Publications

Peer-Reviewed Publications

Synthesis of Soluble Poly(Methacrylic Anhydride) by Radical Cyclopolymerization [doi link]
P. Sivabalan, M. J. Kozody, P. Yuya, D. S. K. Samways, D. A. Shipp
Macromolecules, 2024, 57, in press (ASAP).


Surface Eroding Methacrylic Anhydride Copolymers and Model Drug Release [doi link]
A. L. Santefort, A. C. Appolon, L. J. Cowart, D. A. Shipp
Macromol. Chem. Phys., 2023, 224, 2300134.


Dynamic Covalent Exchange in Methacrylic Anhydride Copolymers [doi link]
A. L. Santefort, P. A. Yuya, D. A. Shipp
Polymer, 2023, 281, 126120.


Particle Formation in Thermally Initiated Radical-Mediated Thiol-Ene Emulsion Polymerizations [doi link]
K. J. Cassidy, D. A. Shipp
J. Polym. Sci., 2023, 61, 166-173.


Dynamic Covalent Exchange Induced Cyclization in Poly(Methacrylic Anhydride) [doi link]
A. L. Santefort, P. Yuya, D. A. Shipp
Polym. Chem., 2022, 13, 4502-4510. 


Stepwise Gradient Copolymers of n-Butyl Acrylate and Isobornyl Acrylate by Emulsion RAFT Copolymerizations [doi link]
I. H. Alshehri, D. Pahovnik, E. Zagar, D. A. Shipp
Macromolecules, 2022, 55, 391-400.


Force-Induced Near-Infrared Chromism of Mechanophore-Linked Polymers [doi link]
Q. Qi, G. Sekhon, R. Chandradat, N. M. Ofodum, T. Shen, J. Scrimgeour, M. Joy, M. Wriedt, M. Jayathirtha, C. C. Darie, D. A. Shipp, X. Liu, X. Lu
J. Am. Chem. Soc., 2021, 143, 17337-17343.


Glycolipid-Containing Nanoparticle Vaccine Engages Invarient NKT Cells to Enhance Humoral Protection against Systemic Bacterial Infection but Abrogates T-Independent Vaccine Responses [doi link]
T. Shute, E. Amiel, N. Alam, J. L. Yates, K. Mohrs, E. Dudley, B. Salas, C. Mesa, A. Serrate, D. Angel, B. K. Vincent, A. Weyers, P. A. Lanthier, E. Vomhof-Dekrey, R. Fromme, M. Laughlin, O. Durham, J. Miao, D. Shipp, R. J. Lindhardt, K. Nash, E. A. Leadbetter
J. Immunol., 2021, 206, 1806-1816.


Polymer Colloids from Step-Growth Thiol-X Polymerizations [doi link]
O. Z. Durham, D. A. Shipp
Polym. Rev., 2021, 61, 54-79.


Dynamic Covalent Exchange in Poly(thioether anhydrides) [doi link]
K. R. Tillman, R. Meacham, A. N. Rolsma, M. Barankovich, A. M. Witkowski, P. T. Mather, T. Graf, D. A. Shipp
Polym. Chem., 2020, 11, 7551-7561.


Drug Delivery and Drug Efficacy from Amorphous Poly(thioether anhydrides) [doi link]
B. L. Snyder, H. S. Mohammed, D. S. K. Samways, D. A. Shipp
Macromol. Biosci., 2020, 20, 1900377.


Raman Microspectroscopy Study of the Hydrolytic Degradation of Polyanhydride Network Polymers [doi link]
L. Bian, H. S. Mohammed, D. A. Shipp, P. J. G. Goulet
Langmuir, 2019, 35, 6387-6392.


Composite Particles From Pickering-Stabilized Radical-Mediated Thiol-Ene Suspension Polymerizations [doi link]
K. J. Cassidy, O. Z. Durham, D. A. Shipp
Macromol. React. Eng., 2019, 13, 1800075.


