49. Driving Diverse Bond Functionalisation with N-heterocyclic Silylene-Coinage Metal-Aryl Complexes
Moushakhi Ghosh, Kumar Gaurav, Prakash Panwaria, Rishukumar Panday, Srinu Tothadi, and Shabana Khan. Chem. Sci., 2025, 16, 14518–14533
Embedded Files
48- Ce[N(SiMe3)2]3(THF)3-Catalyzed Hydroboration of CO2, Esters and Epoxides with Pinacolborane: Selective Synthesis of Methanol in Multigram Scale”
Cover Feature: Link
Md Jabed Hossain, Brij Kumar Shah, Soumya Ranjan Dash, Kashish, Kumar Vanka and Shabana Khan. Chem. Eur. J. 2025, e202403449
47. "Access to Bis-Silylene-Stabilized Group 13 Cations”
Moushakhi Ghosh, Prakash Panwaria, Srinu Tothadi and Shabana Khan. Inorg. Chem. 2025, 64, 1110−1123
46. "N-heterocyclic silylene-Cu(I) Complexes as Efficient Catalysts for three-Component Coupling Reactions”
Kashish, Md Jabed Hossain, and Shabana Khan. Chem Asian J. 2025, 20, e202401058
45. "UiO-67 MOF-Encapsulated NHC-Based Single-Site Copper Catalyst and Its Application in Regioselective Borylation of Terminal Alkynes”
Vijay Kumar Mandal, Kumar Gaurav, Sandeep H. Kaulage, and Shabana Khan. Inorg. Chem. 2024, 63, 20510−20520
44. "Cationic Sb(III) and Bi(III) in Catalysis”
Nilanjana Sen and Shabana Khan. Encyclopedia of Inorganic and Bioinorganic Chemistry (2024). DOI: 10.1002/9781119951438.eibc2874 (Invited Contribution)
43. "Silylene-Copper-Amide Emitters: From Thermally Activated Delayed Fluorescence to Dual Emission”
Moushakhi Ghosh, Joy Chatterjee, Prakash Panwaria, Aswath Kudlu, Srinu Tothadi, and Shabana Khan. Angew. Chem. Int. Ed. 2024, e202410792
42. "Hybrid silylene-Pd catalyst: efficient C-N cross-coupling of sterically bulky amines and chiral amines.”.
Sandeep H. Kaulage, Nasrina Parvin, Kishor V. Khopade, and Shabana Khan. Chem. Commun., 2024, 60, 9958–9961
41. "Synthesis and catalytic application of a donor-free bismuthenium cation†”
Nilanjana Sen, Pallavi Sarkar, Yadram Meena, Srinu Tothadi, Swapan K. Pati, and Shabana Khan. Chem. Commun., 2024, 60, 6877
40. "Applications of low-valent compounds with heavy group-14 elements”.
Ruksana Akhtar, Kumar Gaurav, and Shabana Khan. Chem. Soc. Rev., 2024, 53, 6150–6243 (Invited Review)
39. "Cyclic(alkyl)(amino)carbene-Stabilized Gold Nanoparticles for Selective CO2 Reduction”.
Moushakhi Ghosh, Paramita Saha, Sumit Roy, Sudip Barman, Pramod Pillai, Abhishek Dey, and Shabana Khan. ACS Catal. 2024, 14, 7011−7019.
38. "Diverse structural reactivity patterns of a POCOP ligand with coinage metals”.
Moushakhi Ghosh, Nasrina Parvin, Prakash Panwaria, Srinu Tothadi, Rangarajan Bakthavatsalam, Arshad Therambram and Shabana Khan. Dalton Trans.,2024,53, 7763–7774
37. "Deoxygenation of 1° and 2° Amides with Ce[N(SiMe3)2]3(THF)3 under Mild Conditions”.
Md Jabed Hossain, Brij Kumar Shah and Shabana Khan, ACS Catal. 2023, 13, 20, 13577–13587.
36. "N-Heterocyclic Carbenes Capped Metal Nanoparticles: An Overview of Their Catalytic Scope”.
