2024

508.  

Metal–Metal Redox Exchange to Produce Heterometallic Manganese–Cobalt Oxo Cubanes via a “Dangler” Intermediate. T. A. Wheeler and T. D. Tilley, J. Am. Chem. Soc. 2024, XX, XXXX-XXXX DOI: 10.1021/jacs.4c05367

507.  

Diborane Reductions of CO2 and CS2 Mediated by Dicopper μ-Boryl Complexes of a Robust Bis(phosphino)-1,8-naphthyridine Ligand. M. S. See, P. Rios, and T. D. Tilley, Organometallics 2024, 43, 1180-1189 DOI: 10.1021/acs.organomet.4c00122

506.  

M–Ge–Si thermolytic molecular precursors and models for germanium-doped transition metal sites on silica. J. P. Dombrowski, V. Kalendra, M. S. Ziegler, A. T. Bell, and T. D. Tilley, Dalton Trans. 2024, 53, 7340-7349 DOI: 10.1039/D4DT00644E

505.  

A Ruthenophosphanorcaradiene as a Synthon for an Ambiphilic Metallophosphinidene. T. G. Saint-Denis, T. A. Wheeler, Q. Chen, G. Balazs, N. S. Settineri, M. Scheer, and T. D. Tilley, J. Am. Chem. Soc. 2024, 146, 7, 4369–4374 DOI: 10.1021/jacs.3c14779

2023

504.  

A [CoSiH2] Silylene Synthon Provides Modular Access to Homo- and Hetero-Bimetallic [Co=Si=M] (M = Co, Fe) Silicide Complexes. R. C. Handford and T. D. Tilley, J. Am. Chem. Soc. 2023, 145, 45, 24690–24697 DOI: 10.1021/jacs.3c07998 

503. 

Supported Electrophilic Organoruthenium Catalyst for the Hydrosilylation of Olefins. U. Kanbur, R. J. Witzke, J. Xu, M. A. Ferrandon, T. A. Goetjen, A. J. Kropf, F. A. Perras, C. Liu, T. D. Tilley, D. M. Kaphan, and M. Delferro, ACS Catal. 2023, 13, 20, 13383–13394 DOI: 10.1021/acscatal.3c03399.  

502.  

Tetracopper σ-Bound μ-Acetylide and -Diyne Units Stabilized by a Naphthyridine-based Dinucleating Ligand. P. Rios, M. S. See, R. C. Handford, J. K. Cooper, and T. D. Tilley, Angew. Chem. Int. Ed. 2023, 62, e202310307. DOI: 10.1002/anie.202310307 

501.

Dimetalloylene (M-E-M) Complexes of Heavier Main Group Elements Ge, Sn, Pb, Bi via Cleavage of E-X Bonds (X=N(SiMe3)2, OtBu) with an Iridium Hydride. T. G. Saint-Denis, B. Zhang, N. Settineri, R. C. Handford, M. B. Hall and T. D. Tilley, Chem. Eur. J. 2023, e202301863. DOI: 10.1002/chem.202301863

500. 

Direct Transformation of SiH4 to a Molecular L(H)2Co=Si=Co(H)2L Silicide Complex. R. Handford, T. Nguyen, S. Teat, R. Britt and T. D. Tilley, J. Am. Chem. Soc. 2023, 145, 3031–3039. DOI: 10.1021/jacs.2c11569

2022

499.

Expanded [23]-Helicenes with Exceptional Chiroptical Properties via an Iterative Ring-Fusion Strategy. G. R. Kiel, H. M. Bergman, A. E. Samkian, N. J. Schuster, R. C. Handford, A. Rothenberger, R. Gomez-Bombarelli, C. Nuckolls and T. D. Tilley, J. Am. Chem. Soc. 2022, 144, 23421-23427. DOI: 10.1021/jacs.2c09555

Synfacts Highlight: D. Zhao, P. Wang, Synfacts. 2023; 19(05): 0451, DOI: 10.1055/s-0042-1751875

498.

Selective Carbon-Fluorine Bond Functionalization by Lanthanide Photocatalysts: Importance of Metal – Ligand Cooperativity. A. Kynman, A. Desnoyer, Y. Yang, L. Severy, A. Di Giuseppe, T. D. Tilley, L. Maron, P. Arnold, Chem. Sci. 2022, 13, 14090-14100. DOI: 10.1039/D2SC04192H

497.

Late 3d-Transition Metal Complexes Bearing a bis-Phosphine Borane Ligand, PhB(CH2PtBu2)2. R. C. Handford, L. Zhong and T. D. Tilley, Organometallics 2022, 41, 2631-2637. DOI: 10.1021/acs.organomet.2c00378

496.

Synthesis and Reactivity of a Rare Ni(I) Methyl Complex. R. J. Witzke and T. D. Tilley, Organometallics 2022, 41, 1565-1571. DOI: 10.1021/acs.organomet.2c00188

495.

Synthesis, Characterization, and Reactivity of Low-Coordinate Titanium(III) Amido Complexes. A. J. Cuellar De Lucio, I. C. Cai, R. J. Witzke, A. Desnoyer, T. D. Tilley, Organometallics 2022, 41, 1434-1444. DOI: 10.1021/acs.organomet.2c00162

494.

Copper(III) Metallacyclopentadienes via Zirconocene-Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene. H. M. Bergman, D. D. Beattie, R. C. Handford, E. Rossome, B. A. Suslick, M. Head-Gordon, T. R. Cundari, Y. Liu and T. D. Tilley, J. Am. Chem. Soc. 2022, 144, 9853-9858. DOI: 10.1021/jacs.2c02581

Synfacts Highlight: T. M. Swager, T. Q. Chen, Synfacts. 2022; 18(08): 0864, DOI: 10.1055/s-0041-1738332

493.

Robust dicopper(I) µ-boryl complexes supported by a dinucleating naphthyridine-based ligand. P. Ríos, M. S. See, R. C. Handford, S. J. Teat and T. D. Tilley, Chem. Sci. 2022, 13, 6619 – 6625. DOI: 10.1039/D2SC00848C

492.

Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes. M. Piesch, A. Nicolay, M. Haimerl, M. Seidl, G. Balázs, T. D. Tilley and M. Scheer, Chem. Eur. J. 2022, Chem. Eur. J. 2022, e202201144. DOI: 10.1002/chem.20220114

491.

A sequential cyclization/π-extension strategy for modular construction of nanographenes enabled by stannole cycloadditions. H. M. Bergman, D. D. Beattie, G. R. Kiel, R. Handford, Y. Liu, and T. D. Tilley. Chem. Sci. 2022, 13, 5568-5573. DOI: 10.1039/d2sc00397j

Synfacts Highlight: T. M. Swager, S.-X. L. Luo. Synfacts. 2022; 18(06): 0620, DOI: 10.1055/s-0041-1738332

490.

Mechanistic Aspects of Cobalt Oxo Cubane Clusters in Oxidation Chemistry. J. Amtawong, A. I. Nguyen and T. D. Tilley, J. Am. Chem. Soc. 2022, 144, 4, 1475–1492. DOI: 10.1021/jacs.1c11445

489.

Versatile Fe–Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C–H Bond Activation. R. C. Handford, M. A. Nesbit, P. W. Smith, R. D. Britt and T. D. Tilley, J. Am. Chem. Soc. 2022, 144, 358-367. DOI: 0.1021/jacs.1c1o144

2021

488.

Switchable Product Selectivity in Diazoalkane Coupling Catalyzed by a Two-coordinate Cobalt Complex. Y. Dong, M. I. Lipschutz, R. J. Witzke, J. A. Panetier and T. D. Tilley, ACS Catal 2021, 11, 11160-11170. DOI: 10.1021/acscatal.1c02926

487.

C–H Activation by RuCo3O4 Oxo Cubanes: Effects of Oxyl Radical Character and Metal–Metal Cooperativity. J. Amtawong, B. B. Skjelstad, R. C. Handford, B. A. Suslick, D. Balcells and T. D. Tilley, J. Am. Chem. Soc. 2021, 143, 12108-12119. DOI: 10.1021/jacs.1c04069

486.

Unsymmetrical Naphthyridine-Based Dicopper(I) Complexes: Synthesis, Stability, and Carbon–Hydrogen Bond Activations. A. Nicolay, J. Heron, C. Shin, S. Kuramarohit, M. S. Ziegler, D. Balcells and T. D. Tilley, Organometallics 2021, 40, 1866-1873. DOI: 10.1021/acs.organomet.1c00188

485.

Scalable, Divergent Synthesis of a High Aspect Ratio Carbon Nanobelt. H. M. Bergman, G. R. Kiel, R. C. Handford, Y. Liu and T. D. Tilley, J. Am. Chem. Soc. 2021, 143, 8619–8624. DOI: 10.1021/jacs.1c04037

JACS Spotlight: Yardley, R. J. Am. Chem. Soc. 2021, 143, 8949−8950., DOI: 10.1021/jacs.1c06113

Nature Reviews Materials Highlight: Vartanian, A. Nat. Rev. Mat. 2021, 6, 555. DOI: 10.1038/s41578-021-00342-8

484.

Two-Coordinate Iron(I) Complexes on the Edge of Stability: Influence of Dispersion and Steric Effects. R. Witzke, D. Hait, M. Head-Gordon and T. D. Tilley, Organometallics 2021, 40, 1758–1764. DOI: 10.1021/acs.organomet.1c00218

483.

A Dicopper Nitrenoid by Oxidation of a Cu(I)Cu(I) Core: Synthesis, Electronic Structure and Reactivity. A. N. Desnoyer, A. Nicolay, M. S. Ziegler, K. V. Lakshmi, T. R. Cundari and T. D. Tilley, J. Am. Chem. Soc. 2021, 143, 7135–7143. DOI: 10.1021/jacs.1c02235

482.

Olefin Hydroarylation Catalyzed by a Single-Component Cobalt(-I) Complex. B. A. Suslick and T. D. Tilley, Org. Lett. 2021, 23, 1495–1499. DOI: 10.1021/acs.orglett.1c00258

2020

481.

Elucidation of Diverse Solid-State Packing in a Family of Electron-Deficient Expanded Helicenes via Microcrystal Electron Diffraction (MicroED). A. E. Samkian, G. R. Kiel, C. G. Jones, H. M. Bergman, J. Oktawiec, H. M. Nelson and T. D. Tilley, Angew. Chem. Int. Ed. 2020, 60, 2493-2499. (VIP article.) DOI: 10.1002/anie.202012213

480.

Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially Hydrolyzed Framework Sites in Zeolites and Zeotypes. . P. Dombrowski, M. S. Ziegler, N. M. Phadke, E. Mansoor, D. S. Levine, R. J. Witzke, M. Head-Gordon, A. T. Bell and T. D. Tilley, Chem. Eur. J. 2021, 27, 307-315. (designated a "Hot Paper") DOI: 10.1002/chem.202002926.

479.

Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission. H. M. Bergman, G. R. Kiel, R. J. Witzke, D. P. Nenon, A. M. Schwartzberg, Y. Liu and T. D. Tilley, J. Am. Chem. Soc. 2020, 142, 19850-19855. DOI: 10.1021/jacs.0c09941

Synfacts Highlight: T. M. Swager, M. J. Bezdek. Synfacts. 2021; 17(02): 0153, DOI: 10.1055/s-0040-1719333

478.

Concerted Proton-Electron Transfer Reactivity at a Multimetallic Co4O4 Cubane Cluster. J. Amtawong, B. B. Skjelstad, D. Balcells and T. D. Tilley, Inorg. Chem. 2020, 59, 115553-15560. DOI: 10.1021/acs.inorgchem.0c02625

477.

