Total Synthesis Of Brevianamide A and B
Total Synthesis Of Brevianamide A and B
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A complete biomimetic approach towards brevianamides following an cascade sequence with the help of a molecular trigger
A complete biomimetic approach towards brevianamides following an cascade sequence with the help of a molecular trigger
Progress So Far...
Our Initial DKP (diketopiperazine)
Crystal Data
First Challenge: Reverse Prenylation at C2 position
The reverse prenylation reaction at the C2 position presents a significant challenge for this there are three major things are.....
1. Allene Preparation
2. 9-BBN Preparation
3. Chlorination and Completion
Allene Prepration
9-BBN Prepration
Chlorination and Complition
Next Challenge..... Molecular Trigger Making
Work in Progress
Optimizing....
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