Moushakhi Ghosh and Shabana Khan, ACS Catal. 2023, 13, 14, 9313–9325 . (View point)
35. "NHSi/NHGe-Supported Copper Halide and Pseudohalide Complexes: Synthesis and Application ”.
Jabed Hossain, Jishnu Sai Gopinath, Srinu Tothadi, Pattiyil Parameswaran, and Shabana Khan, Organometallics, 2022, 41, 3706-3717.
34. "Donor free stibenium cation as efficient cyanosilylation catalyst”.
Nilanjana Sen, Prachi Gothe, Pallavi Sarhar, Shubhajit Das, Srinu Tothadi, Swapan K Pati and Shabana Khan, Chem. Commun, 2022, 58, 10380-10383.
33. "Four-Coordinate Germylene and Stannylene and their Reactivity towards Se & Te**”.
Jabed Hossain, Nasrina Parvin, Brij Kumar Shah and Shabana Khan, Z. Anorg. Allg. Chem., 2022, e202200164. (Dedicated to Prof. Cameron Jones on the occasion of his 60th birthday (Invited contribution for special issue)
32. "First-Row Transition Metal Complexes of a Phosphine–Silylene-Based Hybrid Ligand”.
Ruksana Akhtar, Sandeep H. Kaulage, Mayur P. Sangole, Srinu Tothadi, Parameswaran Parvathy, Pattiyil Parameswaran, Kirandeep Singh, and Shabana Khan. Inorg. Chem., 2022, 61, 13330-13341.
31. "Silylene coordinated coinage metal complexes: An itinerary of their utilities”.
Moushakhi Ghosh and Shabana Khan, Advances in Inorganic Chemistry, Academic Press, 2022, ISSN 0898-8838. (Invited Contribution)
30. "Coinage Metal Complexes of Germylene and Stannylene”.
Moushakhi Ghosh, Nilanjana Sen and Shabana Khan, ACS Omega, 2022, 7(8), 6449-6454. (Invited Review)
29. "Carbazole Substituted Amidinato Silylene: Synthesis, Bonding, and Coordination Behavior with Coinage Metals”.
Moushakhi Ghosh, Srinu Tothadi and Shabana Khan, Organometallics, 2021, 40, 3201-3210.
28. "N-Heterocyclic Silylenes in Coinage Metal Chemistry: An Account of Recent Advances ”.
Moushakhi Ghosh and Shabana Khan, Dalton Trans., 2021, 50, 10674-10688.
27. "Reactivity of (TMS)2N(η1-Cp*)Si=Si(η1-Cp*)N(TMS)2 towards the Halides of Group 13-15”.
Nilanjana Sen, Nasrina Parvin, Srinu Tothadi, and Shabana Khan, Organometallics, 2021, 40, 12, 1874-1883.
26. "Synthesis and Application of Silylene Stabilized Low-Coordinate Ag(I)-Arene Cationic Complexes”.
Nasrina Parvin, Nilanjana Sen, Srinu Tothadi, Shahila Muhammed, Pattiyil Parameswaran and Shabana Khan, Organometallics, 2021, 40, 11, 1626-1632.
25. "The Diverse Reactivity of NOBF4 towards Silylene, Disilene, Germylene and Stannylene”.
Nasrina Parvin, Nilanjana Sen, Puthan Veetil Muhasina, Srinu Tothadi, Pattiyil Parameswaran and Shabana Khan, Chem. Comm., 2021, 57, 5008-5011.
24. "Luminescent Coinage Matel Complexes of Carbenes”.
Jabed Hossain, Ruksana Akhtar and Shabana Khan, Polyhedron, 201, 2021, 115151. (Invited review).
23. "Heavier Tetrylenes as Single Site Catalysts”.
Nilanjana Sen and Shabana Khan, Chem. Asian J., 2021, 16, 1-16. (Invited review).
22. "Bis(silanetellurone) with C–H···Te Interaction”.
Moushakhi Ghosh, Prakash Panwaria, Srinu Tothadi, Aloke Das and Shabana Khan, Inorg. Chem, 2020, 59, 17811-17821.