Gauging aromatic conjugation and charge delocalization in the aryl silanes, PhnSiH4-n (n = 0-4), with silicon K-edge XAS and TDDFT. N. A. Phillips, P. W. Smith, T. D. Tilley and S. G. Minasian, Dalton Trans. 2020, 49, 13176-13184. DOI: 10.1039/d0dt03153d

476.

Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands. A. N. Desnoyer, A. Nicolay, P. Rios, M. S. Ziegler and T. D. Tilley, Acc. Chem. Res. 2020, 53, 1944-1959. DOI: 10.1021/acs.accounts.0c00382

475.

Bimetallic Mechanism for Alkyne Cyclotrimerization with a Two-Coordinate Fe Precatalyst. R. J. Witzke, D. Hait, K. Chakarawet, M. Head-Gordon and T. D. Tilley, ACS Catal. 2020, 10, 7800-7807. DOI: 10.1021/acscatal.0c01828

474.

Efficient and Selective Alkene Hydrosilation Promoted by Weak, Double Si–H Activation at an Iron Center. P. W. Smith, Y. Dong, and T. D. Tilley, Chem. Sci. 2020, 11, 7070-7075. DOI: 10.1039/D0SC01749C

473.

Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons. G. R. Kiel, K. L. Bay, A. E. Samkian, N. J. Schuster, J. B. Lin, R. C. Handford, C. Nuckolls, K. N. Houk and T. D. Tilley, J. Am. Chem. Soc. 2020, 142, 11084-11091. DOI: 10.1021/jacs.0c03177

472.

Mechanistic Interrogations of Hydroarylations Catalyzed by Highly Reduced, Single Component Cobalt Complexes. B. A. Suslick and T. D. Tilley, J. Am. Chem. Soc. 2020, 142, 11203-11218. DOI: 10.1021/jacs.0c04072

471.

A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes. A. N. Desnoyer, A. Nicolay, M. S. Ziegler and T. D. Tilley, Angew. Chem. Int. Ed. 2020, 59, 12769-12773. DOI: 10.1002/anie.202004346

470.

Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. R. C. Handford, T. A. Wheeler and T. D. Tilley, Chem. Eur. J. 2020, 26, 6126-6129. DOI: 10.1002/chem.202000969

469.

Efficient Alkene Hydrosilation with Bis(8-quinolyl)phosphine (NPN) Nickel Catalysts. The Dominant Role of Silyl- over Hydrido-Nickel Catalytic Intermediates. J. Yang, V. Postil, M. I. Lipschutz, M. Fasulo, C. Raynaud, E. Clot, O. Eisenstein and T. D. Tilley, Chem. Sci. 2020, 11, 5043-5051. DOI: 10.1039/D0SC00997K

468.

Low-Valent Iron and Cobalt Complexes Supported by a Rigid Xanthene-Based Disilylamido Ligand. A. Nicolay, M. S. Ziegler, L. Rochlitz and T. D. Tilley, Polyhedron 2020, DOI: 10.1016/j.poly.2020.114420 (Issue dedicated to John Bercaw's 75 th birthday)

467.

Site-selective [2+2+n] Cycloadditions for Rapid, Scalable Access to Alkynylated Polycyclic Aromatic Hydrocarbons. G.R. Kiel, H. M. Bergman and T. D. Tilley, Chem. Sci. 2020, DOI: 10.1039/C9SC06102A

Synfacts Highlight: T. M. Swager, A. Concellón. Synfacts 2020; 16(05): 0524, DOI: 10.1055/s-0040-1707483.

466.

Isomerism and Dynamic Behavior of Bridging Phosphaalkynes Bound to a Dicopper Complex. A. Nicolay, M. S. Ziegler, D. W. Small, R. Grünbauer, M. Scheer and T. D. Tilley, Chem. Sci. 2020, 11, 1607-1616. DOI: 10.1039/C9SC05835D

2019

465.

Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV-Oxo with Significant Oxyl Radical Character. J. Amtawong, D. Balcells, J. Wilcoxen, R. C. Handford, N. Biggins, A. I. Nguyen, R. D. Britt and T. D. Tilley, J. Am. Chem. Soc. 141, 19859-19869. DOI: 10.1021/jacs.9b10320

JACS spotlight: https://pubs.acs.org/doi/10.1021/jacs.0c00935

464.

Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(II) complexes. W. Ma, J.-X. Zhang, Z. Lin, T. D. Tilley and Q. Ye, Dalton Trans. 2019, 48, 14962-14965. DOI: 10.1039/c9dt03342d

463.

Heavy Tetrel Complexes of Ru Featuring Ru=E(R)X and Ru–E–R (E = Sn, Pb) Linkages. P. W. Smith, R. C. Handford and T. D. Tilley, Organometallics 2019, 38, 4060-4065. DOI: 10.1021/acs.organomet.9b00550

462.

Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp2(MeCN)Ti(η1Ge9{Si(TMS)3}3)] and K3[Cp2Ti(η1Ge9{Si(TMS)3}2)2]. F. S. Geitner, W. Klein, O. Storcheva, T. D. Tilley, and F. Fässler Inorganic Chemistry 2019, 58, 13293-13298. DOI: 10.1021/jacs.9b04265

461.

Activations of all Bonds to Silicon (Si–H, Si–C) in a Silane with Extrusion of [CoSiCo] Silicide Cores. R. C. Handford, P. W. Smith and T. D. Tilley, J. Am. Chem. Soc. 2019, 141, 8769-8772. DOI: 10.1021/jacs.9b04265

460.

Stabilization of reactive Co4O4 cubane oxygen-evolution catalysts within porous frameworks. A. I. Nguyen, K. M. Van Allsburg, M. W. Terban, M. Bajdich, J. Oktawiec, M. S. Ziegler, J. P. Dombrowski, K. V. Lakshmi, W. S. Drisdell, J. Yano, S. J. L. Billinge and T. D. Tilley, Proc. Nat. Acad. Sci. 2019, 116, 11630-11639. DOI: 10.1073/pnas.1815013116

459.

A two-coordinate Ni(I) silyl complex: CO 2 insertions and oxidatively-induced silyl migrations. R. J. Witzke and T. D. Tilley, Chemical Communications 2019, 55,6559-6562. DOI: 10.1039/C9CC03128F

458.

Element-Hydrogen Bond Activations at Cationic Platinum Centers to Produce Silylene, Germylene, Stannylene, and Stibido Complexes. R. Waterman, R. C. Handford and T. D. Tilley, Organometallics 2019, 38, 2053-2061. DOI:10.1021/acs.organomet.9b00097

457.

Divalent Vanadium Complexes Supported by Bulky Silyl(aryl)amido Ligands: Linkage Isomerism and Reactivity of a Two-Coordinate Species. I. C. Cai, M. S. Ziegler, P. C. Bunting, A. Nicolay, D. S. Levine, V. Kalendra, P. W. Smith, K. V. Lakshmi, and T. D. Tilley, Organometallics 2019, 38, 1648-1663. DOI: 10.1021/acs.organomet.9b00134

456.

An Anionic Ruthenium Dihydride [Cp*(iPr2MeP)RuH2]– and its Conversion to Heterobimetallic Ru(μ-H)2M (M = Ir, Cu) Complexes. P. W. Smith, S. R. Ellis, R. C. Handford and T. D. Tilley, Organometallics 2019, 38, 336-342. DOI: 10.1021/acs.organomet.8b00738

2018

455.

Catalytic Olefin Hydrosilations Mediated by Ruthenium η3-H2Si σ-Complexes of Primary Silanes. M. C. Lipke. M.N. Poradowski, C. Raynaud, O. Eisenstein and T. D. Tilley, ACS Catal. 2018, 8, 11513-11523. DOI: 10.1021/acscatal.8b02161

454.

Silylene Complexes of Late 3d Transition Metals Supported by tris-Phosphinoborate Ligands. R. Handford, P. W. Smith and T. D. Tilley, Organometallics 2018, 37, 4077-4085. DOI: 10.1021/acs.organomet.8b00635

453.

An enigmatic trailblazer on the frontier of discovery: Richard A. Andersen. J. Arnold and T. D. Tilley, Chem. Comm. 2018, 54, 12131-12132. DOI: 10.1039/c8cc90464b

452.

Dicopper Alkyl Complexes: Synthesis, Structure, and Unexpected Persistence. M. S. Ziegler, N. A. Torquato, D. S. Levine, A. Nicolay, H. Celik and T. D. Tilley, Organometallics 2018, 37, 2807-2823. DOI: 10.1021/acs.organomet.8b00443

451.

Synthesis, Structures, and Reactivity Studies of Cyclometalated N-Heterocyclic Carbene Complexes of Ruthenium.. H.-J. Liu, M. S. Ziegler and T. D. Tilley, Dalton Trans. 2018, 47, 12138-12146. (Special issue dedicated to Richard Andersen's 75th birthday). DOI: 10.1039/C8DT01925H

450.

Influence of a “Dangling” Co(II) Ion Bound to a [MnCo4O4] Oxo Cubane. A. Nguyen, L. Darago, D. Balcells and T. D. Tilley, J. Am. Chem. Soc. 2018, 140, 9030-9033. DOI: 10.1021/jacs.8b04065

449.

Selective Synthesis of a Series of Isostructural MIICuI Heterobimetallic Complexes Spontaneously Assembled by an Unsymmetrical Naphthyridine-Based Ligand. A. Nicolay and T. D. Tilley, Chem. Eur. J. 2018, 41, 10329-10333. DOI: 10.1002/chem.201802623

448.

Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing. P.W. Smith and T. D. Tilley, J. Am. Chem. Soc. 2018, 140, 3880-3883. DOI: 10.1021/jacs.8b01185

447.

Artificial Metalloproteins Containing Co4O4 Active Sites. L. Olshansky, R. Huerta-Lavorie, A. I. Nguyen, J. Vallapurackal, A. Furst, T. D. Tilley and A. S. Borovik, J. Am. Chem. Soc. 2018, 140, xxxx. DOI: 10.1021/jacs.7b13052

446.

Titanocene-Mediated Dinitrile Coupling: A Divergent Route to Nitrogen-Containing Polycyclic Aromatic Hydrocarbons. G. R. Kiel, A. E. Samkian, A. Nicolay, R. J. Witzke and T. D. Tilley, J. Am. Chem. Soc. 2018, 140, xxxx. DOI: 10.1021/jacs.7b13823

445.

Electrocatalytic Water Oxidation by Single Site and Small Nuclearity Clusters of Cobalt. J. R. Swierk and T. D. Tilley, J. Electrochem. Soc., 2018, 165, H3028-H3033. DOI: 10.1149/2.0041804jes

2017

444.

2,6-Dimesitylaniline and 2,6-Di(2,4,6-Triisopropylphenyl)aniline. J. Gavenonis, N. Schüwer and T. D. Tilley, Inorg. Synth. 2017, 37, 98-105. ISBN: 978-1-119-47782-2

443.

Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior. G. R. Kiel, S. C. Patel, P. W. Smith, D. S. Levine and T. D. Tilley, J. Am. Chem. Soc. 2017, 139, 18456-18459. DOI: 10.1021/jacs.7b10902

442.

Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium. D. S. Levine, T. D. Tilley and R. A. Andersen, Chem. Comm. 2017, 53, 11881-11884. DOI: 10.1039/C7CC06417A

441.

Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers. B. A. Suslick and T. D. Tilley, Chapter 4 in Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds, T. B. Gunnoe, L. Ackerman and L. G. Habgood, Eds., Wiley-VCH, 2017. DOI: 10.1002/9783527697649.ch4 ISBN: 978-3-527-34013-2

440.

Olefin Hydroarylation Catalyzed by (Pyridyl-Indolate)Pt(II) Complexes: Catalytic Efficiencies and Mechanistic Aspects. B. A. Suslick, A. L. Liberman-Martin, T. C. Wambach and T. D. Tilley, ACS Catal. 2017, 7, 4313-4322. DOI: 10.1021/acscatal.7b01560

439.

