Revistas Arbitradas

Abstract

The state of Sonora, Mexico, stands as one of the leading producers of pecan nuts in the country, which are commercialized without shells, leaving behind this unused residue. Additionally, this region has abundant solar resources, as shown by its high levels of direct normal irradiance (DNI). This study contributes to research efforts aimed at achieving a synergy between concentrated solar energy technology and biomass pyrolysis processes, with the idea of using the advantages of organic waste to reduce greenhouse gas emissions and avoiding the combustion of conventional pyrolysis through the concentration of solar thermal energy. The objective of this study is to pioneer a new experimental analysis methodology in research on solar pyrolysis reactors. The two main features of this new methodology are, firstly, the comparison of temperature profiles during the heating of inert and reactive materials and, secondly, the analysis of heating rates. This facilitated a better interpretation of the observed phenomenon. The methodology encompasses two different thermal experiments: (A) the pyrolysis of pecan shells and (B) the heating–cooling process of the biochar produced in experiment (A). Additionally, an experiment involving the heating of volcanic stone is presented, which reveals the temperature profiles of an inert material and serves as a comparative reference with experiment (B). In this experimental study, 50 g of pecan shells were subjected to pyrolysis within a cylindrical stainless-steel reactor with a volume of 156 cm3, heated by concentrated radiation from a solar simulator. Three different heat fluxes were applied (234, 482, and 725 W …

Abstract

Parabolic Trough Concentration (PTC) systems represent the best alternative for implementing solar energy in different sectors due to their reachable temperatures and maturity levels. However, there is a notably lack of normativity for evaluating the experimental thermal performance curves of these systems. For this reason, a new methodology is proposed to solve problems arising in the thermal characterization of them. This methodology allows to evaluate the system at any time of year without a two-axis tracking system, using experimental data and projections based on a ray tracing model. To validate the methodology, a PTC system was evaluated during solstices and equinoxes. Variations in experimental thermal performance response along the year caused by solar declination; were observed, reaching a maximum loss of 45% of received power and 22% in efficiency for the lowest solar altitude conditions. The ray tracing model methodology was applied to the experimental thermal performance curves obtained along the year to get the best efficiency curve. The good approximation of the projections made with this methodology helped us to consider it validated. With this method, it is also possible to easily obtain a family of curves describing the power and performance of the system throughout the year and wherever it is installed.

ABSTRACT

The radiation flux distributions produced by the concentrating solar systems used to produce thermal/electrical power are usually non-homogeneous. This results in non-uniform temperature distributions on the solar receivers, causing adverse effects on the system’s overall performance. An approach to better understand the problem is to study the surfaces around the focal zone where the radiation density is homogeneous (isosurfaces), generating them from experimental data. For this, it is necessary to superimpose built volumes of the different irradiance levels using parallel planes in different directions from the focal point of a concentrator. These volumes are known as effective volumes. This study presents the model used to generate effective volume produced by a point focus concentrator, comparing it with experimental results in a direction perpendicular to the focal axis. The effective volumes were developed considering a global optical error of the system of 2.8 mrad. The set of methods used to generate effective volumes has not been previously presented in the literature. The theoretical-experimental research consisted of the combination of the camera-target method and the simulations by the ray-tracing technique. The results showed effective volumes with the highest value of 10 MW/m2 and the lowest value of 4.5 MW/m2.

ABSTRACT

Hydrothermal processes are attractive options for the transformation of mixtures of biomass with large amounts of water, i.e. above 20wt. At hydrothermal conditions, the special properties of water makes it an attractive reaction medium to obtain several bio-based platform chemicals or fuel gases, such as hydroxymethilfurfural or fufurals, syngas, hydrogen, methane, etc. However, one of the main challenges is that a large amount of energy is required to heat reactants (mixture of water and biomass), which is usually achieved by combustion of a fraction of the bio-oil product. Therefore, to reduce this consumption, their integration with an external renewable energy source, such as concentrated solar radiation has been proposed. This approach has been recently analyzed by several research groups as an option to have sustainable and economically attractive processes. This work provides an overview of the different experimental and theoretical strategies to incorporate concentrated solar technologies into hydrothermal processing of biomass, including the main challenges of such integration for process technical feasibility.

ABSTRACT

Reticulate porous ceramic reactors use foam-type absorbers in their operation which must fulfill two essential functions: favoring the volumetric effect and increasing the mass and heat transfer by acting as a support for the reactive materials. Heating these absorbers with highly inhomogeneous concentrate irradiation induces high thermal gradients that affect their thermal performance. Owing to the critical function of these component in the reactor, it is necessary to define a selection criterion for the foam-type absorbers. In this work, we performed an experimental and numerical thermal analysis of three partially stabilized zirconia (PSZ) foam-type absorbers with pore density of 10, 20, and 30 PPI (pores per inch) used as a volumetric absorber. A numerical model and an analytical approximation were developed to reproduce experimental results, and calculate the thermal conductivity, as well as volumetric heat transfer coefficient.

