photocathodes. Dalton Trans., 2021, 50, 696 – 704. DOI: 10.1039/d0dt03567j
64) Henriquez M.A., Engl S., Jaque P., Gonzalez I.A., Natali M., Reiser O., Cabrera A.R. Phosphine Evaluation on a New Series of Heteroleptic Copper(I) Photocatalysts with dpa Ligand [Cu(dpa)(P,P)]BF4. Eur. J. Inorg. Chem., 2021, 4020 – 4029. DOI: 10.1002/ejic.202100634
63) Franceschi P., Nicoletti C., Bonetto R., Bonchio M., Natali M., Dell’Amico L., Sartorel A. Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones. Front. Chem., 2021, 9, 783993. DOI: 10.3389/fchem.2021.783993
62) Lucarini F., Bongni D., Schiel P., Bevini G., Benazzi E., Solari E., Fadaei-Tirani F., Scopelliti R., Marazzi M., Natali M., Pastore M., Ruggi A. Rationalizing Photo-Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands. ChemSusChem, 2021, 14, 1874 – 1885. DOI: 10.1002/cssc.202100161
61) Rigodanza F., Marino N., Bonetto A., Marcomini A., Bonchio M., Natali M., Sartorel A. Water-Assisted Concerted Proton-Electron Transfer at Co(II)-Aquo Sites in Polyoxotungstates With Photogenerated RuIII(bpy)33+ Oxidant. ChemPhysChem, 2021, 22, 1208 – 1218. DOI: 10.1002/cphc.202100190
60) Meza-Chincha A.-L., Schindler D., Natali M., Würthner F. Effects of Photosensitizers and Reaction Media on Light-Driven Water Oxidation with Trinuclear Ruthenium Macrocycles. ChemPhotoChem, 2021, 5, 173 – 183. DOI: 10.1002/cptc.202000133
59) Natali M., Amati A., Demitri N., Iengo E. Photoinduced Electron vs. Concerted Proton Electron Transfer Pathways in SnIV (l-Tryptophanato)2 Porphyrin Conjugates. Chem. Eur. J., 2021, 27, 7872 – 7881. DOI: 10.1002/chem.202005487
58) Lucarini F., Fize J., Morozan A., Marazzi M., Natali M., Pastore M., Artero V., Ruggi A. Insights into the mechanism of photosynthetic H2 evolution catalyzed by a heptacoordinate cobalt complex. Sustain. Energy Fuels, 2020, 4, 589 – 599. DOI: 10.1039/c9se00434c
57) González I., Gómez J., Santander-Nelli M., Natali M., Cortés-Arriagada D., Dreyse P. Synthesis and photophysical characterization of novel Ir(III) complexes with a dipyridophenazine analogue (ppdh) as ancillary ligand. Polyhedron, 2020, 186, 114621. DOI: 10.1016/j.poly.2020.114621
56) Natali M., Amati A., Merchiori S., Ventura B., Iengo E. Photoinduced Proton-Coupled Electron Transfer in Supramolecular SnIV Di(l -tyrosinato) Porphyrin Conjugates. J. Phys. Chem. C, 2020, 124, 8514 – 8525. DOI: 10.1021/acs.jpcc.0c00224
55) Mateos J., Rigodanza F., Vega-Peñaloza A., Sartorel A., Natali M., Bortolato T., Pelosi G., Companyó X., Bonchio M., Dell'Amico L. Naphthochromenones: Organic Bimodal Photocatalysts Engaging in Both Oxidative and Reductive Quenching Processes. Angew. Chem. Int. Ed., 2020, 59, 1302 – 1312. DOI: 10.1002/anie.201912455
54) Romero N., Guerra R.B., Gil L., Drouet S., Salmeron-Sànchez I., Illa O., Philippot K., Natali M., García-Antón J., Sala X. TiO2-mediated visible-light-driven hydrogen evolution by ligand-capped Ru nanoparticles. Sustain. Energy Fuels, 2020, 4, 4170 – 4178. DOI: 10.1039/d0se00446d
53) Agosti A., Natali M., Amirav L., Bergamini G. Towards Solar Factories: Prospects of Solar-to-Chemical Energy Conversion using Colloidal Semiconductor Photosynthetic Systems. ChemSusChem, 2020, 13, 4894 – 4899. DOI: 10.1002/cssc.202001274
52) Volpe A., Natali M., Graiff C., Sartorel A., Tubaro C., Bonchio M. Novel iridium complexes with N-heterocyclic dicarbene ligands in light-driven water oxidation catalysis: photon management, ligand effect and catalyst evolution. Dalton Trans., 2020, 49, 2696 – 2705. DOI: 10.1039/c9dt04841c
