Google Scholar Profile

Link, h-index = 83, >230 Publications from independent research

Independent Research Publications

301. Khoshooei, M.A.; Hofmann, J.; Xie, H.M.; Vornholt, S.M.; Yoo, Y.; Sha, F.R.; Chen, Y.W.; Kirlikovali, K.O.; Chapman, K.W.; Farha, O.K., Facile Generation of Active Sites in Nodes of Ni-MFU-4l Metal-Organic Framework for Hydrogenation Reaction. ACS Mater. Lett., (2026). 8(1) 213–219. DOI: 10.1021/acsmaterialslett.5c01329

300. Lien, C.Y.; Chen, J.H.; Schouten, A.O.; Wilkinson, G.R.; Wang, D.; Hofmann, J.; Czaikowski, M.E.; Lavina, B.; Filatov, A.S.; Chapman, K.W.; Higginbotham, A.P.; Talapin, D.V.; Mazziotti, D.A.; La Pierre, H.S.; Patel, S.N.; Anderson, J.S., Spin Glass Behavior and Giant Magnetoresistance via Aliovalent Fe/Ni Alloying in Amorphous Tetrathiafulvalene-Tetrathiolate Coordination Polymers. J. Am. Chem. Soc., (2025). 147(43) 39590–39598. DOI: 10.1021/jacs.5c12985

299. Vornholt, S.M.; Ferrari, J.J.; Monserrate, B.A.S.; Mullens, B.G.; Hofmann, J.; Beauvais, M.L.; Chupas, P.J.; Chapman, K.W., Benchmarking a modern laboratory-based powder diffraction instrument for in situ studies in transmission geometry. J. Appl. Crystallogr., (2025). 58(5) 1852–1858. DOI: 10.1107/S1600576725006259

298. Jiang, N.X.; Velliyarat, S.; Lien, C.Y.; Nguyen, H.; Hofmann, J.; Chen, J.H.; Ramanathan, A.; Filatov, A.S.; La Pierre, H.S.; Patel, S.; Chapman, K.W.; Boyn, J.N.; Anderson, J.S., Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers. Chem. Sci., (2025). 16(41) 19304–19316. DOI: 10.1039/d5sc03070f

297. Rabbani, S.M.G.; Chen, Z.H.Y.; Sui, J.Y.; Hupp, J.T.; Chapman, K.W.; Getman, R.B., Elucidating the geometric and electronic structure of a fully sulfided analog of an Anderson polyoxomolybdate cluster. J. Mat. Chem. A, (2025). 13(38) 32382–32390. DOI: 10.1039/d5ta03649f

296. Celeste, A.; Girdzis, S.P.; Cladek, B.R.; Deschene, C.R.; Wolf, N.R.; Chapman, K.W.; Karunadasa, H.I.; Tucker, M.G.; Mao, W.L.; Lin, Y., Total X-ray scattering and big-box modeling of pressure-induced local disorder and partial amorphization in CsPbBr3. Nat. Commun., (2025). 16(1) . DOI: 10.1038/s41467-025-62893-6

295. Xie, H.M.; Khoshooei, M.A.; Mandal, M.; Vornholt, S.M.; Hofmann, J.; Tufaro, L.M.; Kirlikovali, K.O.; Grimes, D.A.; Lee, S.; Su, S.Y.; Reischauer, S.; Sengupta, D.; Fahy, K.; Ma, K.K.; Wang, X.L.; Sha, F.R.; Gong, W.; Che, Y.W.; Vitillo, J.G.; Anderson, J.S.; Notestein, J.M.; Chapman, K.W.; Gagliardi, L.; Farha, O.K., Introducing metal-sulfur active sites in metal-organic frameworks via post-synthetic modification for hydrogenation catalysis. Nat. Chem., (2025). 17(10) 1514–1523. DOI: 10.1038/s41557-025-01876-y

294. Lin, H.C.; Wang, Z.S.; Solares, O.; Huber, S.; Hofmann, J.; Danitz, S.; Peng, W.T.; Zhou, K.; Lee, P.C.; Liu, H.D.; Hui, Z.Y.; Liu, R.Z.; Liu, M.C.; Tang, W.; Wu, J.L.; Chen, Z.; Chapman, K.W.; Ong, S.P.; Liu, P., A Disordered Rock Salt Anode for Long-Lived All-Vanadium Sodium-Ion Battery. Adv. Mater., (2025). 37(46) . DOI: 10.1002/adma.202503143

293. Niu, Z.Y.; Yang, T.M.; Mcnarney, A.; Tufaro, L.; Vornholt, S.M.; Bourji, H.; Lv, J.; Harold, M.P.; Palmer, J.C.; Chmelka, B.F.; Chapman, K.W.; Moulton, R.; Rimer, J.D., Divergent Mechanisms of SSZ-39 Crystallization Using Structurally Similar but Chemically Distinct Organic Structure-Directing Agents. J. Am. Chem. Soc., (2025). 147(23) 19796–19807. DOI: 10.1021/jacs.5c03712

292. Mao, J.M.; Jiang, N.X.; Darù, A.; Filatov, A.S.; Burch, J.E.; Hofmann, J.; Vornholt, S.M.; Chapman, K.W.; Anderson, J.S.; Ferguson, A.L., Structure and Synthesizability of Iron-Sulfur Metal-Organic Frameworks. J. Am. Chem. Soc., (2025). 147(21) 17651–17667. DOI: 10.1021/jacs.4c16341

291. Li, J.Y.; Hofmann, J.; Stolz, R.M.; Wen, J.J.; Deschene, C.R.; Bartels, H.; Liu, Z.X.; Salleo, A.; Lin, Y.; Chapman, K.W.; Karunadasa, H.I., Suppressing Phase Transitions and High-Pressure Amorphization through Tethered Organic Cations in Organochalcogenide-Halide Perovskites. J. Am. Chem. Soc., (2025). 147(22) 19026–19038. DOI: 10.1021/jacs.5c03696

290. Beauvais, M.L.; Monserrate, B.A.S.; Mi, J.S.; Rossini, A.J.; Parise, J.B.; Chapman, K.W., Non-stoichiometry Governs the Pathway from Amorphous to Crystalline Calcium Carbonate. J. Am. Chem. Soc., (2025). 147(20) 17181–17189. DOI: 10.1021/jacs.5c02800

289. Goncalves, R.B.; Chen, Z.H.Y.; Chapman, K.W.; Snurr, R.Q.; Hupp, J.T., Experimental and theoretical investigation of hydrogen sorption by SnO2 nanostructures in a metal-organic framework scaffold. Mol. Phys., (2025). 123(21) . DOI: 10.1080/00268976.2025.2499204

288. Chen, Z.H.Y.; Vornholt, S.M.; Bryant, J.T.; Uribe-Romo, F.; Chapman, K.W., Metal-Organic Frameworks at the Edge of Stability: Mediating Node Distortion to Access Metastable Nanoparticle Polymorphs. Angew. Chem., Int. Ed. Engl., (2025). 64(27) . DOI: 10.1002/anie.202501813

287. Mullens, B.G.; Marlton, F.P.; Brand, H.E.A.; Maynard-Casely, H.E.; Everett, M.; Tucker, M.G.; Van Auken, E.R.; Manjon-Sanz, A.M.; Baldinozzi, G.; Vornholt, S.M.; Chapman, K.W.; Kennedy, B.J., The Local-Scale Origin of Ferroic Properties in BiVO4. J. Am. Chem. Soc., (2025). 147(9) 7840–7848. DOI: 10.1021/jacs.4c18032

286. Lin, H.C.; Peng, W.T.; Wang, Z.S.; Hofmann, J.; Vornholt, S.M.; Liu, H.D.; Wang, S.; Holoubek, J.; Zhou, K.; Miao, Q.S.; Huber, S.; Chapman, K.W.; Ong, S.P.; Liu, P., Increasing the Energy Density of Disordered Rock Salt Anodes for Fast-Charging Lithium-Ion Batteries. ACS Mater. Lett., (2025). 7(2) 699–706. DOI: 10.1021/acsmaterialslett.4c02086

285. Li, J.Y.; Wang, Y.; Saha, S.; Chen, Z.H.Y.; Hofmann, J.; Misleh, J.; Chapman, K.W.; Reimer, J.A.; Filip, M.R.; Karunadasa, H.I., 3D Lead-Organoselenide-Halide Perovskites and their Mixed-Chalcogenide and Mixed-Halide Alloys. Angew. Chem., Int. Ed. Engl., (2024). 63(41) . DOI: 10.1002/anie.202408443

284. Gu, R.; Rakita, Y.; Lan, L.; Thatcher, Z.; Kamm, G.E.; O'Nolan, D.; Mcbride, B.; Wustrow, A.; Neilson, J.R.; Chapman, K.W.; Du, Q.; Billinge, S.J.L., Stretched non-negative matrix factorization. Npj Comput. Mater., (2024). 10(1) . DOI: 10.1038/s41524-024-01377-5

283. Peterson, V.K.; Bianchini, M.; Chapman, K.W.; Elice, M.; Hibbert, D.B.; Roche, P.; Silvano, L.; Stievano, L., Terms of Latin origin relating to sample characterization (IUPAC Technical Report). Pure Appl. Chem., (2024). 96(11) 1531–1540. DOI: 10.1515/pac-2022-1103

282. Reischauer, S.; Smoljan, C.S.; Rabeah, J.; Xi, H.M.; Formalik, F.; Chen, Z.H.Y.; Vornholt, S.M.; Sha, F.R.; Chapman, K.W.; Snurr, R.Q.; Notestein, J.M.; Farha, O.K., A Titanium-Based Metal-Organic Framework For Tandem Metallaphotocatalysis. ACS Appl. Mater. Interfaces, (2024). 16(26) 33371–33378. DOI: 10.1021/acsami.4c03651

281. Vornholt, S.M.; Chen, Z.; Hofmann, J.; Chapman, K.W., Node Distortions in UiO-66 Inform Negative Thermal Expansion Mechanisms: Kinetic Effects, Frustration, and Lattice Hysteresis. J. Am. Chem. Soc., (2024). 146(25) 16977–16981. DOI: 10.1021/jacs.4c05313

280. Auras, F.; Ascherl, L.; Bon, V.; Vornholt, S.M.; Krause, S.; Doeblinger, M.; Bessinger, D.; Reuter, S.; Chapman, K.W.; Kaskel, S.; Friend, R.H.; Bein, T., Dynamic two-dimensional covalent organic frameworks. Nat. Chem., (2024). 16(8) 1373–1380. DOI: 10.1038/s41557-024-01527-8

279. Monserrate, B.A.S.; Beauvais, M.L.; Vornholt, S.M.; Chupas, P.J.; Parise, J.B.; Chapman, K.W., Real-Time Multiscale Imaging of Heterogeneous Multistage Reactions: Insights into Nanoscale TiO2 Synthesis. J. Am. Chem. Soc., (2024). 146(15) 10745–10752. DOI: 10.1021/jacs.4c00749

278. Chen, Z.H.Y.; Rabbani, S.M.G.; Liu, Q.; Bi, W.T.; Duan, J.X.; Lu, Z.Y.; Schweitzer, N.M.; Getman, R.B.; Hupp, J.T.; Chapman, K.W., Atomically Precise Single-Site Catalysts via Exsolution in a Polyoxometalate-Metal-Organic-Framework Architecture. J. Am. Chem. Soc., (2024). 146(12) 7950–7955. DOI: 10.1021/jacs.4c00523

277. Hu, D.; Beauvais, M.L.; Mullens, B.G.; Monserrate, B.A.S.; Vornholt, S.M.; Kamm, G.E.; Ferrari, J.J.; Chupas, P.J.; Chapman, K.W., The RAPTR furnace: a rapid heating and cooling sample furnace for in situ X-ray scattering studies of temperature-induced reactions. J. Appl. Crystallogr., (2024). 57(1) 88–93. DOI: 10.1107/S1600576723011020

276. Wang, X.L.; Alzayer, M.; Shih, A.J.; Bose, S.; Xie, H.M.; Vornholt, S.M.; Malliakas, C.D.; Alhashem, H.; Joodaki, F.; Marzouk, S.; Xiong, G.C.; Del Campo, M.; Le Magueres, P.; Formalik, F.; Sengupta, D.; Idrees, K.B.; Ma, K.K.; Chen, Y.W.; Kirlikovali, K.O.; Islamoglu, T.; Chapman, K.W.; Snurr, R.Q.; Farha, O.K., Tailoring Hydrophobicity and Pore Environment in Physisorbents for Improved Carbon Dioxide Capture under High Humidity. J. Am. Chem. Soc., (2024). 146(6) 3943–3954. DOI: 10.1021/jacs.3c11671

275. Lee, S.; Xie, H.M.; Chen, Z.H.Y.; Mian, M.R.; Gómez-Torres, A.; Syed, Z.H.; Reischauer, S.; Chapman, K.W.; Delferro, M.; Farha, O.K., Metal-Organic Frameworks as a Tunable Platform to Deconvolute Stereoelectronic Effects on the Catalytic Activity of Thioanisole Oxidation. J. Am. Chem. Soc., (2024). 146(6) 3955–3962. DOI: 10.1021/jacs.3c11809

274. Barsoum, M.L.; Hofmann, J.; Xie, H.M.; Chen, Z.H.Y.; Vornholt, S.M.; dos Reis, R.; Burns, N.; Kycia, S.; Chapman, K.W.; Dravid, V.P.; Farha, O.K., Probing Structural Transformations and Degradation Mechanisms by Direct Observation in SIFSIX-3-Ni for Direct Air Capture. J. Am. Chem. Soc., (2024). 146(10) 6557–6565. DOI: 10.1021/jacs.3c11503

273. Tran, G.T.; Wustrow, A.; O'Nolan, D.; Tao, S.S.; Bartel, C.J.; He, T.J.; Mcdermott, M.J.; Mcbride, B.C.; Chapman, K.W.; Billinge, S.J.L.; Persson, K.A.; Ceder, G.; Neilson, J.R., Selective Synthesis of Defect-Rich LaMnO3 by Low-Temperature Anion Cometathesis. Inorg. Chem., (2023). 63(7) 3250–3257. DOI: 10.1021/acs.inorgchem.3c03305

272. Monserrate, B.A.S.; Grenier, A.; Chupas, P.J.; Chapman, K.W., A high-temperature sample changer for parallelized in situ X-ray studies to efficiently explore reaction space. J. Appl. Crystallogr., (2023). 56(6) 1732–1738. DOI: 10.1107/S160057672300907X

271. Kamm, G.E.; Hu, D.R.; Chapman, K.W., Considerations for quantitative in situ X-ray powder diffraction studies of solid-state reactions. J. Appl. Crystallogr., (2023). 56(6) 1879–1881. DOI: 10.1107/S160057672301021X

270. Hu, D.R.; Beauvais, M.L.; Kamm, G.E.; Mullens, B.G.; Monserrate, B.A.S.; Vornholt, S.M.; Chupas, P.J.; Chapman, K.W., Resolving Fast Relative Kinetics in Inorganic Solid-State Synthesis. J. Am. Chem. Soc., (2023). 145(49) 26545–26549. DOI: 10.1021/jacs.3c10916

269. Dawkins, J.I.G.; Pan, Y.N.; Ghavidel, M.Z.; Geissler, J.; Krueger, B.; Chhin, D.; Yuan, H.; Tong, V.; Pelletier-Villeneuve, B.; Feng, R.F.; Botton, G.A.; Chapman, K.W.; Mauzeroll, J.; Schougaard, S.B., Exploring the Synergistic Effects of Dual-Layer Electrodes for High Power Li-Ion Batteries. CHEMELECTROCHEM, (2023). 10(21) . DOI: 10.1002/celc.202300279