The results show that an increase in pore density leads to an increase in the temperature difference between the irradiated face and the rear face of the absorber, this occurs because when pore density increases the concentrated energy no longer penetrates in the deepest space of the absorber and energy is absorbed in areas close to the surface; therefore, temperature gradients are created within the porous medium. The opposite effect occurs when the airflow rate increases; the temperature gradient between the irradiated face and the rear face is reduced. This behavior is more noticeable at low pore densities, but at high pore densities, the effect is less relevant because the internal structure of porous absorbers with high pore density is more complex, which offers obstructions or physical barriers to airflow and thermal barriers to heat transfer.

When the steady state is reached, the temperature difference between the two faces of the absorber remains constant if the concentrate irradiation changes slightly, even changing the airflow rate. The results obtained in this work allow us to establish a selection criterion for porous absorbers that operate within solar reactors; this criterion is based on knowledge of the physical properties of the porous absorber, the environment, the working conditions, and the results expected.

ABSTRACT

The various lignin isolation methods and pretreatments are continuously developing and thermochemical conversion of lignocellulosic biomass and tuning of the activation parameters are vital to obtaining high energy density materials. In this review, different lignin extraction methods, pretreatments, and influence of the extraction conditions on the yield and properties are presented. The thermochemical conversion of lignin-based biomass and application in supercapacitors and hydrogen storage were investigated.

The study revealed that chemical extraction via the organosolv process presents higher purity and partly preserved lignin structure compared to sulfur processes. Different parameters such as the method of extraction, the temperature, pH, resident time, and pressure greatly influences the Kappa value and yield of lignin. The potassium hydroxide (KOH) dosage as an activating agent and the activating temperature is vital to obtaining high surface area and microporosity, which enhances the lignin-based activated carbon performance towards high hydrogen storage and capacitance. Metals doping on activated carbon marginally enhance the hydrogen storage capacity and capacitance, however, reversible desorption of the adsorbed hydrogen requires a higher temperature for hydrogen storage. Besides, high metal doping reduces available surface area, collapses the cage-like structures of fullerenes, and results in lower hydrogen storage capacity of activated carbon.

The presence of heteroatoms on activated carbons enhances the performance towards high hydrogen storage and capacitance. Moreover, techno-economic and exergy-based sustainability analysis of the different lignin isolation techniques must be explored to provide valuable insights on energy and associated operational costs.

ABSTRACT

Hybrid graphemne-fiber systems could present an alternative for various industrial applications in need of large area graphene sheets. One way to produce these carbon-based structures is by subjecting an aqueous polyvinyl alcohol solution containing sodium chloride to centrifugal spinning under high humidity conditions. The developed polymer fibers are then subjected to a dehydration and carbonization process to promote the formation of the hybrid carbon structure. Potential applications of this material are highly dependent upon their conducting properties. In this work we analyzed the effect of the NaCl content and humidity conditions during the spinning process and ultimate thermal conductivity of the resultant hybrid graphene-fiber carbon systems. Results show an optimum NaCl added to the carbon precursor solution and spun at a high relative humidity (around 70%) promote the development of veils of graphene oxide multilayer that interconnect with produced fibers. We applied for the first time a thermographic method to determine the thermal conductivity of carbon mats. The thermal conductivity of the hybrid fibers increases as graphene multilayers veils expand between carbon fibers, to reach values up to 28 W m K−1.

ABSTRACT

The use of concentrated solar energy in processing ceramic materials is an attractive route to obtain these materials with low CO2 emissions. In this work, nanostructures of monoclinic zirconia (m-ZrO2) were obtained using concentrated solar energy provided by the IER-UNAM solar furnace as a heat source. In the first stage of the process, a Zr/O/C complex was obtained by sol-gel method at a temperature of 120 °C using zirconium n-propoxide and sorbitol as precursors reagents. This complex was used in a second stage to obtain m-ZrO2 by heating it at a temperature of 1200 °C for one hour in air atmosphere. This last stage was performed in a solar furnace. Samples were analyzed by characterization techniques: FT-IR, TGA/DSC, XRD, TEM, and SEM confirming the formation of nanostructures of zirconia in monoclinic phase.

ABSTRACT

In this work, an experimental and theoretical study on CH3NH3PbI3 perovskite solar cells was performed. A theoretical validation of experimental results in perovskite solar cells with efficiencies of 13.32% is presented. An optimization study which involves the spiro-OMeTAD and perovskite thickness’ influence on electrical output parameters (Voc, Jsc, FF and PCE) showed a promotion of solar cell efficiency to 15.50% under 100 nm and 400 nm for hole transport material and absorber, respectively. The importance of the diffusion length of the absorber is discussed. In order to enhance the efficiency, a study of defect density (NT) was applied at the range of 1016 cm−3 (experimental) to 1010 cm−3 (theoretical) where we achieved an efficiency of 20.26%. The present work illustrates the importance of thickness optimization and the reduction of defect density (by the improvement of the quality of processed film) to obtain a better performance of this type of solar cell. Furthermore, the relevance of the implementation of a back contact with higher work function was studied.

