Publications

Citations are hyperlinked to the on-line journal publication. To view these you will require the appropriate subscriber access.

Links to associated X-ray structures are to data entries at the Cambridge Crystallographic Data Centre.

2022

• Ionic Encapsulation of a Methanol Carbonylation Catalyst in a Microporous Metal-Organic Framework
  S. A. Ivko, T. Bailey, L. Brammer and A. Haynes
  Chem. Commun., 2022, 58, 11252

• Heterogenisation of a Carbonylation Catalyst on Dispersible Microporous Polymer Nanoparticles
  S. A. Ivko, A. M. James, M. J. Derry, R. Dawson and A. Haynes
  Catal. Sci. Technol., 2022, 12, 664

2021

• Carbonylations Promoted by Third Row Transition Metal Catalysts
  A. Haynes
  Chapter 10, p333-362 in Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry (ed. G. Bartolo), Wiley-VCH, 2021

2019

• Mechanistic Insight into Organic and Industrial Transformations: General Discussion
  Y. Aoki, M. Bauer, T. Braun, J. A. Cadge, G. E. Clarke, D. J. Durand, O. Eisenstein, S. Gallarati, M. Greaves, J. Harvey, A. Haynes, U. Hintermair et al
  Faraday Discuss., 2019, 220, 282
  
  

• Physical Methods for Mechanistic Understanding: General Discussion
  Y. Aoki, M. Bauer, T. Braun, J. Cadge, D. Davies, D. J. Durand, O. Eisenstein, D. Ess, I. Fairlamb, N. Fey, S. Gallarati, M.. George, M. Greaves, M. Halse, A. Hamilton, J. Harvey, A. Haynes, U. Hintermair et al
  Faraday Discuss., 2019, 220, 144

2018

• Encapsulation of Crabtree's catalyst in sulfonated MIL-101(Cr): enhancement of stability and selectivity between competing reaction pathways by the MOF chemical microenvironment
  A. Grigoropoulos, A. I. McKay, A. P. Katsoulidis, R. Davies, A. Haynes, L. Brammer, J. Xiao, A. S. Weller and M. J Rosseinsky
  Angew. Chem. Int. Ed., 2018, 57, 4532. (German edition: Angew. Chem., 2018, 130, 4622) X-ray Structures

2017

• Infrared Spectroscopic Study of Absorption and Separation of CO Using Copper(I)-Containing Ionic Lliquids
  S. E. Repper, A. Haynes, E. J. Ditzel and G. J. Sunley
  Dalton Trans., 2017, 46, 2821
  
  

• Transition Metal Catalysed Methanol Carbonylation
  A. Haynes
  Contemporary Catalysis: Science, Technology and Applications, 2017, Chapter 28, p795-822 (ed. P. C. J. Kamer, D. Vogt & J. Thybaut), RSC (ISBN 978-1-84973-990-0)

2016

• Encapsulation of an Organometallic Cationic Catalyst by Direct Exchange into an Anionic MOF
  A. Grigoropoulos, G. F. S. Whitehead, N. Perret, A. P. Katsoulidis, M. Chadwick, R. Davies, A. Haynes, L. Brammer, A. S. Weller, J. Xiao and M. J Rosseinsky
  Chem. Sci., 2016, 7, 2037

2013

• Reactivity of Ir(III) Carbonyl Complexes with Water; Alternative By-product Formation Pathways in Catalytic Methanol Carbonylation
  P. I. P. Elliott, S. Haak, A. J. H. M. Meijer, G. J. Sunley and A. Haynes
  Dalton Trans., 2013, 42, 16538
  
  

• Carbonylation Reactions
  A. Haynes
  Comprehensive Inorganic Chemistry II, 2013, 6.01, p1-24  (ed. J. Reedijk and K. Poeppelmeier), Elsevier.

2012

• Ligand Effects on the Reactivity of Cobalt Acyl Complexes
  J. M. Birbeck, A. Haynes, H. Adams, L. Damoense and S. Otto
  ACS Catal., 2012, 2, 2512  X-ray Structures

2011

• Mechanistic Study of Rhodium/Xantphos Catalyzed Methanol Carbonylation
  G. L. Williams, C. M. Parks, C. R. Smith, H. Adams, A. Haynes, A. J. H. M. Meijer, G. J. Sunley and S. Gaemers
  Organometallics, 2011, 30, 6166  X-ray Structures
  
  