268. Ritchhart, A.; Chen, Z.H.Y.; Behera, A.; Jeon, I.R.; Chapman, K.W.; Vaikuntanathan, S.; Anderson, J.S., Cluster-Spin-Glass Magnetic Behavior and Morphology in the Coordination Polymer Alloys FeyCo1-yBTT. J. Am. Chem. Soc., (2023). 145(44) 24089–24097. DOI: 10.1021/jacs.3c07527

267. Mcdermott, M.J.; Mcbride, B.C.; Regier, C.E.; Tran, G.T.; Chen, Y.; Corrao, A.A.; Gallant, M.C.; Kamm, G.E.; Bartel, C.J.; Chapman, K.W.; Khalifah, P.G.; Ceder, G.; Neilson, J.R.; Persson, K.A., Assessing Thermodynamic Selectivity of Solid-State Reactions for the Predictive Synthesis of Inorganic Materials. ACS Cent. Sci., (2023). 9(10) 1957–1975. DOI: 10.1021/acscentsci.3c01051

266. Chen, Z.H.Y.; Ho, C.H.; Wang, X.L.; Vornholt, S.M.; Rayder, T.M.; Islamoglu, T.; Farha, O.K.; Paesani, F.; Chapman, K.W., Humidity-Responsive Polymorphism in CALF-20: A Resilient MOF Physisorbent for CO2 Capture. ACS Mater. Lett., (2023). 5(11) 2942–2947. DOI: 10.1021/acsmaterialslett.3c00930

265. Wolfman, M.; May, B.M.; Goel, V.; Du, S.C.; Yu, Y.S.; Faenza, N.V.; Pereira, N.; Grenier, A.; Wiaderek, K.M.; Xu, R.Q.; Wang, J.J.; Chapman, K.W.; Amatucci, G.G.; Thornton, K.; Cabana, J., Origin of Rapid Delithiation In Secondary Particles Of LiNi0.8Co0.15Al0.05O2 and LiNiyMnzCo1-y-zO2 Cathodes. ADVANCED ENERGY MATERIALS, (2023). 13(37) . DOI: 10.1002/aenm.202300895

264. Small, L.J.; Vornholt, S.M.; Percival, S.J.; Meyerson, M.L.; Schindelholz, M.E.; Chapman, K.W.; Nenoff, T.M., Impedance-Based Detection of NO2 Using Ni-MOF-74: Influence of Competitive Gas Adsorption. ACS Appl. Mater. Interfaces, (2023). 15(31) 37675–37686. DOI: 10.1021/acsami.3c06864

263. Rayder, T.M.; Formalik, F.; Vornholt, S.M.; Frank, H.; Lee, S.; Alzayer, M.; Chen, Z.H.Y.; Sengupta, D.; Islamoglu, T.; Paesani, F.; Chapman, K.W.; Snurr, R.Q.; Farha, O.K., Unveiling Unexpected Modulator-CO2 Dynamics within a Zirconium Metal-Organic Framework. J. Am. Chem. Soc., (2023). 145(20) 11195–11205. DOI: 10.1021/jacs.3c01146

262. Yoon, Y.H.; 'Nolan, D.O.; Beauvais, M.L.; Chapman, K.W.; Lively, R.P., Direct evidence of the ultramicroporous structure of carbon molecular sieves. CARBON, (2023). 210 . DOI: 10.1016/j.carbon.2023.118002

261. Duan, J.X.; Shabbir, H.; Chen, Z.H.Y.; Bi, W.T.; Liu, Q.; Sui, J.Y.; Dordevic, L.; Stupp, S.I.; Chapman, K.W.; Martinson, A.B.F.; Li, A.L.C.; Schaller, R.D.; Goswami, S.; Getman, R.B.; Hupp, J.T., Synthetic Access to a Framework-Stabilized and Fully Sulfided Analogue of an Anderson Polyoxometalate that is Catalytically Competent for Reduction Reactions. J. Am. Chem. Soc., (2023). 145(13) 7268–7277. DOI: 10.1021/jacs.2c12992

260. Chen, Z.H.Y.; Beauvais, M.L.; Chapman, K.W., Pair distribution function analysis of discrete nanomaterials in PDFgui. J. Appl. Crystallogr., (2023). 56(2) 328–337. DOI: 10.1107/S1600576723000237

259. Bryant, J.T.; Logan, M.W.; Chen, Z.H.Y.; Djokic, M.; Cairnie, D.R.; Vazquez-Molina, D.A.; Nijamudheen, A.; Langlois, K.R.; Markley, M.J.; Pombar, G.; Holland, A.A.; Caranto, J.D.; Harper, J.K.; Morris, A.J.; Mendoza-Cortes, J.L.; Jurca, T.; Chapman, K.W.; Uribe-Romo, F.J., Synergistic Steric and Electronic Effects on the Photoredox Catalysis by a Multivariate Library of Titania Metal-Organic Frameworks. J. Am. Chem. Soc., (2023). 147(27) 17651–17667. DOI: 10.1021/jacs.2c12147

258. McAuliffe, R.D.; Kamm, G.E.; McDermott, M.J.; Hermann, R.P.; Vasquez-Garcia, N.; Sacci, R.L.; Persson, K.A.; Chapman, K.W.; Veith, G.M., Direct Mechanochemical Synthesis, Phase Stability, and Electrochemical Performance of α-NaFeO2. Inorg. Chem., (2023). 61(18) 6829–6836. DOI: 10.1021/acs.inorgchem.2c03286

257. Chapman, K.W.; Hu, Y.S.; See, K.A.; Sun, Y.K., Advances in Solid-State Batteries, a Virtual Issue, Part II. ACS ENERGY LETTERS, (2023). 8(2) 1215–1217. DOI: 10.1021/acsenergylett.3c00085

256. Vicchio, S.P.; Chen, Z.H.Y.; Chapman, K.W.; Getman, R.B., Computational and Experimental Characterization of the Ligand Environment of a Ni-Oxo Catalyst Supported in the Metal-Organic Framework NU-1000. J. Am. Chem. Soc., (2023). 147(31) 12090–12099. DOI: 10.1021/jacs.2c10554

255. Hidalgo, M.F.V.; Buyuker, I.S.; Kamm, G.E.; Zhu, Z.Y.; Grenier, A.; Zuba, M.J.; Deng, Z.; Zong, Y.X.; Kaplan, C.; Chernova, N.A.; Zhou, G.W.; Piper, L.F.J.; Ong, S.P.; Chapman, K.W.; Whittingham, M.S., Probing how Ti- and Nb-substitution affect the stability and improve the electrochemical performance of β- and ε-LiVOPO4. J. Mat. Chem. A, (2023). 11(5) 2273–2290. DOI: 10.1039/d2ta08184a

254. Chen, Z.H.Y.; Stroscio, G.D.; Liu, J.; Lu, Z.Y.; Hupp, J.T.; Gagliardi, L.; Chapman, K.W., Node Distortion as a Tunable Mechanism for Negative Thermal Expansion in Metal-Organic Frameworks. J. Am. Chem. Soc., (2023). 145(1) 268–276. DOI: 10.1021/jacs.2c09877

253. Li, J.Y.; Chen, Z.H.Y.; Saha, S.; Utterback, J.K.; Aubrey, M.L.; Yuan, R.F.; Weaver, H.L.; Ginsberg, N.S.; Chapman, K.W.; Filip, M.R.; Karunadasa, H.I., Zwitterions in 3D Perovskites: Organosulfide-Halide Perovskites. J. Am. Chem. Soc., (2022). 147(22) 19026–19038. DOI: 10.1021/jacs.2c09382

252. Wang, X.J.; Syed, Z.H.; Chen, Z.H.Y.; Bazak, J.D.; Gong, X.Y.; Wasson, M.C.; Washton, N.M.; Chapman, K.W.; Notestein, J.M.; Farha, O.K., Enhanced Catalytic Performance of a Ce/V Oxo Cluster through Confinement in Mesoporous SBA-15. ACS Appl. Mater. Interfaces, (2022). 14(47) 52886–52893. DOI: 10.1021/acsami.2c15046

251. Carrington, M.E.; Rampal, N.; Madden, D.G.; O'Nolan, D.; Casati, N.P.M.; Divitini, G.; Martín-Illán, J.A.; Tricarico, M.; Cepitis, R.; Çamur, C.; Curtin, T.; Silvestre-Albero, J.; Tan, J.C.; Zamora, F.; Taraskin, S.; Chapman, K.W.; Fairen-Jimenez, D., Sol-gel processing of a covalent organic framework for the generation of hierarchically porous monolithic adsorbents. Chem, (2022). 8(11) 2961–2977. DOI: 10.1016/j.chempr.2022.07.013

250. Xie, J.Z.; Ewing, S.; Boyn, J.N.; Filatov, A.S.; Cheng, B.R.; Ma, T.Z.; Grocke, G.L.; Zhao, N.; Itani, R.; Sun, X.T.; Cho, H.; Chen, Z.H.Y.; Chapman, K.W.; Patel, S.N.; Talapin, D.; Park, J.; Mazziotti, D.A.; Anderson, J.S., Intrinsic glassy-metallic transport in an amorphous coordination polymer. NATURE, (2022). 611(7936) 479. DOI: 10.1038/s41586-022-05261-4

249. Syed, Z.H.; Mian, M.R.; Patel, R.; Xie, H.M.; Pengmei, Z.; Chen, Z.H.Y.; Son, F.A.; Goetjen, T.A.; Chapovetsky, A.; Fahy, K.M.; Sha, F.R.; Wang, X.J.; Alayoglu, S.; Kaphan, D.M.; Chapman, K.W.; Neurock, M.; Gagliardi, L.; Delferro, M.; Farha, O.K., Sulfated Zirconium Metal-Organic Frameworks as Well-Defined Supports for Enhancing Organometallic Catalysis. J. Am. Chem. Soc., (2022). 144(37) 16883–16897. DOI: 10.1021/jacs.2c05290

248. Liu, Q.; Chen, Z.H.Y.; Shabbir, H.; Duan, J.X.; Bi, W.T.; Lu, Z.Y.; Schweitzer, N.; Alayoglu, S.; Goswami, S.; Chapman, K.W.; Getman, R.B.; Wang, Q.N.; Notestein, J.M.; Hupp, J.T., Presentation of gas-phase-reactant-accessible single-rhodium-atom catalysts for CO oxidation, via MOF confinement of an Anderson polyoxometalate. J. Mat. Chem. A, (2022). 10(35) 18226–18234. DOI: 10.1039/d2ta03975c

247. Chung, H.Y.S.; Li, Y.X.; Zhang, M.H.; Grenier, A.; Mejia, C.; Cheng, D.Y.; Sayahpour, B.; Song, C.Y.; Shen, M.H.; Huang, R.C.Y.; Wu, E.A.; Chapman, K.W.; Kim, S.J.; Meng, Y.S., Mitigating Anisotropic Changes in Classical Layered Oxide Materials by Controlled Twin Boundary Defects for Long Cycle Life Li-Ion Batteries. Chem. Mater., (2022). 34(16) 7302–7312. DOI: 10.1021/acs.chemmater.2c01234

246. Madden, D.G.; O'Nolan, D.; Rampal, N.; Babu, R.; Camur, C.; Al Shakhs, A.N.; Zhang, S.Y.; Rance, G.A.; Perez, J.; Casati, N.P.M.; Cuadrado-Collados, C.; O'Sullivan, D.; Rice, N.P.; Gennett, T.; Parilla, P.; Shulda, S.; Hurst, K.E.; Stavila, V.; Allendorf, M.D.; Silvestre-Albero, J.; Forse, A.C.; Champness, N.R.; Chapman, K.W.; Fairen-Jimenez, D., Densified HKUST-1 Monoliths as a Route to High Volumetric and Gravimetric Hydrogen Storage Capacity. J. Am. Chem. Soc., (2022). 144(30) 13729–13739. DOI: 10.1021/jacs.2c04608

245. Petrova, V.; Corrao, A.A.; Wang, S.; Xiao, Y.X.; Chapman, K.W.; Fullerton, E.E.; Khalifah, P.G.; Liu, P., Synthesis of flexible Co nanowires from bulk precursors. RSC Adv., (2022). 12(33) 21153–21159. DOI: 10.1039/d2ra03790d

244. Kamm, G.E.; Huang, G.L.; Vornholt, S.M.; McAuliffe, R.D.; Veith, G.M.; Thornton, K.S.; Chapman, K.W., Relative Kinetics of Solid-State Reactions: The Role of Architecture in Controlling Reactivity. J. Am. Chem. Soc., (2022). 144(27) 11975–11979. DOI: 10.1021/jacs.2c05043

243. Wustrow, A.; McDermott, M.J.; O'Nolan, D.; Liu, C.H.; Tran, G.T.; McBride, B.C.; Vornholt, S.M.; Feng, C.; Dwaraknath, S.S.; Chapman, K.W.; Billinge, S.J.L.; Sun, W.H.; Persson, K.A.; Neilson, J.R., Reaction Selectivity in Cometathesis: Yttrium Manganese Oxides. Chem. Mater., (2022). 34(10) 4694–4702. DOI: 10.1021/acs.chemmater.2c00636

242. Beauvais, M.L.; Monserrate, B.A.S.; Feng, T.S.; Chen, R.K.; Liu, P.; Chupas, P.J.; Chapman, K.W., A mixing-flow reactor for time-resolved reaction measurements distributed in space. J. Appl. Crystallogr., (2022). 55(2) 258–264. DOI: 10.1107/S1600576722000620

241. Platero-Prats, A.E.; Mavrandonakis, A.; Liu, J.; Chen, Z.H.Y.; Chen, Z.J.; Li, Z.Y.; Yakovenko, A.A.; Gallington, L.C.; Hupp, J.T.; Farha, O.K.; Cramer, C.J.; Chapman, K.W., The Molecular Path Approaching the Active Site in Catalytic Metal-Organic Frameworks. J. Am. Chem. Soc., (2021). 143(48) 20090–20094. DOI: 10.1021/jacs.1c11213

240. Russell, S.E.; Henkelis, S.E.; Vornholt, S.M.; Rainer, D.N.; Chapman, K.W.; Morris, R.E., In situ flow pair distribution function analysis to probe the assembly-disassembly-organisation-reassembly (ADOR) mechanism of zeolite IPC-2 synthesis. Mater Adv, (2021). 2(24) 7949–7955. DOI: 10.1039/d1ma00335f

239. Rimsza, J.M.; Chapman, K.W.; Nenoff, T.M., Influence of Al location on formation of silver clusters in mordenite. Microporous Mesoporous Mater., (2021). 327 . DOI: 10.1016/j.micromeso.2021.111401

238. O'Nolan, D.; Zhao, H.Y.; Chen, Z.H.Y.; Grenier, A.; Beauvais, M.L.; Newton, M.A.; Nenoff, T.M.; Chupas, P.J.; Chapman, K.W., A multimodal analytical toolkit to resolve correlated reaction pathways: the case of nanoparticle formation in zeolites. Chem. Sci., (2021). 12(41) 13836–13847. DOI: 10.1039/d1sc04232g

237. Yang, Y.; Noh, H.; Ma, Q.; Wang, R.; Chen, Z.H.Y.; Schweitzer, N.M.; Liu, J.; Chapman, K.W.; Hupp, J.T., Engineering Dendrimer-Templated, Metal-Organic Framework-Confined Zero-Valent, Transition-Metal Catalysts. ACS Appl. Mater. Interfaces, (2021). 13(30) 36232–36239. DOI: 10.1021/acsami.1c11541