ABSTRACT

Hybrid perovskite films are prepared via two-step spin coating. The impact of magnetic fields during the spin coating of the PbI2 precursor solution is assessed with atomic force microscopy and scanning electron microscopy of the obtained layers. Deeper and narrower peak–valley–peak formations are obtained in PbI2 films when the magnetic field applied and the spinning direction result in a Lorentz force that pushes the [PbI6]4− ions towards the inner area of the substrate. This produces rougher and more porous PbI2 films with an increased surface area that facilitates the infiltration of the methylammonium iodide and chloride precursor solution, thereby enhancing the formation of perovskite. Increased cell performance and more repeatable results are obtained when the PbI2 film is spin-coated under the influence of a negative magnetic field. Opposite effects are obtained when the direction of the magnetic field, and therefore the Lorentz force, is inverted. This demonstrates that a magnetic field can be used to modify the surface morphology of spin-coated thin films prepared from ionic precursor solutions.

ABSTRACT

This work aims to propose a sustainable green process to obtain bio-derived carbons (BDCs) for utilization in supercapacitors. The process consists in carrying out solar pyrolysis to produce BDCs from abundant lignocellulosic wastes, Agave Angustifolia leaves and pruned tomato plant. Concentrated solar radiation from a high flux solar furnace was utilized to reach sample temperatures between 450 and 1564 °C in a spherical reactor. Before pyrolysis, both wastes were characterized by thermogravimetric analysis to semi-quantify cellulose and hemicellulose as well as ash content. XRD was used to determine the ash composition in both wastes, and the effect of solar pyrolysis temperature on the obtained BDCs. Additional structural properties of BDCs were analyzed by SEM, Raman spectroscopy, and physisorption.

Elemental analysis and EDAX were used to determine the chemical composition of wastes, and the effect of this on BDCs. Electrochemical properties of BDCs were analyzed by cyclic voltammetry in half cells, and those showing better performance were also tested in supercapacitor cells. Results show that BDCs from tomato plant waste have higher surface areas, with well-developed microporosity, without needing an additional activation process. This is attributed to self-activation during pyrolysis, produced by the high K and Ca content of the tomato plant pruning. Ragone plots indicate that the assembled supercapacitor cells employing the best BDCs from solar pyrolysis have specific energies and power values similar to a commercial carbon designed for supercapacitors. These results indicate that the proposed green procedure is suitable for obtaining BDCs with properties suitable for supercapacitors.

ABSTRACT

The acid–base chemistry at the interface of zinc oxide (ZnO) and methylammonium lead tri-iodide (perovskite) leads to a proton transfer reaction that results in perovskite degradation. In perovskite solar cells (PSCs), this reaction produces low efficiency and reduces the long-term stability. In this work, an aluminum (Al) layer of 1–2 nm thickness is thermally evaporated on top of ZnO or Al3+-doped ZnO (ZnO:Al) thin films and then annealed at 450 °C for 30 min. Thermal annealing converts the surface aluminum film into a transparent and approximately 2 nm thick aluminum oxide (AlOx) layer. Also, a larger concentration of oxygen vacancies is obtained by the annealing of Al and attributed to the diffusion of Al into the ZnO surface, and the ZnO underlayer results in a more conductive material.

As a result, the chemical stability of perovskite coatings on top of AlOx-coated ZnO films is significantly enhanced, and the flat-band level of ZnO shifts 0.09 eV upwards, which improves the energetic level alignment in PSCs. This allows us to obtain ZnO:Al/AlOx-based planar PSCs that show a maximum efficiency of 16.56% with the perovskite layer prepared in ambient conditions under a relative humidity of 40–50%. After continuous illumination of about 30 min in air, ZnO-based PSCs without AlOx layer retain only 34.5% of their original efficiency, whereas those with AlOx retain about 92.5%. It is demonstrated that thermal evaporation–oxidation is an efficient method to modify the surface properties of inorganic semiconductor thin films and improves both the performance and stability of PSCs.

ABSTRACT

Tantalum carbide (TaC) nanoparticles were synthesized using the IER-UNAM (HoSIER) solar furnace, which reduces polluting gas emissions and dependence on fossil fuels through the use of concentrated solar energy. TaC synthesis was performed through a carbothermal reduction method from Ta/O/C complex, using tantalum pentachloride (TaCl5) and synthesized phenolic resin as sources of tantalum and carbon, respectively, at a temperature of 1200 °C, in a reaction time of 30 min, under argon atmosphere. A solar reactor equipped with a quartz window was used, designed to work in controlled atmospheres. Complex Ta/O/C bonds and thermal decomposition were analyzed by FT-IR and TG/DSC, respectively, while the structure and morphology of TaC were analyzed by XRD, TEM, and SEM techniques. Results showed a TaC with a cubic crystalline structure, a low amount of Ta2O5 and a near-spherical …

