Publications

Journals:

(45) C. E. Johnson, J. Schwarz, M. Deegbey, O. Prakash, K. Sharma, P. Huang, T. Ericsson, L. Häggström, J. Bendix, A. K. Gupta, E. Jakubikova, K. Wärnmark and R. Lomoth "Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited" Chem. Sci. 2023.  [link]

(44) M. A. Shameem, A. K. Gupta, M. Erdelyi,  A. Orthaber "1-Phospha-Butadienes and 1H-Phospholes via Alkynylation of Acetylenic Phosphaalkenes" ChemPlusChem 2023,88,   e2023000. [link]

(43) M. A. Shameem,  J. A. L. Wells,  A. K. Gupta,  A. Orthaber "One, Two Three – Phosphaalkene Decoration Tailoring Solubility and Electronic Properties of Truxene-Based Electron Acceptors" Chem. Eur. J.  2023. [link]

(42) O. Prakash, L. Lindh, N. Kaul, N. W. Rosemann, I. B. Losada, C. Johnson, P. Chábera, A. Ilic, J. Schwarz, A. K. Gupta, J. Uhlig, T. Ericsson, L. Häggström, P. Huang, J. Bendix, D. Strand, A. Yartsev, R. Lomoth, P. Persson, and K. Wärnmark "Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States", Inorg. Chem. 2022, ASAP. [link]

(41) N. D’Imperio, V. Pelliccioli, S. Grecchi, A. Bossi, F. Vasile, S. Cauteruccio, A. I. Arkhypchuk, A. K. Gupta, A. Orthaber, S. Ott, and E. Licandro “Highly Conjugated Bis(benzo[b]phosphole)-P-oxides: Synthesis and Electrochemical, Optical, and Computational Studies” Eur. J. Org.Chem. 2023, 26, e2022012. [link]

(40) S. Dutta, S. Mukherjee, O. T. Qazvini, A. K. Gupta, S. Sharma, D. Mahato, R. Babarao, S. K. Ghosh “Three-in-One C2H2-Selectivity-Guided Adsorptive Separation across an Isoreticular Family of Cationic Square-Lattice MOFs”, Angew. Chem. Int. Ed. 2022, 61, e202114132. [link]

(39) G. Maeda, P. J. Gilissen, A. Rudenko, J. v.-d. Wal, C. Bourgard, A. K. Gupta, P. Sunnerhagen, J. J. E. Munissi, S. S. Nyandoro, and M. Erdélyi, “Oxygenated Cyclohexene Derivatives from the Stem and Root Barks of Uvaria pandensis” J. Nat. Prod. 2021, 84, 3080-3089. [link]

(38) L. Lindh,   O. Gordivska,   S. Persson,   H. Michaels,   H. Fan,   P. Chabera,   N. W Rosemann,   A. K. Gupta,   I. Benesperi,   J. Uhlig,   O. Prakash,   E. Sheibani,   K. S. Kjær,   G. Boschloo,   A. Yartsev,   M. Freitag,   R. Lomoth,   P. Persson  and  K. Wärnmark, “Dye-Sensitized Solar Cells based on Fe N-heterocyclic Carbene Photosensitizers with Improved Rod-like Push-Pull Functionality” Chem. Sci. 2021, 12, 16035-16053. [link]

(37) A. K. Gupta, P. V. V. N. Kishore, J.-Y. Cyue, J.-H. Liao, W. Duminy, W. E. van Zyl and C. W. Liu "[Cu{SC(O)OiPr}]96: A Giant Self-Assembled Copper(I) Supramolecular Wheel Exhibiting Photoluminescence Tuning and Correlations with Dynamic Solvation and Solventless Synthesis", Inorg. Chem. 2021, 60, 8973-8983.[link]

(36) N. Queyriaux, C. Esmieu, A. K. Gupta, L. Vendier, S. Ott, M. Orio, and L. Hammarström "Electrochemical, spectroscopic and computational investigations of a series of polypyridyl ruthenium(II) complexes: reduced states characterizations" Eur. J. Inorg. Chem., 2021, 1263-1270. [link]

(35) M. Boniolo, P. Chernev, M. H. Cheah, P. A. Heizmann, P. Huang, S. I. Shylin, N. Salhi, Md K. Hossain, A. K. Gupta, J. Messinger, A. Thapper and M. Lundberg "Electronic and geometric structure effects on one-electron oxidation of first-row transition metals in the same ligand framework" Dalton Trans. 2021, 50, 660-674. [link]