Current advances in the chemistry of silicon: not exactly a carbon copy. C. Marschner and T. D. Tilley, Dalton Trans. 2017, 46, 8699-8700. DOI: 10.1039/c7dt90112g

438.

Synthetic control and empirical prediction of redox potentials for Co4O4 cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation. A. I. Nguyen, J. Wang, D. S. Levine, M. S. Ziegler and T. D. Tilley, Chem. Sci. 2017, 8, 4274-4284. DOI: 10.1039/c7sc00627f

437.

Titanium Imido Complexes via Displacement of –SiMe3 and C–H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC). Q. Ye, M. S. Ziegler, K. V. Lakshmi and T. D. Tilley, Eur. J. Inorg. Chem. 2017, 2484-2487. DOI: 10.1002/ejic.201700295

436.

Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts. A. I. Nguyen, D. L. M. Suess, L. E. Darago, P. H. Oyala, D. S. Levine, M. S. Ziegler, R. D. Britt and T. D. Tilley, J. Am. Chem. Soc. 2017, 139, 5579–5587. DOI: 10.1021/jacs.7b01792

435.

Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition. M. S. Ziegler, K. V. Lakshmi and T. D. Tilley, J. Am. Chem. Soc. 2017, 139, 5378–5386. DOI: 10.1021/jacs.6b13261

434.

Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons (ZrPAHs). G. R. Kiel, M. S. Ziegler and T. D. Tilley, Angew. Chem. Int. Ed. 2017, 56, 4839-4844. DOI: 10.1002/anie.201700818

433.

Tantalum-Polyhedral Oligosilsesquioxane (POSS) Complexes as Structural Models and Functional Catalysts for Epoxidation. P. Guillo, M. I. Lipschutz, M. E. Fasulo and T. D. Tilley, ACS Catal. 2017, 7, 2303-2312. DOI: 10.1021/acscatal.7b00020

432.

Identification of Second Shell Coordination in Transition Metal Species using Theoretical XANES: Example of Ti-O-(C, Si, Ge) Complexes. C. S. Spanjers, P. Guillo, T. D. Tilley, M. J. Janik and R. M. Rioux, J. Phys. Chem. A 2017, 121, 162-167. DOI: 10.1021/acs.jpca.6b12197

431.

Electrophilic Activation of Silicon-Hydrogen bonds in Catalytic Hydrosilations. (review article) M. C. Lipke, A. Liberman-Martin and T. D. Tilley, Angew. Chem. Int. Ed. 2017, 56, 2260-2294. DOI: 10.1002/anie.201605198

430.

Evidence for the Existence of Group 3 Terminal Methylidene Complexes. D. S. Levine, T. D. Tilley and R. A. Andersen, Organometallics 2017, 36, 80-88. DOI: 10.1021/acs.organomet.6b00394

2016

429.

Tricoordinate Organochromium(III) Complexes Supported by a Bulky Silylamido Ligand Produce Ultra-High-Molecular Weight Polyethylene in the Absence of Activators. H.-J. Liu, I. C. Cai, A. Fedorov, M. S. Ziegler, C. Copéret and T. D. Tilley, Helv. Chim. Acta . 2016, 99, 859-867. DOI: 10.1002/hlca.201600199

428.

Covalent Functionalization of GaP(110) Surfaces via a Staudinger-type Reaction with Perfluorophenyl Azide. M. M. Ugeda, A. J. Bradley, L. Rodrigo, M. Yu, W. Liu, P. Doak, A. Riss, J. B. Neaton, T. D. Tilley, R. Pérez and M. F. Crommie, J. Phys. Chem. C 2016, 120, 26448-26452. DOI: 10.1021/acs.jpcc.6b10691

427.

Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide. M. C. Lipke, A. Liberman-Martin and T. D. Tilley, J. Am. Chem. Soc. 2016, 138, 9704–9713. DOI: 10.1021/jacs.6b05736

426.

Ga[OSi(OtBu)3]3•THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. J. P. Dombrowski, G. R. Johnson, A. T. Bell and T. D. Tilley, Dalton Trans. 2016, 45, 11025–11034. DOI: 10.1039/C6DT01676F

425.

Lewis acid-base interactions between platinum(II) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. A. L. Liberman-Martin, D. S. Levine, M. S. Ziegler, R. G. Bergman and T. D. Tilley, Chem. Comm. 2016, 52, 7039-7042. DOI: 10.1039/c6cc02433e

424.

Functionalization of an Iridium–Diamidocarbene Complex by Ligand-Based Reactions with Titanocene and Zirconocene Sources. A. L. Liberman- Martin, M. S. Ziegler, A. G. DiPasquale, R. G. Bergman and T. D. Tilley, Polyhedron2016, 116, 111-115. (Special issue dedicated to Malcolm H. Green's 80th birthday). DOI: 10.1016/j.poly.2016.03.044

423.

Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and a Mixed-Valence µ-Aryl Dicopper(I,II) Complex. M. S. Ziegler, K. V. Lakshmi and T. D. Tilley, J. Am. Chem. Soc. 2016, 138, 6484–6491. DOI: 10.1021/jacs.6b00802

422.

Regioselective, Transition Metal-Free C–O Coupling Reactions involving Aryne Intermediates. Y. Dong, M. I. Lipschutz and T. D. Tilley, Org. Lett. 2016, 18, 1530–1533. DOI: 10.1021/acs.orglett.6b00183

421.

Biaryl Reductive Elimination is Dramatically Accelerated by a Remote Lewis Acid Chemical Switch: Evidence for an Unusual Bidentate Ligand Dissociation Mechanism. A. L. Liberman-Martin, D. S. Levine, W. Liu, R. G. Bergman and T. D. Tilley, Organometallics 35, 1064–1069. DOI: 10.1021/acs.organomet.5b01003

420.

Computational Characterization of Redox Non-Innocence in Cobalt-Bis(diaryldithiolene) Catalyzed Proton Reduction. J. A. Panetier, C. S. Letko, T. D. Tilley and M. Head-Gordon, J. Chem. Theory Comput. 2016, 12, 223–230. DOI: 10.1021/acs.jctc.5b00968

2015

419.

Mechanistic Investigation of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation. A. I. Nguyen, M. S. Ziegler, P. Oña-Burgos, M. Sturzbecher-Hohne, W. Kim, D. E. Bellone and T. D. Tilley, J. Am. Chem. Soc. 2015, 137, 12865-12872. DOI: 10.1021/jacs.5b08396

418.

An Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)hydroxide Catalysts. J. Swierk, S. Klaus, L. Trotochaud, A. Bell, T. D. Tilley, J. Phys. Chem. C 2015, 119, 19022-19029. DOI: 10.1021/acs.jpcc.5b05861

417.

Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes. H.-J. Liu, C. Landis, C. Raynaud, O. Eisenstein and T. D. Tilley, J. Am. Chem. Soc. 2015, 137, 9186-9194. DOI: 10.1021/jacs.5b05571

416.

C–H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes. D. S. Levine, T. D. Tilley and R. A. Andersen, Organometallics 2015, 34, 4647-4655. DOI: 10.1021/acs.organomet.5b00213

415.

Dinuclear First-Row Transition Metal Complexes with a Naphthyridine-Based Dinucleating Ligand. T. C. Davenport and T. D. Tilley, Dalton Trans. 2015, 44, 12244-12255. DOI: 10.1039/c4dt02727b.

414.

Silane-Allyl coupling Reactions of Cp*(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido-Dinitrogen Complex Cp*(iPr2MeP)FeH(N2). P. W. Smith and T. D. Tilley, Organometallics 2015, 34, 2134-2138. DOI: 10.1021/acs.organomet.5b00184

413.

Synthesis, Characterization and Alkyne Trimerization Catalysis of a Heteroleptic Two-Coordinate FeI Complex. M. I. Lipschutz, T. Chantarojsiri, Y. Dong and T. D. Tilley, J. Am. Chem. Soc. 2015, 137, 6366-6372. DOI: 10.1021/jacs.5b02504

412.

The Ruthenostannylene Cp*(IXy)H2Ru–Sn–Trip Provides Access to Unusual Ru–Sn Bonded Stannaimine, Stannene and Ketenylstannylene Complexes. H.-J. Liu, M. S. Ziegler and T. D. Tilley, Angew. Chem. Int. Ed. 2015, 54, 6622-6626. DOI: 10.1002/anie.201502156

411.

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. A. L. Liberman-Martin, R. G. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2015, 137, 5328-5331. DOI: 10.1021/jacs.5b02807

410.

Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis. H. S. Ahn, J. Yano and T. D. Tilley, ACS Catal. 2015, 5, 2573-2576. DOI: 10.1021/cs502120f

409.

Oxygen-Atom Transfer Chemistry and Thermolytic Properties of a Di-tert-butylphosphate-Ligated Mn4O4 Cubane. K. M. Van Allsburg, E. Anzenberg, W. Drisdell, J. Yano and T. D. Tilley, Chem. Eur. J. 2015, 21, 4646-4654. DOI: 10.1002/chem.201406114

408.

Sterically Controlled Functionalization of Carbon Surfaces with –C6H4CH2X (X = OSO2Me or N3) Groups for Surface Attachment of Redox-Active Molecules. W. Liu and T. D. Tilley, Langmuir 2015, 31, 1189-1195. DOI: 10.1021/cla503796z.

2014

407.

Mono(η5-Pentamethylcyclopentadienyl) Complexes of Osmium. C. L. Gross, J. L. Brumaghim, J. M. Jefferis, P. W. Dickinson, G. S. Girolami, C. W. Gribble and T. D. Tilley, Inorganic Syntheses 2014, 36, 72-77. DOI: 10.1002/9781118744994.ch15

406.

The influence of Mike Lappert on the chemistry landscape. J. Arnold, P. J. Brothers, P. Mountford, W. E. Piers, C. M. Thomas and T. D. Tilley, Dalton Trans., 2014, 43, 16553-16556.

405.

A Useful Method for the Preparation of Low-coordinate Ni(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6-iPr2-C6H3)]2}. M. I. Lipschutz and T. D. Tilley, Organometallics, 2014, 33, 5566–5570.

404.

Hypercoordinate Ketone Adducts of Electrophilic η3-H2SiRR' Ligands on Ruthenium as Key Intermediates for Efficient and Robust Hydrosilation. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2014, 136, 16387-16398.

403.

1,2-Hydrogen Migration to a Saturated Ruthenium Complex, via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannyene Conversion. H.-J. Liu, J. Guihaumé, T. Davin, C. Raynaud, O. Eisenstein and T. Don Tilley, J. Am. Chem. Soc., 2014, 136, 13991–13994.

402.

Ring-Opening and Double-Metallation Reactions of the N-Heterocyclic Carbene Ligand in Cp*(IXy)Ru (IXy = 1,3-Bis(2,6-dimethylphenyl)imidazol-2-ylidene) Complexes. Access to an Anionic Fischer-Type Carbene Complex of Ruthenium. H.-J. Liu, M. S. Ziegler and T. Don Tilley, Polyhedron, 2014, 84, 203-208. (Special issue dedicated to John Bercaw's 70th birthday).

401.

A Bis(amido) Ligand Set That Supports Two-Coordinate Chromium in the +1, +2 and +3 Oxidation States. I. C. Cai, M. I. Lipschutz and T. D. Tilley, Chem. Comm., 2014, 50, 13062-13065.

400.

Cyclometalated N-Heterocyclic Carbene Complexes of Ruthenium for Access to Electron-Rich Silylene Complexes That Bind the Lewis Acids CuOTf and AgOTf. H.-J. Liu, C. Raynaud, O. Eisenstein and T. D. Tilley, J. Am. Chem. Soc., 2014, 136, 11473-11482.

