First Atallah Lab Paper with Denison Students:
Nguyen, L. T.; Zupnick, R.; Vo Truong, Quynh; Atallah, T. L.; Low-Dimensional AgTePh Disordered Aggregation Versus Directed Coalescence for Shortwave-IR to Visible Semiconductors Nanoscale 2025, 17, 19136-19142. https://doi.org/10.1039/D5NR02425K
Open access chemrxiv version
Abstract:
We report a rapid one-pot synthesis of mesoscale 2D AgTePh quantum-well crystals through a mild heating of a 1D nanowire intermediate. We contrast disordered aggregation (broadband NIR–SWIR emission) with directed coalescence (visible emission), revealing synthetic control over dimensionality and photophysics in organic-inorganic silver phenyltellurolate semiconductors.
Shin, A. J.; Zhao, C.; Shen, Y.; Dickerson, C. E.; Li, B. Y.; Roshandel, H.; Bím, D.; Atallah, T. L.; Oyala, P. H.; Alson, L. K.; Kerr, T. A.; Alexandrova, A. N.; Diaconescu, P. L.; Campbell, W. C.; Caram, J. C. Toward Liquid Cell Quantum Sensing: Ytterbium Complexes with Ultra-Narrow Absorption Science 2024, 385, 651-656.
Tenney, S.; Tan, L.; Tan, X.; Sonnleitner, M.; Coffey, B.; Williams, J.; Ronquillo, R.; Atallah, T. L.; Ahmed, T.; Caram, J. Efficient 2D to 0D Energy Transfer in HgTe Nanoplatelet-Quantum Dot Heterostructures through High-Speed Exciton Diffusion. J. Phys. Chem Lett., 2023, 14, 9456-9463.
Bailey, A.; Deshmukh, A.; Bradbury, N. C.; Pengshung, M.; Atallah, T. L.; Williams, J. A.; Barotov, U.; Neuhauser, D..; Sletten, E.; Caram, Exploring the Design of Superradiant J-Aggregates from Amphiphilic Monomer Units Nanoscale, 2023, 15, 3841-3849.
Sica, A. V.; Hua, A. S.; Lin, H. H.; Sletten, E. M.; Atallah, T. L.;* Caram, J.* Spectrally-Selective Time-Resolved Emission through Fourier-Filtering (STEF) J. Phys. Chem. Lett. 2023, 14, 552-558. *Co-Corresponding Author
Guan, X.; Erşan, S.; Hu, X.; Atallah, T. L.; Xie, Y.; Lu, S.; Cao, B.; Sun, J.; Wu, K.; Huang, Y.; Duan, X.; Caram, J. R.; Yu, Y.; Park, J. O.; Liu, C. Maximizing Light-Driven CO2, and N2 Fixation Efficiency in Quantum Dot–Bacteria Hybrids Nat. Catal. 2022, 5, 1019-1029.
Tenney, S. M; Tan, L. A.; Sonnleitner, M. L.; Sica, A. V.; Shin, A. J.; Ronquillo, R.; Ahmed T.; Atallah, T. L.; Caram J. R. Seeded Growth of Mesoscale Quantum-Confined Semiconductor Nanoplatelets Chem. Mater. 2022, 34, 6048-6056.
Deshmukh, A. P; Geue, N.; Bradbury, N. C.; Atallah, T. L.; Chuang, C.; Pengshung, M.; Cao, J.; Sletten, E. M.; Daniel Neuhauser, D.; Caram J. R. Bridging the Gap between H- and J-Aggregates: Classification and Supramolecular Tunability for Excitonic Band Structures in 2-Dimensional Molecular Aggregates Chem. Phys. Rev. 2022, 3, 021401.
Chen, P.;* Atallah, T. L.;* Lin, Z.; Wang, P.; Lee, S-J.; Xu, J.; Huang, Z.; Ping, Y.; Huang, Y.; Duan, X.; Caram, J. R.; Duan, X. Approaching the intrinsic exciton physics limit in two-dimensional semiconductor diodes, Nature, 2021, 599, 404-410. *Co-First Author
Friedman, H. C.; Cosco, E. D.; Atallah, T. L.; Sletten, E. M.; Caram, J. R. Establishing design principles for emissive organic SWIR chromophores from energy gap laws, Chem, 2021, 7, 3359-3376.
