Main Applications
Raman spectroscopy is a non-destructive technique with a wide range of applications. Traditionally, the Raman technique was limited to single spot analysis, however, recent advances now equip the instrument with a high spatial resolution and reproducible stage motions.
Raman spectra of the perfectly crystalline Mudtank zircon standard.
Raman spectra depend on the chemical composition, structure, and interatomic bonds and the degree of amorphization as well as the orientation of the crystal lattice.
Unknown phases can compared the RRUFF database, which contains a large compiled range of mineral Raman spectra in order to identify minerals.
Hadean-aged zircon in cathodoluminescence versus Raman map of FWHW at the v3 position (~1008 cm-1) relates to peak broadening due to alpha-damage.
Maps of single crystals are generated using peak characteristics from the Raman spectra (e.g., peak position, peak width) at high spatial resolutions using the reproducible x-y-z stage of the inVia Qontor microscope.
ALC has focused on U- and Th-bearing minerals (e.g., zircon, baddeleyite, monazite) where Raman spectroscopy can inform you about the degree of radiation damage and, more recently, extract information about thermal annealing histories.
Mapped area using 5 μm pixel resolution in a thin section of the Duluth Gabbro (FC1) resolves mineral phases of Fe-Ti oxides and baddeleyite, in addition to compositional variations in the albite feldspar.
Raman spectra over large areas can be acquired to generate phase maps to identify minerals and estimate modal percentages within that region.
Advanced Applications
U-Pb age (Ma) versus alpha-dose calculated using the Raman calibration based on the full-width half-maximum of the ~1008 cm-1 Raman peak in zircon.
Raman spectroscopy permits to identify metamict crystals and can be useful in regular studies that rely on U-Pb LA-ICP-MS geochronology. Coupling both datasets provide a very usuful perspective when interpreting provenance and maximum depositional ages in the geological record. For a more detailed explanation on this application, see this poster.
Garnet mounted in epoxy observed using transmitted light to reveal mineral host inclusions.
The quartz-in-garnet (QuiG) elastic geothermobarometer calibration uses quartz inclusions trapped in garnet to estimate entrapment pressures based on the Raman shift of quartz peaks.
Photoluminescence map within a Fish Canyon zircon grain. PL map area overlies white light image.
Luminescence spectroscopy relates to the emission of light from a mineral upon excitation of the laser. For zircon, this corresponds to elemental impurities that have photoluminescence properties (e.g., REE). Due to the wavelength of our laser (633 nm), only light spectra emitted at wavelengths greater than 634 nm can be measured.