399.

Mechanism of the Electrocatalytic Reduction of Protons with Diaryldithiolene Cobalt Complexes. C. S. Letko, J. A. Panetier, M. Head-Gordon and T. D. Tilley, J. Am. Chem. Soc., 2014, 136, 9364-9376.

398.

Carbon-carbon cross-coupling reactions catalyzed a two-coordinate nickel(II) bis(amido) complex via observable NiI, NiII and NiIII intermediates. M. I. Lipschutz and T. D. Tilley, Angew. Chem. Int. Ed., 2014, 53, 7290-7294.

397.

Efficient C–H bond activations via O2 cleavage by a dianionic Cobalt(II) complex. A. I. Nguyen, R. G. Hadt, E. I. Solomon and T. D. Tilley, Chem. Sci., 2014, 5, 2874-2878.

396.

Organometallics Roundtable 2013. J. A. Gladysz, R. B. Bedford, M. Fujita, F. P. Gabbai, K. I. Goldberg, P. L. Holland, J. L. Kiplinger, M. J. Krische, J. Louie, C. C. Lu, J. R. Norton, M. A. Petrukhina, T. Ren, S. S. Stahl, T. D. Tilley, C. E. Webster, M. C. White and G. T. Whiteker, Organometallics, 2014, 33, 1505-1527.

395.

A Molecular Structural Analog of Proposed Dinuclear Active Sites in Cobalt-Based Water Oxidation Catalysts. T. C. Davenport, H. S. Ahn, M. S. Ziegler and T. D. Tilley, Chem. Comm., 2014, 50, 6326-6329.

394.

Interconversion of η3-H2SiRR' σ-Complexes and 16 Electron Silylene Complexes via Reversible H–H and C–H Elimination. M. C. Lipke, F. Neumeyer and T. D. Tilley, J. Am. Chem. Soc., 2014, 136, 6092-6102.

393.

Molecular cobalt electrocatalyst for proton reduction at low overpotential. H. S. Ahn, T. C. Davenport and T. D. Tilley. Chem. Comm., 2014, 50, 3834-3847.

392.

Multi-Functional Silicon Surfaces: Reaction of Dichlorocarbene Generated from the Seyferth Reagent with Hydrogen-Terminated Silicon (111) Surfaces. W. Liu, I. D. Sharp and T. D. Tilley, Langmuir, 2014, 30, 172.

2013

391.

Adsorption and Stability of π-Bonded Ethylene on GaP(110). M. Moreno Ugeda, M. Yu, A. J. Bradley, P. Doak, W. Liu, G. F. Moore, I. D. Sharp, J. B. Neaton, T. D. Tilley and M. F. Crommie, J. Phys. Chem. C 2013, 117, 26091.

390.

Group 8 transition metal complexes of the new tripodal triphosphino ligands PhSi(CH2PR2)3 (R = Ph, iPr). F. Neumeyer, M. I. Lipschutz and T. D. Tilley, Eur. J. Inorg. Chem.2013, 6075.

389.

A Structurally Rigid Bis(amido) Ligand Framework in Low-Coordinate Ni(I), Ni(II) and Ni(III) Analogues Provides Access to a Ni(III) Methyl Complex via Oxidative Addition. M. I. Lipschutz, X. Yang and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 15298.

388.

Isolation of a Dicationic Platinum Complex with Two Accessible Coordination Sites. M. Bowring, R. G. Bergman and T. D. Tilley, Organometallics 2013, 32, 5266.

387.

Photocatalytic Water Oxidation by Very Small Cobalt Domains on a Silica Surface. H. S. Ahn, J. Yano and T. D. Tilley, Energy Environ. Sci. 2013, 6, 3080.

386.

Titanium-Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with Enhanced Activity. P. J. Cordeiro, P. Guillo, C. S. Spanjers, J. W. Chang, M. E. Fasulo, R. M. Rioux and T. D. Tilley, ACS Catal. 2013, 3, 2269.

385.

Platinum-Catalyzed C-C Activation Induced by C-H Activation. M. Bowring, R. G. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 13121.

384.

Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation. M. Fasulo, M. C. Lipke and T. D. Tilley, Chem. Sci. 2013, 4, 3882.

383.

Water Oxidation Catalysis via Immobilization of the Dimanganese Complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto Silica. E. M. W. Rumberger, H. S. Ahn, A. T. Bell and T. D. Tilley, Dalton Trans. 2013, 42, 12238.

382.

The Osmium-Silicon Triple Bond: Synthesis and Reactivity of an Osmium Silylyne Complex. P. G. Hayes, Z. Xu, C. Beddie, J. M. Keith, M. B. Hall and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 11780.

381.

Silane-Isocyanide Coupling Involving 1,1-Insertion of XylNC into the Si-H Bond of a σ-Silane Ligand. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 10298.

380.

A Remote Lewis Acid Trigger Dramatically Accelerates Biaryl Reductive Elimination from a Platinum Complex. A. Liberman-Martin, R. G. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 9612.

379.

Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 Di(phosphine) Complexes of Rhodium and Iridium. M. E. Fasulo, E. Calimano, J. M. Buchanan and T. D. Tilley, Organometallics 2013, 32, 1016.

378.

Synthesis and Characterization of Tantalum Silsesquioxane Complexes. P. Guillo, M. E. Fasulo, M. I. Lipschutz and T. D. Tilley, Dalton Trans. 2013, 42, 1991.

377.

Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific BlueTM) succinimidyl ester under acidic and basic conditions. A. M. Stockton, M. F. Mora, M. L. Cable, T. C. Davenport, T. D. Tilley and P. A. Willis, Dyes Pigments 2013, 96, 148.

376.

Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode. H. S. Ahn and T. D. Tilley, Adv. Func. Mater. 2013, 23, 227.

2012

375.

Stabilization of ArSiH4– and SiH62– Anions in Diruthenium Si—H σ-Complexes. M. C. Lipke and T. D. Tilley, Angew. Chem. Int. Ed. 2012, 51, 11115.

374.

Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward Polar and Non-polar Organic Substrates. M. Fasulo and T. D. Tilley, Organometallics 2012, 31, 5049.

373.

Synthesis and Reactivity of Cationic Ruthenium Germylene Complexes [Cp*(PiPr3)RuH2(=GeRR')]+. M. Fasulo and T. D. Tilley, Chem. Comm. 2012, 48, 7690.

372.

Synthesis and Reactivity of a Conveniently Prepared Two-Coordinate Bis(amido) Nickel(II) Complex. M. Lipschutz and T. D. Tilley, Chem. Comm. 2012, 48, 7146.

371.

Preparation and Physical Properties of Early-Late Heterobimetallic Compounds Featuring Ir–M Bonds (M = Ti, Zr, Hf). J. J. Curley, R. G. Bergman and T. D. Tilley, Dalton Trans. 2012, 42, 192.

370.

Epoxidation catalysts derived from introduction of titanium centers onto the surface of mesporporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica. L. Raboin, J. Yano and T. D. Tilley, J. Catal. 2012, 285, 168.

369.

Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. R. J. Wright, W. Zhang, X. Yang, M. Fasulo and T. D. Tilley, Dalton Trans. 2012, 41, 73.

2011

368.

Dinucleating Naphthyridine-Based Ligand for Assembly of Bridged Dicopper(I) Centers: Three-Center Two-Electron Bonding Involving an Acetonitrile Donor. T. C. Davenport and T. D. Tilley, Angew. Chem. Int. Ed. 2011, 50, 12205.

367.

Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous TiSBA15 and TS-1 Selective Oxidation Catalysts: Insights from Spectroscopic and Density Functional Theory Studies. C. W. Yoon, K. F. Hirsekorn, M. L. Neidig, X. Yang and T. D. Tilley, ACS Catal. 2011, 1, 1665.

366.

Cp*(PiPr3)RuOTf: A Reagent for Access to Ruthenium Silylene Complexes. M. E. Fasulo, P. B. Glaser and T. D. Tilley, Organometallics 2011, 30, 5524.

365.

Inverse Rectification in Donor-Acceptor Molecular Heterojunctions. S. K. Yee, J. Sun, P. Darancet, T. D. Tilley, A. Majumdar, J. B. Neaton and R. A. Segalman, ACS Nano 2011, 5, 9256.

364.

Comparison of Cobalt-based Nanoparticles as Electrocatalysts for Water Oxidation. N. H. Chou, P. N. Ross, A. T. Bell and T. D. Tilley, ChemSusChem 2011, 4, 1566.

363.

High Electrophilicity at Silicon in η3-Silane σ-Complexes: Lewis Base Adducts of a Silane Ligand, Featuring Octahedral Silicon and Three Ru-H-Si Interactions. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2011, 133, 16374.

362.

Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II). Y. S. Choi, E. G. Moschetta, J. T. Miller, M. Fasulo, M. J. McMurdo, R. M. Rioux and T. D. Tilley, ACS Catal. 2011, 1, 1166.

361.

Assembly of Macrocycles by Zirconocene-Mediated, Reversible Carbon-Carbon Bond Formation. V. Gessner, J. Tannaci, A. Miller and T. D. Tilley. Acc. Chem. Res. 2011, 44, 435.

360.

Terminal Hafnium Phosphinidene Complexes and Phosphinidene Ligand Exchange. R. Waterman and T. D. Tilley, Chem. Sciences 2011, 2, 1320.

359.

Enhancement of Epoxidation Efficiencies for Ta-SBA15 Catalysts. The Influence of Modification with –EMe3 (E = Si, Ge, Sn) Groups. P. J. Cordeiro and T. D. Tilley, Langmuir 2011, 27, 6295.

358.

Enhancement of the Catalytic Activity of Titanium-Based Terminal Olefin Epoxidation Catalysts via Surface Modification with Functionalized Protic Molecules. P. J. Cordeiro and T. D. Tilley, ACS Catal. 2011, 1, 455.

357.

Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine. S. Roggan, C. Limberg, C. Knispel and T. D. Tilley. Dalton Trans. 2011, 40, 4315.

356.

Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with a Platinum(II) Catalyst. M. Bowring, R. G. Bergman and T. D. Tilley, Organometallics 2011, 30, 1295.

355.

Diphenylanthracene Macrocycles from Reductive Zirconocene Coupling: On the Edge of Steric Overload. V. H. Gessner and T. D. Tilley, Org. Lett. 2011, 13, 1154.

354.

Interligand H…Si Interactions in Tungsten Silyl Trihydride Complexes. M. E. Fasulo and T. D. Tilley. J. Organomet. Chem. 2011, 696, 1325.

353.

Disulfide Passivation of the Ge(100)-2 × 1 Surface. J. S. Kachian, J. Tannaci, R. J. Wright, T. D. Tilley and S. F. Bent, Langmuir 2011, 27, 179.

2010

352.

Active and Efficient Hydrosilylation of Carbonyl Compounds with the Simple Iron-Based Catalyst Fe[N(SiMe3)2]2. J. Yang and T. D. Tilley, Angew. Chem. Int. Ed. 2010, 52, 10186.

351.

Unusual Ruthenium Hydride Complexes Supported by the [N(2-PPh2-4-Me-C6H3)2] Pincer Ligand M. E. Fasulo and T. D. Tilley, Inorg. Chim. Acta 2010, 364, 246. (special issue to commemorate the 70th birthday of Prof. Arnold L. Rheingold).

350.

Nickel Complexes with Bis(8-Quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster Containing Six-Coordinate Silicon. J. Yang, I. D. Rosal, M. Fasulo, P. Sangtrirutnugul, L. Maron and T. D. Tilley, Organometallics 2010, 29, 5544.

349.

(MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-Quinolyl): An Unusual δ-Agostic Iron Complex Containing an η1-SiH Interaction.  J. Yang, M. Fasulo and T. D. Tilley, New J. Chem. 2010, 34, 2528.