51) Benazzi E., Coni V.C., Boni M., Mazzaro R., Morandi V., Natali M. The role of the capping agent and nanocrystal size in photoinduced hydrogen evolution using CdTe/CdS quantum dot sensitizers. Dalton Trans., 2020, 49, 10212 – 10223. DOI: 10.1039/d0dt01195a
50) Mazzaro R., Boscolo Bibi S., Natali M., Bergamini G., Morandi V., Ceroni P., Vomiero A. Hematite nanostructures: An old material for a new story. Simultaneous photoelectrochemical oxidation of benzylamine and hydrogen production through Ti doping. Nano Energy, 2019, 61, 36 – 46. DOI: 10.1016/j.nanoen.2019.04.013
49) Orbelli Biroli A., Tessore F., Di Carlo G., Pizzotti M., Benazzi E., Gentile F., Berardi S., Bignozzi C.A., Argazzi R., Natali M., Sartorel A., Caramori S. Fluorinated ZnII Porphyrins for Dye-Sensitized Aqueous Photoelectrosynthetic Cells. ACS Appl. Mater. Interfaces, 2019, 11, 32895 – 32908. DOI: 10.1021/acsami.9b08042
48) Bergamini G., Natali M. Homogeneous: Vs. heterogeneous catalysis for hydrogen evolution by a nickel(ii) bis(diphosphine) complex. Dalton Trans., 2019, 48, 14653 – 14661. DOI: 10.1039/c9dt02846c
47) Amati A., Natali M., Indelli M.T., Iengo E., Würthner F. Photoinduced Energy- and Electron-Transfer Processes in a Side-to-Face RuII-Porphyrin/Perylene-bisimide Array. ChemPhysChem, 2019, 20, 2195 – 2203. DOI: 10.1002/cphc.201900611
46) Amati A., Cavigli P., Demitri N., Natali M., Indelli M.T., Iengo E. Sn(IV) Multiporphyrin Arrays as Tunable Photoactive Systems. Inorg. Chem., 2019, 58, 4399 – 4411. DOI: 10.1021/acs.inorgchem.8b03542
45) Volpe A., Tubaro C., Natali M., Sartorel A., Brudvig G.W., Bonchio M. Light-Driven Water Oxidation with the Ir-blue Catalyst and the Ru(bpy)32+/S2O82- Cycle: Photogeneration of Active Dimers, Electron-Transfer Kinetics, and Light Synchronization for Oxygen Evolution with High Quantum Efficiency. Inorg. Chem., 2019, 58, 16537 – 16545. DOI: 10.1021/acs.inorgchem.9b02531
44) Natali M., Nastasi F., Puntoriero F., Sartorel A. Mechanistic Insights into Light-Activated Catalysis for Water Oxidation. Eur. J. Inorg. Chem., 2019, 2027 - 2039. DOI: 10.1002/ejic.201801236
43) Natali M., Nastasi F., Puntoriero F., Sartorel A. Mechanistic Insights into Light-Activated Catalysis for Water Oxidation. Eur. J. Inorg. Chem., 2019, 2013. DOI: 10.1002/ejic.201900365
42) Volpato G.A., Bonetto A., Marcomini A., Mialane P., Bonchio M., Natali M., Sartorel A. Proton coupled electron transfer from Co3O4 nanoparticles to photogenerated Ru(bpy)33+: Base catalysis and buffer effect. Sustain. Energy Fuels, 2018, 2, 1951 – 1956. DOI: 10.1039/c8se00275d
41) Sartori A., Orlandi M., Berardi S., Mazzi A., Bazzanella N., Caramori S., Boaretto R., Natali M., Fernandes R., Patel N., Bignozzi C.A., Miotello A. Functionalized p-silicon photocathodes for solar fuels applications: Insights from electrochemical impedance spectroscopy. Electrochim. Acta, 2018, 271, 472 – 480. DOI: 10.1016/j.electacta.2018.03.188
40) González I.A., Henríquez M.A., Cortés-Arriagada D., Natali M., Daniliuc C.G., Dreyse P., Maze J., Rojas R.S., Salas C.O., Cabrera A.R. Heteroleptic Cu(i) complexes bearing methoxycarbonyl-imidoylindazole and POP ligands-an experimental and theoretical study of their photophysical properties. New J. Chem., 2018, 42, 12576 – 12586. DOI: 10.1039/c8nj00699g