236. Vaughn, B.A.; Koller, A.J.; Chen, Z.H.Y.; Ahn, S.H.; Loveless, C.S.; Cingoranelli, S.J.; Yang, Y.; Cirri, A.; Johnson, C.J.; Lapi, S.E.; Chapman, K.W.; Boros, E., Homologous Structural, Chemical, and Biological Behavior of Sc and Lu Complexes of the Picaga Bifunctional Chelator: Toward Development of Matched Theranostic Pairs for Radiopharmaceutical Applications. Bioconjugate Chem., (2021). 32(7) 1232–1241. DOI: 10.1021/acs.bioconjchem.0c00574

235. Chen, Z.H.Y.; Chen, Z.J.; Farha, O.K.; Chapman, K.W., Mechanistic Insights into Nanoparticle Formation from Bimetallic Metal-Organic Frameworks. J. Am. Chem. Soc., (2021). 143(24) 8976–8980. DOI: 10.1021/jacs.1c04269

234. Liu, C.H.; Wright, C.J.; Gu, R.; Bandi, S.; Wustrow, A.; Todd, P.K.; O'Nolan, D.; Beauvais, M.L.; Neilson, J.R.; Chupas, P.J.; Chapman, K.W.; Billinge, S.J.L., Validation of non-negative matrix factorization for rapid assessment of large sets of atomic pair distribution function data. J. Appl. Crystallogr., (2021). 54(3) 768–775. DOI: 10.1107/S160057672100265X

233. Wustrow, A.; Huang, G.L.; McDermott, M.J.; O'Nolan, D.; Liu, C.H.; Tran, G.T.; McBride, B.C.; Dwaraknath, S.S.; Chapman, K.W.; Billinge, S.J.L.; Persson, K.A.; Thornton, K.; Neilson, J.R., Lowering Ternary Oxide Synthesis Temperatures by Solid-State Cometathesis Reactions. Chem. Mater., (2021). 33(10) 3692–3701. DOI: 10.1021/acs.chemmater.1c00700

232. Beauvais, M.L.; Chupas, P.J.; O'Nolan, D.; Parise, J.B.; Chapman, K.W., Resolving Single-layer Nanosheets as Short-lived Intermediates in the Solution Synthesis of FeS. ACS Mater. Lett., (2021). 3(6) 698–703. DOI: 10.1021/acsmaterialslett.1c00193

231. Grenier, A.; Kamm, G.E.; Li, Y.X.; Chung, H.; Meng, Y.S.; Chapman, K.W., Nanostructure Transformation as a Signature of Oxygen Redox in Li-Rich 3d and 4d Cathodes. J. Am. Chem. Soc., (2021). 143(15) 5763–5770. DOI: 10.1021/jacs.1c00497

230. Wu, E.A.; Banerjee, S.; Tang, H.M.; Richardson, P.M.; Doux, J.M.; Qi, J.; Zhu, Z.Y.; Grenier, A.; Li, Y.X.; Zhao, E.Y.; Deysher, G.; Sebti, E.; Nguyen, H.; Stephens, R.; Verbist, G.; Chapman, K.W.; Clément, R.J.; Banerjee, A.; Meng, Y.S.; Ong, S.P., A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries. Nat. Commun., (2021). 12(1) . DOI: 10.1038/s41467-021-21488-7

229. Zuba, M.J.; Grenier, A.; Lebens-Higgins, Z.; Fajardo, G.J.P.; Li, Y.X.; Ha, Y.; Zhou, H.; Whittingham, M.S.; Yang, W.L.; Meng, Y.S.; Chapman, K.W.; Piper, L.F.J., Whither Mn Oxidation in Mn-Rich Alkali-Excess Cathodes?. ACS ENERGY LETTERS, (2021). 6(3) 1055–1064. DOI: 10.1021/acsenergylett.0c02418

228. Chung, H.; Lebens-Higgins, Z.; Sayahpour, B.; Mejia, C.; Grenier, A.; Kamm, G.E.; Li, Y.X.; Huang, R.; Piper, L.F.J.; Chapman, K.W.; Doux, J.M.; Meng, Y.S., Experimental considerations to study Li-excess disordered rock salt cathode materials. J. Mat. Chem. A, (2021). 9(3) 1720–1732. DOI: 10.1039/d0ta07836k

227. Hua, X.; Eggeman, A.S.; Castillo-Martínez, E.; Robert, R.; Geddes, H.S.; Lu, Z.H.; Pickard, C.J.; Meng, W.; Wiaderek, K.M.; Pereira, N.; Amatucci, G.G.; Midgley, P.A.; Chapman, K.W.; Steiner, U.; Goodwin, A.L.; Grey, C.P., Revisiting metal fluorides as lithium-ion battery cathodes. Nat. Mater., (2021). 20(6) 841. DOI: 10.1038/s41563-020-00893-1

226. Girdzis, S.P.; Lin, Y.; Leppert, L.; Slavney, A.H.; Park, S.; Chapman, K.W.; Karunadasa, H.; Mao, W.L., Revealing Local Disorder in a Silver-Bismuth Halide Perovskite upon Compression. J. Phys. Chem. Lett., (2021). 12(1) 532–536. DOI: 10.1021/acs.jpclett.0c03412

225. Chung, H.; Lebens-Higgins, Z.; Sayahpour, B.; Mejia, C.; Grenier, A.; Kamm, G.E.; Li, Y.; Huang, R.; Piper, L.F.J.; Chapman, K.W.; Doux, J.-M.; Meng, Y.S., Experimental considerations to study Li-excess disordered rock salt cathode materials. J. Mat. Chem. A, (2021). 9(3) 1720-1732. DOI: 10.1039/D0TA07836K.

224. Nagatomi, H.; Gallington, L.C.; Goswami, S.; Duan, J.; Chapman, K.W.; Yanai, N.; Kimizuka, N.; Farha, O.K.; Hupp, J.T., Regioselective Functionalization of the Mesoporous Metal–Organic Framework, NU-1000, with Photo-Active Tris-(2,2′-bipyridine)ruthenium(II). ACS Omega, (2020). 5(46) 30299-30305. DOI: 10.1021/acsomega.0c04823.

223. Hackler, R.A.; Pandharkar, R.; Ferrandon, M.S.; Kim, I.S.; Vermeulen, N.A.; Gallington, L.C.; Chapman, K.W.; Farha, O.K.; Cramer, C.J.; Sauer, J.; Gagliardi, L.; Martinson, A.B.F.; Delferro, M., Isomerization and Selective Hydrogenation of Propyne: Screening of Metal–Organic Frameworks Modified by Atomic Layer Deposition. J. Am. Chem. Soc., (2020). 142(48) 20380-20389. DOI: 10.1021/jacs.0c08641.

222. Todd, P.K.; Wustrow, A.; McAuliffe, R.D.; McDermott, M.J.; Tran, G.T.; McBride, B.C.; Boeding, E.D.; O’Nolan, D.; Liu, C.-H.; Dwaraknath, S.S.; Chapman, K.W.; Billinge, S.J.L.; Persson, K.A.; Huq, A.; Veith, G.M.; Neilson, J.R., Defect-Accommodating Intermediates Yield Selective Low-Temperature Synthesis of YMnO3 Polymorphs. Inorg. Chem., (2020). 59(18) 13639-13650. DOI: 10.1021/acs.inorgchem.0c02023.

221. Rimsza, J.M.; Chapman, K.W.; Nenoff, T.M., Energetics and Structure of Ag–Water Clusters Formed in Mordenite. J. Phys. Chem. C, (2020). DOI: 10.1021/acs.jpcc.9b08983.

220. Rakita, Y.; O’Nolan, D.; McAuliffe, R.D.; Veith, G.M.; Chupas, P.J.; Billinge, S.J.L.; Chapman, K.W., Active Reaction Control of Cu Redox State Based on Real-Time Feedback from In Situ Synchrotron Measurements. J. Am. Chem. Soc., (2020). 142(44) 18758–18762. DOI: 10.1021/jacs.0c09418.

219. O'Nolan, D.; Huang, G.; Kamm, G.E.; Grenier, A.; Liu, C.-H.; Todd, P.K.; Wustrow, A.; Tran Thinh, G.; Montiel, D.; Neilson, J.R.; Billinge, S.J.L.; Chupas, P.J.; Thornton, K.S.; Chapman, K.W., A thermal-gradient approach to variable-temperature measurements resolved in space. J. Appl. Crystallogr., (2020). 53 662-670.

218. Liu, H.; Li, Z.; Grenier, A.; Kamm, G.E.; Yin, L.; Mattei, G.S.; Cosby, M.R.; Khalifah, P.G.; Chupas, P.J.; Chapman, K.W., Best practices for operando depth-resolving battery experiments. J. Appl. Crystallogr., (2020). 53(1) 133-139. DOI: doi:10.1107/S1600576719016315.

217. Li, Z.; Yin, L.; Mattei, G.S.; Cosby, M.R.; Lee, B.-S.; Wu, Z.; Bak, S.-M.; Chapman, K.W.; Yang, X.-Q.; Liu, P.; Khalifah, P.G., Synchrotron Operando Depth Profiling Studies of State-of-Charge Gradients in Thick Li(Ni0.8Mn0.1Co0.1)O2 Cathode Films. Chem. Mater., (2020). 32(15) 6358-6364. DOI: 10.1021/acs.chemmater.0c00983.

216. Grenier, A.; Reeves, P.J.; Liu, H.; Seymour, I.D.; Märker, K.; Wiaderek, K.M.; Chupas, P.J.; Grey, C.P.; Chapman, K.W., Intrinsic Kinetic Limitations in Substituted Lithium-Layered Transition-Metal Oxide Electrodes. J. Am. Chem. Soc., (2020). 142(15) 7001-7011. DOI: 10.1021/jacs.9b13551.

215. Cosby, M.R.; Mattei, G.S.; Wang, Y.; Li, Z.; Bechtold, N.; Chapman, K.W.; Khalifah, P.G., Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies. J. Phys. Chem. C, (2020). 124(12) 6522-6527. DOI: 10.1021/acs.jpcc.0c00067.

214. Tran, N.; Spindler, B.D.; Yakovenko, A.A.; Wiaderek, K.M.;Chapman, K.W.; Huang, S.; Smyrl, W.H.; Truhlar, D.G.; Stein, A., Effective Electrochemical Charge Storage in the High-Lithium Compound Li8ZrO6. ACS Appl. Energy Mater., (2019). 2(2) 1274-1287.

213. Tian, Y.; Sun, Y.; Hannah, D.C.; Xiao, Y.; Liu, H.; Chapman, K.W.; Bo, S.-H.; Ceder, G., Reactivity-Guided Interface Design in Na Metal Solid-State Batteries. Joule, (2019). 3(4) 1037-1050. DOI: https://doi.org/10.1016/j.joule.2018.12.019.

212. Zhang, J.Y.; Longley, L.; Liu, H.; Ashling, C.W.; Chater, P.A.; Beyer, K.A.; Chapman, K.W.; Tao, H.Z.; Keen, D.A.; Bennett, T.D.; Yue, Y.Z., Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment. Chem. Commun., (2019). 55(17) 2521-2524.

211. Small, L.J.; Hill, R.C.; Krumhansl, J.L.; Schindelholz, M.E.; Chen, Z.H.Y.; Chapman, K.W.; Zhang, X.R.; Yang, S.H.; Schroder, M.; Nenoff, T.M., Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas. ACS Appl. Mater. Interfaces, (2019). 11(31) 27982-27988.

210. Shi, Y.; Zhou, H.; Britto, S.; Seymour, I.D.; Wiaderek, K.M.; Omenya, F.; Chernova, N.A.; Chapman, K.W.; Grey, C.P.; Whittingham, M.S., A high-performance solid-state synthesized LiVOPO4 for lithium-ion batteries. Electrochem. Commun., (2019). 105 6.

209. Redfern, L.R.; Robison, L.; Wasson, M.C.; Goswami, S.; Lyu, J.F.; Islamoglu, T.; Chapman, K.W.; Farha, O.K., Porosity Dependence of Compression and Lattice Rigidity in Metal-Organic Framework Series. J. Am. Chem. Soc., (2019). 141(10) 4365-4371.

208. Liu, H.; Kazemiabnavi, S.; Grenier, A.; Vaughan, G.; Di Michiel, M.; Polzin, B.J.; Thornton, K.; Chapman, K.W.; Chupas, P.J., Quantifying Reaction and Rate Heterogeneity in Battery Electrodes in 3D through Operando X-ray Diffraction Computed Tomography. ACS Appl. Mater. Interfaces, (2019). 11(20) 18386-18394.

207. Kamysbayev, V.; Srivastava, V.; Ludwig, N.B.; Borkiewicz, O.J.; Zhang, H.; Ilavsky, J.; Lee, B.; Chapman, K.W.; Vaikuntanathan, S.; Talapin, D.V., Nanocrystals in Molten Salts and Ionic Liquids: Experimental Observation of Ionic Correlations Extending beyond the Debye Length. ACS Nano, (2019). 13(5) 5760-5770.

206. Hidalgo, M.F.; Lin, Y.C.; Grenier, A.; Xiao, D.D.; Rana, J.; Tran, R.; Xin, H.L.; Zuba, M.; Donohue, J.; Omenya, F.O.; Chu, I.H.; Wang, Z.B.; Li, X.G.; Chernova, N.A.; Chapman, K.W.; Zhou, G.W.; Piper, L.; Ong, S.P.; Whittingham, M.S., Rational synthesis and electrochemical performance of LiVOPO4 polymorphs. J. Mater. Chem. A, (2019). 7(14) 8423-8432.

205. Goswami, S.; Noh, H.; Redfern, L.R.; Otake, K.; Kung, C.W.; Cui, Y.X.; Chapman, K.W.; Farha, O.K.; Hupp, J.T., Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal-Organic Framework. Chem. Mat., (2019). 31(5) 1485-1490.

204. Gochez, R.; Chapman, K.W.; Wambaugh, J.; Kitchens, C.L., Phosphoric acid-modified magnesium oxychloride: Study of water stability, kinetics, and pair distribution function. J. Am. Ceram. Soc., (2019). 102(6) 3728-3737.

203. Eremenko, M.; Krayzman, V.; Bosak, A.; Playford, H.Y.; Chapman, K.W.; Woicik, J.C.; Ravel, B.; Levin, I., Local atomic order and hierarchical polar nanoregions in a classical relaxor ferroelectric. Nat. Commun., (2019). 10 9.

202. Chung, H.; Grenier, A.; Huang, R.; Wang, X.F.; Lebens-Higgins, Z.; Doux, J.M.; Sallis, S.; Song, C.Y.; Ercius, P.; Chapman, K.; Piper, L.F.J.; Cho, H.M.; Zhang, M.H.; Meng, Y.S., Comprehensive study of a versatile polyol synthesis approach for cathode materials for Li-ion batteries. Nano Res., (2019). 12(9) 2238-2249.

201. Burbano, M.; Duttine, M.; Morgan, B.J.; Borkiewicz, O.J.; Chapman, K.W.; Wattiaux, A.; Demourgues, A.; Groult, H.; Salanne, M.; Dambournet, D., Impact of Anion Vacancies on the Local and Electronic Structures of Iron-Based Oxyfluoride Electrodes. J. Phys. Chem. Lett., (2019). 10(1) 107-112.

