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2023-2024

1. Sahu, P. K., Kharel, R., Shome, S., Goswami, S., and Konar, S., Understanding the unceasing evolution

of Co(II) based single-ion magnets, Coord. Chem. Rev., 2023, 475, 214871.

2. Kapurwan, S., Sahu, P.K., Raizada, M., Kharel, R., and Konar, S., [α-AsW9O33]9− bridged hexagonal

clusters of Ln(III) showing field induced SMM behavior: experimental and theoretical insight, Dalton

Trans., 2023, 52, 9377-9388.

3. Kharel, R., Yadav, J., and Konar S., Modulation of single-chain magnet behaviour in a heterometallic

Fe2Co cyanide-bridged 2D sheet, Chem. Commun., 2024, 60, 839-842.

Understanding the unceasing evolution of Co(II) based single-ion magnetsSingle-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin inversion. The slow relaxation of magnetization is of molecular orig…

Modulation of single-chain magnet behaviour in a heterometallic Fe2Co cyanide-bridged 2D sheetA cyanide-bridged Fe2Co 2D sheet exhibiting electron transfer coupled spin transition (ETCST) with co-existence of magnetic ordering below 50 K is reported. The complex exhibits single-chain magnet behaviour where the uncoordinated water molecules act as an exchange-breaking impurity by allowing only a fract

[α-AsW9O33]9− bridged hexagonal clusters of Ln(III) showing field induced SMM behavior: experimental and theoretical insightPolyoxometalates (POM), as inorganic polydentate oxygen donors, provide binding opportunities for oxophilic lanthanide metal centers to construct novel Ln-substituted POM materials with exciting structures and attractive properties. Herein, we have reported four arsenotungstate [α-AsW9O33]9− based lanthanide

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