Shin, A. J.; Hossain, A.; Tenney, S. T; Tan, X.; Tan, L.; Foley IV, J. J.; Atallah, T. L.;* Caram, J. R.* Dielectric Screening Modulates Nanoplatelet Excitons J. Phys. Chem. Lett. 2021, 12, 4958-4964. *Co-Corresponding Author
Cosco, E. D.; Arús, B. A.; Spearman, A. L.; Atallah, T. L.; Leland, O. S.; Bischof, Caram, J. R.; T. S.; Bruns, O. T.; Sletten, E. M. Bright Polymethine Emitters for Multiplexed Shortwave Infrared in Vivo Imaging J. Am. Chem. Soc. 2021, 143, 6836-6846.
Wang, Y.; Jia, C.; Fan, Z.; Lin, Z.; Lee, S.-J.; Atallah, T. L.; Caram, J. R.; Huang, Y.; Duan, X. Large-Area Synthesis and Patterning of All-Inorganic Lead Halide Perovskite Thin Films and Heterostructures Nano Lett. 2021, 21, 1451-1460.
Guo, H.; Dickerson, C. E.; Shin, A. J.; Zhao, C.; Atallah, T. L.; Caram, J. R.; Campbell, W. C.; Alexandrova, A. N. Surface Chemical Trapping of Optical Cycling Centers Phys. Chem. Chem. Phys. 2021, 23, 211-213.
Tenney, S. M.; Vilchez, V.; Sonnleitner, M.; Huang, C.; Friedman, H. C.; Shin, A. J.; Deshmukh,A.; Atallah, T. L.; Ithurria S.; Caram, J. R. Mercury Chalcogenide Nanoplatelet-Quantum Dot Heterostructures as a New Class of Continuously Tunable Bright Shortwave Infrared Emitters J. Phys. Chem. Lett. 2020, 11, 3473–3480.
Pengshung, M.; Neal, P.; Atallah, T. L.; Kwon, J.; Caram, J. R.; Lopez, S. A.; Sletten, E. M. Silicon Incorporation in Polymethine Dyes Chem. Comm. 2020, 56, 6110-6113.
Atallah, T. L.; Sica, A. V.; Shin, A. J.; Friedman, H. C.; Kahrobai, Y. K.; Caram, J. R. Decay-Associated Fourier Spectroscopy: Visible to Shortwave Infrared Time-Resolved Photoluminescence Spectra J. Phys. Chem. A 2019, 123, 6792-6798.
Evans, T. J. S.; Schlaus, A.; Fu, Y.; Zhong, X.; Atallah, T. L.; Spencer, M .S.; Brus, L. E.; Jin, S.; Zhu, X.-Y. Continuous-Wave Lasing in Cesium Lead Bromide Perovskite Nanowires Adv. Opt. Mat. 2018, 6, 1700982.
Miyata, K.; Atallah, T. L.; Zhu, X.-Y. Lead Halide Perovskites: Crystal-Liquid Duality, Phonon Glass Electron Crystals, and Large Polaron Formation Sci. Adv. 2017, 3, e1701469.
O ’Brien, E. S.; Trinh, M. T.; Kann, R. L.; Chen, J.; Elbaz, G. A.; Masurkar, A.; Atallah, T. L.; Paley, M. V; Patel, N.; Paley, D. W.; Kymissis, I.; Crowther, A. C.; Millis, A. J.; Reichman, D. R.; Zhu, X.; Roy, X. Single-Crystal-to-Single-Crystal Intercalation of a Low-Bandgap Superatomic Crystal Nat. Chem. 2017, 9, 1170-1174.
Atallah, T. L.; Wang, J.; Bosch, M.; Seo, D.; R. Burke, Moneer, O.; Zhu, J.; Theibault, M.; Brus, L.; Hone, J.; Zhu, X.-Y. Electrostatic Screening of Charged Defects in Monolayer MoS2 J. Phys. Chem. Lett. 2017, 8, 2148-2152.
Atallah, T. L.; Gustafsson, M. V; Schmidt, E.; Frisbie, C. D.; Zhu, X.-Y. Charge Saturation and Intrinsic Doping in Electrolyte-Gated Organic Semiconductors J. Phys. Chem. Lett. 2015, 6, 4840–4844.
Morris, J. D.; Atallah, T. L.; Park, H.; Ooi, Z.; Dodabalapur, A.; Zhu, X.-Y. Quantifying Space Charge Accumulation in Organic Bulk Heterojunctions by Nonlinear Optical Microscopy Org. Electron. 2013, 14, 3014–3018.