Effect of Polymer Chain Architecture on the Aqueous Solution Properties of Amphiphilic Copolymers: A Study of Poly(N-vinylpyrrolidone-co-vinyl acetate) [doi link]
K. A. Knapp, I. M. Nuñez, D. A. Shipp
Polymer, 2018, 141, 54-61.


Poly(N-vinylpyrrolidone)-Polydimethylsiloxane Amphiphilic ABA Triblock Copolymers [doi link]
D. Pavlović, Q. Lou, J. G. Linhardt, J. F. Künzler, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem., 2017, 55, 3387-3394.


Polyanhydride Nanoparticles: Thiol-Ene ‘Click’ Polymerizations Provide Functionalized and Cross-Linkable Nanoparticles with Tuneable Degradation Times  [doi link]
O. Z. Durham, K. L. Poetz, D. A. Shipp
Aust. J. Chem., 2017, 70, 735-742.


Radical Mediated Thiol-Ene/Yne Dispersion Polymerizations [doi link]
F. Alimohammadi, C. Wang, O. Z. Durham, H. R. Norton, C. N. Bowman, D. A. Shipp
Polymer, 2016, 105, 180-186.


Polyanhydrides: Synthesis, Properties, and Applications [doi link]
K. L. Poetz, D. A. Shipp
Aust. J. Chem. 2016, 69, 1223-1239. 


Quantitative and Qualitative Toxicological Evaluation of Thiol-Ene “Click” Chemistry-Based Polyanhydrides and their Degradation Products [doi link]
H. S. Mohammed, B. L. Snyder, D. S. K. Samways, D. A. Shipp
J. Biomed. Mater. Res. Part A, 2016, 104, 1936-1945.


Anhydride-Based Reconfigurable Shape Memory Elastomers [doi link]
M. I. Lawton, K. R. Tillman, H. S. Mohammed, W. Kuang, D. A. Shipp, P. T. Mather
ACS Macro Lett., 2016, 5, 203-207. 


Functional Polymer Particles via Thiol-Ene and Thiol-Yne Suspension “Click” Polymerization [doi link]
O. Z. Durham, H. R. Norton, D. A. Shipp
RSC Adv., 2015, 5, 66757-66766. 


Polyanhydride Nanoparticles by ‘Click’ Thiol-Ene Polymerization [doi link]
K. L. Poetz, O. Z. Durham, D. A. Shipp
Polym. Chem., 2015, 6, 5464-5469.


Suspension “Click” Polymerizations: Thiol-Ene Polymer Particles Prepared with Natural Gum Stabilizers [doi link]
O. Z. Durham, D. A. Shipp
Colloid Polym. Sci., 2015, 293, 2385-2394.


Surface Eroding, Semicrystalline Polyanhydrides via Thiol-Ene “Click” Photopolymerization [doi link]
K. L. Poetz, H. S. Mohammed, D. A. Shipp
Biomacromolecules, 2015, 16, 1650-1659.


Reaction-diffusion degradation model for delayed erosion of cross-linked polyanhydride biomaterials [doi link]

S. Domanskyi, K. L. Poetz, D. A. Shipp, V. Privman
Phys. Chem. Chem. Phys., 2015, 17, 13215-13222. (Feature cover of journal)


Photopolymerized Crosslinked Thiol-Ene Polyanhydrides: Erosion, Release and Toxicity Studies [doi link]
K. L. Poetz, H. S. Mohammed, B. L. Snyder, G. Liddil, D. S. K. Samways, D. A. Shipp
Biomacromolecules, 2014, 15, 2573-2582.


Benzotriazole as a Passivating Agent During Chemical Mechanical Planarization of Ni-P Alloy Substrates [doi link]
Y. Mu, M. Zhong, K. J. Rushing, Y. Li, D. A. Shipp
Appl. Surf. Sci., 2014, 315, 190-195.


Suspension Thiol-Ene Photopolymerization: Effect of Stabilizing Agents on Particle Size and Stability [doi link]
O.Z. Durham, D.A. Shipp
Polymer, 2014, 55, 1674-1680. 