21. "N-Heterocyclic Silylene/Germylene Ligands in Au(I) Catalysis”.
Nasrina Parvin, Bijoyananda Mishra, Anjana George, Mahesh Neralkar, Jabed Hossain, Pattiyil Parameswaran, Srinivas Hotha, Shabana Khan, Chem. Commun, 2020, 56, 7625-7628.
20. Book Chapter: "N-heterocyclic germylenes and stannylenes: Synthesis reactivity and catalytic application in a nutshell".
Rajarshi Dasgupta and Shabana Khan; Advances in Organometallic Chemistry, Elsvier, academic press, 2020, Volume 74: AID 53 (in press).
19. "N-heterocyclic silylene stabilized monocordina-ted copper(I)-arene cationic complexes and their application in Click chemistry " .
Nasrina Parvin, Jabed Hossain, Anjana George, Pattiyil Parameswaran and Shabana Khan, Chem. Commun, 2020, 56, 273-276.
18. "Cyclic Four-Membered Stanna Thio and Seleno Compounds from 2-Aminopyridinato Stannylenes " .
Nilanjana Sen, Shiv Pal, Vikas Vilas Khade and Shabana Khan, European Journal of Inorganic Chemistry, 2019 , 4450-4454.
17. "N-Heterocyclic germylene and stannylene catalyzed cyanosilylation and hydroboration of aldehydes" .
Rajarshi Dasgupta, Shubhajit Das, Shweta Hiwase, Swapan Pati and Shabana Khan, Organometallics, 2019 , 38, 7, 1429-1435.
16. "Synthesis and Photophysical Properties of PNP Based Au(I) Complexes with Strong Intramolecular Au•••Au Interaction".
Neha Kathewad, Nandha Kumar, Rajarshi Dasgupta, Moushakhi Ghosh, Shiv Pal and Shabana Khan, Dalton Transactions, 2019, DOI:10.1039/C8DT04471F.
15. "Facile Buchwald–Hartwig coupling of sterically encumbered substrates effected by PNP ligands".
Neha Kathewad, Anagha M.C., Nasrina Parvin, Sneha Parambath, Pattiyil Parameswaran and Shabana Khan, Dalton Transactions, 2019, 48, 2730-2734.
14. "Carbene Stabilized Exceptional Silicon Halides".
Shabana Khan, and Herbert W. Roesky, Chem. Eur. J., 2018 , 25, 1636-1648.
13. "Reactivity of N-heterocyclic carbene, 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, towards heavier halogens (Br2 and I2)".
Shiv Pal, Meghna A. Manae, Vikas V. Khade and Shabana Khan, J. Ind. Chem. Sci., 2018 , 95, 765-770 (Invited Contribution).
12. "Taming Monomeric [Cu(η6-C6H6)]+ Complex with Silylene".
Nasrina Parvin, Shiv Pal, Jorge Echeverría, Santiago Alvarez, and Shabana Khan, Chemical Science , 2018 , 9, 4333-4337. (selected as ChemSci Pick of the Week, selected as collection of 100 women in Chemistry and highlighted in Chemistry World).
11. "Synthetic Diversity and Luminescence Property of ArN(PPh2)2 Based Copper(I) Complexes".
Neha Kathewad, Shiv Pal, Rameshwar L. Kumawat, Ehesan Ali, and Shabana Khan, European Journal of Inorganic Chemistry , 2018 ,2518-2523 .
10. "Catalyst free boron carbon bond cleavage and facile formation of five-membered PNBCC heterocycles".
Rajarshi Dasgupta, Atanu Panda, Shiv Pal, Puthan V. Muhasina, Susmita De, Attyil Parameswaran, and Shabana Khan, Dalton Transactions , 2017 , 46, 15190-15194.
9. "Strikingly diverse reactivity of structurally identical silylene and stannylene".
Nasrina Parvin,Rajarshi Dasgupta, Shiv Pal, Sakya S. Sen and Shabana Khan, Dalton Transactions , 2017, 46, 6528-6532.
8."Unique Approach to Copper(I) Silylene Chalcogenone Complexes".