39) González I., Natali M., Cabrera A.R., Loeb B., Maze J., Dreyse P. Substituent influence in phenanthroline-derived ancillary ligands on the excited state nature of novel cationic Ir(iii) complexes. New J. Chem., 2018, 42, 6644 – 6654. DOI: 10.1039/c8nj00334c
38) Natali M., Amati A., Demitri N., Iengo E. Formation of a long-lived radical pair in a Sn(iv) porphyrin-di(l-tyrosinato) conjugate driven by proton-coupled electron-transfer. Chem. Commun., 2018, 54, 6148 – 6152. DOI: 10.1039/c8cc03441a
37) Natali M. Elucidating the Key Role of pH on Light-Driven Hydrogen Evolution by a Molecular Cobalt Catalyst. ACS Catal., 2017, 7, 1330 – 1339. DOI: 10.1021/acscatal.6b03087
36) Carmo Dos Santos N.A., Natali M., Badetti E., Wurst K., Licini G., Zonta C. Cobalt, nickel, and iron complexes of 8-hydroxyquinoline-di(2-picolyl)amine for light-driven hydrogen evolution. Dalton Trans., 2017, 46, 16455 – 16464. DOI: 10.1039/c7dt02666h
35) Bazzan I., Volpe A., Dolbecq A., Natali M., Sartorel A., Mialane P., Bonchio M. Cobalt based water oxidation catalysis with photogenerated Ru(bpy)33+: Different kinetics and competent species starting from a molecular polyoxometalate and metal oxide nanoparticles capped with a bisphosphonate alendronate pendant. Catal. Today, 2017, 290, 39 – 50. DOI: 10.1016/j.cattod.2017.03.027
34) Burian M., Syrgiannis Z., La Ganga G., Puntoriero F., Natali M., Scandola F., Campagna S., Prato M., Bonchio M., Amenitsch H., Sartorel A. Ruthenium based photosensitizer/catalyst supramolecular architectures in light driven water oxidation. Inorg. Chim. Acta, 2017, 454, 171 – 175. DOI: 10.1016/j.ica.2016.04.010
33) Natali M., Bazzan I., Goberna-Ferrón S., Al-Oweini R., Ibrahim M., Bassil B.S., Dau H., Scandola F., Galán-Mascarós J.R., Kortz U., Sartorel A., Zaharieva I., Bonchio M. Photo-assisted water oxidation by high-nuclearity cobalt-oxo cores: Tracing the catalyst fate during oxygen evolution turnover. Green Chem., 2017, 19, 2416 – 2426. DOI: 10.1039/c7gc00052a
32) Natali M., Scandola F. Supramolecular Artificial Photosynthesis. Springer International Publishing Switzerland. G. Bergamini, S. Silvi (eds.) Applied Photochemistry, Lecture Notes in Chemistry, 2016, 92, 1-66.
31) Natali M., Scandola F. Photoinduced Charge Separation in Porphyrin Ion Pairs. J. Phys. Chem. A, 2016, 120, 1588 – 1600. DOI: 10.1021/acs.jpca.6b00960
30) Cabrera A.R., Gonzalez I.A., Cortés-Arriagada D., Natali M., Berke H., Daniliuc C.G., Camarada M.B., Toro-Labbé A., Rojas R.S., Salas C.O. Synthesis of new phosphorescent imidoyl-indazol and phosphine mixed ligand Cu(I) complexes-structural characterization and photophysical properties. RSC Adv., 2016, 6, 5141 – 5153. DOI: 10.1039/c5ra20450j
29) Deponti E., Natali M. Photocatalytic hydrogen evolution with ruthenium polypyridine sensitizers: Unveiling the key factors to improve efficiencies. Dalton Trans., 2016, 45, 9136 – 9147. DOI: 10.1039/c6dt01221c
28) Natali M., Badetti E., Deponti E., Gamberoni M., Scaramuzzo F.A., Sartorel A., Zonta C. Photoinduced hydrogen evolution with new tetradentate cobalt(II) complexes based on the TPMA ligand. Dalton Trans., 2016, 45, 14764 – 14773. DOI: 10.1039/c6dt01705c
27) La Gatta S., Hassan Omar O., Agostiano A., Milano F., Tangorra R. R., Operamolla A., Chiorboli C., Argazzi R., Natali M., Trotta M., Farinola G. M., Ragni R. A far-red emitting aryleneethynylene fluorophore used as light harvesting antenna in hybrid assembly with the photosynthetic reaction center. MRS Advances, 2016, 1, 495 – 500. DOI: 10.1557/adv.2015.33
