Bispinel Multilayers- toward multifunctional materials

By stacking materials of compatible structure with different functionality, we hope to create

multifunctional materials- thus coupling the triad of mechanical stress, magnetic fields, and electric fields.

Local electronic and magnetic structure of mixed ferrite multilayer materials

Wells, Daniel M.; Cheng, J.; Ellis, Donald E.; Wessels, B. W.

Physical Review B, vol. 81, Issue 17, id. 174422 (2010)

Multilayer bispinel composites, in which one member is magnetite, Fe3O4 , and the other is XFe2O4 (X=Mg,Mn,Ni,Co) are modeled using first-principles density-functional theory in a periodic supercell scheme. Effects of transition metal composition on charge distribution and magnetization are examined in detail in order to determine the range of variability attainable upon cation substitution and distribution. Magnetic measurement on bilayer Fe3O4/MgFe2O4 and Fe3O4/CoFe2O4 compositions are reported, showing a considerable increase in magnetization relative to the separate bulk compounds, in qualitative agreement with theory.