Nasrina Parvin, Shiv Pal, Shabana Khan, Shubhajit Das, Swapan K. Pati, and Herbert W. Roesky, Inorganic Chemistry, 2017 , 56, 1706–1712.
7."Acyclic α-Phosphinoamido-Germylene: Synthesis and Characterization".
Shiv Pal, Rajarshi Dasgupta, and Shabana Khan, Organometallics , 2016 , 35, 3635-3640.
6.Book Chapter: "Silene, silamine and siletane derivatives".
Shabana Khan, H. W. Roesky ; Efficient methods for preparing silicon compounds, Elsvier, academic press, 2016, 205-219, ISBN 978-0-12-803530-6.
5."Comparing Nucleophilicity of Heavier Heteroleptic Amidinato-Amido Tetrelylenes: An Experimental and Theoretical Study".
Nasrina Parvin, Shiv Pal, Vallyanga Chalil Rojisha, Susmita De, Pattiyil Parameswaran, and Shabana Khan, ChemistrySelect , 2016 ,1, 1991–1995.
4.Cover Page Communication: "Stepwise isolation of an unprecedented silylene supported dinuclear gold(I) cation with aurophilic interaction".
Shabana Khan, Shiv Pal, Neha Kathewad, Pattiyil Parameswaran, Susmita De and Indu Purushothaman, Chem. Commun.,2016,52,3880–3882.
3."Silicon(II) Bis(trimethylsilyl)amide (LSiN(SiMe3)2, L = PhC(NtBu)2) Supported Copper, Silver, and Gold Complexes".
Shabana Khan, Saurabh K. Ahirwar, Shiv Pal, Nasrina Parvin, and Neha Kathewad, Organometallics , 2015 ,34,5401–5406.
2."Synthesis, Characterization, and Luminescence Studies of Gold(I) Complexes with PNP- and PNB-Based Ligand Systems".
Shiv Pal, Neha Kathewad, Rakesh Pant, and Shabana Khan, Inorganic Chemistry , 2015 , 54, 10172-10183.
1."Cations and dications of heavier group 14 elements in low oxidation state".
V.S.V.S.N. Swamy, Shiv Pal, Shabana Khan and Sakya Singha Sen, Dalton Transactions , 2015 , 44, 12903-12923.
Published Papers From PhD and PostDoc
Published Papers From PhD and PostDoc
Book Chapter 1: Carbon-Based Frustrated Lewis Pairs.
Shabana Khan, Manuel Alcarazo; Top Curr Chem ,Springer-Verlag Berlin Heidelberg, 2012, DOI: 10.1007/128_2012_380.
1.Stabilization of Dicoordinate [GeCl]+ Cation by Simultaneous s- and p-Donation from a Monodentate Carbodiphosphorane.
Shabana Khan, Gopinadhanpillai Gopakumar, Walter Thiel, Manuel Alcarazo, Angew. Chem. Int. Ed. 2013, 52, 5644-5647
2. Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand.
Shabana Khan, Prinson P. Samuel, Reent Michel, Johannes M. Dieterich, Ricardo A. Mata, Jean-Philippe Demers, Adam Lange, Herbert W. Roesky, Dietmar Stalke, Chem. Commun. 2012, 48, 4890-4892.
3.Interconnected Bis-Silylenes: A New Dimension in Organosilicon Chemistry.
Sakya S. Sen, Shabana Khan, Selvarajan Nagendran, Herbert W. Roesky, Acc. Chem. Res. 2012, 45, 578-587.
4.Activation of phosphorus by group 14 elements in low oxidation states .
Shabana Khan, Sakya S. Sen, Herbert W. Roesky, Chem. Commun. 2012,48, 2169-2179.
5.Chemistry of functionalized silylenes.
Sakya S. Sen, Shabana Khan, Prinson P. Samuel, Herbert W. Roesky, Chem. Sci. 2012, 3, 659-682.
6. A P4 Chain and Cage from Silylene-Activated White Phosphorus .
Shabana Khan, Reent Michel, Sakya S. Sen, Herbert W. Roesky, Dietmar Stalke, Angew. Chem. Int. Ed. 2011, 50, 11786-11789.