26) Natali M., Puntoriero F., Chiorboli C., La Ganga G., Sartorel A., Bonchio M., Campagna S., Scandola F. Working the other way around: Photocatalytic water oxidation triggered by reductive quenching of the photoexcited chromophore. J. Phys. Chem. C, 2015, 119, 2371 – 2379. DOI: 10.1021/jp512541s
25) Genoni A., La Ganga G., Volpe A., Puntoriero F., Di Valentin M., Bonchio M., Natali M., Sartorel A. Water oxidation catalysis upon evolution of molecular Co(III) cubanes in aqueous media. Faraday Disc., 2015, 185, 121 – 141. DOI: 10.1039/c5fd00076a
24) Ladomenou K., Natali M., Iengo E., Charalampidis G., Scandola F., Coutsolelos A.G. Photochemical hydrogen generation with porphyrin-based systems. Coord. Chem. Rev., 2015, 304-305, 38 – 54. DOI: 10.1016/j.ccr.2014.10.001
23) Gualandi A., Marchini M., Mengozzi L., Natali M., Lucarini M., Ceroni P., Cozzi P.G. Organocatalytic Enantioselective Alkylation of Aldehydes with [Fe(bpy)3]Br2 Catalyst and Visible Light. ACS Catal., 2015, 5, 5927 – 5931. DOI: 10.1021/acscatal.5b01573
22) Natali M., Deponti E., Vilona D., Sartorel A., Bonchio M., Scandola F. A Bioinspired System for Light-Driven Water Oxidation with a Porphyrin Sensitizer and a Tetrametallic Molecular Catalyst. Eur. J. Inorg. Chem., 2015, 3467 – 3477. DOI: 10.1002/ejic.201500063
21) Cebrián C., Natali M., Villa D., Panigati M., Mauro M., D'Alfonso G., De Cola L. Luminescent supramolecular soft nanostructures from amphiphilic dinuclear Re(i) complexes. Nanoscale, 2015, 7, 12000 – 12009. DOI: 10.1039/c5nr01668a
20) Nastasi F., Puntoriero F., Natali M., Mba M., Maggini M., Mussini P., Panigati M., Campagna S. Photoinduced intercomponent excited-state decays in a molecular dyad made of a dinuclear rhenium(I) chromophore and a fullerene electron acceptor unit. Photochem. Photobio. Sci., 2015, 14, 909 – 918. DOI: 10.1039/c4pp00301b
19) Natali M., Campagna S., Scandola F. Photoinduced electron transfer across molecular bridges: Electron- and hole-transfer superexchange pathways. Chem. Soc. Rev., 2014, 43, 4005 – 4018. DOI: 10.1039/c3cs60463b
18) Al-Oweini R., Sartorel A., Bassil B.S., Natali M., Berardi S., Scandola F., Kortz U., Bonchio M. Photocatalytic Water Oxidation by a Mixed-Valent MnIII3MnIVO3 Manganese Oxo Core that Mimics the Natural Oxygen-Evolving Center. Angew. Chem. Int. Ed., 2014, 53, 11182 – 11185. DOI: 10.1002/anie.201404664
17) Ravotto L., Mazzaro R., Natali M., Ortolani L., Morandi V., Ceroni P., Bergamini G. Photoactive dendrimer for water photoreduction: A scaffold to combine sensitizers and catalysts. J. Phys. Chem. Lett., 2014, 5, 798 – 803. DOI: 10.1021/jz500160w
16) Arrigo A., Santoro A., Indelli M.T., Natali M., Scandola F., Campagna S. On the effect of the nature of the bridge on oxidative or reductive photoinduced electron transfer in donor-bridge-acceptor systems. Phys. Chem. Chem. Phys., 2014, 16, 818 – 826. DOI: 10.1039/c3cp53992j
15) Deponti E., Luisa A., Natali M., Iengo E., Scandola F. Photoinduced hydrogen evolution by a pentapyridine cobalt complex: Elucidating some mechanistic aspects. Dalton Trans., 2014, 43, 16345 – 16353. DOI: 10.1039/c4dt02269f
14) López A.M., Natali M., Pizzolato E., Chiorboli C., Bonchio M., Sartorel A., Scandola F. A Co(ii)-Ru(ii) dyad relevant to light-driven water oxidation catalysis. Phys. Chem. Chem. Phys., 2014, 16, 12000 – 12007. DOI: 10.1039/c3cp55369h
