Publications

32. Jenny, S.E; Serviano, J.M.; Nova, A.; Dobereiner, G.E. A Hydride Migration Mechanism for the Mo-Catalyzed Z-2-Selective Isomerization of Terminal Alkenes. ChemCatChem, 2023, e202301052. DOI: 10.1002/cctc.202301052

Invited for Virtual Special Collection, "Non-Innocent Ligands in Sustainable Catalysis".

31. Singh. S.; Dobereiner, G.E. Efforts Towards Control of Regioselectivity in the Gold(I) Catalyzed Hydration of Internal Alkynes. Effects of Solvent, Temperature and Substrate on Regioselectivity. Advanced Synthesis and Catalysis, 2022, 20, 3551-3558. DOI: 10.1002/adsc.202200812

30. Jenny, S.E.; Dobereiner, G.E. Tungsten's Tandem Transformation. Nature Chemistry, 2022, DOI: 10.1038/s41557-022-00953-w

29. Dobereiner, G.E.; Hazari, N.; Schley, N.D. Pioneers and Influencers in Organometallic Chemistry: Professor Robert Crabtree's Storied Career via an Unusual Journey to the Ivy League. Organometallics, 2021, 40, 295-301. DOI: 10.1021/acs.organomet.0c00797

28. Becica, J.; Glaze, O.D.; Hruszkewycz, D.P.; Dobereiner, G.E.; Leitch, D.C. The influence of additives on orthogonal reaction pathways in the Mizoroki–Heck arylation of vinyl ethers. Reaction Chemistry & Engineering, 2021, Advance Article. DOI: 10.1039/D1RE00124H

27. Becica, J.; Hruszkewycz, D.P.; Steves, J.E.; Elward, J.M.; Leitch, D.C.; Dobereiner, G.E. High-Throughput Discovery and Evaluation of a General Catalytic Method for N-Arylation of Weakly Nucleophilic Sulfonamides. Organic Letters, 2019, 21, 8981-8986. DOI: 10.1021/acs.orglett.9b03380

Preprint: ChemRxiv, 2019, DOI:10.26434/chemrxiv.9108461

26. Wozniak, D.I.; Hicks, A.J.; Sabbers, W.A.; Dobereiner, G.E. Imidazolyl-Phenyl (IMP) Anions: A Modular Structure for Tuning Solubility and Coordinating Ability. Dalton Transactions, 2019, 48, 14138-14155. DOI: 10.1039/C9DT03511G

Preprint: ChemRxiv, 2019, DOI: 10.26434/chemrxiv.8792192

25. Becica, J.; Dobereiner, G.E. The roles of Lewis acidic additives in organotransition metal catalysis. Organic & Biomolecular Chemistry, 2019, 17, 2055-2069. DOI: 10.1039/c8ob02856g

24. Kaplan, J.M.; Hruszkewycz, D.P.; Strambeanu, I.I.; Nunn, C.J.; Kelsey VanGelder, K.; Dunn, A.L.; Wozniak, D.I.; Dobereiner, G.E.; Leitch, D.C. Scalable and Chemoselective Synthesis of γ-Keto Esters and Acids via Pd-Catalyzed Carbonylation of Cyclic β-Chloro Enones. Organometallics, 2019, 38, 85-96. DOI: 10.1021/acs.organomet.8b00468

23. Zhao, S.; Teijaro, C.N.; Chen, H.; Sirasani, G.; Vaddypally, S.; O’Sullivan, O.; Zdilla, M.J.; Dobereiner, G.E.; Andrade, R.B. Enantiospecific Syntheses of Bis-Strychnos Alkaloids (−)-Sungucine, (−)-Isosungucine, and (−)-Strychnogucine B. Journal of the Brazilian Chemical Society, 2019, 30, 436-453. DOI: 10.21577/0103-5053.20180217

22. Samples, E.M.; Schuck, J.M.; Joshi, P.B.; Willets, K.A.; Dobereiner, G.E. Synthesis and Properties of N-arylpyrrole-functionalized poly(1-hexene-alt-CO). Macromolecules, 2018, 51, 9323-9332. DOI: 10.1021/acs.macromol.8b01629

21. Wozniak, D.I.; Sabbers, W.A.; Weerasiri, K.C.; Dinh, L.V.; Quenzer, J.L.; Hicks, A.J.; Dobereiner, G.E. Comparing interactions of a three-coordinate Pd cation with common weakly-coordinating anions. Organometallics, 2018, 37, 2376-2385. DOI: 10.1021/acs.organomet.8b00356

An Organometallics Most Read Article, July 2018

20. Yin, H.; Jin, L.; Qian, Y.; Li, X.; Wu, Y.; Bowen, M. S.; Kaan, D.; He, C.; Wozniak, D.I.; Xu, B.; Lewis, A.J.; Shen, W.; Chen, K.; Dobereiner, G.E.; Zhao, Y.; Wayland, B.B.; Rao, Y. Excitonic and Confinement Effects of 2D Layered (C10H21NH3)2PbBr4 Single Crystals. ACS Applied Energy Materials, 2018, 1, 1476-1482. DOI: 10.1021/acsaem.7b00265

19. Becica, J.; Glaze, O.D.; Dobereiner, G.E. Selective isomerization of terminal alkenes to Z-2-alkenes catalyzed by an air-stable molybdenum(0) complex. Organometallics, 2018, 37, 482-490. DOI: 10.1021/acs.organomet.7b00914