Role of 1,2,4-Triazole as a Passivating Agent for Cobalt during Post-Chemical Mechanical Planarization Cleaning [doi link]
M. Zhong, S. S. Venkataraman, Y. Lan, Y. Li, D. A. Shipp
J. Electrochem. Soc., 2014, 161, C138-C144. 


RAFT Polymerization of Monomers with Highly Disparate Reactivities: Use of a Single RAFT Agent and the Synthesis of Poly(styrene-block-vinyl acetate) [doi link]
L. A. Dayter, K. A. Murphy, D. A. Shipp
Aust. J. Chem., 2013, 66, 1564-1569. 


Thiol-Ene Polymerizations Using Imide-Based Monomers [doi link]
K. A. Murphy, A. S. Zebertavage, B. E. Kiliman, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem., 2013, 51, 4637-4642. 


Recent Developments in Atom Transfer Radical Polymerization (ATRP): Methods to Reduce Metal Catalyst Concentrations [doi link]
Q. Lou, D. A. Shipp
ChemPhysChem, 2012, 13, 3251-3261.


Imprint Lithography with Degradable Elastomeric Polyanhydrides [doi link]
Q. Lou, D. A. Shipp
ACS Appl. Mater. Interfaces 2012, 4, 4457-4460.


Polymer Microspheres Prepared by Water-Borne Thiol-Ene Suspension Photopolymerization [doi link]
O. Z. Durham, S. Krishnan, D. A. Shipp
ACS Macro Lett. 2012, 1, 1134-1137.  


Mechanism of Titania Deposition into Cylindrical Poly(styrene-block-4-vinyl pyridine) Block Copolymer Templates [doi link]
Q. Lou, P. S. Chinthamanipeta, D. A. Shipp
Langmuir 2011, 27, 15206-15212.


Photodecarbonylation and Photoinitiated Polymerization from a Monomer and Polymer Based on the alpha-Keto Ester Methacryloyl Phenylglyoxylate [doi link]
K. Omrane, J.-J. Feng, R. E. Partch, D. A. Shipp
Polym. Chem. 2011, 2, 1307-1311.


Reversible-Deactivation Radical Polymerizations [doi link]
D. A. Shipp
Polym. Revs. 2011, 51, 99-103. (in a special edition edited by Prof. Shipp)


Periodic Titania Nanostructures Using Block Copolymer Templates [doi link]
P. S. Chinthamanipeta, Q. Lou, D. A. Shipp
ACS Nano 2011, 5, 450-456.


Polyanhydride Networks from Thiol-Ene Polymerizations
B. G. Rutherglen, R. A. McBath, Y. L. Huang, D. A. Shipp
Macromolecules 2010, 43, 10297-10303.  [doi link]

 

Swelling and Degradation of Hydrogels Synthesized with Degradable Poly(b-amino ester) Crosslinkers [doi link]
R. A. McBath, D. A. Shipp
Polym. Chem. 2010, 1, 860-865.


Synthesis and Characterization of Polydimethylsiloxane, Poly(N-vinyl pyrrolidone) and Polystyrene-Containing ABCBA Pentablock Copolymers [doi link]
D. Pavlović, J. G. Linhardt, J. F. Künzler, D. A. Shipp
Macromol. Chem. Phys. 2010, 211, 1482-1487.


Synthesis of Statistical and Block Copolymers Containing Adamantyl and Norbornyl Moieties by Reversible Addition-Fragmentation Chain Transfer Polymerization [doi link]
Q. Lou, M. A. Kishpaugh, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 943-951.


Elastomeric and Degradable Polyanhydride Network Polymers by Thiol-Ene Step-Growth Photopolymerization [doi link]
D. A. Shipp, C. W. McQuinn, B. G. Rutherglen, R. A. McBath
Chem. Comm. 2009, 6415-6417.