200. Bassett, K.L.; Warburton, R.E.; Deshpande, S.; Fister, T.T.; Ta, K.; Esbenshade, J.L.; Kinaci, A.; Chan, M.K.Y.; Wiaderek, K.M.; Chapman, K.W.; Greeley, J.P.; Gewirth, A.A., Operando Observations and First-Principles Calculations of Reduced Lithium Insertion in Au-Coated LiMn2O4. Adv. Mater. Interfaces, (2019). 6(4) 11.

199. Zhao, W.Y.; Wang, Z.; Malonzo, C.D.; Webber, T.E.; Platero-Prats, A.E.; Sotomayor, F.; Vermeulen, N.A.; Wang, T.C.; Hupp, J.T.; Farha, O.K.; Penn, R.L.; Chapman, K.W.; Thommes, M.; Stein, A., Extending the Compositional Range of Nanocasting in the Oxozirconium Cluster-Based Metal-Organic Framework NU-1000-A Comparative Structural Analysis. Chem. Mat., (2018). 30(4) 1301-1315.

197. Rangwani, S.; Howarth, A.J.; DeStefano, M.R.; Malliakas, C.D.; Platero-Prats, A.E.; Chapman, K.W.; Farha, O.K., Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal-organic framework. Polyhedron, (2018). 151 338-343.

196. Rana, J.; Shi, Y.; Zuba, M.J.; Wiaderek, K.M.; Feng, J.; Zhou, H.; Ding, J.; Wu, T.P.; Cibin, G.; Balasubramanian, M.; Omenya, F.; Chernova, N.A.; Chapman, K.W.; Whittingham, M.S.; Piper, L.F.J., Role of disorder in limiting the true multi-electron redox in epsilon-LiVOPO4. J. Mater. Chem. A, (2018). 6(42) 20669-20677.

195. Petkov, V.; Maswadeh, Y.; Lu, A.L.; Shan, S.Y.; Kareem, H.; Zhao, Y.G.; Luo, J.; Zhong, C.J.; Beyer, K.; Chapman, K., Evolution of Active Sites in Pt-Based Nanoalloy Catalysts for the Oxidation of Carbonaceous Species by Combined in Situ Infrared Spectroscopy and Total X-ray Scattering. ACS Appl. Mater. Interfaces, (2018). 10(13) 10870-10881.

194. Peters, A.W.; Otake, K.; Platero-Prats, A.E.; Li, Z.Y.; DeStefano, M.R.; Chapman, K.W.; Farha, O.K.; Hupp, J.T., Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal Organic Framework. ACS Appl. Mater. Interfaces, (2018). 10(17) 15073-15078.

193. Park, S.; Rittman, D.R.; Tracy, C.L.; Chapman, K.W.; Zhang, F.X.; Park, C.; Tkachev, S.N.; O'Quinn, E.; Shamblin, J.; Lang, M.; Mao, W.L.; Ewing, R.C., A(2)TiO(5) (A = Dy, Gd, Er, Yb) at High Pressure. Inorg. Chem., (2018). 57(4) 2269-2277.

192. Malonzo, C.D.; Wang, Z.; Duan, J.X.; Zhao, W.Y.; Webber, T.E.; Li, Z.Y.; Kim, I.S.; Kumar, A.; Bhan, A.; Platero-Prats, A.E.; Chapman, K.W.; Farha, O.K.; Hupp, J.T.; Martinson, A.B.F.; Penn, R.L.; Stein, A., Application and Limitations of Nanocasting in Metal-Organic Frameworks. Inorg. Chem., (2018). 57(5) 2782-2790.

191. Liu, H.D.; Liu, H.; Seymour, I.D.; Chernova, N.; Wiaderek, K.M.; Trease, N.M.; Hy, S.; Chen, Y.; An, K.; Zhang, M.H.; Borkiewicz, O.J.; Lapidus, S.H.; Qiu, B.; Xia, Y.G.; Liu, Z.P.; Chupas, P.J.; Chapman, K.W.; Whittingham, M.S.; Grey, C.P.; Meng, Y.S., Identifying the chemical and structural irreversibility in LiNi0.8Co0.15Al0.05O2 - a model compound for classical layered intercalation. J. Mater. Chem. A, (2018). 6(9) 4189-4198.

190. Li, W.; Borkiewicz, O.J.; Saubanere, M.; Doublet, M.L.; Flahaut, D.; Chupas, P.J.; Chapman, K.W.; Dambournet, D., Atomic Structure of 2 nm Size Metallic Cobalt Prepared by Electrochemical Conversion: An in Situ Pair Distribution Function Study. J. Phys. Chem. C, (2018). 122(42) 23861-23866.

189. Li, R.; Chawla, A.; Linares, N.; Sutjianto, J.G.; Chapman, K.W.; Martinez, J.G.; Rimer, J.D., Diverse Physical States of Amorphous Precursors in Zeolite Sol Gel Syntheses. Ind. Eng. Chem. Res., (2018). 57(25) 8460-8471.

188. Kung, C.W.; Platero-Prats, A.E.; Drout, R.J.; Kang, J.; Wang, T.C.; Audu, C.O.; Hersam, M.C.; Chapman, K.W.; Farha, O.K.; Hupp, J.T., Inorganic "Conductive Glass" Approach to Rendering Mesoporous Metal-Organic Frameworks Electronically Conductive and Chemically Responsive. ACS Appl. Mater. Interfaces, (2018). 10(36) 30532-30540.

187. Kim, I.S.; Li, Z.Y.; Zheng, J.; Platero-Prats, A.E.; Mavrandonakis, A.; Pellizzeri, S.; Ferrandon, M.; Vjunov, A.; Gallington, L.C.; Webber, T.E.; Vermeulen, N.A.; Penn, R.L.; Getman, R.B.; Cramer, C.J.; Chapman, K.W.; Camaioni, D.M.; Fulton, J.L.; Lercher, J.A.; Farha, O.K.; Hupp, J.T.; Martinson, A.B.F., Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework. Angew. Chem.-Int. Edit., (2018). 57(4) 909-913.

186. Kim, C.; Adil, A.A.; Bayliss, R.D.; Kinnibrugh, T.L.; Lapidus, S.H.; Nolis, G.M.; Freeland, J.W.; Phillips, P.J.; Yi, T.H.; Yoo, H.D.; Kwon, B.J.; Yu, Y.S.; Klie, R.; Chupas, P.J.; Chapman, K.W.; Cabana, J., Multivalent Electrochemistry of Spinel MgxMn3-xO4 Nanocrystals. Chem. Mat., (2018). 30(5) 1496-1504.

185. Jung, D.; Saleh, L.M.A.; Berkson, Z.J.; El-Kady, M.F.; Hwang, J.Y.; Mohamed, N.; Wixtrom, A.I.; Titarenko, E.; Shao, Y.W.; McCarthy, K.; Guo, J.; Martini, I.B.; Kraemer, S.; Wegener, E.C.; Saint-Cricq, P.; Ruehle, B.; Langeslay, R.R.; Delferro, M.; Brosmer, J.L.; Hendon, C.H.; Gallagher-Jones, M.; Rodriguez, J.; Chapman, K.W.; Miller, J.T.; Duan, X.F.; Kaner, R.B.; Zink, J.I.; Chmelka, B.F.; Spokoyny, A.M., A molecular cross-linking approach for hybrid metal oxides. Nat. Mater., (2018). 17(4) 341-+.

184. Ding, J.; Lin, Y.C.; Liu, J.; Rana, J.; Zhang, H.L.; Zhou, H.; Chu, I.H.; Wiaderek, K.M.; Omenya, F.; Chernova, N.A.; Chapman, K.W.; Piper, L.F.J.; Ong, S.P.; Whittingham, M.S., KVOPO4: A New High Capacity Multielectron Na-Ion Battery Cathode. Adv. Energy Mater., (2018). 8(21) 8.

183. Desai, S.P.; Ye, J.; Zheng, J.; Ferrandon, M.S.; Webber, T.E.; Platero-Prats, A.E.; Duan, J.X.; Garcia-Holley, P.; Camaioni, D.M.; Chapman, K.W.; Delferro, M.; Farha, O.K.; Fulton, J.L.; Gagliardi, L.; Lercher, J.A.; Penn, R.L.; Stein, A.; Lu, C.C., Well-Defined Rhodium-Gallium Catalytic Sites in a Metal-Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes. J. Am. Chem. Soc., (2018). 140(45) 15309-15318.

182. Demortiere, A.; Leonard, D.N.; Petkov, V.; Chapman, K.; Chattopadhyay, S.; She, C.X.; Cullen, D.A.; Shibata, T.; Pelton, M.; Shevchenko, E.V., Strain-Driven Stacking Faults in CdSe/CdS Core/Shell Nanorods. J. Phys. Chem. Lett., (2018). 9(8) 1900-1906.

181. Cui, Y.X.; Rimoldi, M.; Platero-Prats, A.E.; Chapman, K.W.; Hupp, J.T.; Farha, O.K., Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework. ChemCatChem, (2018). 10(8) 1772-1777.

180. Chen, X.; Wang, Y.C.; Wiaderek, K.; Sang, X.H.; Borkiewicz, O.; Chapman, K.; LeBeau, J.; Lynn, J.; Li, X., Super Charge Separation and High Voltage Phase in NaxMnO2. Adv. Funct. Mater., (2018). 28(50) 12.

179. Butala, M.M.; Doan-Nguyen, V.V.T.; Lehner, A.J.; Gobel, C.; Lumley, M.A.; Arnon, S.; Wiaderek, K.M.; Borkiewicz, O.J.; Chapman, K.W.; Chupas, P.J.; Balasubramanian, M.; Seshadri, R., Operando Studies Reveal Structural Evolution with Electrochemical Cycling in Li-CoS2. J. Phys. Chem. C, (2018). 122(43) 24559-24569.

178. Buru, C.T.; Platero-Prats, A.E.; Chica, D.G.; Kanatzidis, M.G.; Chapman, K.W.; Farha, O.K., Thermally induced migration of a polyoxometalate within a metal-organic framework and its catalytic effects. J. Mater. Chem. A, (2018). 6(17) 7389-7394.

177. Xiang, K.; Xing, W.T.; Ravnsbaek, D.B.; Hong, L.; Tang, M.; Li, Z.; Wiaderek, K.M.; Borkiewicz, O.J.; Chapman, K.W.; Chupas, P.J.; Chiang, Y.M., Accommodating High Transformation Strains in Battery Electrodes via the Formation of Nanoscale Intermediate Phases: Operando Investigation of Olivine NaFePO4. Nano Lett., (2017). 17(3) 1696-1702.

176. Wang, X.Y.; Huang, Y.Q.; Ji, D.S.; Omenya, F.; Karki, K.; Sallis, S.; Piper, L.F.J.; Wiaderek, K.M.; Chapman, K.W.; Chernova, N.A.; Whittinghama, M.S., Structure Evolution and Thermal Stability of High-Energy-Density Li-Ion Battery Cathode Li2VO2F. J. Electrochem. Soc., (2017). 164(7) A1552-A1558.

175. Thygesen, P.M.M.; Paddison, J.A.M.; Zhang, R.H.; Beyer, K.A.; Chapman, K.W.; Playford, H.Y.; Tucker, M.G.; Keen, D.A.; Hayward, M.A.; Goodwin, A.L., Orbital Dimer Model for the Spin-Glass State in Y2Mo2O7. Phys. Rev. Lett., (2017). 118(6) 6.

174. Stratford, J.M.; Mayo, M.; Allan, P.K.; Pecher, O.; Borkiewicz, O.J.; Wiaderek, K.M.; Chapman, K.W.; Pickard, C.J.; Morris, A.J.; Grey, C.P., Investigating Sodium Storage Mechanisms in Tin Anodes: A Combined Pair Distribution Function Analysis, Density Functional Theory, and Solid-State NMR Approach. J. Am. Chem. Soc., (2017). 139(21) 7273-7286.

173. Shi, X.B.; Xu, W.Q.; Yakovenko, A.; Halder, G.; Liu, Z.P.; Kurtz, C.; Ribaud, L.; Beyer, K.; Chapman, K.; Chupas, P., Bent Bragg-Laue monochromator for high-energy X-rays. J. Appl. Crystallogr., (2017). 50 1158-1164.

172. Seo, J.K.; Cho, H.M.; Takahara, K.; Chapman, K.W.; Borkiewicz, O.J.; Sina, M.; Meng, Y.S., Revisiting the conversion reaction voltage and the reversibility of the CuF2 electrode in Li-ion batteries. Nano Res., (2017). 10(12) 4232-4244.

171. Sava Gallis, D.F.; Rohwer, L.E.S.; Rodriguez, M.A.; Barnhart -Dailey, M.C.; Butler, K.S.; Luk, T.S.; Timlin, J.A.; Chapman, K.W., Multifunctional, Tunable Metal-Organic Framework Materials Platform for Bioimaging Applications. ACS Appl. Mater. Interfaces, (2017). 9(27) 22268-22277.

170. Sava Gallis, D.F.; Ermanoski, I.; Greathouse, J.A.; Chapman, K.W.; Nenoff, T.M., Iodine Gas Adsorption in Nanoporous Materials: A Combined Experiment Modeling Study. Ind. Eng. Chem. Res., (2017). 56(8) 2331-2338.

169. Rimoldi, M.; Gallington, L.C.; Chapman, K.W.; MacRenaris, K.; Hupp, J.T.; Farha, O.K., Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework. Chem.-Eur. J., (2017). 23(35) 8532-8536.

168. Rimoldi, M.; Bernales, V.; Borycz, J.; Vjunov, A.; Gallington, L.C.; Platero-Prats, A.E.; Kim, I.S.; Fulton, J.L.; Martinson, A.B.F.; Lercher, J.A.; Chapman, K.W.; Cramer, C.J.; Gagliardi, L.; Hupp, J.T.; Farha, O.K., Atomic Layer Deposition in a Metal-Organic Framework: Synthesis, Characterization, and Performance of a Solid Acid. Chem. Mat., (2017). 29(3) 1058-1068.

167. Platero-Prats, A.E.; Li, Z.Y.; Gallington, L.C.; Peters, A.W.; Hupp, J.T.; Farha, O.K.; Chapman, K.W., Addressing the characterisation challenge to understand catalysis in MOFs: the case of nanoscale Cu supported in NU-1000. Faraday Discuss., (2017). 201 337-350.

166. Platero-Prats, A.E.; League, A.B.; Bernales, V.; Ye, J.Y.; Gallington, L.C.; Vjunov, A.; Schweitzer, N.M.; Li, Z.Y.; Zheng, J.; Mehdi, B.L.; Stevens, A.J.; Dohnalkova, A.; Balasubramanian, M.; Farha, O.K.; Hupp, J.T.; Browning, N.D.; Fulton, J.L.; Camaioni, D.M.; Lercher, J.A.; Truhlar, D.G.; Gagliardi, L.; Cramer, C.J.; Chapman, K.W., Bridging Zirconia Nodes within a Metal-Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires. J. Am. Chem. Soc., (2017). 139(30) 10410-10418.

165. Miera, G.G.; Gomez, A.B.; Chupas, P.J.; Martin-Matute, B.; Chapman, K.W.; Platero-Prats, A.E., Topological Transformation of a Metal-Organic Framework Triggered by Ligand Exchange. Inorg. Chem., (2017). 56(8) 4576-4583.

164. Meng, W.; Pigliapochi, R.; Bayley, P.M.; Pecher, O.; Gaultois, M.W.; Seymour, I.D.; Liang, H.P.; Xu, W.Q.; Wiaderek, K.M.; Chapman, K.W.; Grey, C.P., Unraveling the Complex Delithiation and Lithiation Mechanisms of the High Capacity Cathode Material V6O13. Chem. Mat., (2017). 29(13) 5513-5524.