(34) D. Umereweneza, Y. Atilaw, A. Rudenko, Y. Gütlin, C. Bourgard, A. K. Gupta, A. Orthaber, T. Muhizi, P. Sunnerhagen, M. Erdélyi, A. Gogoll, "Antibacterial and Cytotoxic Prenylated Dihydrochalcones from Eriosema montanum" Fitoterapia 2021, 149, 104809.  [link] 

(33)  J. A. L. Wells, M. A. Shameem, A. K. Gupta, and A. Orthaber “Core and double bond functionalization of Cyclopentadithiophene- phosphaalkenes”  Inorg. Chem. Front. 2020,7, 4052-4061. [link]

(32) J. P. Green, D. M. Salazar, A. K. Gupta, and A. Orthaber “The golden age of fluorenylidene phosphaalkenes -Synthesis, structures and optical properties of heteroaromatic derivatives and their gold complexes”, J. Org. Chem., 2020, 85, 14619–14626. [link]

(31) A. C. Reiersølmoen, S. Battaglia, S. Øien-Ødegaard, A. K. Gupta, A. Fiksdahl, R. Lindh, M. Erdélyi, “Symmetry of Three-Center, Four-Electron Bonds” Chem. Sci. 2020, 11, 7979-7990.[link]

(30) T. Slanina, R. Ayub, J. Toldo, J. Sundell, W. Rabten, M. Nicaso, I. V. Alabugin, A. K. Gupta, I. Fdez, G. R. Lindh, A. Orthaber, R. J. Lewis, G. Grönberg, J. Bergman, and H. Ottosson, “On the Impact of Excited State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes”, J. Am. Chem. Soc. 2020, 142, 10942–10954. [link]  

(29) A. K. Gupta and A. Orthaber, "Serendipitous and targeted synthesis of high nuclearity clusters – carbonate and oxalate encapsulating silver alkynides" Cryst. Growth Des. 2020, 20, 4232–4237. [link]  

(28) A. C. Reiersølmoen, D. Csókás, S. Øien-Ødegaard, A. Vanderkooy, A. K. Gupta, A.-C. C. Carlsson, A. Orthaber, A. Fiksdahl, I. Pápai, and M. Erdélyi, "The catalytic activity of trans-bis(pyridine)gold Complexes” J. Am. Chem. Soc. 2020, 142, 13, 6439–6446 . [link]

(27) G. Maeda, J. Wal, A. K. Gupta, Joan J.E. M., A. Orthaber, P. Sunnerhagen, S. S. Nyandoro, M. Erdélyi “Polyoxygenated Cyclohexene Derivatives from the Roots of Monanthotaxis trichocarpa” J. Nat. Prod. 2020, 83, 2, 210-215. [link] 

(26) A. K. Gupta, A. Orthaber, “The self-assembly of [{Ag3(tBuC≡C)2}n](PF6)n building units into a template-free cuboctahedron cluster and anion encapsulating silver cages”,  Inorg. Chem. 2019, 58, 16236-16240. [link] 

(25) A. K. Gupta, A. Orthaber, “Facile synthesis of silver alkynide cluster and coordination polymers using  picolinic acid as co-ligand”, Dalton Trans. 2019, 48, 16518-16524. DOI: 10.1039/C9DT03697K. [link] 

(24) S. Roy, Z. Huang, A. Bhunia, A. Castner, A. K. Gupta, X. Zou, S. Ott “Electrocatalytic Hydrogen Evolution from a Cobaloxime based Metal-Organic Framework Thin Film” J. Am. Chem. Soc. 2019, 141, 15942-15950. [link]                  

(23) P. V. V. N. Kishore, De-Ren Shi, Jian-Hong Liao, A. K. Gupta and C. W.  Liu,  Synthesis and structural characterization of xanthate ligated hydrido Cu(I) clusters and Cu(I) coordination polymer, Inorg. Chim. Acta, 2019, 496, 119068. [link]

(22) A. K. Gupta, D. M. Salazar and A. Orthaber, Solvent and Counter‐Ion Induced Coordination Environment Changes Towards Ag(I) Coordination Polymers, Eur. J. Inorg. Chem., 2019, 3740–3744 . [link]

