YES!!!!
Here are some of the amazing things that can only be seen from locations experiencing 100% totality:
The moon is not a perfect sphere! It has mountains and valleys. The Sun peeks through at those points and looks like little beads. This happens moments before totality
The last of Bailey's beads appears bright and looks like a diamond ring. This happens an instant before totality
The Sun's atmosphere is called the Coronasphere. It can only be viewed during a total eclipse. If you look closely you may be able to see solar flares.