163. Ma, J.; Reeves, K.G.; Gutierrez, A.G.P.; Body, M.; Legein, C.; Kakinuma, K.; Borkiewicz, O.J.; Chapman, K.W.; Groult, H.; Salanne, M.; Dambournet, D., Layered Lepidocrocite Type Structure Isolated by Revisiting the Sol-Gel Chemistry of Anatase TiO2: A New Anode Material for Batteries. Chem. Mat., (2017). 29(19) 8313-8324.

162. Liu, H.; Wolf, M.; Karki, K.; Yu, Y.S.; Stach, E.A.; Cabana, J.; Chapman, K.W.; Chupas, P.J., Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes. Nano Lett., (2017). 17(6) 3452-3457.

161. Liu, H.; Liu, H.D.; Lapidus, S.H.; Meng, Y.S.; Chupas, P.J.; Chapman, K.W., Sensitivity and Limitations of Structures from X-ray and Neutron-Based Diffraction Analyses of Transition Metal Oxide Lithium-Battery Electrodes. J. Electrochem. Soc., (2017). 164(9) A1802-A1811.

160. Li, Z.Y.; Peters, A.W.; Platero-Prats, A.E.; Liu, J.; Kung, C.W.; Noh, H.; DeStefano, M.R.; Schweitzer, N.M.; Chapman, K.W.; Hupp, J.T.; Farha, O.K., Fine-Tuning the Activity of Metal-Organic Framework-Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane. J. Am. Chem. Soc., (2017). 139(42) 15251-15258.

159. Li, Z.Y.; Peters, A.W.; Bernales, V.; Ortuno, M.A.; Schweitzer, N.M.; DeStefano, M.R.; Gallington, L.C.; Platero-Prats, A.E.; Chapman, K.W.; Cramer, C.J.; Gagliardi, L.; Hupp, J.T.; Farha, O.K., Metal-Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature. ACS Central Sci., (2017). 3(1) 31-38.

158. Li, W.; Fukunishi, M.; Morgan, B.J.; Borkiewicz, O.J.; Chapman, K.W.; Pralong, V.; Maignan, A.; Lebedev, O.I.; Ma, J.W.; Groult, H.; Komaba, S.; Damboumet, D., A Reversible Phase Transition for Sodium Insertion in Anatase TiO2. Chem. Mat., (2017). 29(4) 1836-1844.

157. Li, R.F.; Wang, L.H.; Li, L.L.; Yu, T.; Zhao, H.Y.; Chapman, K.W.; Wang, Y.B.; Rivers, M.; Chupas, P.J.; Mao, H.K.; Liu, H.Z., Local structure of liquid gallium under pressure. Sci Rep, (2017). 7 7.

156. Li, R.F.; Wang, L.H.; Li, L.L.; Yu, T.; Zhao, H.Y.; Chapman, K.W.; Rivers, M.L.; Chupas, P.J.; Mao, H.K.; Liu, H.Z., Multiple scaling power in liquid gallium under pressure conditions. Phys. Rev. B, (2017). 95(22) 5.

155. Li, L.L.; Wang, L.H.; Li, R.F.; Qu, D.D.; Zhao, H.Y.; Chapman, K.W.; Chupas, P.J.; Liu, H.Z., Pressure-induced polyamorphism in lanthanide-solute metallic glasses. Phys. Status Solidi-Rapid Res. Lett., (2017). 11(6) 5.

154. Li, L.L.; Luo, Q.; Li, R.F.; Zhao, H.Y.; Chapman, K.W.; Chupas, P.J.; Wang, L.H.; Liu, H.Z., Polyamorphism in Yb-based metallic glass induced by pressure. Sci Rep, (2017). 7 6.

153. Levin, I.; Krayzman, V.; Cibin, G.; Tucker, M.G.; Eremenko, M.; Chapman, K.; Paul, R.L., Coupling of emergent octahedral rotations to polarization in (K,Na) NbO3 ferroelectrics. Sci Rep, (2017). 7 8.

152. Koketsu, T.; Ma, J.W.; Morgan, B.J.; Body, M.; Legein, C.; Dachraoui, W.; Giannini, M.; Demortiere, A.; Salanne, M.; Dardoize, F.; Groult, H.; Borkiewicz, O.J.; Chapman, K.; Strasser, P.; Dambournet, D., Reversible magnesium and aluminium ions insertion in cation-deficient anatase TiO2. Nat. Mater., (2017). 16(11) 1142-+.

151. Hua, X.; Liu, Z.; Fischer, M.G.; Borkiewicz, O.; Chupas, P.J.; Chapman, K.W.; Steiner, U.; Bruce, P.G.; Grey, C.P., Lithiation Thermodynamics and Kinetics of the TiO2 (B) Nanoparticles. J. Am. Chem. Soc., (2017). 139(38) 13330-13341.

150. Howe, J.D.; Morelock, C.R.; Jiao, Y.; Chapman, K.W.; Walton, K.S.; Sholl, D.S., Understanding Structure, Metal Distribution, and Water Adsorption in Mixed-Metal MOF-74. J. Phys. Chem. C, (2017). 121(1) 627-635.

149. Grenier, A.; Porras-Gutierrez, A.G.; Groult, H.; Beyer, K.A.; Borkiewicz, O.J.; Chapman, K.W.; Dambournet, D., Electrochemical reactions in fluoride-ion batteries: mechanistic insights from pair distribution function analysis. J. Mater. Chem. A, (2017). 5(30) 15700-15705.

148. Grenier, A.; Liu, H.; Wiaderek, K.M.; Lebens-Higgins, Z.W.; Borkiewicz, O.J.; Piper, L.F.J.; Chupas, P.J.; Chapman, K.W., Reaction Heterogeneity in LiNi0.8Co0.15Al0.05O2 Induced by Surface Layer. Chem. Mat., (2017). 29(17) 7345-7352.

147. Gaillac, R.; Pullumbi, P.; Beyer, K.A.; Chapman, K.W.; Keen, D.A.; Bennett, T.D.; Coudert, F.X., Liquid metal-organic frameworks. Nat. Mater., (2017). 16(11) 1149-+.

146. Butala, M.M.; Mayo, M.; Doan-Nguyen, V.V.T.; Lumley, M.A.; Gobel, C.; Wiaderek, K.M.; Borkiewicz, O.J.; Chapman, K.W.; Chupas, P.J.; Balasubramanian, M.; Laurita, G.; Britto, S.; Morris, A.J.; Grey, C.P.; Seshadri, R., Local Structure Evolution and Modes of Charge Storage in Secondary Li-FeS2 Cells. Chem. Mat., (2017). 29(7) 3070-3082.

145. Buru, C.T.; Li, P.; Mehdi, B.L.; Dohnalkoya, A.; Platero-Prats, A.E.; Browning, N.D.; Chapman, K.W.; Hupp, J.T.; Farha, O.K., Adsorption of a Catalytically Accessible Polyoxometalate in a Mesoporous Channel-type Metal-Organic Framework. Chem. Mat., (2017). 29(12) 5174-5181.

144. Zhang, W.; Banerjee, D.; Liu, J.; Schaef, H.T.; Crum, J.V.; Fernandez, C.A.; Kukkadapu, R.K.; Nie, Z.; Nune, S.K.; Motkuri, R.K.; Chapman, K.W.; Engelhard, M.H.; Hayes, J.C.; Silvers, K.L.; Krishna, R.; McGrail, B.P.; Liu, J.; Thallapally, P.K., Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications. Adv. Mater., (2016). 28(18) 3572-+.

143. Wangoh, L.W.; Sallis, S.; Wiaderek, K.M.; Lin, Y.C.; Wen, B.H.; Quackenbush, N.F.; Chernova, N.A.; Guo, J.H.; Ma, L.; Wu, T.P.; Lee, T.L.; Schlueter, C.; Ong, S.P.; Chapman, K.W.; Whittingham, M.S.; Piper, L.F.J., Uniform second Li ion intercalation in solid state epsilon-LiVOPO4. Appl. Phys. Lett., (2016). 109(5) 4.

142. Trease, N.M.; Seymour, I.D.; Radin, M.D.; Liu, H.; Liu, H.; Hy, S.; Chernova, N.; Parikh, P.; Devaraj, A.; Wiaderek, K.M.; Chupas, P.J.; Chapman, K.W.; Whittingham, M.S.; Meng, Y.S.; Van der Van, A.; Grey, C.P., Identifying the Distribution of Al3+ in LiNi0.8Co0.15Al0.05O2. Chem. Mat., (2016). 28(22) 8170-8180.

141. Thompson, A.B.; Pahis, D.R.; Bernales, V.; Gallington, L.C.; Malonzo, C.D.; Webber, T.; Tereniak, S.J.; Wang, T.C.; Desai, S.P.; Li, Z.Y.; Kim, I.S.; Gagliardi, L.; Penn, R.L.; Chapman, K.W.; Stein, A.; Farha, O.K.; Hupp, J.T.; Martinson, A.B.F.; Lu, C.C., Installing Heterobimetallic Cobalt-Aluminum Single Sites on a Metal Organic Framework Support. Chem. Mat., (2016). 28(18) 6753-6762.

140. Strobridge, F.C.; Liu, H.; Leskes, M.; Borkiewicz, O.J.; Wiaderek, K.M.; Chupas, P.J.; Chapman, K.W.; Grey, C.P., Unraveling the Complex Delithiation Mechanisms of Olivine-Type Cathode Materials, LiFexCo1-xPO4. Chem. Mat., (2016). 28(11) 3676-3690.

139. See, K.A.; Chapman, K.W.; Zhu, L.Y.; Wiaderek, K.M.; Borkiewicz, O.J.; Barile, C.J.; Chupas, P.J.; Gewirth, A.A., The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions. J. Am. Chem. Soc., (2016). 138(1) 328-337.

138. Sciortino, N.F.; Ragon, F.; Zenere, K.A.; Southon, P.D.; Halder, G.J.; Chapman, K.W.; Pineiro-Lopez, L.; Real, J.A.; Kepert, C.J.; Neville, S.M., Exploiting Pressure To Induce a "Guest-Blocked" Spin Transition in a Framework Material. Inorg. Chem., (2016). 55(20) 10490-10498.

137. Sava Gallis, D.F.; Pratt, H.D.; Anderson, T.M.; Chapman, K.W., Electrochemical activity of Fe-MIL-100 as a positive electrode for Na-ion batteries. J. Mater. Chem. A, (2016). 4(36) 13764-13770.

136. Sava Gallis, D.F.; Chapman, K.W.; Rodriguez, M.A.; Greathouse, J.A.; Parkes, M.V.; Nenoff, T.M., Selective O-2 Sorption at Ambient Temperatures via Node Distortions in Sc-MIL-100. Chem. Mat., (2016). 28(10) 3327-3336.

135. Sa, N.; Kinnibrugh, T.L.; Wang, H.; Gautam, G.S.; Chapman, K.W.; Vaughey, J.T.; Key, B.; Fister, T.T.; Freeland, J.W.; Proffit, D.L.; Chupas, P.J.; Ceder, G.; Bareno, J.G.; Bloom, I.D.; Burrell, A.K., Structural Evolution of Reversible Mg Insertion into a Bilayer Structure of V2O5 center dot nH(2)O Xerogel Material. Chem. Mat., (2016). 28(9) 2962-2969.

134. Ravnsbaek, D.B.; Xiang, K.; Xing, W.T.; Borkiewicz, O.J.; Wiaderek, K.M.; Gionet, P.; Chapman, K.W.; Chupas, P.J.; Tang, M.; Chiang, Y.M., Engineering the Transformation Strain in LiMnyFe1-yPO4 Olivines for Ultrahigh Rate Battery Cathodes. Nano Lett., (2016). 16(4) 2375-2380.

133. Platero-Prats, A.E.; Mavrandonakis, A.; Gallington, L.C.; Liu, Y.Y.; Hupp, J.T.; Farha, O.K.; Cramer, C.J.; Chapmant, K.W., Structural Transitions of the Metal -Oxide Nodes within Metal- Organic Frameworks: On the Local Structures of NU-1000 and UiO-66. J. Am. Chem. Soc., (2016). 138(12) 4178-4185.

132. Marchbank, H.R.; Clark, A.H.; Hyde, T.I.; Playford, H.Y.; Tucker, M.G.; Thompsett, D.; Fisher, J.M.; Chapman, K.W.; Beyer, K.A.; Monte, M.; Longo, A.; Sankar, G., Structure of Nano-sized CeO2 Materials: Combined Scattering and Spectroscopic Investigations. ChemPhysChem, (2016). 17(21) 3494-3503.

131. Malonzo, C.D.; Shaker, S.M.; Ren, L.M.; Prinslow, S.D.; Platero-Prats, A.E.; Gallington, L.C.; Borycz, J.; Thompson, A.B.; Wang, T.C.; Farha, O.K.; Hupp, J.T.; Lu, C.C.; Chapman, K.W.; Myers, J.C.; Penn, R.L.; Gagliardi, L.; Tsapatsis, M.; Stein, A., Thermal Stabilization of Metal-Organic Framework-Derived Single Site Catalytic Clusters through Nanocasting. J. Am. Chem. Soc., (2016). 138(8) 2739-2748.