348.

Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted pincer ligand. E. Calimano and T. D. Tilley, Dalton Trans. 2010, 39, 9250.

347.

Synthesis and Electronic Properties of Extended, Fused-Ring Aromatic Systems Containing Multiple Pentalene Units. Z. Levi and T. D. Tilley, J. Am. Chem. Soc. 2010, 132, 11012.

346.

Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic Substrates. E. Calimano and T. D. Tilley, Organometallics 2010, 29, 1680.

345.

Synthesis and Characterization of Fluorinated Heterofluorene-Containing Donor-Acceptor Systems. K. Geramita, Y. Tao, R. A. Segalman and T. D. Tilley. J. Org. Chem. 2010, 75, 1871.

344.

Facile Interconversion of Cp2(Cl)Hf-SnH3 and Cp2(Cl)Hf(μ-H)SnH2: DFT Investigations of Hafnocene Stannyl Complexes as Masked Stannylenes. J. Guihaumé, C. Raynaud, O. Eisenstein, L. Perrin, L. Maron and T. D. Tilley. Angew. Chem. Int. Ed. 2010, 49, 1816.

343.

Nucleophilic Attack of Amides onto Coordinated Ethylene in Platinum Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand: Azaplatinacyclobutane and Vinylamine Complexes. J. L. McBee and T. D. Tilley. Organometallics 2010, 29, 184.

2009

342.

Spatial Resolution of a Type II Heterojunction in a Single Bipolar Molecule. C. G. Tao, J. B. Sun, X. W. Zhang, R. Yamachika, D. Wegner, Y. Bahri, G. Samsonidze, S. G. Louie, T. D. Tilley, R. A. Segalman and M. F. Crommie. Nano Lett. 2009, 9, 3963.

341.

N-Heterocyclic Carbene-Stabilized Gold Nanoparticles and their Assembly into 3D Superlattices. J. Vignolle and T. D. Tilley. Chem. Comm. 2009, 7230.

340.

The Nature of Transport Variations in Molecular Heterojunction Electronics. J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, A. Majumdar and R. A. Segalman. Nano Lett. 2009, 9, 3406.

339.

Synthesis, Structure and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes. P. G. Hayes, R. Waterman, P. B. Glaser and T. D. Tilley. Organometallics 2009, 28, 5082.

338.

Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a Bipyridine Ligand. J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 5072.

337.

High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand. J. L. McBee, J. Escalada and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 12703.

336.

Germylene and Silylene Complexes of Molybdenum via E-H (E = Ge, Si) Bond Activations. Steric Influences on Intramolecular MoH···E Interactions. A. Shinohara, J. L. McBee and T. D. Tilley. Inorg. Chem. 2009, 48, 8081.

335.

Size-Dependent Activity of Co3O4 Anodes for Alkaline Water Electrolysis. A. J. Esswein, M. J. McMurdo, P. N. Ross, A. T. Bell and T. D. Tilley. J. Phys. Chem. C 2009, 113, 15068.

334.

Diiron Proton Reduction Catalysts Possessing Electron-rich and Electron-poor Naphthalene-1,8-dithiolate Ligands. R. J. Wright, C. Lim and T. D. Tilley. Chem. Eur. J. 2009, 15, 8518.

333.

Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes. E. Calimano and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 11161.

332.

Five-Coordinate Dihydridosilyl Platinum(IV) Complexes Supported by a Chelating Monoanionic Nitrogen-Based Ligand. J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 3947.

331.

Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT Method. L. Perrin, L. Maron, O. Eisenstein and T. D. Tilley. Organometallics 2009, 28, 3767.

330.

Octa- and Nonamethylfluorenyl Complexes of Zr(IV): Reactive Hydride Derivatives and Reversible Hydrogen Migration between the Metal and the Fluorenyl Ligand. P. Bazinet and T. D. Tilley. Organometallics 2009, 28, 2285.

329.

Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron-Deficient Compounds. K. Huynh, J. Vignolle and T. D. Tilley. Angew. Chem. Intl. Ed. 2009, 48, 2835.

328.

Mesityl Alkyne Substituents for Control of Regiochemistry and Reversibility in Zirconocene Couplings: New Synthetic Strategies for Unsymmetrical Zirconacyclopentadienes and Conjugated Polymers. A. D. Miller, J. F. Tannaci, S. A. Johnson, H. Lee, J. L. McBee and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 4917.

327.

A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium. P. G. Hayes, C. W. Gribble, R. Waterman and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 4606.

326.

Identifying the Length Dependence of Orbital Alignment and Contact Coupling in Molecular Heterojunctions. J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R. A. Segalman and A. Majumdar. Nano Lett. 2009, 9, 1164.

325.

Zirconocene-Mediated Macrocyclizations of Diynes Containing Di-o-Methylphenylene Spacers. A. D. Miller, J. L. McBee and T. D. Tilley. J. Org. Chem. 2009, 74, 2880.

324.

Versatile Synthesis of Pentalene Derivatives via the Pd-Catalyzed Homocoupling of Haloenynes. Z. U. Levi and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 2796.

323.

Unsymmetrical Zirconacyclopentadienes from Isolated Zirconacyclopropenes with 1-Alkynylphosphine Ligands. A. D. Miller, S. A. Johnson, K. A. Tupper, J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 1252.

322.

2,7-Substituted Hexafluoroheterofluorenes as Potential Building Blocks for Electron Transporting Materials. K. Geramita, J. McBee and T. D. Tilley. J. Org. Chem. 2009, 74, 820.

321.

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. C. A. Bradley, M. J. McMurdo, B. D. Yuhas and T. D. Tilley. Chem. Mater., 2009, 21, 174.

320.

Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes. J. F. Tannaci, I. H. Kratter, E. A. Rider, J. McBee, A. D. Miller and T. D. Tilley. Chem. Commun. 2009, 233.

2008

319.

Mechanistic Studies of Hydroamination of Norbornene with Electrophilic Platinum Complexes: The Role of Proton Transfer. J. L. McBee, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 16562.

318.

Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoro-heterofluorenes: New materials with high electron affinities. K. Geramita, J. McBee, Y. Tao, R. A. Segalman and T. D. Tilley. Chem. Commun. 2008, 5107.

317.

Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and Pt(IV). D. A. Ruddy, J. Jarupatrakorn, R. M. Rioux, J. T. Miller, J. L. McBee, M. J. McMurdo, K. A. Tupper and T. D. Tilley. Chem. Mater. 2008, 20, 6517.

316.

Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure and Reactivity. A. Shinohara, J. McBee, R. Waterman and T. D. Tilley. Organometallics 2008, 27, 5717.

315.

9,10-Disubstituted Octafluoroanthracene Derivatives via Palladium-Catalyzed Cross-Coupling. J. F. Tannaci, M. Noji, J. McBee and T. D. Tilley. J. Org. Chem. 2008, 73, 7895.

314.

Kinetics and Mechanism of Olefin Epoxidation with Aqueous H2O2 and a Highly Selective Surface-Modified TaSBA15 Heterogeneous Catalyst. D. A. Ruddy and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 11088.

313.

Alkene Hydrosilation by a Cationic Hydrogen–Substituted Iridium Silylene Complex. E. Calimano and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 9226.

312.

The Influence of Surface Modification on the Epoxidation Selectivity and Mechanism of TiSBA15 and TaSBA15 Catalysts with Aqueous Hydrogen Peroxide. D. A. Ruddy, R. L. Brutchey and T. D. Tilley. Topics in Catalysis 2008, 48, 99.

311.

Mechanism of Reversible Alkyne Coupling at Zirconocene: Ancillary Ligand Effects. A. D. Miller, J. L. McBee and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 4992.

310.

DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the ansa Ligand on Propene and Isobutylene Hydromethylation. N. Barros, O. Eisenstein, L. Maron and T. D. Tilley. Organometallics 2008, 27, 2252.

309.

Alkyl and Hydrido Pt(IV) Complexes Supported by a Bis(8-quinolyl)methylsilyl Ligand. P. Sangtrirutnugul and T. D. Tilley. Organometallics 2008, 27, 2223.

308.

Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of Steric and Electronic Effects. P. Bazinet and T. D. Tilley. Organometallics 2008, 27, 1267.

307.

1,2-Phosphinoboranes as Amphoteric Ligands in Nickel-Methyl Complexes. A. Fischbach, P. R. Bazinet, R. Waterman, and T. D. Tilley. Organometallics 2008, 27, 1135.

306.

Probing the Chemistry of Molecular Heterojunctions Using Thermoelectricity. K. Baheti, J. A. Malen, P. Doak, P. Reddy, S.-Y. Jang, T. D. Tilley, A. Majumdar, and R. Segalman. Nano Lett. 2008, 8, 715.

2007

305.

Selective, Catalytic Cyclohexene Oxidation using Titanium-Functionalized Silicone Nanospheres. C. A. Bradley, M. J. Meredith and T. D. Tilley. J. Phys. Chem. C. 2007, 111, 17570.

304.

Silyl Derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) Complexes: Catalytic Redistribution of Arylsilanes and Dehydrogenative Arene Silylation. P. Sangtrirutnugul and T. Don Tilley. Organometallics 2007, 26, 5557.

303.

Highly Selective Olefin Epoxidation with Aqueous H2O2 over Surface-Modified TaSBA15 Prepared via the TMP Method. D. A. Ruddy and T. D. Tilley. Chem. Comm. 2007, 3350.

302.

Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes. R. Waterman, P. G. Hayes and T. D. Tilley. Acc. Chem. Res. 2007, 40, 712.

301.

9,10-Dichlorooctafluoroanthracene as a Building Block for n-Type Organic Semiconductors. J. F. Tannaci, M. Noji, J. McBee and T. Don Tilley. J. Org. Chem. 2007, 72, 5567.

300.

Reverse Micelle Synthesis of Rhodium Nanoparticles. J. D. Hoefelmeyer, H. Liu, G. A. Somorjai and T. D. Tilley. J. Coll. Int. Sci. 2007, 309, 86.

299.

Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles. Y. Borodko, S. M. Humphrey, T. D. Tilley, H. Frei and G. A. Somorjai. J. Phys. Chem. C. 2007, 111, 6288.

298.

Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor Addition Rate. S. M. Humphrey, M. E. Grass, S. E. Habas, K. Niesz, G. A. Somorjai and T. D. Tilley. Nano Lett. 2007, 7, 785.

297.

Photoinduced β-Hydrogen Elimination and Radical Formation with CpW(CO)3(CH2CH3): Ultrafast IR and DFT Studies. E. A. Glascoe, M. F. Kling, J. E. Shanoski, R. A. DiStasio, Jr., C. K. Payne, B. V. Mork, T. D. Tilley and C. B. Harris.  Organometallics 2007, 26, 1424.

2006

296.

Antimony-Antimony Bond Formation by Reductive Elimination from a Hafnium Bis(stibido) Complex. R. Waterman and T. D. Tilley. Inorg. Chem. 2006, 45, 9625.

295.

DFT Investigation of the Catalytic Hydromethylation of α-Olefins by Metallocenes. 1. Differences between Scandium and Lutetium in Propene Hydromethylation. N. Barros, O. Eisenstein, L. Maron and T. D. Tilley. Organometallics 2006, 25, 5699.

294.

Selective Homo- and Heterodehydrocouplings of Phosphines Catalyzed by Rhodium Phosphido Complexes. L.-B. Han and T. D. Tilley. J. Am. Chem. Soc. 2006, 128, 13698.

293.

Synthesis, Characterization and Reactivity of Tetramethylphospholyl Complexes of Scandium. F.-G. Fontaine, K. A. Tupper and T. D. Tilley. J. Organomet. Chem. 2006, 691, 4595.