An Organometallics Most Read Article, February 2018

18. Becica, J.; Dobereiner, G.E. Acceleration of Pd-catalyzed amide N-arylations using co-catalytic metal triflates: Substrate scope and mechanistic study. ACS Catalysis, 2017, 7, 5862-5870. DOI: 10.1021/acscatal.7b01317

Highlighted in Organic Process Research & Development: November, 2017

Highlighted in Organic Chemistry Portal: June 18, 2018

17. Weerasiri, K.C.; Chen, D.; Wozniak, D.I.; Dobereiner, G.E. Internal Alkyne Regio- and Chemoselectivity Using a Zwitterionic N-heterocyclic Carbene Gold Catalyst in a Silver-free Alkyne Hydration Reaction. Advanced Synthesis and Catalysis, 2016, 358, 4106-4113. DOI: 10.1002/adsc.201601013

Highlighted in Organic Chemistry Portal: May 29, 2017

16. Zhao, S.; Teijaro, C.N.; Chen, H.; Sirasani, G.; Vaddypally, S.; Zdilla, M.J.; Dobereiner, G.E.; Andrade, R.B. Concise Syntheses of Bis-Strychnos Alkaloids (-)-Sungucine, (-)-Isosungucine, and (-)-Strychnogucine B from (-)-Strychnine. Chemistry - A European Journal, 2016, 22, 11593-11596. DOI: 10.1002/chem.201602663

15. Chen, D.; Gau, M.R.; Dobereiner, G.E. Palladium and Platinum Acyl Complexes and Their Lewis Acid Adducts. Experimental and Computational Study of Thermodynamics and Bonding. Organometallics, 2015, 34, 4069-4075. DOI: 10.1021/acs.organomet.5b00507

14. Imler, G.H.; Li, X.; Xu, B.; Dobereiner, G.E.; Dai, H.-L.; Rao, Y.; Wayland, B.B. Solid State Transformation of the Crystalline Monohydrate (CH3NH3)PbI3(H2O) to the (CH3NH3)PbI3 Perovskite. Chemical Communications, 2015, 51, 11290-11292. DOI: 10.1039/C5CC03741G

GED publications before 2014

13. Dobereiner, G.E.; Erdogan, G.; Larsen, C.R.; Grotjahn, D.B.; Schrock, R.R. A One-Pot Tandem Olefin Isomerization/Metathesis-Coupling (ISOMET) Reaction. ACS Catalysis, 2014, 4, 3069-3076.

12. Dobereiner, G.E.; Yuan, J.; Schrock, R.R.; Goldman, A.S.; Hackenberg, J.D. Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross-Metathesis. Journal of the American Chemical Society, 2013, 135, 12572-12575.

11. Manas, M.G.; Graeupner, J.; Allen, L.J.; Dobereiner, G.E.; Rippy, K.C.; Hazari, N.; Crabtree, R.H. Hydrogenation of Quinaldine and Benzylic Aldehydes both Separately and Combined in a Tandem Hydrogenation–Reductive Alkylation of Quinaldine by Aldehydes with Iridium Benzoquinoline Catalysts. Organometallics, 2013, 32, 4501-4506.

10. Reithofer, M.R.; Dobereiner, G.E.; Schrock, R.R.; Müller, P. Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R-2-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene. Organometallics, 2013, 32, 2489-2492.

9. Dobereiner, G.E.; Wu, J.; Manas, M.G.; Schley, N.D.; Takase, M.K.; Crabtree, R.H.; Hazari, N.; Maseras, F.; Nova, A. Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide. Inorganic Chemistry, 2012, 51, 9683-9693.

8. Yuan, J.; Schrock, R.R.; Mueller, P.; Axtell, J. C.; Dobereiner, G.E. Pentafluorophenylimido Alkylidene Complexes of Molybdenum and Tungsten. Organometallics, 2012, 31, 4650-4653.

7. Schley, N.D.; Dobereiner, G.E.; Crabtree, R.H. Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes. Organometallics, 2011, 30, 4174-4179.

6. Schmeier, T.J.; Dobereiner, G.E.; Crabtree, R.H.; Hazari, N. Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2 Reduction Catalyst. Journal of the American Chemical Society, 2011, 133, 9274-9277.

5. Dobereiner, G.E.; Nova, A.; Schley, N.D.; Hazari, N.; Miller, S. J.; Eisenstein, O.; Crabtree, R.H. Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway. Journal of the American Chemical Society, 2011, 133, 7547-7562.

4. Nova, A.; Balcells, D.; Schley, N.D.; Dobereiner, G.E.; Crabtree, R.H.; Eisenstein, O. An Experimental-Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation. Organometallics, 2010, 29, 6548-6558.

3. Dobereiner, G.E.; Chamberlin, C.A.; Schley, N.D.; Crabtree, R.H. Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis. Organometallics, 2010, 29, 5728-5731.

2. Dobereiner, G.E.; Crabtree, R.H. Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis. Chemical Reviews, 2010, 110, 681-703.

1. Chen, X.; Dobereiner, G.E.; Hao, X.S.; Giri, R.; Maugel, N.; Yu, J.Q. Cu(II)-Mediated Oxidative Dimerization of 2-Phenylpyridine Derivatives. Tetrahedron 2009, 65, 3085-3089.