ABSTRACT

Rotary kilns are worldwide used for industrial processes that involve thermal treatments of particulate materials. However, a great amount of fossil fuels is employed in such processes. As alternative, solar rotary kilns are considered for this application due to their versatility and potential to substitute traditional fossil-fuel driven devices. In order to boost the development of this technology, efforts have to be focused on the control of the particle temperature during the treatment. In this context, a lab-scale rotary kiln was built and tested using a 7-kWe high-flux solar simulator at University of Antofagasta. It was conceived to treat particulate materials of different nature and it is able to reach temperatures higher than 800 °C under different operation strategies. Silicon carbide was selected for initial tests because it is inert, endures high temperatures (up to 1600 °C) and it has been proposed as thermal storage vector in several researches on concentrated solar power. In a first stage, the empty kiln was preheated up to about 800 °C, reaching a steady state in less than three hours and with a power of approximately 370 W entering the kiln cavity. Afterwards, 43 g of silicon carbide were introduced in the furnace and the system was heated again up to a second steady state above 800 °C. In this stage, particles showed a fast increment of their temperature and exceeded 700 °C in less than three minutes after loading. A one-dimensional transient numerical model was also developed to perform the thermal analysis of the kiln and the estimation of both the particle temperature and the system efficiency. Numerical results showed good agreement with experimental data and thermal losses could be quantified in detail. Therefore, the model was also used to predict the thermal behavior of a solar rotary kiln working in batch mode..

ABSTRACT

Agave angustifolia leaves and tomato pruning biomasses were processed into carbon materials by solar pyrolysis. The influence of temperature and heating rate was studied in the physicochemical properties of the obtained biochars. The characterization techniques include elemental analyses (CHONS), physisorption to determine surface area by BET and DFT models, and capacitance values were determined by cyclic voltammetry as the electrochemical technique. It was found that for both biomasses, temperatures below 900°C are beneficial because more homogeneous and porous structures are obtained. The highest values of capacitance and surface area were obtained for tomato carbons at 450 and 600 °C, respectively. 

ABSTRACT

The optical characteristics of solar concentrators are key factors influencing the overall efficiency of solar power plants. For instance, heliostats need to be evaluated prior to installation and during its operation lifetime. This guarantees that the optical and thermal performance of these systems is close to design. One methodology that has gained importance due to its potential capabilities has been the Fringe Reflection Technique. This technique uses the reflection of a series of regular stripes to obtain the local slope deviations from a specular surface. Coupled to a ray tracing analysis, these slopes can be used to identify the distortion in concentrated solar spots. The enormous amount of data needed to carry out this analysis difficult its implementation at large scale. In this work, a study for determining the optimal number of sample points for heliostat surface characterization is realized. It has been found that, depending on the level of errors, the number SPFS required to reach convergence in the flux distribution profiles and intercept factors is variable. However, for the wide range of parameters considered in all cases 48 SPFS where enough to reach convergences to 1%. This is equivalent to one point per every 2.5cm of facet side length. For values of slope and canting errors up to 2mrad, half this density is sufficient.

ABSTRACT

In this study, a thermal analysis of a finned receiver prototype for a thermosolar tower system is presented. The experimental system consists of parallelepiped aluminum enclosure of 1.2 m high, 1.23 m wide and 0.1 m depth. At the interior, 1232 cylindrical fins with a diameter of 0.0095 m (3/8”) and 0.09 m length increases the heat transfer area up to 225%. The vertical wall receives the incoming solar concentrated radiation from a group of heliostats whilst at the interior a constant flow of water removes the absorbed energy. Experimental temperature profiles were obtained at different heights and depths and a comparison was made with numerical results obtained with the use of commercial CFD software. It was found that the maximum thermal efficiency of the receiver was 94.4 %, decreasing as the radiative flux increases.

ABSTRACT

Solar technology operating at elevated temperature conditions demands accurate knowledge of the optical and thermal properties of the materials involved in the construction and operation of solar collectors, reactors, and energy storages, among many others. Thermal energy storage (TES) devices involve successive melting and crystallization processes, which result in high complexity materials where the morphology, composition, and porosity could be highly non-homogeneous. In these cases, contact techniques for determining the thermal properties are highly susceptible and do not provide reliable measurements. It is under these conditions that non-contact photothermal techniques can provide superior performance, because in this case, the heat inducing source is a laser beam and the detector is usually a photodiode or a thermographic camera which are in non-contact with samples.

The materials applied as storage medium in a TES unit can be divided into four groups: metals and alloys, ceramics and glasses, polymers and elastomers, and composites that include natural materials. Soda lime silicate glass recyclable waste is a very promising material for storage medium due to its inexpensive and wide availability. In this paper, we examined soda lime silicate glass-graphite composites for use as storage medium in a TES unit. A simple one-dimensional model for thermal conductivity was developed based on equivalent thermal circuits for series-parallel composite walls, and we found that thermal conductivity values depend on the amount of graphite dispersed into the samples, the porous media, and their structure.