292.

Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 3-butyne. R. Waterman and T. D. Tilley.  Chem. Commun. 2006, 4030.

291.

Stoichiometric and Catalytic Reactions Involving Si-H Bond Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand. D. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2006, 25, 4471.

290.

Octa- and Nonamethylfluorene and an Electron-Rich Permethylfluorenyl Ruthenocene Derivative. P. Bazinet, K. A. Tupper and T. D. Tilley.  Organometallics 2006, 25, 4286.

289.

Synthesis of Polysilanyl Magnesium Compounds. W. Gaderbauer, M. Zirngast, J. Baumgartner, C. Marschner and T. D. Tilley. Organometallics 2006, 25, 2599.

288.

Synthesis and Characterization of Perfluoroaryl-Substituted Siloles and Thiophenes: A Series of Electron-Deficient Blue Light-Emitting Materials. K. Geramita, J. McBee, Y. Shen. N. S. Radu and T. D. Tilley. Chem. Mater. 2006, 18, 3261.

287.

Single Source Molecular Precursors to Niobia-Silica and Niobium Phosphate Materials. C. G. Lugmair and T. D. Tilley. Monatshefte für Chemie 2006, 137, 557 (special issue to commemorate the 60th birthday of Prof. Ulrich Schubert).

286.

Catalytic Antimony-Antimony Bond Formation through Stibinidene Elimination from Zirconocene and Hafnocene Complexes. R. Waterman and T. D. Tilley.  Angew. Chem. Intl. Ed. 2006, 45, 2926.

285.

Stoichiometric and Catalytic Arene Activations by Pt Complexes Containing a Bidentate Monoanionic Nitrogen-Based Ligand. D. Karshtedt, J. L. McBee, A. T. Bell and T. D. Tilley. Organometallics 2006, 25, 1801.

284.

Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity. P. Sangtrirutnugul, M. Stradiotto, and T. D. Tilley.  Organometallics 2006, 25, 1607.

283.

Thermolytic Molecular Precursor Route to Site-Isolated Vanadia-Silica Materials and their Catalytic Performance in Methane Partial Oxidation.  D. A. Ruddy, N. L. Ohler, A. T. Bell, and T. D. Tilley.  J. Catal. 2006, 238, 277.

282.

Hydrogen-Substituted Osmium Silylene Complexes: Effect of Charge Localization on Catalytic Hydrosilation P. G. Hayes, C. Beddie, M. B. Hall, R. Waterman and T. D. Tilley. J. Am. Chem. Soc. 2006, 128, 428.

2005

281.

Synthesis, Structure, and α-Elimination Chemistry of Hafnocene Triarylstannyl Complexes.  N. R. Neale and T. D. Tilley.  J. Am. Chem. Soc. 2005, 127, 14745.

280.

Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials. K. L. Fujdala and T. D. Tilley. Z. Anorg. Allg. Chem. 2005, 631, 2619 (special issue to commemorate the 70th birthday of Prof. Herbert Roesky).

279.

Influence of Surface Modification of Ti-SBA15 Catalysts on the Epoxidation Mechanism for Cyclohexene with Aqueous Hydrogen Peroxide.  R. L. Brutchey, D. A. Ruddy, L. K. Andersen and T. D. Tilley.  Langmuir 2005, 21, 9576.

278.

Transition Metals in Organosilicon Chemistry. In Organosilicon Chemistry VI - From Molecules to Materials, N. Auner and J. Weis, Eds.; Wiley-VCH: Weinheim, Germany, 2005. T. D. Tilley, pp 382-391.

277.

Tailored Oxide Materials via Thermolytic Molecular Precursor (TMP) Methods.  In Topics in Organometallic Chemistry 16: Surface and Interfacial Organometallic Chemistry and Catalysis, C. Copéret and B. Chaudret, Eds.; Springer-Verlag: Heidelberg, 2005. K. L. Fujdala, R. L. Brutchey and T. D. Tilley, pp 69-115.

276.

Platinum-Based Catalysts for the Hydroamination of Olefins with Sulfonamides and Weakly Basic Anilines.  D. Karshtedt, A. T. Bell and T. D. Tilley.  J. Am. Chem. Soc. 2005, 127, 12640.

275.

Control of Selectivity in the Hydromethylation of Olefins via Ligand Modification in Scandocene Catalysts.  F.-G. Fontaine and T. D. Tilley.  Organometallics 2005, 24, 4340.

274.

New Fe/SiO2 Materials Prepared Using Diiron Molecular Precursors: Synthesis, Characterization and Catalysis. A. W. Holland, G. Li, A. M. Shahin, G. J. Long, A. T. Bell and T. D. Tilley.  J. Catal. 2005, 235, 150.

273.

Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15. C. Hess, I. J. Drake, J. D. Hoefelmeyer, T. D. Tilley and A. T. Bell. Catal. Lett. 2005, 105, 1.

272.

A dimeric molecular precursor [(tBuO)2Ti{μ-O2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation. R. L. Brutchey, B. V. Mork, D. J. Sirbuly, P. Yang and T. D. Tilley. J. Molec. Catal. 2005, 238, 1.

271.

Liquid phase oxidation of alkylaromatics by an H-atom transfer mechanism with a new heterogeneous CoSBA15 catalyst.  R. L. Brutchey, I. J. Drake, A. T. Bell and T. D. Tilley.  Chem. Commun. 2005, 3736.

270.

Synthesis and characterization of scandium complexes with reduced ligands. Crystal structures of Cp*ScI2, [Cp*ScI(bpy)]2, and [Cp*ScCl(bpy)]2 K. A. Tupper and T. D. Tilley. J. Organomet. Chem. 2005, 690, 1689.

269.

Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches. I. J. Drake, K. L. Fujdala, A. T. Bell and T. D. Tilley. J. Catal. 2005, 230, 14.

268.

Synthesis and Characterization of MoO[OSi(OtBu)3]4 and MoO2[OSi(OtBu)3]2 (M = Mo, W): Models for Isolated Oxo-Molybdenum and –Tungsten Sites on Silica and Precursors to Molybdenum- and Tungsta-Silica Materials. J. Jarupatrakorn, M. P. Coles and T. D. Tilley. Chem. Mater. 2005, 17, 1818.

267.

Radial Anisotropic Growth of Rhodium Nanoparticles. J. D. Hoefelmeyer, K. Niesz, G. A. Somorjai and T. D. Tilley. Nano Lett. 2005, 5, 435.

266.

Synthesis and Characterization of Scandium Silyl Complexes of the Type Cp*2ScSiHRR'. α-Bond Metathesis Reactions and Catalytic Dehydrogenative Silation of Hydrocarbons. A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 643.

265.

Thermolytic Conversion of a Bis(alkoxy)tris(siloxy)tantalum(V) Single-Source Molecular Precursor to Catalytic Tantala-Silica Materials. R. L. Brutchey, C. G. Lugmair, L. O. Schebaum and T. D. Tilley. J. Catal. 2005, 229, 72.

2004

264.

Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane. H. X. Dai, L. Chen, T. D. Tilley, E. Iglesia and A. T. Bell. Studies in Surface Science and Catalysis 2004, 147, 679.

263.

Synthesis and Reactivity of Ti(III) Tris(tert-butoxy)siloxy Complexes. C. G. Lugmair and T. D. Tilley. Zeitschrift für Naturforschung 2004, 59b, 1540 (special issue to commemorate the 70th birthday of Prof. Hubert Schmidbaur).

262.

Synthesis and Reactivity of Silyl and Silylene Ligands in the Coordination Sphere of the 14-Electron Fragment Cp*(iPr3P)Os+. P. B. Glaser and T. D. Tilley. Organometallics 2004, 23, 5799.

261.

Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous Silica: A Detailed X-ray Absorption Spectroscopy Study. I. J. Drake, K. L. Fujdala, S. Baxamusa, A. T. Bell and T. D. Tilley. J. Phys. Chem. B 2004, 108, 18421.

260.

C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions. In Activation and Functionalization of C-H Bonds, ACS Symposium Series 885, K. I. Goldberg and A. S. Goldman, Eds.; American Chemical Society, Washington, 2004.  S. R. Klei, K. L. Tan, J. T. Golden, C. M. Yung, R. K. Thalji, K. A. Ahrendt, J. A. Ellman, T. D. Tilley, and R. G. Bergman, Chap. 2, p. 46.

259.

Unusual Ar-H/Rh-H JHH NMR Coupling in Complexes of Rhodium(III): Experimental Evidence and Theoretical Support for an η1-Arene Structure. J. R. Krumper, M. Gerisch, A. Magistrato, U. Röthlisberger, R. G. Bergman and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 12492.

258.

Atomic Level Control Over Surface Species via a Molecular Precursor Approach: Isolated Cu(I) Sites and Cu Nanoparticles Supported on Mesoporous Silica. K. L. Fujdala, I. J. Drake, A. T. Bell and T. D. Tilley.  J. Am. Chem. Soc. 2004, 126, 10864.

257.

Pt-Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins. D. Karshtedt, A. T. Bell and T. D. Tilley.  Organometallics 2004, 23, 4169.

256.

Silylene Hydride Complexes of Molybdenum with Silicon-Hydrogen Interactions. Neutron Structure of (η5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2). B. V. Mork, T. D. Tilley, A. J. Schultz and J. A. Cowan.  J. Am. Chem. Soc. 2004, 126, 10428.

255.

Synthesis and Characterization of {(diene)Rh[µ-OSi(OtBu)3]}2, a Model for Silica-Bound Rhodium. J. Jarupatrakorn and T. D. Tilley. Dalton Trans. 2004, 2808.

254.

Reactions of hafnocene stannyl complexes with stannanes: implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes. N. R. Neale and T. D. Tilley. Tetrahedron 2004, 60, 7247.

253.

Oxidative Dehydrogenation of Propane over Vanadia Based Catalysts Supported on High-Surface-Area Mesoporous MgAl2O4. O. R. Evans, A. T. Bell and T. D. Tilley. J. Catal. 2004, 226, 292.

252.

Spectroscopic Characterization of Highly Dispersed Vanadia Supported on SBA-15 Silica. C. Hess, J. D. Hoefelmeyer and T. D. Tilley. J. Phys. Chem. B 2004, 108, 9703.

251.

Synthesis and Reactivity of Tris(imido) Rhenium Complexes Containing Rhenium-Main Group Element Bonds.  Silicon-Carbon Bond Activations of PhSiH3 by Silyl Complexes. J. Gavenonis and T. D. Tilley. Inorg. Chem. 2004, 43, 4353.

250.

The [(η5-C5Me5)(2,2'-bipyridine)Ru]- Anion, and its Use in the Synthesis of Alkyl, Gallyl, and Stannyl Complexes of Ruthenium. B. V. Mork, A. McMillan, H. Yuen and T. D. Tilley. Organometallics 2004, 23, 2855.

249.

Coordination Chemistry and Reactivity of New Zwitterionic Rhodium and Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-.  Activation of H-H, Si-H, and Ligand B-C Bonds. L. Turculet, J. D. Feldman and T. D. Tilley. Organometallics 2004, 23, 2488.

248.

Synthons for Coordinatively Unsaturated Complexes of Tungsten, and their Use for the Synthesis of High Oxidation-State Silylene Complexes. B. V. Mork and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 4375.

247.

Dimolybdenum(III) Complexes of -OSi(OtBu)3, -O2P(OtBu)2 and -OB[OSi(OtBu)3]2 as Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials. K. L. Fujdala and T. D. Tilley.  Chem. Mater. 2004, 16, 1035.

246.

Probing the Structure of the Silylene Complex (Cy3P)2Pt=SiMes2. UV-Vis and Preresonance Raman Investigations. S. S. Bukalov, I. A. Garbuzova, L. A. Leites, J. D. Feldman and T. D. Tilley. Spectrochim. Acta Part A 2004, 60, 801.