(21) A. K. Gupta, J. P. Green, and Andreas Orthaber, Rearrangement and Redistribution reaction of Ph2PCH2TMS with PhAsCl2 or AsCl3, Phosphorus Sulfur Silicon Relat. Elem. 2019, 194, 967-971 . [link]

(20) A. Vanderkooy, A. K. Gupta, Tamás Földes, Sofia Lindblad, Andreas Orthaber, Imre Pápai and Mate Erdelyi, Halogen Bonding Helicates Encompassing Iodonium Cations, Angew. Chem. Int. Ed.,  2019, 58, 9012-9016. [link]

(19) J. P. Green, A. K. Gupta, and Andreas Orthaber, Effect of Arsenic Coordination State on the Structure, Aromaticity, and Optical Properties of Dithieno[3,2-b:2′,3′-d]-arsoles, Eur. J. Inorg. Chem., 2019, 1539-1543. [link]

(18) J. Mai, A. Arkhypchuk, A. K. Gupta, and S. Ott, Reductive coupling of two aldehydes to unsymmetrical E-alkenes via phosphaalkene and phosphinate intermediates, Chem. Commun. 2018, 54, 7163-7166. [link]

(17) D. M. Salazar, A. K. Gupta, and A. Orthaber, Reactivity Studies of imine-functionalised phosphaalkene; Unusual electrostatic and supramolecular stabilization of σ2λ3-phosphorus Motif via hydrogen bonding Dalton Trans. 2018, 47, 10404-10409.  [link]

(16) A. K. Gupta, S. A. D. Reddy, P. Rajasekar, P. Prakash and R. Boomishankar, Chloro-Bridged Hexanuclear Pd(II) Clusters Supported by cis-Blocking Tris(imido)phosphate Trianions, ChemistrySelect, 2017, 2, 10636-10641. [link]

(15) A. Yadav, A. K. Gupta, A. Steiner and R. Boomishankar, Mapping the Assembly of Metal-organic Cages into Complex Coordination Networks, Chem. Eur. J.  2017, 23, 18296-18302. [link]  

(14) A. K. Gupta, S. Akkarasamiyo and A. Orthaber, Rich Coordination Chemistry of pi-Acceptor Dibenzoarsole Ligands, Inorg. Chem. 2017, 56, 4505-4512. [link]

(13) A. K. Gupta, P. V. V. N. Kishore, J.-H. Liao, Y.-J. Chen, and C. W. Liu, Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block, Eur. J. Inorg. Chem., 2017, 1989–1993. [link

(12) A. K. Gupta, A. Yadav, K. R. Ramya, A. K. Srivastava, S. Nandi, H. Paithankar, J. C. and R. Boomishankar, A Neutral Cluster Cage with a Tetrahedral [PdII12L6] Framework: Crystal Structures and Host-Guest Studies, Inorg. Chem. 2015, 54, 3196-3202. (Appeared in most read) [link]

(11) A. K. Gupta , A. K. Srivastava and R. Boomishankar, A tetrakis(amido)phosphonium cation containing 2-pyridyl (2Py) substituents, [P(N2Py)4] +, and its reactivity studies with Ag(I) salts, J. Chem. Sci., 2015, 127, 619-629. (Invited article) [link] 

(10) A. K. Gupta, A. K. Srivastava, I. K. Mahawar and R. Boomishankar, Discrete and Polymeric Cu(II) complexes derived from in-situ generated bis(pyridylamido)phosphate,  [PO2(NHPy)2] − ligands, Cryst. Growth Des., 2014, 17, 1701 -1709. (Appeared in spotlight) [link]

(9) A. K. Gupta, A. Yadav and R. Boomishankar, Discrete and polymeric coordination assemblies derived from 3-pyridyl attached flexible phosphoric  triamide ligand and copper salts, PNAS, India, Sect. A Phys. Sci., 2014, 84, 205-212. (Invited article) [link]

 (8) A. K. Gupta, S. A. D. Reddy and R. Boomishankar, Facile formation of stable tris(imido)phosphate trianions as their tri-and hexanuclear Pd(II) complexes  in protic solvents, Inorg. Chem., 2013, 52, 7608-7614. [link]

(7) A. K. Gupta, S. S. Nagarkar and R. Boomishankar, Zn(II) coordination polymer of an in-situ generated 4-pyridyl (4py) attached bis(amido)phosphate ligand, [PO2(NH4py)2]− showing preferential water uptake over aliphatic alcohols, Dalton Trans., 2013, 42, 10964-10974. [link]