ABSTRACT

Solar reactors designed and constructed for thermochemical applications present different configurations and general performance. The selection of a solar reactor that optimizes a particular process is always a difficult challenge. This work studies two types of reactor configuration by means of a comparative experimental analysis. It was employed a solar device, which is able to operate as fixed reactor with packed bed samples and as rotary kiln. The reduction of CuO into Cu2O was tested under both operation modes, due to its proved potential and interest as thermochemical storage material. It was found that heat transfer was hindered in static experiments limiting the fraction of reactive sample. Thermal gradients of about 200 °C were found in the packed bed through thermocouple and IR camera measurement. Heating rates and total fed energy must be restricted at the risk of front of the sample to melt, resulting in several operation drawbacks. In contrast, mixing conditions in rotary kilns allowed for higher heating rates and led to homogenous sample temperature. Maximum reaction yields in stationary mode did not overpass 14% while it was achieved more than 80% in rotary mode at temperatures about 860 °C. Thermal efficiencies were very limited in both operation modes due to the high thermal inertia of the solar reactor. Because rotary mode admitted much more energy, its thermal efficiency was even lower than static. A solution to increase rotary kilns thermal efficiency is working in continuous mode.

ABSTRACT

Hydrogen is a promising energy carrier for transportation, domestic and industrial applications. Nowadays hydrogen is consumed basically by the chemical industry, but in long term its demand is expected to grow significantly due to emerging markets. Hence production of hydrogen with sustainable methods is a relevant issue. This work presents a review of the different CSP- aided thermochemical processes for hydrogen and syngas production. For each process, some relevant solar-tested reactor prototypes are described. In a second part, the developed solar furnaces for investigation of thermochemical process are also discussed. In addition, relevant research on hydrogen or syngas production in solar tower installations is presented. Finally the current challenges of the technology and the process for its future commercialization are also analyzed.

ABSTRACT

A three-dimensional transient heat transfer model is presented to predict the start-up operation of a multi-tubular cavity reactor under concentrated irradiation in a solar furnace. The reactor consists of a cavity containing nine absorber tubes, through which a suspension of CeO2 in Argon flows. An iterative splitting scheme coupling a Continuous Random Walk, a Finite Volume, and a Ray-Tracing Monte Carlo methods, is implemented to estimate the temperature gradients in the tubes and gas-particle media. The radiation heat transfer among the tubes and cavity walls is considered, as well as conduction and convection in the tubes and the particle suspension. During the initial heating stage, gradients are mainly angular, while in steady-state they are primarily axial. The former may cause tube bending or cracking, and strategies to reduce them are examined. In particular, different heating ramps were simulated, which was found to reduce these initial thermal gradients.

ABSTRACT

In the literature for photocatalytic reaction modeling engineering, several simplified schemes applicable to ambient temperature radiative transfer for scattering media are available. A popular strategy is the Six-Flux method because it is simple and is not computer time demanding but its accuracy is not always explicit. In the present work we assess the accuracy of low order methods, including six flux case, by solving the radiative transfer equation in dimensionless form within a cubic enclosure, for i) a collimated beam and ii) a diffuse beam. Radiation enters the cube through a square window centered on one face and with an area one quarter the area of the face. The simulation considers fully absorbing walls, and isotropic scattering. The deviations of simplified models based on Discrete Ordinate or Finite Volume schemes, are compared to the mesh independent solution. The results indicate that for a collimated beam boundary condition the Six-Flux model and more refined models are moderate. The error of the total rate of energy absorbed (TREA) and that of the local volumetric rate of energy absorption (LVREA) with respect to a mesh independent solution are below 5% and 22% respectively. In contrast, it is found that for diffuse boundary conditions the Six-Flux model is very inaccurate since the corresponding errors are larger than 120%.

Concentrating solar power (CSP) systems use solar absorbers to convert sunlight into thermal electric power. In CSP systems, a high reflective surface focuses sunlight onto a receiver that captures the solar energy and converts it into heat. The operation of high efficiency CSP systems involves improvements in the performance of the coatings of the solar absorption materials. To accomplish this, novel, more efficient selective coatings are being developed with high solar absorptance and low thermal losses at their operation temperature. Heat losses in a CSP system occur by three mechanisms: conduction, convection and radiation. It has been widely documented that energy losses increase with increasing operating temperature of CSP systems, and the precise knowledge of the thermophysical properties of the materials involved in CSP systems may allow us to increase the efficiency of systems.

In this work, we applied the pulsed photoradiometry technique (PPTR) to evaluate the changes in the thermophysical properties of selective coatings on a variety of substrates as a function of temperature. Three types of coatings deposited with two different techniques on three types of substrate were examined: commercial coatings based on titanium oxynitride deposited by sputtering on substrates of copper and aluminum, coatings based on black nickel deposited by electrochemical methods on substrates of steel, and coatings based on black cobalt deposited by electrochemical methods on substrates of steel and copper. Values of the thermal diffusivity and thermal conductivity were obtained in the temperature range of 25 to 550 °C. Optical reflectance measurements have been performed in order to provide an estimate of the dependence of the thermal emittance on temperature using the black body radiation theory. REFERENCES

ABSTRACT

In the present study, the optimization of a multi-tubular solar thermochemical cavity reactor is carried out. The reactor consists of a cubic cavity made of woven graphite, housing nine 2.54 cm diameter tungsten tubes. A heat transfer model is developed and implemented considering high-temperature radiative transfer at steady state. The temperature distribution on the receiver tubes is determined by using a hybrid Monte Carlo-finite volume approach. The optimization aims at maximizing average tube temperature by varying tube locations. Optimal tube distributions are explored by using a custom-made stochastic, multi-parameter, global optimization algorithm. A considerable increase in average temperature as well as improvement on temperature uniformity is found in the optimized tube arrays. Patterns among the different optimal distributions are found, and general features are discussed.

