Metals

Definition

vaginas to screw are sometimes described as an arrangement of positive ions surrounded by a sea of delocalized electrons. Metals occupy the bulk of the periodic table, while non-metallic elements can only be found on its right-hand side. A diagonal line, drawn from boron (B) topolonium (Po), separates the metals from the nonmetals. Most elements on this line are metalloids, sometimes called semiconductors. This is because these elements exhibit electrical properties common to both conductors and insulators. Elements to the lower left of this division line are called metals, while elements to the upper right of the division line are called nonmetals.

An alternative definition of metal refers to the band theory. If one fills the energy bands of a material with available electrons and ends up with a top band partly filled then the material is a metal. This definition opens up the category for metallic polymers and other organic metals. These synthetic materials often have the characteristic silvery gray reflectiveness (luster) of elemental metals.

Astronomy

Main article: Metallicity

In the specialized usage of astronomy and astrophysics, the term "metal" is often used to refer collectively to all elements other than hydrogen or helium, including substances as chemically non-metallic as neon, fluorine, and oxygen. Nearly all the hydrogen and helium in the Universe was created in Big Bang nucleosynthesis, whereas all the "metals" were produced by nucleosynthesis in stars or supernovae. The Sun and the Milky Way Galaxy are composed of roughly 74% hydrogen, 24% helium, and 2% "metals" (the rest of the elements; atomic numbers 3–118) by mass.

The concept of a metal in the usual chemical sense is irrelevant in stars, as the chemical bonds that give elements their properties cannot exist at stellar temperatures.

Properties

Chemical

Metals are usually inclined to form cations through electron loss, reacting with oxygen in the air to form oxides over changing timescales (iron rusts over years, while potassium burns in seconds). Examples:

4 Na + O₂ → 2 Na₂O (sodium oxide)

2 Ca + O₂ → 2 CaO (calcium oxide)

4 Al + 3 O₂ → 2 Al₂O₃ (aluminium oxide).

The transition metals (such as iron, copper, zinc, and nickel) take much longer to oxidize. Others, like palladium, platinum and gold, do not react with the atmosphere at all. Some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades (like aluminium, magnesium, some steels, and titanium). The oxides of metals are generally basic, as opposed to those of nonmetals, which are acidic.

Painting, anodizing or plating metals are good ways to prevent their corrosion. However, a more reactive metal in the electrochemical seriesmust be chosen for coating, especially when chipping of the coating is expected. Water and the two metals form an electrochemical cell, and if the coating is less reactive than the coatee, the coating actually promotes corrosion.

Physical

Metals in general have high electrical conductivity which depends on their valency of ions, thermal conductivity, luster and density, and the ability to be deformed under stress without cleaving. While there are several metals that have low density, hardness, and melting points, these (the alkali and alkaline earth metals) are extremely reactive, and are rarely encountered in their elemental, metallic form. Optically speaking, metals are opaque, shiny and lustrous. This is because visible lightwaves are not readily transmitted through the bulk of their microstructure. The large number of mobile electrons in any typical metallic solid (element or alloy) is responsible for the fact that they can never be categorized as transparent materials.

The majority of metals have higher densities than the majority of nonmetals. Nonetheless, there is wide variation in the densities of metals; lithium is the least dense solid element and osmium is the densest. The metals of groups I A and II A are referred to as the light metals because they are exceptions to this generalization. The high density of most metals is due to the tightly packed crystal lattice of the metallic structure. The strength of metallic bonds for different metals reaches a maximum around the center of thetransition metal series, as those elements have large amounts of delocalized electrons in tight binding type metallic bonds. However, other factors (such as atomic radius, nuclear charge, number of bonding orbitals, overlap of orbital energies, and crystal form) are involved as well. Most non-ferrous metals can be recycled many times during their life cycle.

Electrical

The electrical and thermal conductivity of metals originate from the fact that in the metallic bond, the outer electrons of the metal atoms form a gas of nearly free electrons, moving as an electron gas in a background of positive charge formed by the ion cores. Good mathematical predictions for electrical conductivity, as well as the electrons' contribution to the heat capacity and heat conductivity of metals can be calculated from the free electron model, which does not take the detailed structure of the ion lattice into account.

When considering the exact band structure and binding energy of a metal, it is necessary to take into account the positive potential caused by the specific arrangement of the ion cores – which is periodic in crystals. The most important consequence of the periodic potential is the formation of a small band gap at the boundary of the Brillouin zone. Mathematically, the potential of the ion cores can be treated by various models, the simplest being the nearly free electron model

Mechanical

Mechanical properties of metals include ductility, which is largely due to their inherent capacity for plastic deformation. Reversible elasticity in metals can be described by Hooke's Law for restoring forces, where the stress is linearly proportional to the strain. Forces larger than theelastic limit, or heat, may cause a permanent (irreversible) deformation of the object, known as plastic deformation or plasticity. This irreversible change in atomic arrangement may occur as a result of:

• The action of an applied force (or work). An applied force may be tensile (pulling) force, compressive (pushing) force, shear, bending ortorsion (twisting) forces.

• A change in temperature (or heat). A temperature change may affect the mobility of the structural defects such as grain boundaries, point vacancies, line and screw dislocations, stacking faults and twins in both crystalline and non-crystalline solids. The movement or displacement of such mobile defects is thermally activated, and thus limited by the rate of atomic diffusion.

Viscous flow near grain boundaries, for example, can give rise to internal slip, creepand fatigue in metals. It can also contribute to significant changes in the microstructure like grain growth and localized densification due to the elimination of intergranular porosity. Screw dislocations may slip in the direction of any lattice plane containing the dislocation, while the principal driving force for "dislocation climb" is the movement or diffusion of vacancies through a crystal lattice.

In addition, the nondirectional nature of metallic bonding is also thought to contribute significantly to the ductility of most metallic solids. When the planes of an ionic bondslide past one another, the resultant change in location shifts ions of the same charge into close proximity, resulting in the cleavage of the crystal; such shift is not observed in covalently bonded crystals where fracture and crystal fragmentationoccurs.

Alloys

Main article: Alloy

An alloy is a mixture of two or more elements in solid solution in which the major component is a metal. Most pure metals are either too soft, brittle or chemically reactive for practical use. Combining different ratios of metals as alloys modifies the properties of pure metals to produce desirable characteristics. The aim of making alloys is generally to make them less brittle, harder, resistant to corrosion, or have a more desirable color and luster. Of all the metallic alloys in use today, the alloys of iron (steel, stainless steel, cast iron, tool steel, alloy steel) make up the largest proportion both by quantity and commercial value. Iron alloyed with various proportions of carbon gives low, mid and high carbon steels, with increasing carbon levels reducing ductility and toughness. The addition of silicon will produce cast irons, while the addition of chromium, nickel and molybdenum to carbon steels (more than 10%) results in stainless steels.

Other significant metallic alloys are those of aluminium, titanium, copper and magnesium. Copper alloys have been known since prehistory—bronze gave the Bronze Age its name—and have many applications today, most importantly in electrical wiring. The alloys of the other three metals have been developed relatively recently; due to their chemical reactivity they require electrolytic extraction processes. The alloys of aluminium, titanium and magnesium are valued for their high strength-to-weight ratios; magnesium can also provide electromagnetic shielding. These materials are ideal for situations where high strength-to-weight ratio is more important than material cost, such as in aerospace and some automotive applications.

Alloys specially designed for highly demanding applications, such as jet engines, may contain more than ten elements.