245.

Synthesis and Reactivity of d0 Alkyl, Silyl, and Hydride Complexes of Titanium and Zirconium Featuring an Aryl-Substituted Tripodal Triamide Ligand Derived from cis-cis-1,3,5-Triaminocyclohexane. L. Turculet and T. D. Tilley. Organometallics 2004, 23, 1542.

244.

Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] (R= Me, iPr; X = Cl, OTf). P. B. Glaser, P. W. Wanandi and T. D. Tilley. Organometallics 2004, 23, 693.

243.

Synthesis and reactivity of bis(heptamethylindenyl)yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: crystal structure of Ind*2YCl(THF). J. Gavenonis and T. D. Tilley. J. Organomet. Chem. 2004, 689, 870.

242.

Activated Boron Nitride Derived From Activated Carbon. W.Q. Han, R. Brutchey, T. D. Tilley and A. Zettl. Nano Lett., 2004, 4, 173.

241.

Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN=)Ta (Cp* = η5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN=)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3). J. Gavenonis and T. D. Tilley.  Organometallics 2004, 23, 31.

2003

240.

Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism.P. B. Glaser and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 13640.

239.

Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective Formation of Cyclopropanes from Ethyl Diazoacetate at Room Temperature. J. R. Krumper, M. Gerisch, J. M. Suh, R. G. Bergman and T. D. Tilley. J. Org. Chem. 2003, 68, 9705.

238.

Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-. L. Turculet, J. D. Feldman and T. D. Tilley. Organometallics 2003, 22, 4627.

237.

Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl).  J. D. Feldman, G. P. Mitchell, J.-O. Nolte and T. D. Tilley.  Can. J. Chem. 2003, 81, 1127.

236.

Tailoring Properties of Silicon-Containing Oxide Catalysts via the Thermolytic Molecular Precursor Route.  In Organosilicon Chemistry V - From Molecules to Materials, N. Auner and J. Weis, Eds.; K. L. Fujdala and T. D. Tilley; Wiley-VCH, Weinheim, Germany, p. 379-388.

235.

Cationic Hafnium Silyl Complexes and their Enhanced Reactivity in σ-Bond Metathesis Processes with Si-H and C-H Bonds.  A. D. Sadow and T. D. Tilley.  J. Am. Chem. Soc. 2003, 125, 9462.

234.

Enhanced Reactivity of Cationic Hafnocene Complexes towards σ-Bond Metathesis Reactions.  Si–H and Si–C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions.  A. D. Sadow and T. D. Tilley.  Organometallics 2003, 22, 3577.

233.

Synthesis and Study of Heterobimetallic Complexes Supported by a Ferrocene-Based Bisphosphine-Diamine Ligand.  D. Karshtedt, A. T. Bell and T. D. Tilley.  Organometallics 2003, 22, 2855.

232.

Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins Based on the Nondegenerate Exchange of Alkyl Groups and σ-Bond Metathesis at Scandium.  A. D. Sadow and T. D. Tilley.  J. Am. Chem. Soc. 2003, 125, 7971.

231.

Thermolytic Molecular Precursor Routes to Cr/Si/Al/O and Cr/Si/Zr/O Catalysts for the Oxidative Dehydrogenation and Dehydrogenation of Propane.  K. L. Fujdala and T. D. Tilley.  J. Catal. 2003, 218, 123.

230.

Design and synthesis of heterogeneous catalysts:  the thermolytic molecular precursor approach.  K. L. Fujdala and T. D. Tilley.  J. Catal. 2003, 216, 265.

229.

Regioselective Coupling of Pentafluorophenyl Substituted Alkynes:  Mechanistic Insight into the Zirconocene Coupling of Alkynes and a Facile Route to Conjugated Polymers Bearing Electron-Withdrawing Pentafluorophenyl Substituents.  S. A. Johnson, F.-Q. Liu, M. C. Suh, S. Zürcher, M. Haufe, S. S. H. Mao and T. D. Tilley.  J. Am. Chem. Soc. 2003, 125, 4199.

228.

Rhodium(III) and Rhodium(II) Complexes of Novel Bis(Oxazoline) Pincer Ligands.  M. Gerisch, J. R. Krumper, R. G. Bergman and T. D. Tilley.  Organometallics 2003, 22, 47.

227.

Nonaqueous, Molecular Precursor Route to Hybrid Inorganic/Organic Zirconia-Silica Materials Containing Covalently Linked Organic Bridges.  R. L. Brutchey and T. D. Tilley.  Chem. Mater.  2003, 15, 1040.

226.

Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium, and their activities as olefin polymerization catalysts.  T. I. Gountchev and T. D. Tilley.  Inorg. Chim. Acta 2003, 345, 81.

225.

Catalytic Functionalization of Hydrocarbons via σ-Bond Metathesis Chemistry:  Dehydrosilylation of Methane with a Scandium Catalyst.  A. D. Sadow and T. D. Tilley.  Angew. Chem. Int. Ed. 2003, 42, 803.

224.

Tris(tert-butoxy)siloxy Derivatives of Boron, Including the Boronous Acid HOB[OSi(OtBu)3]2 and the Metal (Siloxy)boryloxide Complex Cp2Zr(Me)OB[OSi(OtBu)3]2.  A Remarkable Crystal Structure with 18 Independent Molecules in its Asymmetric Unit.  K. L. Fujdala, A. G. Oliver, F. J. Hollander and T. D. Tilley.  Inorg. Chem. 2003, 42, 1140.

223.

Multiple Bonding Between Silicon and Molybdenum: A Transition Metal Complex with Considerable Silylyne Character.  B. V. Mork and T. D. Tilley.  Angew. Chem. Int. Ed. 2003, 42, 357.

222.

Convenient, Zirconocene-Coupling Routes to Germole- and Thiophene-Containing Macrocycles with Triangular Geometries.  J. R. Nitschke and T. D. Tilley.  J. Organomet. Chem. 2003, 666, 15.

2002

221.

Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl-Phosphine Ligands as C-H Activation Catalysts for the Deuteration of Hydrocarbons in D2O.  S. R. Klei, T. D. Tilley and R. G. Bergman.  Organometallics 2002, 21, 4905.

220.

Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N=]2- ([Ar*N=]2-).  Generation and Reactivity of [(Ar*N=)(Ar*NH)Ta–(H)(OSO2CF3)], which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand.  J. Gavenonis and T. D. Tilley.  Organometallics 2002, 21, 5549.

219.

Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and iron.  R. H. Heyn and T. D. Tilley.  Inorg. Chim. Acta 2002, 341, 91.

218.

Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes.  S. R. Klei, T. D. Tilley and R. G. Bergman.  Organometallics 2002, 21, 4648.

217.

Synthesis, Characterization, and Catalytic Performance of Single-Site Iron(III) Centers on the Surface of SBA-15 Silica.  C. Nozaki, C. G. Lugmair, A. T. Bell and T. D. Tilley.  J. Am. Chem. Soc. 2002, 124, 13194.

216.

Activations of Silanes with [PhB(CH2PPh2)3]Ir(H)(η3-C8H13).  Formation of Iridium Silylene Complexes via the Extrusion of Silylenes from Secondary Silanes R2SiH2.  J. D. Feldman, J. C. Peters and T. D. Tilley.  Organometallics 2002, 21, 4065.

215.

Structural and Chemical Properties of Zwitterionic Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PPh2)3]-.  J. D. Feldman, J. C. Peters and T. D. Tilley.  Organometallics 2002, 21, 4050.

214.

Zirconium Amide, Halide, and Alkyl Complexes Supported by Tripodal Amido Ligands Derived from cic,cis-1,3,5-Triaminocyclohexane.  L. Turculet and T. D. Tilley.  Organometallics 2002, 21, 3961.

213.

Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands.  S. R. Klei, T. Don Tilley and R. G. Bergman.  Organometallics 2002, 21, 3376.

212.

Neutral and Anionic Silyl Hydride Derivatives of the Tantalum Imido Fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3).  Reactive σ-Bonds and Intramolecular C-H Bond Activations Involving the Silyl Ligands.  U. Burckhardt, G. L. Casty, J. Gavenonis and T. D. Tilley.  Organometallics 2002, 21, 3108.

211.

Reversible Intramolecular Hydride Transfer between Tantalum and an Aromatic Ring.  An η5-Cyclohexadienyl Complex as a Masked Hydride.  J. Gavenonis and T. D. Tilley.  J. Am. Chem. Soc. 2002, 124, 8536.

210.

Silica-Supported, Single-Site Titanium Catalysts for Olefin Epoxidation. A Molecular Precursor Strategy for Control of Catalyst Structure.  J. Jarupatrakorn and T. D. Tilley.  J. Am. Chem. Soc. 2002, 124, 8380.

209.

Activation of Arene C-H Bonds by a Cationic Hafnium Silyl Complex Possessing an α-Agostic Si-H Interaction.  A. D. Sadow and T. D. Tilley.  J. Am. Chem. Soc. 2002, 124, 6814.

208.

Synthesis and Reactivity of η5-Germacyclopentadienyl Complexes of Iron.  W. P. Freeman, J. M. Dysard, T. D. Tilley and A. L. Rheingold.  Organometallics 2002, 21, 1734.

207.

A New Mechanism for Metal-Catalyzed Stannane Dehydrocoupling Based on α-H-Elimination in a Hafnium Hydrostannyl Complex.  N. R. Neale and T. D. Tilley.  J. Am. Chem. Soc. 2002, 124, 3802.

206.

New Vanadium Tris(tert-butoxy)siloxy Complexes and Their Thermolytic Conversions to Vanadia-Silica Materials.  K. L. Fujdala and T. D. Tilley.  Chem. Mater. 2002, 14, 1376.

205.

Iridium-Catalyzed H/D Exchange into Organic Compounds in Water.  S. R. Klei, J. T. Golden, T. D. Tilley, and R. G. Bergman.  J. Am. Chem. Soc. 2002, 124, 2092.

204.

Hafnium imido complexes containing silyl ligands.  I. Castillo and T. D. Tilley.  J. Organomet. Chem. 2002, 643-644, 431.

203.

New Tris(tert-butoxy)siloxy Complexes of Aluminum and Their Transformation to Homogeneous Aluminosilicate Materials via Low Temperature Thermolytic Pathways.  C. G. Lugmair, K. L. Fujdala and T. D. Tilley.  Chem. Mater. 2002, 14, 888.

202.

Order-Disorder Phase Transition in Poly(di-n-butylstannane) Observed by UV-Vis and Raman Spectroscopy.  S. S. Bukalov, L. A. Leites, V. Lu and T. D. Tilley.  Macromolecules 2002, 35, 1757.

201.

Oxidative Dehydrogenation of Propane over Vanadia-Magnesia Catalysts Prepared by Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO.  C. Pak, A. T. Bell and T. D. Tilley.  J. Catal. 2002, 206, 49.

200.

Coordination of 2,2'-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes:  An Experimental Investigation of Spin Coupling in Lanthanide Complexes.  M. Schultz, J. M. Boncella, D. J. Berg, T. D. Tilley and R. A. Andersen.  Organometallics 2002, 21, 460.

199.

Zirconocene-Mediated, High-Yielding Macrocyclizations of Silyl-Terminated Diynes.  L. L. Schafer, J. R. Nitschke, S. S. H. Mao, F.-Q. Liu, G. Harder, M. Haufe and T. D. Tilley.  Chem. Eur. J. 2002, 8, 74.

198.

Molecular Design and Synthesis of Heterogeneous and Single-Site, Supported Catalysts.  T. D. Tilley.  J. Molec. Catal. A: Chem. 2002, 182-183, 17.

2001

197.