Grafting of Polystyrene ‘From’ and ‘Through’ Surface Modified Titania Nanoparticles [doi link]
B. J. Lowes, A. G. Bohrer, T. T. Tran, D. A. Shipp
Polym. Bull. 2009, 62, 281-289.


Synthesis of Poly(Methyl Methacrylate)-Silica Nanocomposites Using Methacrylate-Functionalized Silica Nanoparticles and RAFT Polymerization [doi link]
P. S. Chinthamanipeta S., S. Kobukata, H. Nakata, D. A. Shipp
Polymer, 2008, 46, 5636-5642.


Synthesis of Poly(tert-butyl acrylate-block-vinyl acetate) Copolymers by Combining ATRP and RAFT Polymerizations [doi link]
C. D. Petruczok, R. F. Barlow, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 7200-7206.


Synthesis of Amphiphilic Multiblock and Triblock Copolymers of Polydimethylsiloxane and Poly(N,N-Dimethylacrylamide) [doi link]
D. Pavlovic, J. G. Linhardt, J. F. Kunzler, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 7033-7048.


Stoichiometric Complexes of Polyelectrolyte and Azo-Functionalized Surfactant [doi link]
D. Abdallah, M. J. Cully, Y. Li, D. A. Shipp
Coll. Polym. Sci. 2008, 286, 739-745.


Uniform Sub-Micron Polymer Spheres Coated with Ag Nanoparticles [doi link]
H. Mohammed, D. A. Shipp
Macromol. Rapid Commun. 2006, 27, 1774-1778.


Polymer-Layered Silicate Nanocomposites Prepared Through in situ Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization [doi link]
N. Salem, D. A. Shipp
Polymer 2005, 46, 8573-8581


Structure and Melt Rheology of Polystyrene-Based Layered Silicate Nanocomposites [doi link]
L. Xu, S. Reeder, M. Thopasridharan, J. Ren, D. A. Shipp, R. Krishnamoorti
Nanotechnology, 2005, 16, S514-S521.


Living Radical Polymerization: Controlling Molecular Size and Chemical Functionality in Vinyl Polymers [doi link]
D. A. Shipp
J. Macromol. Sci. Polym. Rev. 2005, 45, 171-194.


Kinetic Analysis of Styrene Atom Transfer Radical Polymerization: Extraction of Termination Rate Coefficients [doi link]
D. A. Shipp, X. Yu
J. Polym. Sci. A: Polym. Chem. 2004, 42, 5548-5558.


Nanopatterns of Poly(styrene-block-butyl acrylate) Block Copolymer Brushes on the Surface of Exfoliated and Intercalated Clay Layers [doi link]
H. Zhao, B. P. Farrell, D. A. Shipp
Polymer 2004, 45, 4473-4481.


Polymer-Silicate Nanocomposites Produced by in situ Atom Transfer Radical Polymerization [doi link]
H. Zhao, S. D. Argoti, B. P. Farrell, D. A. Shipp
J. Polym. Sci. Part A: Polym. Chem. 2004, 42, 916-924.


Preparation of Poly(styrene-block-butyl acrylate) Block Copolymer-Silicate Nanocomposites [doi link]
H. Zhao, D. A. Shipp
Chem. Mater. 2003, 15, 2693-2695.


The Chain Length Dependence of Radical-Radical Termination in Free Radical Polymerization: A Pulsed Laser Photolysis Investigation [doi link]
D. A. Shipp, D. H. Solomon, T. A. Smith, G. Moad
Macromolecules 2003, 36, 2032-2040.


Kinetic Analysis of the Atom Transfer Radical Polymerization of n-Butyl Acrylate Mediated by Cu(I)Br/N,N,N’,N’,N”-Pentamethyldiethylenetriamine [doi link]
M. Reyes, X. Yu, D. A. Shipp
Macromol. Chem. Phys. 2001, 202, 3268-3272. (featured on journal cover)


Free-Radical Intermediates in Atom Transfer Radical Addition and Polymerization: Study of Racemization, Halogen Exchange, and Trapping Reactions [doi link]
K. Matyjaszewski, H.-j. Paik, D. A. Shipp, Y. Isobe, Y. Okamoto
Macromolecules 2001, 34, 3127-3129.


