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Sayantan Mahapatra's Academic Homepage.

I am a Core Postdoctoral Appointee in the Nanoscale and Synthesis Characterization (NSC) group at the Centre for Nanoscale Materials (CNM), Argonne National Laboratory (ANL). My work involves Quantum Information Science (QIS) projects with 2D Semiconductors through STM, AFM, and nanoscale optical spectroscopy.


Due to the diffraction limit of light, it has been a long-standing goal to chemically detect and characterize single molecules using visible light. In recent times, with the integration of STM and optical spectroscopy inside the ultrahigh vacuum (UHV), TERS can obtain both the topographic and chemical information simultaneously with ultrahigh resolution (angstrom scale sensitivity). Therefore, by probing the light-matter interaction at the atomic scale using TERS, I aim to shed light on some of the vital chemistry and physics-related problems in the single-molecule study ranging from spectroscopy to molecular-level catalysis.

Single-molecule engineering of precursor molecules to different desired products on the surface is another area that draws my attention in recent times. With atomically confined light at the STM tip apex, the highly energetic plasmons generated at the tip apex can be specifically utilized to probe certain chemical reactions. The utilization of visible light towards chemical transformation could prove extremely useful in terms of lower energy requirements as well as in solar-to-chemical energy conversion.

At IIT Kanpur, I have worked on ambient-STM and ambient-AFM to study Molecular Switches which are one of the most important components of Nanoelectronics. We have designed and analyzed the azo-benzene derivative compounds via room-temperature STM, STS, and DFT calculations.      

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