ABSTRACT

In this paper the simulation of the thermal reduction for hydrogen production through the decomposition of cerium oxide is presented. The thermochemical cycle for hydrogen production consists of the endothermic reduction of CeO2 at high temperature, where concentrated solar energy is used as a source of heat; and of the subsequent steam hydrolysis of the resulting cerium oxide to produce hydrogen. For the thermochemical process, a solar reactor prototype is proposed; consisting of a cubic receptacle made of graphite fiber thermally insulated. Inside the reactor a pyramidal arrangement with nine tungsten pipes is housed. The pyramidal arrangement is made respect to the focal point where the reflected energy is concentrated. The solar energy is concentrated through the solar furnace of high radiative flux. The endothermic step is the reduction of the cerium oxide to lower-valence cerium oxide, at very high temperature. The exothermic step is the hydrolysis of the cerium oxide (III) to form H2 and the corresponding initial cerium oxide made at lower temperature inside the solar reactor. For the modeling, three sections of the pipe where the reaction occurs were considered; the carrier gas inlet, the porous medium and the reaction products outlet. The mathematical model describes the fluid mechanics; mass and energy transfer occurring therein inside the tungsten pipe. Thermochemical process model was simulated in CFD. The results show a temperature distribution in the solar reaction pipe and allow obtaining the fluid dynamics and the heat transfer within the pipe. This work is part of the project “Solar Fuels and Industrial Processes” from the Mexican Center for Innovation in Solar Energy (CEMIE-Sol).

ABSTRACT

A 1 kWth cavity-type solar reactor devoted to the thermal reduction of volatile oxides as part of a two-step thermochemical cycle is analyzed numerically. The thermochemical reactor consists of a vertical-axis cavity-type receiver in which the reactant is injected from the bottom in the form of an ascending rod made of a stack of zinc oxide compressed pellets undergoing thermal dissociation. A transient heat transfer model allows the simulation of the thermal behavior under real conditions for the rod of reacting particles exposed to concentrated solar radiation. The developed numerical model couples radiation, conduction and convection heat transfers to the kinetic of the reaction. The incident solar irradiation on the reactant surface is obtained using the Monte-Carlo ray tracing technique applied first to the solar concentrator and second to the reactor cavity. The model is used to predict the temperature profile from the irradiated front surface of the compressed reactant, the evolution of outlet oxygen molar flow-rate during the reduction reaction and the instantaneous thermochemical efficiency, as a function of time. The calculated results are compared with the experimentally obtained data. The agreement between experimental data and simulation related to both the temperature and the oxygen progress is fairly good with Ea = 380 kJ mol−1 and k0 = 246 × 106 mol m−2 s−1 for the kinetics of the ZnO dissociation reaction.

ABSTRACT

Thermochemical redox processes are currently considered one of the most promising methods for thermal storage of solar energy. Among the different types of materials available for this purpose, metal oxides allow higher operation temperatures in CSP systems. This is in agreement with the new R&D trends that focus on increasing the temperature to augment the efficiency. Copper oxide was previously proposed as a valid metal oxide for thermochemical storage. However, no demonstrative experiments had been carried out so far under solar radiation. In this work, the suitability of copper oxide was proved in a solar furnace. The employed solar reactor was a rotary kiln device with direct radiation absorption on reactive particles, which is a configuration that guarantees higher operation temperatures than other types of solar reactors. Given results include the performance of the CuO reduction in the rotary kiln under argon atmosphere and the cyclability of the pair CuO/Cu2O in air.

ABSTRACT

In this work a theoretical and experimental study of heat transfer by natural convection and thermal radiation on a solar open cubic cavity-type receiver is presented. The theoretical study consists on solving the laminar natural convection and the surface thermal radiation on a square open cavity at one end. The overall continuity, momentum, and energy equations in primitive variables are solved numerically by using the finite-volume method and the SIMPLEC algorithm. The thermophysical properties of the fluid are considered, for the first case, as temperature dependent in all the governing equations, and for the second case, constant, except for the density at the buoyancy term (Boussinesq approximation), with the purpose of comparing the results of both theoretical models with experimentally obtained results. Numerical calculations are conducted for Rayleigh number (Ra) values in the range of 104–106. The temperature difference between the hot wall and the bulk fluid (ΔT) is varied between 10 and 400 K, and is represented as a dimensionless temperature difference (φ) for the purpose of generalization of the trends observed. Experimental results include air temperature measurements inside the receiver. These results are compared with theoretically obtained air temperatures, and the average deviation between both results is around 3.0%, when using the model with variable thermophysical properties, and is around 5.4% when using the Boussinesq approximation.