Water-Borne Block and Statistical Copolymers Synthesized Using Atom Transfer Radical Polymerization [doi link]
K. Matyjaszewski, D. A. Shipp, J. Qiu, S. G. Gaynor
Macromolecules 2000, 33, 2296-2298.


Simple and Effective One-Pot Synthesis of (Meth)Acrylic Block Copolymers Through Atom Transfer Radical Polymerization [doi link]
K. Matyjaszewski, D. A. Shipp, G. P. McMurtry, S. G. Gaynor
J. Polym. Sci. Part A: Polym. Chem. 2000, 38, 2023-2031.


Kinetic Analysis of Controlled/’Living’ Radical Polymerizations by Simulations. 2. Apparent External Orders of Reactants in Atom Transfer Radical Polymerization [doi link]
D. A. Shipp, K. Matyjaszewski
Macromolecules 2000, 33, 1553-1559.


Controlled/’Living’ Radical Polymerization Applied to Water-Borne Systems [doi link]
K. Matyjaszewski, J. Qiu, D. A. Shipp, S. G. Gaynor
Macromol. Symp. 2000, 155, 15-29.


An Investigation into the CuX/2,2’-Bipyridine (X = Br or Cl) Mediated Atom Transfer Radical Polymerization of Acrylonitrile [doi link]
K. Matyjaszewski, S. M. Jo, H.-j. Paik, D. A. Shipp
Macromolecules 1999, 32, 6431-6438.


Measurement of Primary Radical Concentrations Generated by Pulsed Laser Photolysis Using Fluorescence Detection [doi link]
G. Moad, D. A. Shipp, T. A. Smith, D. H. Solomon
J. Phys. Chem. A 1999, 103, 6580-6586.


Kinetic Analysis of Controlled Radical Polymerizations by Simulations. 1. The Importance of Diffusion Controlled Reactions [doi link]
D. A. Shipp, K. Matyjaszewski
Macromolecules 1999, 32, 2948-2955.


Synthesis of Acrylate and Methacrylate Block Copolymers Using Atom Transfer Radical Polymerization
D. A. Shipp, J.-L. Wang, K. Matyjaszewski [doi link]
Macromolecules 1998, 31, 8005-8008.


Utilizing Halide Exchange to Improve Control of Atom Transfer Radical Polymerization [doi link]
K. Matyjaszewski, D. A. Shipp, J.-L. Wang, T. Grimaud, T. E. Patten
Macromolecules 1998, 31, 6836-6840.


Controlled/’Living’ Atom Transfer Radical Polymerization of Methyl Methacrylate Using Various Initiation Systems [doi link]
K. Matyjaszewski, J.-L. Wang, T. Grimaud, D. A. Shipp
Macromolecules 1998, 31, 1527-1534.


Direct Measurement of Primary Radical Concentrations in Pulsed Laser Photolysis [doi link]
G. Moad, D. A. Shipp, T. A. Smith, D. H. Solomon
Macromolecules 1997, 30, 7627-7630.


Functionality in Phenol-Formaldehyde Step-Growth Polymerization [doi link]
D. A. Shipp, D. H. Solomon
Polymer 1997, 38, 4229-4232.


Determination of Molecular Weight Distributions of Novolac Resins by Gel Permeation Chromatography [link]
T. R. Dargaville, F. N. Guerzoni, M. G. Looney, D. A. Shipp, D. H. Solomon, X. Zhang
J. Polym. Sci., A: Polym. Chem. 1997, 35, 1399-1407.


Evaluation of Propagation Rate Constants for the Free Radical Polymerization of Methacrylonitrile by Pulsed Laser Photolysis [doi link]
D. A. Shipp, T. A. Smith, D. H. Solomon, G. Moad
Macromol. Rapid Commun. 1995, 16, 837-844.