Morris, J. D.; Atallah, T. L.; Lombardo, C. J.; Park, H.; Dodabalapur, A.; Zhu, X.-Y. Mapping Electric Field Distributions in Biased Organic Bulk Heterojunctions under Illumination by Nonlinear Optical Microscopy Appl. Phys. Lett. 2013, 102, 33301.
Atallah, T. L.; Blankespoor, R. L.; Homan, P.; Hulderman, C.; Samas, B. M.; Van Allsburg, K.; Vrieze, D. C. Substituent Effects on the Amination of Racemic Allyl Carbonates Using Commercially Available Chiral Rhodium Catalysts. Tetrahedron Lett. 2013, 54, 5795–5798.
Haan, S. L.; Smith, Z. S.; Shomsky, K. N.; Plantinga, P. W.; Atallah, T. L. Anticorrelated Electrons from High-Intensity Nonsequential Double Ionization of Atoms. Phys. Rev. A 2010, 81, 23409.
“Rapid One-Pot Synthesis of 2D AgTePh: Pathways Governing SWIR (Aggregates) vs Visible (Platelets) Emission”, Oral, American Chemical Society National Meeting and Exposition, Atlanta, GA, Spring 2026.
“Doping of Organic and Nanocrystalline Semiconductors Enhances Optoelectronic Properties”, Poster, American Chemical Society National Meeting and Exposition, New Orleans, LA, Spring 2024.
“Doping Next Gen. Semiconductors: Principles of “Performance Enhancement”, Department Seminar, Denison University, Granville, OH, Fall 2023.
“Chemical Doping in Crystalline Organic and Nanocrystalline Semiconductors Unlock New Optoelectronic Properties”, Poster, American Chemical Society National Meeting and Exposition, Indianapolis, IN, Spring 2023.
“Photocurrent Imaging and Photoluminescence Lifetimes Reveal Intrinsic Excitonic 2D PN Junction Behavior”, Oral, American Chemical Society National Meeting and Exposition, Indianapolis, IN, Spring 2023.
“Exciton-Charge Auger Limit Photovoltaic Performance of 2D Semiconductor Devices”, Oral, Material Research Society Meeting and Exhibit, Boston, MA, Fall 2022.
“Semiconductors and Devices on A Plane: Accessing Fundamental 2D Atomic Semiconductor Properties”, Invited Seminar, Kenyon College, Gambier, OH, Spring 2022.
“Decay Associated Fourier Spectra: Visible to Shortwave Infrared Time-Resolved Emission Spectra”, Oral & Poster, American Chemical Society National Meeting and Exposition, San Diego, CA, Fall 2019.
“Decay Associated Fourier Spectra: Visible to SWIR Time-Resolved Emission Spectra”, Oral, Pacific Conference on Spectroscopy and Dynamics, San Diego, CA, January 2019.
“Decay Associated Fourier Spectroscopy: Detecting Luminescence from Visible to Shortwave”, Poster, Seaborg Symposium, Los Angeles, CA, November 2018.
“Defects in Narrow Bandgap 2D Semiconductors”, Poster, Gordon Research Conference: Two Dimensional Electronics Beyond Graphene, Easton, MA, June 2018.
“Electrostatic Screening of Charged Defects in 2D Materials”, Oral, American Physical Society Meeting, New Orleans, LA, Spring 2017.
“Intrinsic Doping at Liquid Electrolyte/Organic Semiconductor Interfaces”, Oral, Material Research Society Meeting and Exhibit, Boston, MA, Fall 2014.
“Ultrafast Charge Separation at Organic Donor-Acceptor Interfaces: Experiment and Theory”, Poster, International Conference on Science and Technology of Synthetic Metals, Atlanta, GA, 2012.
“Mechanistic Insights into Rhodium Catalyzed Asymmetric Allylic Substitution Reactions”, Poster, American Chemical Society National Meeting and Exposition, Boston, MA, Fall 2012.
“Scope of a Rhodium Catalyzed Asymmetric Allylic Substitution Reactions”, West Michigan Regional Undergraduate Science Research Conference, Grand Rapids MI, 2010.
“Rhodium Catalyzed Asymmetric Allylic Substitution Reactions”, West Michigan Regional Undergraduate Science Research Conference, Grand Rapids, MI, 2009.
“Classical Modeling of Non-Sequential Double Ionization: Recollision, Time-Delayed ionization, Drift, and Possible Reattachment”, Poster, International Conference on Photonic, Electronic and Atomic Collisions, Kalamazoo, MI, 2009