13) Maggini L., Füstös M.-E., Chamberlain T.W., Cebrián C., Natali M., Pietraszkiewicz M., Pietraszkiewicz O., Székely E., Kamarás K., De Cola L., Khlobystov A.N., Bonifazi D. Fullerene-driven encapsulation of a luminescent Eu(iii) complex in carbon nanotubes. Nanoscale, 2014, 6, 2887 – 2894. DOI: 10.1039/c3nr05876j
12) Natali M., Luisa A., Iengo E., Scandola F. Efficient photocatalytic hydrogen generation from water by a cationic cobalt(II) porphyrin. Chem. Commun., 2014, 50, 1842 – 1844. DOI: 10.1039/c3cc48882a
11) Santoni M.-P., La Ganga G., Mollica Nardo V., Natali M., Puntoriero F., Scandola F., Campagna S. The use of a vanadium species as a catalyst in photoinduced water oxidation. J. Am. Chem. Soc., 2014, 136, 8189 – 8192. DOI: 10.1021/ja5040182
10) La Ganga G., Nardo V.M., Cordaro M., Natali M., Vitale S., Licciardello A., Nastasi F., Campagna S. A functionalized, ethynyl-decorated, tetracobalt(iii) cubane molecular catalyst for photoinduced water oxidation. Dalton Trans., 2014, 43, 14926 – 14930. DOI: 10.1039/c4dt01785d
9) Pizzolato E., Natali M., Posocco B., Montellano López A., Bazzan I., Di Valentin M., Galloni P., Conte V., Bonchio M., Scandola F., Sartorel A. Light-driven water oxidation by a single-site cobalt salophen catalyst. Chem. Commun., 2013, 49, 9941 – 9943. DOI: 10.1039/c3cc45457f
8) Natali M., Ravaglia M., Scandola F., Boixel J., Pellegrin Y., Blart E., Odobel F. Long-range charge separation in a ferrocene-(zinc porphyrin)-naphthalenediimide triad. Asymmetric role of 1,2,3-triazole linkers. J. Phys. Chem. C, 2013, 117, 19334 – 19345. DOI: 10.1021/jp406405k
7) Natali M., Argazzi R., Chiorboli C., Iengo E., Scandola F. Photocatalytic hydrogen evolution with a self-assembling reductant-sensitizer-catalyst system. Chem. Eur. J., 2013, 19, 9261 – 9271. DOI: 10.1002/chem.201300133
6) Natali M., Orlandi M., Chiorboli C., Iengo E., Bertolasi V., Scandola F. Porphyrin-cobaloxime dyads for photoinduced hydrogen production: Investigation of the primary photochemical process. Photochem. Photobio. Sci., 2013, 12, 1749 – 1753. DOI: 10.1039/c3pp50184a
5) Berberich M., Natali M., Spenst P., Chiorboli C., Scandola F., Würthner F. Nondestructive photoluminescence read-out by intramolecular electron transfer in a perylene bisimide-diarylethene dyad. Chem. Eur. J., 2012, 18, 13651 – 13664. DOI: 10.1002/chem.201201484
4) Berardi S., La Ganga G., Natali M., Bazzan I., Puntoriero F., Sartorel A., Scandola F., Campagna S., Bonchio M. Photocatalytic water oxidation: Tuning light-induced electron transfer by molecular Co4O4 cores. J. Am. Chem. Soc., 2012, 134, 11104 – 11107. DOI: 10.1021/ja303951z
3) Natali M., Berardi S., Sartorel A., Bonchio M., Campagna S., Scandola F. Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments. Chem. Commun., 2012, 48, 8808 – 8810. DOI: 10.1039/c2cc34804g
2) Natali M., Orlandi M., Berardi S., Campagna S., Bonchio M., Sartorel A., Scandola F. Photoinduced water oxidation by a tetraruthenium polyoxometalate catalyst: Ion-pairing and primary processes with Ru(bpy)32+ photosensitizer. Inorg. Chem., 2012, 51, 7324 – 7331. DOI: 10.1021/ic300703f
1) La Ganga G., Puntoriero F., Campagna S., Bazzan I., Berardi S., Bonchio M., Sartorel A., Natali M., Scandola F. Light-driven water oxidation with a molecular tetra-cobalt(iii) cubane cluster. Faraday Discussions, 2012, 155, 177 – 190. DOI: 10.1039/c1fd00093d