Excimer Kinetics in Di(naphthyl)propane [doi link]
T. A. Smith, D. A. Shipp, G. D. Scholes, K. P Ghiggino
Photochem. Photobiol. A: Chem. 1994, 80, 177-185.

Peer-Reviewed Book Chapters

RAFT Polymerization of Vinyl Acetate, Styrene and Acrylates Using N,N-Dithiocarbamates

V. Malepu, C. D. Petruczok, T. T. Tran, T. Zhang, M. Thopasridharan, D. A. Shipp

ACS Symposium Series 2009, 1024, 37-47. [doi link]

(in “Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP and OMRP”, K. Matyjaszewski - editor, American Chemical Society 2009).


Grafting from Clay Surfaces Using Atom Transfer Radical Polymerization

D. A. Shipp

In Polymer Nanocomposites: Advances in Filler Surface Modification Techniques; V. Mittal, ed.; Nova Science Publishers 2009;Chapter 5.


Polymer-Layered Silicate Nanocomposites

D. A. Shipp

In Comprehensive Nanoscience and Technology; David Andrews, Greg Scholes and Gary Wiederrecht, eds.; Elsevier 2010.  [doi link]


Degradable Polymer Particles in Biomedical Applications

B. G. Rutherglen, D. A. Shipp

In Fine Particles in Medicine and Pharmacy, Egon Matijevic, ed.; Spring 2011; Chapter 6.


Poly(glycidyl methacrylate-block-styrene) for Photolithographically Patternable Resist Materials [doi link]

Lou, D. A. Shipp

In “Progress in Controlled/Living Radical Polymerization: Materials and Applications”, K. Matyjaszewski, B. S. Sumerlin, N. V. Tsarevsky – editors, American Chemical Society 2012.

ACS Symposium Series 2012, 1101, 115-125. 


Thiol-X Chemistries for the Production of Degradable Polymers 

K. L. Poetz, O. Z Durham, D. A. Shipp

In “Thiol-X Chemistries in Polymer and Materials Science”, A. B. Lowe and C. N. Bowman (Eds.), 2013, Chapter 3, pp. 59-75. Royal Society of Chemistry (London).

Patents Granted

“Coating Solutions Comprising Segmented Reactive Block Copolymers”

Inventors: J. G. Linhardt, D. A. Shipp, J. F. Kunzler

Assignee: Bausch and Lomb, Inc.

Patent Information: granted May 17, 2011; US Patent # 7,942,929

Application: US-12/334,618, application filed December 15, 2008.


“Biomedical Devices”

Inventors: J. G. Linhardt, I. M. Nunez, J. A. McGee, J. Hunt, M. Alton, D. Pavlovic, D. A. Shipp

Assignee: Bausch and Lomb, Inc.

Patent Information: granted October 25, 2011; US Patent # 8,043,369

Application: US-12/456,419, application filed June 16, 2009.


“Biomedical Devices”

Inventors: J. G. Linhardt, J. F. Kunzler, D. A. Shipp

Assignee: Bausch and Lomb, Inc.

Patent Information: granted December 27, 2011; US Patent # 8,083,348

Application: US-12/456,420, application filed June 16, 2009.


“Coating Solutions Comprising Segmented Interactive Block Copolymers”

Inventors: J. G. Linhardt, D. A. Shipp, J. F. Kunzler, D. P. Vanderbilt

Assignee: Bausch and Lomb, Inc.

Patent Information: granted January 24, 2012; US Patent # 8,100,528

Application: US-12/334,619, application filed December 15, 2008.


“Elastomeric and Degradable Polyanhydride by Step-Growth Thiol-Ene Photopolymerization”

Inventor: D. A. Shipp

Assignee: Clarkson University

Patent Information: granted May 7, 2019; US Patent # 10,280,263

Application: US-12/731,282, application filed March 27, 2009.