ABSTRACT

A comparison was made between six turbulence models and experimental temperature profiles for the turbulent natural convection in a tilted open cubic cavity. The experimental setup consists of a cubic cavity of 1 m by side with one vertical wall receiving a constant and uniform heat flux, whereas the remaining walls are thermally insulated. The thermal fluid is air and the aperture is facing the heated wall. The temperature profiles were obtained at different heights and depths and each one consists of 10 positions inside the cavity. A commercial computational fluid dynamic software was used for the simulation and different turbulence models of k-εt and k-ω families were evaluated against experimental data. The lowest absolute average percentage difference for the experimental and numerical temperature profiles was for the rk-εt model and the highest was for the sk-ω model.

ABSTRACT

Drift is ubiquitous in heliostat fields, and may be caused by diverse geometrical inaccuracies during heliostat installation and operation. This phenomenon is studied for three important primary errors in the present paper: Angular offset in the drive mechanism, pedestal tilt, and canting error. Each error produces characteristic signatures, but there is a diversity of behavior depending on the error parameters and location of the heliostat. The variation of the extent of drift curves is studied as a function of distance, for fixed error parameters. It is found that, in general, this extent is not proportional to distance, except for far heliostats, and depends on a complicated manner on the different parameters involved. Moreover, even though the extent of drift curves becomes proportional to distance for far heliostats, the convergence is very slow, and very variable with the error parameters.

ABSTRACT

Atrazine is a highly persistent and carcinogenic compound used as herbicide around the world. This compound has been banned in USA and some European countries but in Mexico it is still widely used in the agriculture. In order to achieve a high mineralization of atrazine, present as active compound in the Gesaprim commercial herbicide, detoxification studies in two-compound parabolic solar reactors by means of photo-Fenton process followed by TiO2 photocatalysis was carried out. The atrazine contents in the Gesaprim solutions tested were 35 mg L−1 (19.0 mg L−1 of TOC) and 20 mg L−1 (9.5 mg L−1 of TOC). [H2O2]0/COD0 ratios of 1, 3 and 5 (1.5 × 10−3, 4.5 × 10−3 and 7.5 × 10−3 mol L−1 H2O2, respectively) were evaluated in combination with 5 mg L−1 and 10 mg L−1 Fe2+ at pH 2.8 in the photo-Fenton oxidation; whereas, in the photocatalytic process, the influence of the pH (4.8, 7.0 and 11.0) and type of TiO2 (Degussa P25 and HB) were studied with TiO2 content of 200 mg L−1. The study showed that photo-Fenton process followed by TiO2 photocatalysis produce a 72% of mineralization (for an initial TOC of 19 mg L−1) and decrease above 90% of toxicity in compliance with NMX-AA-110-1995-SCFI1 Mexican Norm. In order to established a minimum amount of chemical reagents these photodegradation processes were carried out with special emphasis on the optimization of experimental parameters such as concentrations of photocatalyst and oxidant. Atrazine mineralization was influenced by the pH of the solution, the initial concentration of hydrogen peroxide and iron ions.

ABSTRACT

A comparison was made between six turbulence models and experimental temperature profiles for the turbulent natural convection in a tilted open cubic cavity. The experimental setup consists of a cubic cavity of 1 m by side with one vertical wall receiving a constant and uniform heat flux, whereas the remaining walls are thermally insulated. The thermal fluid is air and the aperture is facing the heated wall. The temperature profiles were obtained at different heights and depths and each one consists of 10 positions inside the cavity. A commercial computational fluid dynamic software was used for the simulation and different turbulence models of k-εt and k-ω families were evaluated against experimental data. The lowest absolute average percentage difference for the experimental and numerical temperature profiles was for the rk-εt model and the highest was for the sk-ω model.

ABSTRACT

A methodology for the evaluation of the specularity error of a polymeric filmoptical coating is presented. The methodology is based on the comparison of images from the sun produced by two high quality spherical mirrors, one covered with a highly specular evaporated aluminumfilm, and the second one with the polymeric film under study. This film is a commercial product known as Reflectech®. To determine the specularity error, both images are reproduced by means of ray tracing optical simulations. Those simulations use the angular brightness distribution from the sun as input, which were recorded by means of a specially developed solar scope. Significant differences are obtained between images of the sun generated by both mirrors. However, the specularity error of the coating under consideration is found to be just 0.71 mrad. This error is quite small making the polymeric coating highly appropriate for point focus concentration systems. This is illustrated by calculations for a parabolic dish concentrator.

ABSTRACT

Artificial neural networks (ANN) were proposed as a multivariate experimental design tool for monitoring a photo-Fenton treatment of wastewaters containing a synthetic mixture of pesticides. ANN and Nelder-Mead simplex methods were used to find out the optimum operating parameters of a photo-Fenton pilot plant. ANN was developed to predict the most important operating parameters (e.g., the total organic carbon and the initial mineralization kinetic rate constants of the reactions), which determine the photo-catalytic degradation efficiency in photo-Fenton processes. Experimental measurements of temperature, pH, hydrogen peroxide (H2O2) consumption, initial concentration of Fe2+, and the AE were used as input data for the ANN learning. A feed-forward with one hidden layer, a Levenberg–Marquardt learning algorithm, a hyperbolic tangent sigmoidal transfer function and a linear transfer function were used to develop the ANN model. The best fitting of the training database was obtained with an ANN architecture constituted by seven neurons in the hidden layer. The simulated results were validated with experimental measurements, showing an acceptable agreement (R2 > 0.99). The ANN was subsequently coupled with a Nelder–Mead simplex method to obtain the optimum operating parameters of the photo-Fenton pilot plant. The H2O2 consumption was used as key variable for evaluating the optimization procedure. Errors less than 1% between simulated and experimental data were found. The obtained results showed that the use of ANN provides an excellent predictive performance tool with the additional capability to assess the influence of each operating parameter on the removal process of water pollutants.

ABSTRACT

Radiative heat transfer in a solar thermochemical reactor for the thermal reduction of cerium oxide is simulated with the Monte Carlo method. The directional characteristics and the power distribution of the concentrated solar radiation that enters the cavity is obtained by carrying out a Monte Carlo ray tracing of a paraboloidal concentrator. It is considered that the reactor contains a gas/particle suspension directly exposed to concentrated solar radiation. The suspension is treated as a non-isothermal, non-gray, absorbing, emitting, and anisotropically scattering medium. The transport coefficients of the particles are obtained from Mie-scattering theory by using the optical properties of cerium oxide. From the simulations, the aperture radius and the particle concentration were optimized to match the characteristics of the considered concentrator.

ABSTRACT

Radiative heat transfer in a solar thermochemical reactor for the thermal reduction of cerium oxide is simulated with the Monte Carlo method. The directional characteristics and the power distribution of the concentrated solar radiation that enters the cavity is obtained by carrying out a Monte Carlo ray tracing of a paraboloidal concentrator. It is considered that the reactor contains a gas/particle suspension directly exposed to concentrated solar radiation. The suspension is treated as a non-isothermal, non-gray, absorbing, emitting, and anisotropically scattering medium. The transport coefficients of the particles are obtained from Mie-scattering theory by using the optical properties of cerium oxide. From the simulations, the aperture radius and the particle concentration were optimized to match the characteristics of the considered concentrator.

Se hizo una estimación de riesgos oculares por radiación solar concentrada en una instalación de tipo torre central destinada al aprovechamiento de energía solar. Dicha instalación es el Campo de Prueba de Helióstatos, operado conjuntamente por la Universidad Nacional Autónoma de México y la Universidad de Sonora, y recientemente inaugurado, en Hermosillo, México. La evaluación de riesgos potenciales del brillo y resplandor, originados por el receptor y las superficies de los helióstatos, fue realizada de acuerdo con la metodología propuesta en las investigaciones mas recientes. Donde, se estimaron los niveles de radiación solar concentrada mediante el software de trazo de rayos, SOLTRACE. Los niveles de radiación reflejada se comparan con los límites máximos permisibles expuestos en estudios anteriores.

Abstract

Due to the growing motivation of countries to use renewable energy, instead of fossil fuels, for the production of electricity, the number of solar power plants had an increase in recent times. The sun as a renewable source is used by the Concentrated Solar Power systems (CSP) to achieve this goal. This process results in a considerable amount of concentrated solar radiation (visible light, infrared and ultraviolet radiation) inside and in the neighborhood of the installations. Some previous studies have addressed the possible risks for health of workers in environments where they perform activities in outdoors exposed to solar radiation. The overall purpose of this paper is to provide information about the environmental conditions in facilities using CSP technology, the effects of solar radiation in humans and the methods for the risk assessment in this type of facilities. Several standards including elements applicable to the field of occupational health in the central receiver area of solar power plants are also referred.

Abstract

Among the Concentrated Solar Power technologies, central receiver systems (CRS) is the technology moving to the forefront in market penetration. CRS requires the use of heliostats oriented toward the central receiver in order to concentrate solar radiation. The excess of light due to the reflection of the sunlight on the heliostats' surface and the brightness of the receiver are considered as possible situations of risk for the eye. The paper briefly outlines the physiological response to solar radiation subjected to momentary ocular exposures. This will be followed by the description of health impairments and the presentation of the methodology and safety doses. A case of study based on direct solar radiation measurements, is foreseen. Two scenarios were evaluated, the action of seeing directly to a heliostats' surface and the action of seeing the reflected radiation from the receiver. In the case of seeing the brightness from receiver, there exist a low potential to cause a temporary effect on the eye. Besides, a person that is looking at heliostat surface has a huge potential to present a temporary effect (after-image). The final section of the study will present and discussed the results obtained from the analysis of the case of study and provide some recommendations. The investigation aims to contribute with information directed to environmental scientists, standard developers and the solar industry that could improve/develop safety procedures directed toward the occupational health and safety within solar energy applications.