Organolutetium Complexes in σ-Bond Metathesis Reactions Involving Silicon.  Catalysts for the Hydrogenolysis of Si-C Bonds.  I. Castillo and T. D. Tilley.  Organometallics 2001, 20, 5598.

196.

Reactions of Zirconacyclopentadienes with Nitrosobenzene.  Characterization of Zirconacycle Intermediates and Formation of N-Phenylpyrroles.  M. Nakamoto and T. D. Tilley.  Organometallics 2001, 20, 5515.

195.

Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-κP]}-{[2,4,6-tri(tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]): Catalytic C−P Bond Formation via Intramolecular C−H/P−H Dehydrogenative Cross-Coupling. M. Stradiotto, K. L. Fujdala and T. D. Tilley.  Helv. Chim. Acta 2001, 84, 2958 (memorial issue for Professor Luigi Venanzi).

194.

Carbosilane Dendrimers as Nanoscopic Building Blocks for Hybrid Organic-Inorganic Materials and Catalyst Supports.  J. W. Kriesel and T. D. Tilley.  Adv. Mater. 2001, 13, 1645.

193.

Mechanistic Aspects of Samarium-Mediated σ-Bond Activations of Arene C-H and Arylsilane Si-C Bonds.  I. Castillo and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 10526.

192.

Enhanced Reactivity of Cationic vs. Neutral Hafnocene Complexes in Stoichiometric and Catalytic σ-Bond Metathesis Reactions Involving Si-H and Si-C Bonds.  A. Sadow and T. D. Tilley. Organometallics 2001, 20, 4457.

191.

Efficient, High-Yield Route to Long, Functionalized p-Paraphenylene Oligomers Containing Perfluorinated Segments, and Their Cyclodimerizations by Zirconocene Coupling.  J. R. Nitschke and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 10183.

190.

Block Copolymer Assisted Synthesis of Mesoporous, Multicomponent Oxides by Non-hydrolytic, Thermolytic Decomposition of Molecular Precursors in Nonpolar Media.  J. W. Kriesel, M. S. Sander and T. Don Tilley.  Chem. Mater. 2001, 13, 3554.

189.

An Efficient, Single-Source Molecular Precursor to Silicoaluminophosphates.  K. L. Fujdala and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 10133.

188.

High Oxidation-State (Formally d0) Tungsten Silylene Complexes via Double Si-H Bond Activation.  B. V. Mork and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 9702.

187.

Synthesis and Chemistry of the 16-Electron Osmium Complex (η5-C5Me5)(iPr3P)OsBr.  P. B. Glaser and T. D. Tilley.  Eur. J. Inorg. Chem. 2001, 2747.

186.

Synthesis, Structure and Hydrosilylation Catalysis of a Chiral A-Frame Rhodium(I) Dimer with Cis-Diphosphite Ligands.  S. Ini, A. G. Oliver, T. D. Tilley and R. G. Bergman.  Organometallics 2001, 20, 3839.

185.

An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex.  S. R. Klei, R. G. Bergman and T. D. Tilley.  Organometallics 2001, 20, 3220.

184.

Intramolecular Rearrangements on Ultrafast Timescales:  Femtosecond Infrared Studies of Ring Slip in (η1-C5Cl5)Mn(CO)5.  C. K. Payne, P. T. Snee, H. Yang, K. T. Kotz, L. L. Schafer, T. D. Tilley and C. B. Harris.  J. Am. Chem. Soc. 2001, 123, 7425.

183.

Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) Complexes.  M. Gerisch, J. R. Krumper, R. G. Bergman and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 5818.

182.

Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (NSiN) ligand. M. Stradiotto, K. L. Fujdala and T. D. Tilley.  Chem. Commun. 2001, 1200.

181.

Thermolytic Transformation of Tris(alkoxy)siloxychromium(IV) Single-Source Molecular Precursors to Catalytic Chromia-Silica Materials.  K. L. Fujdala and T. D. Tilley.  Chem. Mater. 2001, 13, 1817.

180.

Novel Templating Effect in the Macrocyclization of Functionalized Diynes via Zirconocene Coupling.  J. R. Nitschke and T. D. Tilley.  Angew. Chem., Int. Ed. Engl. 2001, 40, 2142.

179.

Efficient Diastereoselective Syntheses of Chiral Macrocycles via Zirconocene-Coupling.  Synthetic Control of Size and Geometry.  L. L. Schafer and T. D. Tilley.  J. Am. Chem. Soc. 2001, 123, 2683.

178.

Silabenzene and Disilabenzene Complexes of Ruthenium.  J. M. Dysard, T. D. Tilley and T. K. Woo.  Organometallics 2001, 20, 1195.

177.

A new molecular precursor for magnesia-silica materials.  J. W. Kriesel and T. Don Tilley.  J. Mater. Chem. 2001, 11, 1081.

176.

General Route to Homogeneous, Mesoporous, Multicomponent Oxides Based on the Thermolytic Transformation of Molecular Precursors in Nonpolar Media.  J. W. Kriesel, M. S. Sander and T. Don Tilley.  Adv. Mater. 2001, 13, 331.

2000

175.

Synthesis of Sm-SiH3 Complexes via σ-Bond Metathesis of the Si-C bond of Phenylsilane.  I. Castillo and T. D. Tilley.  Organometallics 2000, 19, 4733.

174.

Synthesis and Reactivity of Pentamethylcyclopentadienyl Ruthenium Complexes of the Stable Neutral Silylene Si(tBuNCH=CHNtBu).  J. M. Dysard and T. D. Tilley.  Organometallics 2000, 19, 4726.

173.

Tantalum-Mediated Substitution at Germanium:  A Germolyl-to-Germole Transformation Leading to η4-C4Me4GeMeCl Complexes.  J. M. Dysard and T. D. Tilley.  Organometallics 2000, 19, 4720.

172.

New Zirconocene-Coupling Route to Large, Functionalized Macrocycles.  J. R. Nitschke, S. Zürcher and T. D. Tilley.  J. Am. Chem. Soc. 2000, 122, 10345.

171.

Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling.  A Combined Spectroscopic and Theoretical Investigation.  U. Burckhardt, G. L. Casty, T. D. Tilley, T. K. Woo and U. Rothlisberger.  Organometallics 2000, 19, 3830.

170.

Thermolytic Molecular Precursor Route to Active and Selective Vanadia-Zirconia Catalysts for the Oxidative Dehydrogenation of Propane.  J. L. Male, H. G. Niessen, A. T. Bell, and T. D. Tilley.  J. Catal. 2000, 194, 431.

169.

Poly(2,5-diphenylgermole): Incorporation of a Germole Ring into a Conjugated Polymer.  B. L. Lucht, M. A. Buretea, and T. D. Tilley.  Organometallics 2000, 19, 3469.

168.

Hafnium-Rhodium and Hafnium-Iridium Heterobimetallic Complexes Featuring the Bridging Germole Dianion Ligand [GeC4Me4]2-.  J. M. Dysard and T. D. Tilley.  Organometallics 2000, 19, 2671.

167.

An Efficient, Modular Synthetic Route to Oligomers Based on Zirconocene-Coupling.  Properties for Phenylene-Thiophene-1-Oxide and Phenylene-Thiophene-1,1-Dioxide Chains.  M. C. Suh, B. Jiang and T. D. Tilley.  Angew. Chem. Int. Ed. Engl. 2000, 39, 2870.

166.

The first structurally characterised oligosilylmagnesium compound.  J. D. Farwell, M. F. Lappert, C. Marschner, C. Strissel and T. D. Tilley.  J. Organomet. Chem. 2000, 603, 185.

165.

Synthesis and Chemical Functionalization of High Surface Area Dendrimer-Based Xerogels and Their use as New Catalyst Supports.  J. W. Kriesel and T. D. Tilley.  Chem. Mater. 2000, 12, 1171.

164.

Synthesis and Reactivity of η5-Silolyl, η5-Germolyl and η5-Germole Dianion Complexes of Zirconium and Hafnium.  J. M. Dysard and T. D. Tilley.  J. Am. Chem. Soc. 2000, 122, 3097.

163.

Poly(diaryl)stannanes:  Influence of Substituents on the σ-σ* Transition Energy.  V. Y. Lu and T. D. Tilley.  Macromolecules 2000, 33, 2403.

162.

Synthesis of Novel Conjugated Polymers for Potential LED Applications.  B. Jiang and T. D. Tilley.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 829.

161.

Hybrid Organic-Inorganic Gels Based on Dendrimeric Building Blocks: High Surface Area Xerogels as Catalyst Supports.  J. W. Kriesel and T. D. Tilley.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 566.

160.

Versatile Zirconocene-Coupling Pathway to Conjugated Polymers with a Range of Structural and Electronic Properties.  T. D. Tilley and B. Jiang.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 418.

159.

Synthesis and Structure of the (Tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O.  R. Rulkens, M. P. Coles, and T. D. Tilley.  Dalton Trans. 2000, 627.

158.

The Mechanism of Silicon-Hydrogen and Carbon-Hydrogen Bond Activation by Iridium(III):  Production of a Silylene Complex, and the First Direct Observation of Ir(III)/Ir(V) C-H Bond Oxidative Addition and Reductive Elimination.  S. R. Klei, T. D. Tilley, and R. G. Bergman.  J. Am. Chem. Soc. 2000, 122, 1816.

157.

Reactivity of an Osmium Silylene Complex towards Chlorocarbons.  Promotion of Metal Redox Chemistry by a Silylene Ligand, and Relevance to the Mechanism of the Direct Process.  P. W. Wanandi, P. B. Glaser, and T. D. Tilley.  J. Am. Chem. Soc. 2000, 122, 972.

156.

Titania-Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4: Selective Epoxidation Catalysts.  M. P. Coles, C. G. Lugmair, K. W. Terry, and T. D. Tilley.  Chem. Mater. 2000, 12, 122.

1999

155.

Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes of Yttrium.  T. I. Gountchev and T. D. Tilley.  Organometallics 1999, 18, 5661.

154.

Silylene Extrusion from a Silane.  Direct Conversion of Mes2SiH2 to an Iridium Silylene Dihydride.  J. C. Peters, J. D. Feldman, and T. D. Tilley.  J. Am. Chem. Soc. 1999 121, 9871.

153.

General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed Thiophene-Thiophene-1-Oxide Oligomers.  B. Jiang and T. D. Tilley.  J. Am. Chem. Soc. 1999, 121, 9744.

152.

Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3:  A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia-Silica Xerogels.  R. Rulkens, J. L. Male, K. W. Terry, B. Olthof, A. Khodakov, A. T. Bell, E. Iglesia, and T. D. Tilley.  Chem. Mater. 1999, 11, 2966.

151.

Yttrium Complexes of the Chelating, C2-Symmetric, Bis(silylamido)biphenyl Ligand [DADMB]2- {=[6,6'-Me2-(C6H3)2](2,2'-NSiMe2tBu)2}2-.  T. I. Gountchev and T. D. Tilley.  Organometallics 1999, 18, 2896.

150.

Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N=)–Ta[Si(SiMe3)3]H: The Unexpected Formation of a Ta(V) Carbonyl Complex and the Complete Reduction of CO.  U. Burckhardt and T. D. Tilley.  J. Am. Chem. Soc. 1999, 121, 6328.

149.

Di(tert-butyl)phosphate Complexes of Aluminum.  Precursors to Aluminum Phosphate Xerogels and Thin Films.  C. G. Lugmair, T. D. Tilley, and A. L. Rheingold.  Chem. Mater. 1999, 11, 1615.

148.

Strained, Ring Tilted Dicarbon-bridged [2]Ferrocenophanes and Ferrocene Revisited:  57Fe Mössbauer Spectroscopic Study of Bonding, Hyperfine Interactions, and Lattice Dynamics.  R. H. Herber, K. Temple, I. Manners, M. