Physical Chemistry of Hydroxyapatite

In this research area, we study the optical and electrical properties of vacancy-type defects in hydroxyapatite (HAp) undoped and doped with magnetic impurities. 

We evaluate the luminescent properties of such HAp nanostructures using advanced electron microscopy techniques such as cathodoluminescence; in addition, we use the photoluminescence and the paramagnetic electron resonance technique to correlate the characterization of point-defects. To evaluate the physical chemistry properties of HAp, we use the X-ray photoelectron spectroscopy technique. 

Finally, we assess the biocompatibility of HAp to fabricate osteoinductive scaffolds and materials to use as a contrast medium in nuclear magnetic resonance imaging during bone regeneration treatments. 


Heads of research: 

Dr. Manuel Herrera ), (UNAM), and Dra. Olivia Graeve (UCSD).


Recent publications of Prof M. Herrera's group:

White emission in 3D-printed phosphor microstructures.  

Winczewski, M. Herrera, H. Gardeniers, A. Susarrey.  

Chemical Communications 59 (2023) 3095

https://doi.org/10.1039/d2cc06953a

 

Enabling high-quality transparent conductive oxide on 3D printed ZrO2 architectures through atomic layer deposition. 

J. Arriaga, J. Winczewski, M. Herrera, E. Murillo, C. Rosero, N. Pineda, L. Cholula, I De León, H. Gardeniers, A. Susarrey, E. Martínez

Applied Surface Science 636 (2023) 157796

https://doi.org/10.1016/j.apsusc.2023.157796   

 

Influence of single-ionized oxygen vacancies on the generation of ferromagnetism in SnO2 and SnO2:Cr nanowires.

D. Montalvo, V. Gómez, W. de la Cruz, S. Camacho, I. Rivero, K. Carrera, V. Orozco, C. Santillán, J. Matutes, and M. Herrera

Applied Physics A 129 (2023) 537

https://doi.org/10.1007/s00339-023-06790-z


Additive Manufacturing of 3D Luminescent ZrO2:Eu3+ Architectures

J Winczewski, M Herrera, C Cabriel, I Izeddin, S Gabel, B Merle, A Susarrey, H Gardeniers

Adv. Optical Mater. (2022), 2102758

doi.org/10.1002/adom.202102758 


Spectroscopic Ellipsometry Study on Tuning the Electrical and Optical Properties of Zr-Doped ZnO Thin Films Grown by Atomic Layer Deposition

C. Bohorquez, H. Bakkali, J. J. Delgado, E. Blanco, M Herrera, M. Domínguez

ACS Applied Electronic Materials 4 (2022) 925

https://doi.org/10.1021/acsaelm.1c01026


Additive Effect of inert ambient annealing on structural and defect characteristics of coaxial N-CNTs@ZnO nanotubes coated by atomic layer deposition. 

H.A. Borbon, D. Domínguez , M. Herrera, J.M. Romo, R.C. Carrillo, F.F. Castillon, O.E. Contreras, G. Soto, H. Tiznado. 

Ceramics International 48 (2022) 29829 

https://doi.org/10.1016/j.ceramint.2022.06.245


Morphology control of tantalum carbide nanoparticles through dopant addition

T. Ren, R. Tran, S. Lee, A. Bandera, M. Herrera, X. Li, S. Ping-Ong and O. Graeve.

Journal of Physical Chemistry C 125 (2021) 10665- 10675

https://doi.org/10.1021/acs.jpcc.1c01387


Effect of Oxygen Vacancies on the Mechanoluminescence Response of Magnesium Oxide.

E. Novitskaya, A. Manheim, M. Herrera, O. A. Graeve

Journal of Physical Chemistry C 121 (2021) 854 - 864

https://doi.org/10.1021/acs.jpcc.0c07674


Photoluminescence up-conversion and cathodoluminescence in quaternary CdxZnyOγSδ nanoparticles embedded on zeolite

O. E. Jaime-Acuña, R. E San-Juan Farfán, H. Villavicencio, M. Herrera, O. Raymond-Herrera

Journal of Physics and Chemistry of Solids 159 (2021) 110004

https://doi.org/10.1016/j.jpcs.2021.110004


A combined optical and morphological study of 2,5-bis(dodecanoxy) phenyleneethynylene-butadiynes films for oLEDs

B Kinzeeva, G Turlakov, I Moggio, E Arias, G Rodríguez, M Herrera, T Cooper, M Ottonelli, R F Ziolo.

Materials Science and Engineering B 263 (2021) 114779

https://doi.org/10.1016/j.mseb.2020.114779


Defect-related luminescence properties of hydroxyapatite nanobelts

V. Huerta, P. Fernández, V. Gómez, O. A. Graeve and M. Herrera

Applied Materials Today 21 (2020) 100822

https://doi.org/10.1016/j.apmt.2020.100822


Defect-related luminescence properties of hydroxyapatite nanobelts

V. Huerta, P. Fernández, V. Gómez, O. A. Graeve and M. Herrera

Applied Materials Today 21 (2020) 100822

https://doi.org/10.1016/j.apmt.2020.100822


Hole-mediated ferromagnetism in GaN doped with Cu and Mn.

G. Guzmán, D. Maestre and M. Herrera

Journal of Material Science: Materials in Electronics 31 (2020)

https://link.springer.com/article/10.1007/s10854-020-04070-7