130. Doan-Nguyen, V.V.T.; Subrahmanyam, K.S.; Butala, M.M.; Gerbec, J.A.; Islam, S.M.; Kanipe, K.N.; Wilson, C.E.; Balasubramanian, M.; Wiaderek, K.M.; Borkiewicz, O.J.; Chapman, K.W.; Chupas, P.J.; Moskovits, M.; Dunn, B.S.; Kanatzidis, M.G.; Seshadri, R., Molybdenum Polysulfide Chalcogels as High-Capacity, Anion-Redox-Driven Electrode Materials for Li-Ion Batteries. Chem. Mater., (2016). 28(22) 8357–8365. DOI: 10.1021/acs.chemmater.6b03656

129. Ahn, S.; Thornburg, N.E.; Li, Z.Y.; Wang, T.C.; Gallington, L.C.; Chapman, K.W.; Notestein, J.M.; Hupp, J.T.; Farha, O.K., Stable Metal-Organic Framework-Supported Niobium Catalysts. Inorg. Chem., (2016). 55(22) 11954–11961. DOI: 10.1021/acs.inorgchem.6b02103

128. Li, L.L.; Wang, L.H.; Li, R.F.; Zhao, H.Y.; Qu, D.D.; Chapman, K.W.; Chupas, P.J.; Liu, H.Z., Constant real-space fractal dimensionality and structure evolution in Ti62Cu38 metallic glass under high pressure. Phys. Rev. B, (2016). 94(18) . DOI: 10.1103/PhysRevB.94.184201

127. Gallington, L.C.; Kim, I.S.; Liu, W.G.; Yakovenko, A.A.; Platero-Prats, A.E.; Li, Z.Y.; Wang, T.C.; Hupp, J.T.; Farha, O.K.; Truhlar, D.G.; Martinson, A.B.F.; Chapman, K.W., Regioselective Atomic Layer Deposition in Metal-Organic Frameworks Directed by Dispersion Interactions. J. Am. Chem. Soc., (2016). 138(41) 13513–13516. DOI: 10.1021/jacs.6b08711

126. Liu, H.; Allan, P.K.; Borkiewicz, O.J.; Kurtz, C.; Grey, C.P.; Chapman, K.W.; Chupas, P.J., A radially accessible tubular in situ X-ray cell for spatially resolved operando scattering and spectroscopic studies of electrochemical energy storage devices. J. Appl. Crystallogr., (2016). 49(5) 1665–1673. DOI: 10.1107/S1600576716012632

125. Wangoh, L.W.; Sallis, S.; Wiaderek, K.M.; Lin, Y.C.; Wen, B.H.; Quackenbush, N.F.; Chernova, N.A.; Guo, J.H.; Ma, L.; Wu, T.P.; Lee, T.L.; Schlueter, C.; Ong, S.P.; Chapman, K.W.; Whittingham, M.S.; Piper, L.F.J., Uniform second Li ion intercalation in solid state ε-LiVOPO4. Appl. Phys. Lett., (2016). 109(5) . DOI: 10.1063/1.4960452

124. Blanchard, P.E.R.; Chapman, K.W.; Heald, S.M.; Zbiri, M.; Johnson, M.R.; Kennedy, B.J.; Line, C.D., Direct Observation of Pressure-Driven Valence Electron Transfer in Ba3BiRu2O9, Ba3BiIr2O9, and Ba4BiIr3O12. Inorg. Chem., (2016). 55(11) 5649–5654. DOI: 10.1021/acs.inorgchem.6b00718

123. Sava Gallis, D.F.; Chapman, K.W.; Rodriguez, M.A.; Greathouse, J.A.; Parkes, M.V.; Nenoff', T.M., Selective O2 Sorption at Ambient Temperatures via Node Distortions in Sc-MIL-100. Chem. Mater., (2016). 28(10) 3327–3336. DOI: 10.1021/acs.chemmater.6b00249

122. Ascherl, L.; Sick, T.; Margraf, J.T.; Lapidus, S.H.; Calik, M.; Hettstedt, C.; Karaghiosoff, K.; Döblinger, M.; Clark, T.; Chapman, K.W.; Auras, F.; Bein, T., Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks. Nat. Chem., (2016). 8(4) 310–316. DOI: 10.1038/NCHEM.2444

121. Lin, Y.C.; Wen, B.H.; Wiaderek, K.M.; Sallis, S.; Liu, H.; Lapidus, S.H.; Borkiewicz, O.J.; Quackenbush, N.F.; Chernova, N.A.; Karki, K.; Omenya, F.; Chupas, P.J.; Piper, L.F.J.; Whittingham, M.S.; Chapman, K.W.; Ong, S.P., Thermodynamics, Kinetics and Structural Evolution of ε-LiVOPO4 over Multiple Lithium Intercalation. Chem. Mater., (2016). 28(6) 1794–1805. DOI: 10.1021/acs.chemmater.5b04880

120. Chapman, K.W., Emerging operando and x-ray pair distribution function methods for energy materials development. MRS Bull., (2016). 41(3) 231–238. DOI: 10.1557/mrs.2016.26

119. Allan, P.K.; Griffin, J.M.; Darwiche, A.; Borkiewicz, O.J.; Wiaderek, K.M.; Chapman, K.W.; Morris, A.J.; Chupas, P.J.; Monconduit, L.; Grey, C.P., Tracking Sodium-Antimonide Phase Transformations in Sodium-Ion Anodes: Insights from Operando Pair Distribution Function Analysis and Solid-State NMR Spectroscopy. J. Am. Chem. Soc., (2016). 138(7) 2352–2365. DOI: 10.1021/jacs.5b13273

118. Donakowski, M.D.; Wallace, J.M.; Sassin, M.B.; Chapman, K.W.; Parker, J.F.; Long, J.W.; Rolison, D.R., Crystal engineering in 3D: converting nanoscale lamellar manganese oxide to cubic spinel while affixed to a carbon architecture. CRYSTENGCOMM, (2016). 18(32) 6035–6048. DOI: 10.1039/c6ce00861e

117. Chapman, K.W.; Lapidus, S.H.; Chupas, P.J., Applications of principal component analysis to pair distribution function data. J. Appl. Crystallogr., (2015). 48(6) 1619–1626. DOI: 10.1107/S1600576715016532

116. Chapman, K.W.; Parsons, S.; Walton, R.I., Introduction to the special issue on energy materials. Acta Crystallogr. Sect. B, (2015). 71(6) 583–584. DOI: 10.1107/S2052520615022477

115. Kwon, G.; Kokhan, O.; Han, A.; Chapman, K.W.; Chupas, P.J.; Du, P.W.; Tiede, D.M., Oxyanion induced variations in domain structure for amorphous cobalt oxide oxygen evolving catalysts, resolved by X-ray pair distribution function analysis. Acta Crystallogr. Sect. , (2015). 71(6) 713–721. DOI: 10.1107/S2052520615022180

114. Ashton, T.E.; Borrás, D.H.; Iadecola, A.; Wiaderek, K.M.; Chupas, P.J.; Chapman, K.W.; Corr, S.A., Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures. Acta Crystallogr. Sect. B, (2015). 71(6) 722–726. DOI: 10.1107/S2052520615021289

113. Beyzavi, M.H.; Vermeulen, N.A.; Howarth, A.J.; Tussupbayev, S.; League, A.B.; Schweitzer, N.M.; Gallagher, J.R.; Platero-Prats, A.E.; Hafezi, N.; Sarjeant, A.A.; Miller, J.T.; Chapman, K.W.; Stoddart, J.F.; Cramer, C.J.; Hupp, J.T.; Farha, O.K., A Hafnium-Based Metal-Organic Framework as a Nature-Inspired Tandem Reaction Catalyst. J. Am. Chem. Soc., (2015). 137(42) 13624–13631. DOI: 10.1021/jacs.5b03440

112. Deibert, B.J.; Zhang, J.M.; Smith, P.F.; Chapman, K.W.; Rangan, S.; Banerjee, D.; Tan, K.; Wang, H.; Pasquale, N.; Chen, F.; Lee, K.B.; Dismukes, G.C.; Chabal, Y.J.; Li, J., Surface and Structural Investigation of a MnOx Birnessite-Type Water Oxidation Catalyst Formed under Photocatalytic Conditions. Chem. Eur. J., (2015). 21(40) 14218–14228. DOI: 10.1002/chem.201501930

111. Dambournet, D.; Chapman, K.W.; Duttine, M.; Borkiewicz, O.; Chupas, P.J.; Groult, H., Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis. CHEMISTRYOPEN, (2015). 4(4) 443–447. DOI: 10.1002/open.201500031

110. Li, W.; Corradini, D.; Body, M.; Legein, C.; Salanne, M.; Ma, J.W.; Chapman, K.W.; Chupas, P.J.; Rollett, A.L.; Julien, C.; Zhagib, K.; Duttine, M.; Demourgues, A.; Groult, H.; Dambournet, D., High Substitution Rate in TiO2 Anatase Nanoparticles with Cationic Vacancies for Fast Lithium Storage. Chem. Mater., (2015). 27(14) 5014–5019. DOI: 10.1021/acs.chemmater.5b01407

109. Kim, I.S.; Borycz, J.; Platero-Prats, A.E.; Tussupbayev, S.; Wang, T.C.; Farha, O.K.; Hupp, J.T.; Gagliardi, L.; Chapman, K.W.; Cramer, C.J.; Martinson, A.B.F., Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition. Chem. Mater., (2015). 27(13) 4772–4778. DOI: 10.1021/acs.chemmater.5b01560

108. Britto, S.; Leskes, M.; Hua, X.; Hébert, C.A.; Shin, H.S.; Clarke, S.; Borkiewicz, O.; Chapman, K.W.; Seshadri, R.; Cho, J.; Grey, C.P., Multiple Redox Modes in the Reversible Lithiation of High-Capacity, Peierls-Distorted Vanadium Sulfide. J. Am. Chem. Soc., (2015). 137(26) 8499–8508. DOI: 10.1021/jacs.5b03395

107. Howarth, A.J.; Katz, M.J.; Wang, T.C.; Platero-Prats, A.E.; Chapman, K.W.; Hupp, J.T.; Farha, O.K., High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal-Organic Frameworks. J. Am. Chem. Soc., (2015). 137(23) 7488–7494. DOI: 10.1021/jacs.5b03904

106. Hancock, J.C.; Chapman, K.W.; Halder, G.J.; Morelock, C.R.; Karlan, B.S.; Gallington, L.C.; Bongiorno, A.; Han, C.; Zhou, S.; Wilkinson, A.P., Large Negative Thermal Expansion and Anomalous Behavior on Compression in Cubic ReO3-Type AIIBIVF6: CaZrF6 and CaHfF6. Chem. Mater., (2015). 27(11) 3912–3918. DOI: 10.1021/acs.chemmater.5b00662

105. Borkiewicz, O.J.; Wiaderek, K.M.; Chupas, P.J.; Chapman, K.W., Best Practices for Operando Battery Experiments: Influences of X-ray Experiment Design on Observed Electrochemical Reactivity. J. Phys. Chem. Lett., (2015). 6(11) 2081–2085. DOI: 10.1021/acs.jpclett.5b00891

104. Yakovenko, A.A.; Chapman, K.W.; Halder, G.J., Pressure-induced structural phase transformation in cobalt(II) dicyanamide. Acta Crystallogr. Sect. B, (2015). 71(3) 252–257. DOI: 10.1107/S2052520615005867

103. Jung, H.; Allan, P.K.; Hu, Y.Y.; Borkiewicz, O.J.; Wang, X.L.; Han, W.Q.; Du, L.S.; Pickard, C.J.; Chupas, P.J.; Chapman, K.W.; Morris, A.J.; Grey, C.P., Elucidation of the Local and Long-Range Structural Changes that Occur in Germanium Anodes in Lithium-Ion Batteries. Chem. Mater., (2015). 27(3) 1031–1041. DOI: 10.1021/cm504312x

102. Platero-Prats, A.E.; Gómez, A.B.; Chapman, K.W.; Martín-Matute, B.; Zou, X.D., Functionalising metal-organic frameworks with metal complexes: the role of structural dynamics. CRYSTENGCOMM, (2015). 17(40) 7632–7635. DOI: 10.1039/c5ce01732g

101. Newton, M.A.; Di Michiel, M.; Ferri, D.; Fernàndez-Garcia, M.; Beale, A.M.; Jacques, S.D.M.; Chupas, P.J.; Chapman, K.W., Catalytic Adventures in Space and Time Using High Energy X-rays. Catal. Surv. Asia., (2014). 18(4) 134–148. DOI: 10.1007/s10563-014-9173-z

100. Nenoff, T.M.; Rodriguez, M.A.; Soelberg, N.R.; Chapman, K.W., Silver-mordenite for radiologic gas capture from complex streams: Dual catalytic CH3I decomposition and I confinement. Microporous Mesoporous Mater., (2014). 200 297–303. DOI: 10.1016/j.micromeso.2014.04.041

99. Nguyen, S.D.; Ryan, K.; Chai, P.; Shatruk, M.; Xin, Y.; Chapman, K.W.; Chupas, P.J.; Fronczek, F.R.; Macaluso, R.T., Pr1.33Pt4Ga10: Superstructure and magnetism. J. Solid State Chem., (2014). 220 9–16. DOI: 10.1016/j.jssc.2014.07.033

98. Strobridge, F.C.; Clément, R.J.; Leskes, M.; Middlemiss, D.S.; Borkiewicz, O.J.; Wiaderek, K.M.; Chapman, K.W.; Chupas, P.J.; Grey, C.P., Identifying the Structure of the Intermediate, Li2/3CoPO4, Formed during Electrochemical Cycling of LiCoPO4. Chem. Mater., (2014). 26(21) 6193–6205. DOI: 10.1021/cm502680w

97. Lapidus, S.H.; Rajput, N.N.; Qu, X.H.; Chapman, K.W.; Persson, K.A.; Chupas, P.J., Solvation structure and energetics of electrolytes for multivalent energy storage. Phys. Chem. Chem. Phys., (2014). 16(40) 21941–21945. DOI: 10.1039/c4cp03015j

96. Ko, J.K.; Wiaderek, K.M.; Pereira, N.; Kinnibrugh, T.L.; Kim, J.R.; Chupas, P.J.; Chapman, K.W.; Amatucci, G.G., Transport, Phase Reactions, and Hysteresis of Iron Fluoride and Oxyfluoride Conversion Electrode Materials for Lithium Batteries. ACS Appl. Mater. Interfaces, (2014). 6(14) 10858–10869. DOI: 10.1021/am500538b

95. Duttine, M.; Dambournet, D.; Penin, N.; Carlier, D.; Bourgeois, L.; Wattiaux, A.; Chapman, K.W.; Chupas, P.J.; Groult, H.; Durand, E.; Demourgues, A., Tailoring the Composition of a Mixed Anion Iron-Based Fluoride Compound: Evidence for Anionic Vacancy and Electrochemical Performance in Lithium Cells. Chem. Mater., (2014). 26(14) 4190–4199. DOI: 10.1021/cm501396n

94. Hua, X.; Robert, R.; Du, L.S.; Wiaderek, K.M.; Leskes, M.; Chapman, K.W.; Chupas, P.J.; Grey, C.P., Comprehensive Study of the CuF2 Conversion Reaction Mechanism in a Lithium Ion Battery. J. Phys. Chem. C, (2014). 118(28) 15169–15184. DOI: 10.1021/jp503902z

93. Bo, S.H.; Nam, K.W.; Borkiewicz, O.J.; Hu, Y.Y.; Yang, X.Q.; Chupas, P.J.; Chapman, K.W.; Wu, L.J.; Zhang, L.; Wang, F.; Grey, C.P.; Khalifah, P.G., Structures of Delithiated and Degraded LiFeBO3, and Their Distinct Changes upon Electrochemical Cycling. Inorg. Chem., (2014). 53(13) 6585–6595. DOI: 10.1021/ic500169g

92. Lei, Y.; Zhao, H.Y.; Rivas, R.D.; Lee, S.; Liu, B.; Lu, J.L.; Stach, E.; Winans, R.E.; Chapman, K.W.; Greeley, J.P.; Miller, J.T.; Chupas, P.J.; Elam, J.W., Adsorbate-Induced Structural Changes in 1-3 nm Platinum Nanoparticles. J. Am. Chem. Soc., (2014). 136(26) 9320–9326. DOI: 10.1021/ja4126998

91. Liu, H.; Strobridge, F.C.; Borkiewicz, O.J.; Wiaderek, K.M.; Chapman, K.W.; Chupas, P.J.; Grey, C.P., Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes. Science, (2014). 344(6191) . DOI: 10.1126/science.1252817

90. Dambournet, D.; Duttine, M.; Chapman, K.W.; Wattiaux, A.; Borkiewicz, O.; Chupas, P.J.; Demourgues, A.; Groult, H., Resolving and Quantifying Nanoscaled Phases in Amorphous FeF3 by Pair Distribution Function and Mossbauer Spectroscopy. J. Phys. Chem. C, (2014). 118(25) 14039–14043. DOI: 10.1021/jp504083g

89. Yao, S.Y.; Mudiyanselage, K.; Xu, W.Q.; Johnston-Peck, A.C.; Hanson, J.C.; Wu, T.P.; Stacchiola, D.; Rodriguez, J.A.; Zhao, H.Y.; Beyer, K.A.; Chapman, K.W.; Chupas, P.J.; Martínez-Arias, A.; Si, R.; Bolin, T.B.; Liu, W.J.; Senanayake, S.D., Unraveling the Dynamic Nature of a CuO/CeO2 Catalyst for CO Oxidation in Operando: A Combined Study of XANES (Fluorescence) and DRIFTS. ACS Catal., (2014). 4(6) 1650–1661. DOI: 10.1021/cs500148e

88. Kumara, C.; Zuo, X.B.; Ilavsky, J.; Chapman, K.W.; Cullen, D.A.; Dass, A., Super-Stable, Highly Monodisperse Plasmonic Faradaurate-500 Nanocrystals with 500 Gold Atoms: Au∼500(SR)∼120. J. Am. Chem. Soc., (2014). 136(20) 7410–7417. DOI: 10.1021/ja502327a

87. Wiaderek, K.M.; Borkiewicz, O.J.; Pereira, N.; Ilavsky, J.; Amatucci, G.G.; Chupas, P.J.; Chapman, K.W., Mesoscale Effects in Electrochemical Conversion: Coupling of Chemistry to Atomic- and Nanoscale Structure in Iron-Based Electrodes. J. Am. Chem. Soc., (2014). 136(17) 6211–6214. DOI: 10.1021/ja501854y

86. Gallington, L.C.; Chapman, K.W.; Morelock, C.R.; Chupas, P.J.; Wilkinson, A.P., Dramatic softening of the negative thermal expansion material HfW2O8 upon heating through its WO4 orientational order-disorder phase transition. J. Appl. Phys., (2014). 115(5) . DOI: 10.1063/1.4864258

85. Beyer, K.A.; Zhao, H.Y.; Borkiewicz, O.J.; Newton, M.A.; Chupas, P.J.; Chapman, K.W., Simultaneous diffuse reflection infrared spectroscopy and X-ray pair distribution function measurements. J. Appl. Crystallogr., (2014). 47(1) 95–101. DOI: 10.1107/S1600576713028410

84. Chapman, K.W.; Chupas, P.J.; Long, G.G.; Bendersky, L.A.; Levine, L.E.; Mompiou, F.; Stalick, J.K.; Cahn, J.W., An ordered metallic glass solid solution phase that grows from the melt like a crystal. Acta Mater., (2014). 62 58–68. DOI: 10.1016/j.actamat.2013.08.063

83. Mohideen, M.I.; Allan, P.K.; Chapman, K.W.; Hriljac, J.A.; Morris, R.E., Ultrasound-driven preparation and pair distribution function-assisted structure solution of a copper-based layered coordination polymer. J. Chem. Soc., Dalton Trans., (2014). 43(27) 10438–10442. DOI: 10.1039/c3dt53124d

82. Lee, D.H.; Carroll, K.J.; Chapman, K.W.; Borkiewicz, O.J.; Calvin, S.; Fullerton, E.E.; Meng, Y.S., Understanding improved electrochemical properties of NiO-doped NiF2-C composite conversion materials by X-ray absorption spectroscopy and pair distribution function analysis. Phys. Chem. Chem. Phys., (2014). 16(7) 3095–3102. DOI: 10.1039/c3cp54431a

81. Morelock, C.R.; Greve, B.K.; Gallington, L.C.; Chapman, K.W.; Wilkinson, A.P., Negative thermal expansion and compressibility of Sc1-xYxF3 (x ≤ 0.25). J. Appl. Phys., (2013). 114(21) . DOI: 10.1063/1.4836855

80. Hu, Y.Y.; Liu, Z.G.; Nam, K.W.; Borkiewicz, O.J.; Cheng, J.; Hua, X.; Dunstan, M.T.; Yu, X.Q.; Wiaderek, K.M.; Du, L.S.; Chapman, K.W.; Chupas, P.J.; Yang, X.Q.; Grey, C.P., Origin of additional capacities in metal oxide lithium-ion battery electrodes. Nat. Mater., (2013). 12(12) 1130–1136. DOI: 10.1038/NMAT3784

79. Sava, D.F.; Chapman, K.W.; Rodriguez, M.A.; Greathouse, J.A.; Crozier, P.S.; Zhao, H.Y.; Chupas, P.J.; Nenoff, T.M., Competitive I2 Sorption by Cu-BTC from Humid Gas Streams. Chem. Mater., (2013). 25(13) 2591–2596. DOI: 10.1021/cm401762g

78. Long, G.G.; Chapman, K.W.; Chupas, P.J.; Bendersky, L.A.; Levine, L.E.; Mompiou, F.; Stalick, J.K.; Cahn, J.W., Highly Ordered Noncrystalline Metallic Phase. Phys. Rev. Lett., (2013). 111(1) . DOI: 10.1103/PhysRevLett.111.015502

77. Lapidus, S.H.; Halder, G.J.; Chupas, P.J.; Chapman, K.W., Exploiting High Pressures to Generate Porosity, Polymorphism, And Lattice Expansion in the Nonporous Molecular Framework Zn(CN)2. J. Am. Chem. Soc., (2013). 135(20) 7621–7628. DOI: 10.1021/ja4012707

76. Morelock, C.R.; Greve, B.K.; Cetinkol, M.; Chapman, K.W.; Chupas, P.J.; Wilkinson, A.P., Role of Anion Site Disorder in the Near Zero Thermal Expansion of Tantalum Oxyfluoride. Chem. Mater., (2013). 25(9) 1900–1904. DOI: 10.1021/cm400536n

75. Wiaderek, K.M.; Borkiewicz, O.J.; Castillo-Martínez, E.; Robert, R.; Pereira, N.; Amatucci, G.G.; Grey, C.P.; Chupas, P.J.; Chapman, K.W., Comprehensive Insights into the Structural and Chemical Changes in Mixed-Anion FeOF Electrodes by Using Operando PDF and NMR Spectroscopy. J. Am. Chem. Soc., (2013). 135(10) 4070–4078. DOI: 10.1021/ja400229v

74. Orendt, A.M.; Pimienta, I.S.O.; Badu, S.R.; Solum, M.S.; Pugmire, R.J.; Facelli, J.C.; Locke, D.R.; Chapman, K.W.; Chupas, P.J.; Winans, R.E., Three-Dimensional Structure of the Siskin Green River Oil Shale Kerogen Model: A Comparison between Calculated and Observed Properties. Energy Fuels, (2013). 27(2) 702–710. DOI: 10.1021/ef3017046

73. Chapman, K.W.; Beyer, K.A.; Zhao, H.Y.; Chupas, P.J., Correlating structure and chemistry through simultaneous in situ pair distribution function and infrared spectroscopy measurements. CRYSTENGCOMM, (2013). 15(45) 9377–9381. DOI: 10.1039/c3ce41458b

72. Gallington, L.C.; Chapman, K.W.; Morelock, C.R.; Chupas, P.J.; Wilkinson, A.P., Orientational order-dependent thermal expansion and compressibility of ZrW2O8 and ZrMo2O8. Phys. Chem. Chem. Phys., (2013). 15(45) 19665–19672. DOI: 10.1039/c3cp52876f

71. Chapman, K.W.; Chupas, P.J., PAIR DISTRIBUTION FUNCTION ANALYSIS OF HIGH-ENERGY X-RAY SCATTERING DATA. IN-SITU CHARACTERIZATION OF HETEROGENEOUS CATALYSTS, (2013).  147–168.

70. Borkiewicz, O.J.; Chapman, K.W.; Chupas, P.J., Mapping spatially inhomogeneous electrochemical reactions in battery electrodes using high energy X-rays. Phys. Chem. Chem. Phys., (2013). 15(22) 8466–8469. DOI: 10.1039/c3cp50590a

69. Borkiewicz, O.J.; Shyam, B.; Wiaderek, K.M.; Kurtz, C.; Chupas, P.J.; Chapman, K.W., The AMPIX electrochemical cell: a versatile apparatus for in situ X-ray scattering and spectroscopic measurements. J. Appl. Crystallogr., (2012). 45(6) 1261–1269. DOI: 10.1107/S0021889812042720

68. Katz, J.E.; Zhang, X.Y.; Attenkofer, K.; Chapman, K.W.; Frandsen, C.; Zarzycki, P.; Rosso, K.M.; Falcone, R.W.; Waychunas, G.A.; Gilbert, B., Electron Small Polarons and Their Mobility in Iron (Oxyhydr)oxide Nanoparticles. Science, (2012). 337(6099) 1200–1203. DOI: 10.1126/science.1223598

67. Thompson, J.A.; Chapman, K.W.; Koros, W.J.; Jones, C.W.; Nair, S., Sonication-induced Ostwald ripening of ZIF-8 nanoparticles and formation of ZIF-8/polymer composite membranes. Microporous Mesoporous Mater., (2012). 158 292–299. DOI: 10.1016/j.micromeso.2012.03.052

66. Wilkinson, A.P.; Greve, B.K.; Ruschman, C.J.; Chapman, K.W.; Chupas, P.J., Pressure induced amorphization of ZrMo2O8 and its relaxation on decompression as seen by in situ total x-ray scattering. J. Appl. Phys., (2012). 112(2) . DOI: 10.1063/1.4737128

65. Du, P.W.; Kokhan, O.; Chapman, K.W.; Chupas, P.J.; Tiede, D.M., Elucidating the Domain Structure of the Cobalt Oxide Water Splitting Catalyst by X-ray Pair Distribution Function Analysis. J. Am. Chem. Soc., (2012). 134(27) 11096–11099. DOI: 10.1021/ja303826a

64. Newton, M.A.; Chapman, K.W.; Thompsett, D.; Chupas, P.J., Chasing Changing Nanoparticles with Time-Resolved Pair Distribution Function Methods. J. Am. Chem. Soc., (2012). 134(11) 5036–5039. DOI: 10.1021/ja2114163

63. Abouimrane, A.; Dambournet, D.; Chapman, K.W.; Chupas, P.J.; Weng, W.; Amine, K., A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium-Sulfur as a Positive Electrode. J. Am. Chem. Soc., (2012). 134(10) 4505–4508. DOI: 10.1021/ja211766q

62. Nemeth, K.; Chapman, K.W.; Balasubramanian, M.; Shyam, B.; Chupas, P.J.; Heald, S.M.; Newville, M.; Klingler, R.J.; Winans, R.E.; Almer, J.D.; Sandi, G.; Srajer, G., Efficient simultaneous reverse Monte Carlo modeling of pair-distribution functions and extended x-ray-absorption fine structure spectra of crystalline disordered materials. J. Chem. Phys., (2012). 136(7) . DOI: 10.1063/1.3684547

61. Schlueter, J.A.; Park, H.; Halder, G.J.; Armand, W.R.; Dunmars, C.; Chapman, K.W.; Manson, J.L.; Singleton, J.; McDonald, R.; Plonczak, A.; Kang, J.; Lee, C.; Whangbo, M.H.; Lancaster, T.; Steele, A.J.; Franke, I.; Wright, J.D.; Blundell, S.J.; Pratt, F.L.; Degeorge, J.; Turnbull, M.M.; Landee, C.P., Importance of Halogen•••Halogen Contacts for the Structural and Magnetic Properties of CuX2(pyrazine-N,N′-dioxide)(H2O)2 (X = Cl and Br). Inorg. Chem., (2012). 51(4) 2121–2129. DOI: 10.1021/ic201924q

60. Allan, P.K.; Chapman, K.W.; Chupas, P.J.; Hriljac, J.A.; Renouf, C.L.; Lucas, T.C.A.; Morris, R.E., Pair distribution function-derived mechanism of a single-crystal to disordered to single-crystal transformation in a hemilabile metal-organic framework. Chem. Sci., (2012). 3(8) 2559–2564. DOI: 10.1039/c2sc20261a

59. Zhao, H.Y.; Chupas, P.J.; Chapman, K.W., Fast time-resolved pair distribution function studies of supported gold nanoparticle formation. Z. Kristallogr. Cryst. Mater., (2012). 227(5) 268–271. DOI: 10.1524/zkri.2012.1497

58. Kim, H.J.; Nakamura, J.; Shao, H.Y.; Nakamura, Y.; Akiba, E.; Chapman, K.W.; Chupas, P.J.; Proffen, T., Variation in the ratio of Mg2Co and MgCo2 in amorphous-like mechanically alloyed MgxCo100-x using atomic pair distribution function analysis. Z. Kristallogr. Cryst. Mater., (2012). 227(5) 299–303. DOI: 10.1524/zkri.2012.1496

57. Shyam, B.; Chapman, K.W.; Balasubramanian, M.; Klingler, R.J.; Srajer, G.; Chupas, P.J., Structural and Mechanistic Revelations on an Iron Conversion Reaction from Pair Distribution Function Analysis. Angew. Chem., Int. Ed. Engl., (2012). 51(20) 4852–4855. DOI: 10.1002/anie.201200244

56. Dyer, L.G.; Chapman, K.W.; English, P.; Saunders, M.; Richmond, W.R., Insights into the crystal and aggregate structure of Fe3+ oxide/silica co-precipitates. Am. Mineral., (2012). 97(1) 63–69. DOI: 10.2138/am.2011.3874

55. Sciortino, N.F.; Scherl-Gruenwald, K.R.; Chastanet, G.; Halder, G.J.; Chapman, K.W.; Létard, J.F.; Kepert, C.J., Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework. Angew. Chem., Int. Ed. Engl., (2012). 51(40) 10154–10158. DOI: 10.1002/anie.201204387

54. Allan, P.K.; Wheatley, P.S.; Aldous, D.; Mohideen, M.I.; Tang, C.; Hriljac, J.A.; Megson, I.L.; Chapman, K.W.; De Weireld, G.; Vaesen, S.; Morris, R.E., Metal-organic frameworks for the storage and delivery of biologically active hydrogen sulfide. J. Chem. Soc., Dalton Trans., (2012). 41(14) 4060–4066. DOI: 10.1039/c2dt12069k

53. Werner-Zwanziger, U.; Chapman, K.W.; Zwanziger, J.W., Multinuclear NMR Study of Zinc Dicyanide. Z. Phys. Chem., (2012). 226(11) 1205–1218. DOI: 10.1524/zpch.2012.0285

52. Chapman, K.W.; Sava, D.F.; Halder, G.J.; Chupas, P.J.; Nenoff, T.M., Trapping Guests within a Nanoporous Metal-Organic Framework through Pressure-Induced Amorphization. J. Am. Chem. Soc., (2011). 133(46) 18583–18585. DOI: 10.1021/ja2085096

51. Zhao, H.Y.; Nenoff, T.M.; Jennings, G.; Chupas, P.J.; Chapman, K.W., Determining Quantitative Kinetics and the Structural Mechanism for Particle Growth in Porous Templates. J. Phys. Chem. Lett., (2011). 2(21) 2742–2746. DOI: 10.1021/jz201260n

50. Kim, H.; Nakamura, J.; Shao, H.Y.; Nakamura, Y.; Akiba, E.; Chapman, K.W.; Chupas, P.J.; Proffen, T., Insight into the Hydrogenation Properties of Mechanically Alloyed Mg50Co50 from the Local Structure. J. Phys. Chem. C, (2011). 115(41) 20335–20341. DOI: 10.1021/jp207197k

49. Wilkinson, A.P.; Morelock, C.R.; Greve, B.K.; Jupe, A.C.; Chapman, K.W.; Chupas, P.J.; Kurtz, C., Reducing the background from pressure vessels using a BRIM. J. Appl. Crystallogr., (2011). 44(5) 1047–1053. DOI: 10.1107/S0021889811028925

48. Dambournet, D.; Chapman, K.W.; Chupas, P.J.; Gerald, R.E. .; Penin, N.; Labrugere, C.; Demourgues, A.; Tressaud, A.; Amine, K., Dual Lithium Insertion and Conversion Mechanisms in a Titanium-Based Mixed-Anion Nanocomposite. J. Am. Chem. Soc., (2011). 133(34) 13240–13243. DOI: 10.1021/ja204284h