• Dicarbonylrhodium(I) Complexes of Bipyridine Ligands with Proximate H-Bonding Substituents and Their Application in Methyl Acetate Carbonylation
  C. M. Conifer, D. J. Law, G. J. Sunley, A. Haynes, J. R. Wells, A. J. P. White, and G. J. P. Britovsek
  Eur. J. Inorg, Chem., 2011, 3511

2010

• Catalytic Methanol Carbonylation
  A. Haynes
  Adv. Catal., 2010, 53, 1

2009

• Identification of the Reactive cis,mer Isomer of [Ir(CO)2I3Me]-; Relation to the Mechanism of Iridium-Catalyzed Methanol Carbonylation
  A. Haynes, A. J. H. M. Meijer, J. R. Lyons and H. Adams
  Inorg. Chem., 2009, 48, 28   X-ray Structures    (selected for journal front cover - to view larger image click here)

• Book Review of:  Iridium Complexes in Organic Synthesis (ed. L. A. Oro and C. Claver).
  A. Haynes
  Angew. Chem. Int. Ed., 2009, 48, 5993

• The Structural Characterization and Hydroformylation Activity of the Tri-Rhodium Complex [Rh3(µ2-dppm)2(µ2-CO)3(κ1-CO)3]BF4
  F. Lorenzini, E. O'Hara, S. Qian, F. Marchetti, J. M. Birbeck, A. Haynes, A. J. Blake, G. C. Saunders, A. C. Marr
  Inorg. Chem. Commun., 2009, 12, 1071  

2007

• Reactivity of Rhodium(I) Iminophosphine Carbonyl Complexes with Methyl Iodide
  J. Best, J. M. Wilson, H. Adams, L. Gonsalvi, M. Perruzzini and A. Haynes
  Organometallics, 2007, 26, 1960   X-ray Structure
  
  

• Ligand stereoelectronic effects in complexes of phospholanes, phosphinanes and phosphepanes and their implications for hydroformylation catalysis
  R. A. Baber, M. F. Haddow, A. J. Middleton, A. G. Orpen, P. G. Pringle, A. Haynes, G. L. Williams and R. Papp
  Organometallics, 2007, 26, 713    X-ray Structures
  
  

• Commercial Applications of Iridium Complexes in Homogeneous Catalysis
  A. Haynes
  Comprehensive Organometallic Chemistry III, 2007, vol 7, p427-444 (ed. R. H. Crabtree and D. M. P. Mingos), Elsevier. 

2006

• Formation and Reactivity of Ir(III) Hydroxycarbonyl Complexes
  P. I. P. Elliott, C. E. Haslam, S. E. Spey and A. Haynes
  Inorg. Chem., 2006, 45, 6269  X-ray Structure
  
  

• Acetic Acid Synthesis by Catalytic Carbonylation of Methanol
  A. Haynes
  Topics in Organometallic Chemistry, 2006, 18, p179-205
  
  

• Syntheses Based on Carbon Monoxide
  P. M. Maitlis and A. Haynes
  Chapter 4 (p114-162) in Metal-Catalysis in Industrial Organic Processes, (ed. P. M. Maitlis, G. P. Chiusoli), 2006, RSC, ISBN 0854048626.
  
  

• The Synthesis, Characterisation and Reactivity of 2-Phosphanylethylcyclopentadienyl Complexes of Cobalt, Rhodium and Iridium
  A. C. McConnell, P. J. Pogorzelec, A. M. Z. Slawin, G. L. Williams, P. I. P. Elliott, A. Haynes, A. C. Marr and D. J. Cole-Hamilton
  Dalton Trans., 2006, 91  X-ray Structures (also previously published X-ray Structures of Rh complexes)

2005

• Oxidative Addition of MeI to Cationic Rh(I) Carbonyl Complexes with Pyridyl bis(carbene) Ligands
  J. M. Wilson, G. J. Sunley, H. Adams and A. Haynes
  J. Organomet. Chem., 2005, 690, 6089 
  
  

• The Use of High Pressure Infrared Spectroscopy to Study Catalytic Mechanisms
  A. Haynes
  Chapter 3 (p107-150) in Mechanisms in Homogeneous Catalysis - A Spectroscopic Approach, (ed. B. T. Heaton), 2005, Wiley-VCH, Weinheim ISBN 3-527-31025-8
  
  

• Catalyst and Process for the Production of Acetic Acid
  A. Haynes, D. J. Law, A. Miller, G. E. Morris, M. J. Payne and J. G. Sunley
  World Pat. WO2005009939, 2005 

2004

• Facile Alkene Insertion into a Rh(III)-Acetyl Bond; Potential Catalysts for CO/Alkene Copolymerization
  A. Haynes, C. E. Haslam, K. J. Bonnington, L. Parish, H. Adams, S. E. Spey, T. B. Marder and D. N. Coventry
  Organometallics, 2004, 23, 5907  X-ray Structures
  
  

• Promotion of Iridium Catalyzed Methanol Carbonylation: Mechanistic Studies of the Cativa Process
  A. Haynes, P. M. Maitlis, G. E. Morris, G. J. Sunley, H. Adams, P. W. Badger, C. M. Bowers, D. B. Cook, P. I. P. Elliott, T. Ghaffar, H. Green, T. R. Griffin, M. Payne, J. M. Pearson, M. J. Taylor, P. W. Vickers and R. J. Watt
  J. Am. Chem. Soc., 2004, 126, 2847  X-ray Structures
  
  

• Iodide Effects in Transition Metal Catalyzed Reactions
  P. M. Maitlis, A. Haynes, B. R. James, M Catellani and G. P. Chiusoli
  Dalton Trans., 2004, 3409
  
  

• Oxidative Addition of Methyl Iodide to [Rh(CO)2I]2; Synthesis, Structure and Reactivity of Neutral Rhodium Acetyl Complexes, [Rh(CO)(NCR)(COMe)I2]2
  A. Haynes, P. M. Maitlis, I. A. Stanbridge, S. Haak, J. M. Pearson, H. Adams and N. A. Bailey
  Inorg. Chim. Acta., 2004, 357, 3027  X-ray Structures
  
  

• Kinetics and Thermodynamics of C-Cl Bond Activation by [Ir(CO)2Cl2]-
  P. W. Vickers, J. M. Pearson, T. Ghaffar, H. Adams and A. Haynes
  J. Phys. Org. Chem., 2004, 17, 1007  X-ray Structures
  
  

• Bis(imino)carbazolide Complexes of Rhodium: Highly Nucleophilic Ligands Exerting a Dramatic Accelerating Effect on MeI Oxidative Addition
  J. A. Gaunt, V. C. Gibson, A. Haynes, S. K. Spitzmesser, A. J. P. White and D. J. Williams
  Organometallics, 2004, 23, 1015  X-ray Structure

2003

• Oxidative Addition of MeI to a Rhodium(I) N-Heterocyclic Carbene Complex. A Kinetic Study
  H. C. Martin, N. H. James, J. Aitken, J. A. Gaunt, H. Adams and A. Haynes
  Organometallics, 2003, 22, 4451  X-ray Structure
  
  

• Quantifying Steric Effects of a-Diimine Ligands. Oxidative Addition of MeI to Rhodium(I) and Migratory Insertion in Rhodium(III) Complexes
  L. Gonsalvi, J. Gaunt, H. Adams, A. Castro, G. J. Sunley, and A. Haynes
  Organometallics, 2003, 22, 1047  X-ray Structures
  
  

• Mid-IR Spectroscopy for Rapid On-line Analysis in Heterogeneous Catalyst Testing
  O. M. Wilkin, P. M. Maitlis, A. Haynes and M. L. Turner
  Catal. Today, 2003, 81, 309  

2002

• Steric and Electronic Effects on the Reactivity of Rh and Ir Complexes Containing P-S, P-P and P-O Ligands; Implications for the Effects of Chelate Ligands in Catalysis
  L. Gonsalvi, H. Adams, G. J. Sunley, E. Ditzel and A. Haynes
  J. Am. Chem. Soc., 2002, 124, 13597  X-ray structures (see also X-ray structures in prior communication)
  
  

• A Mechanistic Investigation of Oxidative Addition of Methyl Iodide to [Tp*Rh(CO)(L)]
  V. Chauby, J.-C. Daran, C. Serra-Le Berre, F. Malbosc, P. Kalck, O. Delgado Gonzalez, C. E. Haslam and A. Haynes
  Inorg. Chem., 2002, 41, 3280    X-ray structures
  
  

• Structure and Reactivity of Polymer-Supported Carbonylation Catalysts
  A. Haynes, P. M. Maitlis, R. Quyoum, C. Pulling, H. Adams, S. E. Spey and R. W. Strange
  J. Chem. Soc., Dalton. Trans., 2002, 2565    X-ray structures
  
  

• High Throughput Testing of Catalysts for the Hydrogenation of Carbon Monoxide to Ethanol
  O. M. Wilkin, R. W. K. Allen, P. M. Maitlis, J. R. Tippetts, M. L. Turner, V. Tesar, A. Haynes, M. J. Pitt, YY Low and B. Sowerby
  Principles and Methods for Accelerated Catalyst Design and Testing, NATO Science Series II: Mathematics, Physics and Chemistry, 2002, 69, p299-303

2001

• Theoretical, Thermodynamic, Spectroscopic, and Structural Studies of the Consequences of One-Electron Oxidation on the Fe-X Bonds in 17- and 18-Electron Cp*Fe(dppe)X Complexes (X = F, Cl, Br, I, H, CH3)
  M. Tilset, I. Fjeldahl, J.-R. Hamon, P. Hamon, L. Toupet, J.-Y. Saillard, K. Costuas and A. Haynes
  J. Am. Chem. Soc., 2001, 123, 9984    X-ray structures
  
  

• Structure and Reactivity of Polymer-Supported Carbonylation Catalysts
  A. Haynes, P. M. Maitlis, R. Quyoum, H. Adams, R. W. Strange,
  Chapter, p166-175 in Supported Catalysts and Their Applications, (ed. D. C. Sherrington, A.P.Kybett) Spec. Publ. RSC, 2001, 266,
  
  

• Two Metals are Better Than One
  A. Haynes
  Educ. Chem., 2001, 38(4), 99

2000

• Methane Formation During the Iridium/iodide Catalysed Carbonylation of Methanol
  T. Ghaffar, J.P.H. Charmant, G J. Sunley, G.E. Morris, A. Haynes and P.M. Maitlis
  Inorg. Chem. Commun., 2000, 3, 11
  
  

• Chemical Marriage-Brokers
  P. R. Davies and A. Haynes
  chapter on catalysis, p55-76 in Cutting Edge Chemistry Royal Society of Chemistry, 2000
  Winner of the Educational and College category of the British Book Design and Production awards, 2001

1999

• A Dramatic Steric Effect on the Rate of Migratory CO Insertion on Rhodium
  L. Gonsalvi, H. Adams, G J. Sunley, E. Ditzel and A. Haynes
  J. Am. Chem. Soc., 1999, 121, 11233    X-ray structures
  
  

• Chemical Marriage-Brokers
  P. R. Davies and A. Haynes
  chapter on catalysis, p73-96 in The Age of the Molecule Royal Society of Chemistry, 1999
  
  

• The Carbonylation of Methyl Iodide and Methanol to Methyl Acetate Catalysed by Palladium and Platinum Iodides
  J. Yang, A. Haynes and P. M. Maitlis
  Chem. Commun., 1999, 179

1998

• Spectroscopic Identification and Reactivity of [Ir(CO)3I2Me], a Key Reactive Intermediate in Iridium Catalysed Methanol Carbonylation
  T. Ghaffar, H. Adams, P. M. Maitlis, G J. Sunley, M. J. Baker, A. Haynes
  Chem. Commun., 1998, 1023
  
  

• Cis-Trans Isomerism in [M(CO)2I4]- (M = Rh, Ir): Kinetic, Mechanistic and Spectroscopic Studies
  A. Haynes, J. McNish, J. M. Pearson
  J. Organomet. Chem, 1998, 551, 339
  
  

• Model Reactions of a Carbonylation Catalyst: Phosphite Induced Migratory CO Insertion in [MeIr(CO)2I3]-
  A. Haynes, J. M. Pearson, P. W. Vickers, J. P. H. Charmant and P. M. Maitlis
  Inorg. Chim. Acta. 1998, 270, 382
  
  

• New explorations in metal-catalyzed reactions
  P. M. Maitlis, M. L. Turner, R. Quyoum, H. C. Long and A. Haynes
  Selective Reactions of Metal-Activated Molecules,  1998,  p83-93

1997

• Oxidative Addition of Methyl Iodide to [RhI(CO)(Ph2PCH2P(S)Ph2]
  A. Haynes, L. Gonsalvi, D. Evans and G. J. Sunley
  Poster in Electronic Conference on Organometallic Chemistry, ECTOC-3, 1997

1996

• Methanol Carbonylation Revisited: 30 Years On
  P.M. Maitlis, A. Haynes, G.J. Sunley, M.J. Howard
  J. Chem. Soc., Dalton Trans., 1996, 2187
  
  
  
  

• Theoretical and Experimental Evidence for SN2 Transition States in Oxidative Addition of Methyl Iodide to cis-[M(CO)2I2]- (M = Rh, Ir)
  T.R. Griffin, D.B. Cook, A. Haynes, J.M. Pearson, D. Monti, G.E. Morris
  J. Am. Chem. Soc., 1996, 118, 3029    Transition state structures
  
  

• Methyl to Alkylidene Migration within trans-[WMe(=CHPh)(CO)2(η-C5H5)]
  J.E. Muir, A. Haynes, M.J. Winter
  Chem. Commun., 1996, 1765

1995

• Dramatic Acceleration of Migratory Insertion in [Melr(CO)2I3]- by Methanol and by Tin(II) iodide
  J. M. Pearson, A. Haynes, G. E. Morris, G. J. Sunley, P. M. Maitlis
  J. Chem. Soc., Chem. Commun. 1995, 1045
  
  

• The Migratory Insertion of Carbon Monoxide in Pentamethylcyclopentadienyl-iridium(III) Complexes. Structural Effects on Reactivity and Mechanism for Rhodium and Iridium Systems
  D. Monti, G. Frachey, M. Bassetti, A. Haynes, G. J. Sunley, P. M. Maitlis, A. Cantoni, G. Bocelli
  Inorg. Chim. Acta., 1995, 240, 485    X-ray structure

1994

• Oxidative Addition of Alkyl Halides to Rhodium(I) and Iridium(I) Dicarbonyl Diiodides: Key Reactions in the Catalytic Carbonylation of Alcohols
  P. R. Ellis, J. M. Pearson, A. Haynes, H. Adams, N. A. Bailey and P. M. Maitlis
  Organometallics, 1994, 13, 3215   X-ray structure

1993

• Mechanistic Studies on Rhodium Catalyzed Carbonylation Reactions: Spectroscopic Detection and Reactivity of a Key Intermediate, [MeRh(CO)2I3]-
  A. Haynes, B. E. Mann, G. E. Morris and P. M. Maitlis,
  J. Am. Chem. Soc.,1993, 115, 4093
  
  

• The use of spectroscopy, models, and labels to detect intermediates, elucidate mechanisms, and compare reactivities in metal catalyzed carbonylation reactions
  P. M. Maitlis, A. Haynes, B. E. Mann, J. M. Pearson, I. A. Stanbridge, G. J. Sunley, M. Bassetti and D. Monti
  Adv. Catal. Des., Proc. Workshop, 2nd,  1993,  p1-17

1992

• Relative Reaction Rates for Rh and Ir: Oxidative Addition of Methyl Iodide to M(I) and Migratory Insertion in M(III) Methyl Carbonyl Complexes
  M. Bassetti, D. Monti, A. Haynes, J. M. Pearson, I. A. Stanbridge and P. M. Maitlis,
  Gazz. Chim. Ital., 1992, 122, 391
  
  

• Fe(CO)5 in CO Cylinders
  A. Haynes, P. Ellis, P. Byers and P. M. Maitlis,
  Chemistry in Britain, 1992, 28(6), 517

1991

• The Direct Observation of MeRh(CO)2I3-, the Key Intermediate in Rhodium Catalyzed Methanol Carbonylation
  A. Haynes, B. E. Mann, D. J. Gulliver, G. E. Morris and P. M. Maitlis,
  J. Am. Chem. Soc., 1991, 113, 8567
  
  

• A Mechanism for the Photochemical Conversion of FpSi2Me5 to FpSiMe3 (Fp = (η5-C5H5)Fe(CO)2). Infrared Evidence for an Intermediate Iron Silylene Complex
  A. Haynes, M. W. George, M. T. Haward, M. Poliakoff and J. J. Turner,
  J. Am. Chem. Soc., 1991, 113, 2011 

1990

• The Photochemistry of Dinuclear Osmium Carbonyl Complexes; Characterisation of Os2(CO)8 using Matrix Isolation
  A. Haynes, M. Poliakoff, J. J. Turner, B. R. Bender and J. R. Norton,
  J. Organomet. Chem. (Mond Centennial Edition), 1990, 383, 497

1988

• The Photochemistry of Cyclopentadienyl Platinum Carbonyl Dimers; Characterisation of [Pt2(µ-CO)(η5-C5R5)2] (R = H, Me) using Matrix Isolation and Fast Time-Resolved Infrared Spectroscopy
  A. Haynes, A. J. Dixon, S. Firth, M. Poliakoff, J. J. Turner and N. M. Boag,
  J. Chem. Soc., Dalton. Trans., 1988, 1501
  
  

• rs-type Coordinates in Weakly Bonded Dimers: Application to Linear Dimers, B.....HCN, where B = CO, N2 and HCN
  A. Haynes and A. C. Legon,
  J. Mol. Structure., 1988, 189, 153

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