7.Preparation of RSn(I)-Sn(I)R with Two Unsymmetrically Coordinated Sn(I) Atoms and Subsequent Gentle Activation of P4.
Shabana Khan, Reent Michel,Johannes M. Dieterich, Ricardo A. Mata, Herbert W. Roesky, Jean-Philippe Demers, Adam Lange, Dietmar Stalke. J. Am. Chem. Soc. 2011, 133, 17889-17894.
8.Reactivity Studies of a Disilene with N2O and Elemental Sulfur.
Shabana Khan, Reent Michel, Debasis Koley, Herbert W. Roesky, Dietmar Stalke, Inorg. Chem. 2011, 59, 10878-10883.
9.Formation of a Unsymmetrical Ring System via C-H Bond Activation of Diazobenzene by Stable N-Heterocyclic Chlorosilylene (PhC(NtBu)2SiCl).
Shabana Khan,Sakya S. Sen, Reent Michel, Daniel Kratzert, Herbert W. Roesky, Dietmar Stalke,Organometallics 2011, 30, 2643-2645 .
10.Synthesis of Stable Silicon Heterocycles by Reaction of Organic Substrates with a Chlorosilylene [PhC(NtBu)2SiCl].
Shabana Khan, Sakya S. Sen, Daniel Kratzert, Gasper Tavcar, Herbert W. Roesky, Dietmar Stalke, Chem. Eur. J. 2011, 17, 4283-4290.
11.Reaction of a Base-Stablilized Bis(silylene) [PhC(NtBu)2Si]2 with Cyclooctatetraene without Cleavage of the Si-Si Bond.
Sakya S. Sen, Shabana Khan, Daniel Kratzert, Herbert W. Roesky, Dietmar Stalke. Eur. J. Inorg. Chem. 2011, 1370-1373.
12.Zwitterionic Si-C-Si-P and Si-P-Si-P Four-Membered Rings with Two- Coordinate Phosphorus Atoms.
Sakya S. Sen, Shabana Khan, Herbert W. Roesky, Daniel Kratzert, Kathrin Meindl, Julian Henn, Dietmar Stalke, Jean-Philippe Demers, Adam Lange. Angew. Chem. Int. Ed. 2011, 50, 2322-2325.
13.One Pot Synthesis of disilatricycloheptene Analogue and Jutzis Disilene.
Shabana Khan, Sakya S. Sen, Herbert W. Roesky, Daniel Kratzert, Reent Michel, Dietmar Stalke. Inorg. Chem. 2010, 49, 9689-9693.
14.Sterically Encumbered Hexakis(alkylseleno)benzenes: Conformational Behavior of Hexakis(iso-propylselenomethyl)benzene Towards Hg2+ Ions on Selective Recognition.
Jai Deo Singh, Monika Maheshwari, Shabana Khan, Raymond J. Butcher, Tetrahedron Lett. 2008, 49, 117-121.
15. Organochalcogen-supported Azacalix[3]arenes as Membrane Sensor for Potentiometric Determination of Uranyl Ions.
Shabana Khan, Monika Maheshwari, Jai Deo Singh, Phosphorus, Sulphur and Silicon and Related Elements GPSS#290257, VOL 183, ISS
16. Synthesis of Sterically Encumbered Organoselenium Species and Their Selectivity Towards Hg(II) Ions.
Monika Maheshwari, Shabana Khan, Jai Deo Singh, Tetrahedron Lett. 2007, 48, 4737-4741.
17. Synthesis of Lariat Organochalcogenoethers Based on Azacalix[3]arenes for the Potentiometric Detection of UO22+ Ions.
Shabana Khan, Jai Deo Singh, Rakesh Kumar Mahajan, Pallavi Sood, Tetrahedron Lett. 2007, 48, 3605-3608.
18. A facile access to chalcogen and dichalcogen bearing dialkylamines and diols.
Marilyn Daisy Milton, Shabana Khan, Jai Deo Singh, Vivek Mishra, Bishan Lal Khandelwal, Tetrahedron Lett. 2005.
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