47. Sava, D.F.; Rodriguez, M.A.; Chapman, K.W.; Chupas, P.J.; Greathouse, J.A.; Crozier, P.S.; Nenoff, T.M., Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8. J. Am. Chem. Soc., (2011). 133(32) 12398–12401. DOI: 10.1021/ja204757x

46. Dambournet, D.; Chapman, K.W.; Koudriachova, M.V.; Chupas, P.J.; Belharouak, I.; Amine, K., Combining the Pair Distribution Function and Computational Methods To Understand Lithium Insertion in Brookite (TiO2). Inorg. Chem., (2011). 50(13) 5855–5857. DOI: 10.1021/ic2004326

45. Chupas, P.J.; Chapman, K.W.; Halder, G.J., Elucidating the Structure of Surface Acid Sites on γ-Al2O3. J. Am. Chem. Soc., (2011). 133(22) 8522–8524. DOI: 10.1021/ja2029574

44. Kim, H.; Nakamura, J.; Shao, H.Y.; Nakamura, Y.; Akiba, E.; Chapman, K.W.; Chupas, P.J.; Proffen, T., Local Structural Evolution of Mechanically Alloyed Mg50Co50 Using Atomic Pair Distribution Function Analysis. J. Phys. Chem. C, (2011). 115(15) 7723–7728. DOI: 10.1021/jp111711c

43. Halder, G.J.; Chapman, K.W.; Schlueter, J.A.; Manson, J.L., Pressure-Induced Sequential Orbital Reorientation in a Magnetic Framework Material. Angew. Chem., Int. Ed. Engl., (2011). 50(2) 419–421. DOI: 10.1002/anie.201003380

42. Greve, B.K.; Martin, K.L.; Lee, P.L.; Chupas, P.J.; Chapman, K.W.; Wilkinson, A.P., Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF3. J. Am. Chem. Soc., (2010). 132(44) 15496–15498. DOI: 10.1021/ja106711v

41. Oxford, S.M.; Lee, P.L.; Chupas, P.J.; Chapman, K.W.; Kung, M.C.; Kung, H.H., Study of Supported PtCu and PdAu Bimetallic Nanoparticles Using In-Situ X-ray Tools'. J. Phys. Chem. C, (2010). 114(40) 17085–17091. DOI: 10.1021/jp103675n

40. Chapman, K.W.; Chupas, P.J.; Nenoff, T.M., Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation. J. Am. Chem. Soc., (2010). 132(26) 8897–8899. DOI: 10.1021/ja103110y

39. Chapman, K.W.; Chupas, P.J.; Halder, G.J.; Hriljac, J.A.; Kurtz, C.; Greve, B.K.; Ruschman, C.J.; Wilkinson, A.P., Optimizing high-pressure pair distribution function measurements in diamond anvil cells. J. Appl. Crystallogr., (2010). 43(2) 297–307. DOI: 10.1107/S0021889810002050

38. Phillips, A.E.; Halder, G.J.; Chapman, K.W.; Goodwin, A.L.; Kepert, C.J., Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide. J. Am. Chem. Soc., (2010). 132(1) 10–11. DOI: 10.1021/ja906895j

37. Harrington, R.; Hausner, D.B.; Bhandari, N.; Strongin, D.R.; Chapman, K.W.; Chupas, P.J.; Middlemiss, D.S.; Grey, C.P.; Parise, J.B., Investigation of Surface Structures by Powder Diffraction: A Differential Pair Distribution Function Study on Arsenate Sorption on Ferrihydrite. Inorg. Chem., (2010). 49(1) 325–330. DOI: 10.1021/ic9022695

36. Chapman, K.W.; Halder, G.J.; Chupas, P.J., Pressure-Induced Amorphization and Porosity Modification in a Metal-Organic Framework. J. Am. Chem. Soc., (2009). 131(48) 17546–17547. DOI: 10.1021/ja908415z

35. Neville, S.M.; Halder, G.J.; Chapman, K.W.; Duriska, M.B.; Moubaraki, B.; Murray, K.S.; Kepert, C.J., Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material. J. Am. Chem. Soc., (2009). 131(34) 12106–12108. DOI: 10.1021/ja905360g

34. Southon, P.D.; Liu, L.; Fellows, E.A.; Price, D.J.; Halder, G.J.; Chapman, K.W.; Moubaraki, B.; Murray, K.S.; Létard, J.F.; Kepert, C.J., Dynamic Interplay between Spin-Crossover and Host-Guest Function in a Nanoporous Metal-Organic Framework Material. J. Am. Chem. Soc., (2009). 131(31) 10998–11009. DOI: 10.1021/ja902187d

33. Halder, G.J.; Park, H.; Funk, R.J.; Chapman, K.W.; Engerer, L.K.; Geiser, U.; Schlueter, J.A., In-Situ X-ray Diffraction Studies of Host-Guest Properties in Nanoporous Zinc-Triazolate-Based Framework Materials. Cryst. Growth Des., (2009). 9(8) 3609–3614. DOI: 10.1021/cg900349c

32. Chupas, P.J.; Chapman, K.W.; Chen, H.L.; Grey, C.P., Application of high-energy X-rays and Pair-Distribution-Function analysis to nano-scale structural studies in catalysis. Catal. Today, (2009). 145(3) 213–219. DOI: 10.1016/j.cattod.2009.03.026

31. Chapman, K.W.; Chupas, P.J., Anomalous Thermal Expansion of Cuprites: A Combined High Resolution Pair Distribution Function and Geometric Analysis. Chem. Mater., (2009). 21(2) 425–431. DOI: 10.1021/cm802900t

30. Duriska, M.B.; Neville, S.M.; Moubaraki, B.; Cashion, J.A.; Halder, G.J.; Chapman, K.W.; Balde, C.; Létard, J.F.; Murray, K.S.; Kepert, C.J.; Batten, S.R., A Nanoscale Molecular Switch Triggered by Thermal, Light, and Guest Perturbation. Angew. Chem., Int. Ed. Engl., (2009). 48(14) 2549–2552. DOI: 10.1002/anie.200805178

29. Readman, J.E.; Forster, P.M.; Chapman, K.W.; Chupas, P.J.; Parise, J.B.; Hriljac, J.A., Pair distribution function analysis of pressure treated zeolite Na-A. Chem. Commun., (2009). (23) 3383–3385. DOI: 10.1039/b902874a

28. Halder, G.J.; Chapman, K.W.; Neville, S.M.; Moubaraki, B.; Murray, K.S.; Létard, J.F.; Kepert, C.J., Elucidating the Mechanism of a Two-Step Spin Transition in a Nanoporous Metal-Organic Framework. J. Am. Chem. Soc., (2008). 130(51) 17552–17562. DOI: 10.1021/ja8068038

27. Cetinkol, M.; Wilkinson, A.P.; Chapman, K.W., Scandium tungstate above 2.5 GPa. Solid State Commun., (2008). 148(11) 511–515. DOI: 10.1016/j.ssc.2008.10.002

26. Lee, J.H.; Aydiner, C.C.; Almer, J.; Bernier, J.; Chapman, K.W.; Chupas, P.J.; Haeffner, D.; Kump, K.; Lee, P.L.; Lienert, U.; Miceli, A.; Vera, G., Synchrotron applications of an amorphous silicon flat-panel detector. J. Synchrotron Radiat., (2008). 15(5) 477–488. DOI: 10.1107/S090904950801755X

25. Chapman, K.W.; Halder, G.J.; Chupas, P.J., Guest-dependent high pressure phenomena in a nanoporous metal-organic framework material. J. Am. Chem. Soc., (2008). 130(32) 10524–10526. DOI: 10.1021/ja804079z

24. Chupas, P.J.; Chapman, K.W.; Kurtz, C.; Hanson, J.C.; Lee, P.L.; Grey, C.P., A versatile sample-environment cell for non-ambient X-ray scattering experiments. J. Appl. Crystallogr., (2008). 41(4) 822–824. DOI: 10.1107/S0021889808020165

23. Chapman, K.W.; Chupas, P.J.; Winans, R.E.; Pugmire, R.J., High pressure pair distribution function studies of Green River oil shale. J. Phys. Chem. C, (2008). 112(27) 9980–9982. DOI: 10.1021/jp803900s

22. Neville, S.M.; Halder, G.J.; Chapman, K.W.; Duriska, M.B.; Southon, P.D.; Cashion, J.D.; Létard, J.F.; Moubaraki, B.; Murray, K.S.; Kepert, C.J., Single-crystal to single-crystal structural transformation and photomagnetic properties of a porous iron(II) spin-crossover framework. J. Am. Chem. Soc., (2008). 130(9) 2869–2876. DOI: 10.1021/ja077958f

21. Wu, Y.; Kobayashi, A.; Halder, G.J.; Peterson, V.K.; Chapman, K.W.; Lock, N.; Southon, P.D.; Kepert, C.J., Negative Thermal Expansion in the Metal-Organic Framework Material Cu3(1,3,5-benzenetricarboxylate)2. Angew. Chem., Int. Ed. Engl., (2008). 47(46) 8929–8932. DOI: 10.1002/anie.200803925

20. Page, K.; Schade, C.S.; Zhang, J.; Chupas, P.J.; Chapman, K.W.; Proffen, T.; Cheetham, A.K.; Seshadri, R., Preparation and characterization of Pd2Sn nanoparticles. Mater. Res. Bull., (2007). 42(12) 1969–1975. DOI: 10.1016/j.materresbull.2007.05.010

19. Chupas, P.J.; Chapman, K.W.; Jennings, G.; Lee, P.L.; Grey, C.P., Watching nanoparticles grow:: The mechanism and kinetics for the formation of TiO2-supported platinum nanoparticles. J. Am. Chem. Soc., (2007). 129(45) 13822–13824. DOI: 10.1021/ja076437p

18. Chapman, K.W.; Chupas, P.J., Pressure enhancement of negative thermal expansion behavior and induced framework softening in zinc cyanide. J. Am. Chem. Soc., (2007). 129(33) 10090–10091. DOI: 10.1021/ja073791e

17. Martin, C.D.; Chapman, K.W.; Chupas, P.J.; Prakapenka, V.; Lee, P.L.; Shastri, S.D.; Parise, J.B., Compression, thermal expansion, structure, and instability of CaIrO3, the structure model of MgSiO3 post-perovskite. Am. Mineral., (2007). 92(7) 1048–1053. DOI: 10.2138/am.2007.2473

16. Martin, C.D.; Chupas, P.J.; Chapman, K.W.; Parise, J.B., Local versus average structure:: a study of neighborite (NaMgF3) utilizing the pair distribution function method for structure determination. J. Appl. Crystallogr., (2007). 40(3) 441–448. DOI: 10.1107/S0021889807014148

15. Chupas, P.J.; Chapman, K.W.; Lee, P.L., Applications of an amorphous silicon-based area detector for high-resolution, high-sensitivity and fast time-resolved pair distribution function measurements. J. Appl. Crystallogr., (2007). 40(3) 463–470. DOI: 10.1107/S0021889807007856

14. Neville, S.M.; Leita, B.A.; Offermann, D.A.; Duriska, M.B.; Moubaraki, B.; Chapman, K.W.; Halder, G.J.; Murray, K.S., Spin-crossover studies on a series of 1D chain and dinuclear iron(II) triazine-dipyridylamine compounds. Eur. J. Inorg. Chem., (2007). (8) 1073–1085. DOI: 10.1002/ejic.200601034

13. Chapman, K.W.; Chupas, P.J.; Kurtz, C.A.; Locke, D.R.; Parise, J.B.; Hriljac, J.A., Hydrostatic low-range pressure applications of the Paris-Edinburgh cell utilizing polymer gaskets for diffuse X-ray scattering measurements. J. Appl. Crystallogr., (2007). 40(1) 196–198. DOI: 10.1107/S0021889806047923

12. Chapman, K.W.; Chupas, P.J.; Maxey, E.R.; Richardson, J.W., Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2: The relative importance of accessible coordination sites and van der Waals interactions. Chem. Commun., (2006). (38) 4013–4015. DOI: 10.1039/b607250j

Pre-Independent Publications. 

Doctoral Research (with Cameron J. Kepert, University of Sydney)

11. Chapman, K.W.; Hagen, M.; Kepert, C.J.; Manuel, P., Low energy phonons in the NTE compounds Zn(CN)(2) and ZnPt(CN)(6). Physica B, (2006). 385 60-62.

10. Chapman, K.W.; Chupas, P.J.; Kepert, C.J., Compositional dependence of negative thermal expansion in the Prussian blue analogues (MPtIV)-Pt-II(CN)(6) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd). J. Am. Chem. Soc., (2006). 128(21) 7009-7014.

9. Pretsch, T.; Chapman, K.W.; Halder, G.J.; Kepert, C.J., Dehydration of the nanoporous coordination framework Er-III Co-III(CN)6 center dot 4(H2O): single crystal to single crystal transformation and negative thermal expansion in Er-III Co-III(CN)6. Chem. Commun., (2006)(17) 1857-1859.

8. Kurmoo, M.; Kumagai, H.; Chapman, K.W.; Kepert, C.J., Reversible ferromagnetic-antiferromagnetic transformation upon dehydration-hydration of the nanoporous coordination framework, Co-3(OH)(2)(C4O4)(2) center dot 3H(2)O. Chem. Commun., (2005)(24) 3012-3014.

7. Goodwin, A.L.; Chapman, K.W.; Kepert, C.J., Guest-dependent negative thermal expansion in nanoporous Prussian Blue analogues (MPtIV)-Pt-II(CN)(6)center dot x{H2O} (0 <= x <= 2; M = Zn, Cd). J. Am. Chem. Soc., (2005). 127(51) 17980-17981.

6. Chapman, K.W.; Southon, P.D.; Weeks, C.L.; Kepert, C.J., Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues. Chem. Commun., (2005)(26) 3322-3324.

5. Chapman, K.W.; Chupas, P.J.; Kepert, C.J., Selective recovery of dynamic guest structure, in a nanoporous Prussian blue through in situ X-ray diffraction: A differential pair distribution function analysis. J. Am. Chem. Soc., (2005). 127(32) 11232-11233.

4. Chapman, K.W.; Chupas, P.J.; Kepert, C.J., Direct observation of a transverse vibrational mechanism for negative thermal expansion in Zn(CN)(2): An atomic pair distribution function analysis. J. Am. Chem. Soc., (2005). 127(44) 15630-15636.

3. Kumagai, H.; Chapman, K.W.; Kepert, C.J.; Kurmoo, M., Binary metal(II)-pyromellitate coordination polymers, M-2(pm) (M = Co, Fe, Mn): synthesis, structures and magnetic properties. Polyhedron, (2003). 22(14-17) 1921-1927.

Undergraduate Research (with Meredith J.T. Jordan, University of Sydney)

2. Chapman, K.; Crittenden, D.; Bevitt, J.; Jordan, M.J.T.; Del Bene, J.E., Relating environmental effects and structures, IR, and NMR properties of hydrogen-bonded complexes: ClH : pyridine. J. Phys. Chem. A, (2001). 105(22) 5442-5449.

1. Bevitt, J.; Chapman, K.; Crittenden, D.; Jordan, M.J.T.; Del Bene, J.E., An ab initio study of anharmonicity and field effects in hydrogen-bonded complexes of the deuterated analogues of HCl and HBr with NH(3) and N(CH(3))(3). J. Phys. Chem. A, (2001). 105(13) 3371-3378.