The first thing a person should do when identifying snakes is understanding the geographical location of the find. Once the geographical area has been identified, its much easier identifying the snake as you would have developed a presupposition towards the locally and thus towards the snake.
The most useful field identification characteristics to use in identifying snakes is their color and patterns. Some snakes like the Sri Lankan and Indian Cobras are easy to identify due to their prominent monocle and spectacle markings on the back of their neck. Ornate flying snake is easy to identify as its the most colorful snake in Sri Lanka. Some Sri Lankan land snakes are either gray or brown with discernible markings which can give away their identity. However there are many snakes with absolutely no discernible pattern which makes them harder to identify at a distance. Rat snakes and Racers are generally one color with no lines, blotches, or bands. Coral snakes for example have a well colored body that can be identified from a distance.
Another important characteristic to identify snakes is the head color and shape. All vipers for example posses a arrow shaped head with puffy cheeks. Certain snakes like the Green Vine Snake have an extremely narrow pointed head which can easily be identified from a distance.
An easy method of telling the difference between a venomous and non-venomous snake is to look at the shape of the pupil. Non-venomous snakes all have a round pupil (in the center of the eye) whereas all venomous snakes have a vertical elliptical (cat-like) shaped pupil. All pit-vipers (venomous) also have a small hole (pit) between the nostril and the eye which it used to target warm blooded prey. These pits are aligned with heat receptors and can pinpoint warm blooded prey accurately as well as in total darkness.
Heat sensing pits below the eyes.
Elliptical pupils of the eyes (Exception: Pythons)
Larger scales with no heat sensing pits
Circular pupils of the eye (Exception: Boomslang (Africa), Green Mamba (Africa), Black Mamba (Africa)
This is the most reliable way of identifying if a snake is venomous or not. Its the only reliable indicator, however the disposition of its fangs doesn't make it easy for an immediate identification.
Certain species of snakes are back-fanged (Opisthoglyphous) while others are front-fanged (Elapidae)
Its a common misconception that back-fanged snakes are not harmful to humans, however some of the back-fanged venomous snakes can rival that of a Cobra venom (Example: Boomslang, Coral snakes). As certain species are back-fanged, they are at a disadvantage when envenoming humans; however if given a chance, certain extremities of skin (fingers, toes) pose a greater risk from bites.
The following table illustrates the Venomous and Non-venomous snakes in detail. Some species are easier identify owing to their characteristic color and patterns.
Green Tree Viper
Russel's Viper
Saw-scaled Viper
Sri Lankan banded Rat Snake
Indian Rat Snake
Sri Lanka Rock Python
The head of the tit-polonga is wider than the neck and its top is covered with small scales, the nostril is large, and a large scale exists over each eye. Along the back is a row of 22 to 24 elliptical markings up to above the base of the tail, and a row of fig-shaped lateral blotches. It is highly venomous