(6) A. Balamurugan, A. K. Gupta, R. Boomishankar, Mundalapuddy Laximipathy Reddy and Manickam Jayakannan, Heavy Atom Effect Driven Organic Phosphors and Their Luminescent Lanthanide Metal–Organic Frameworks, ChemPlusChem, 2013, 78, 737-745. [link]

(5) A. K. Gupta, A. Steiner and R. Boomishankar, Tri-, hepta- and octa-nuclear Ag(I) complexes derived from 2-pyridyl functionalize tris(amido)phosphate ligands, Dalton Trans., 2012, 41, 9753-9759. [link]

(4) A. K. Gupta, F. A. S. Chipem and R. Boomishankar, A 2-pyridyl (py) attached phosphine imine [P(Npy)(NHpy)3] and an imido phosphinate ion  [P(Npy)2(NHpy)2]− in its Ag(I) complex, Dalton Trans., 2012, 41, 1848-1853. [link]

(3) A. K. Gupta, A. Kalita, and R. Boomishankar, Synthesis and supramolecular structures of iso- and heteropolymetallates assisted by organoamino phosphonium cations, Inorg. Chim. Acta, 2011, 37, 152–159. [link]

(2) A. K. Gupta, J. Nicholls, S. Debnath, I. Rosbottom, A. Steiner and R. Boomishankar, Organoamino phosphonium cations as building blocks for hierarchical supramolecular assemblies, Cryst. Growth Des., 2011, 11, 555-564. [link

(1) R. Boomishankar, P. I. Richards, A. K. Gupta and A. Steiner, Magnesium and Titanium Complexes of Polyanionic Phosphazenates,  Organometallics, 2010, 29, 2515-2520. [link]

International Conferences and Workshop:

• Oral Presentation

(1) The self-assembly of [{Ag3(C≡CtBu)2}n]n+ building units into a template-free cuboctahedron and anion encapsulating silver cages , "Inorganic Chemistry Day" June 2019, Umeå Sweden

• Poster Presentation

(13) The self-assembly of [{Ag3(C≡CtBu)2}n]n+ building units into a template-free cuboctahedron and anion encapsulating silver cages , "14th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-2019)" Lecce Italy.

(12) Arvind K. Gupta and Andreas Orthaber 1st National Meeting of the Swedish Chemical Society, Lund University, Lund, June 2018.

(11) Arvind K. Gupta and Andreas Orthaber International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC) in conjunction with ISACS: Challenges in Organic Materials & Supramolecular Chemistry, Cambridge United Kingdom, July 2017.

(10) Arvind K. Gupta and Andreas Orthaber, Workshop and Training School "Functional hybrid materials: Structural elucidation from molecular to macro level", Stockholm University, Stockholm, May 2016.

(9) Arvind K. Gupta, Suman Debnath, R. Boomishankar  12th CRSI & 4th CRSI-RSC Symposium in Chemistry IICT Hyderabad, February 2010.

(8) Arvind K. Gupta, R. Boomishankar, Chivukula V. Sastri National Conference on Frontiers in Chemical Sciences (FICS) IIT Guwahati, December 2010. (Selected for best poster award)

(7) Arvind K. Gupta, R. Boomishankar International Symposium on Frontiers in Inorganic Chemistry (FIC) IACS Kolkata, December 2010.

(6) Arvind K. Gupta, and R. Boomishankar  CSRI-RSC Mid-Year Zonal Meeting-2011  NCL, Pune, 2011.

(5) Arvind K. Gupta and R. Boomishankar Modern Trends in Inorganic Chemistry (MTIC), University of Hyderabad, India, December 2012.

(4) Arvind K. Gupta, S. Arun Dixit Reddy and R. Boomishankar, IISER Pune-Glasgow symposium, December 2012.

(3) Arvind K. Gupta and R. Boomishankar on Science Day organized by IISER Pune, India, February 2013.

(2) ACS ON CAMPUS Event Organized by CSIR-NCL Pune, 10th October 2012.

(1) RSC Road Show Event. Organized by CSIR-NCL Pune, 11th February 2013.

Thesis:

Thesis title: Synthesis and functional studies of transition metal complexes derived from amido- and imido-P(V) ligands. [link]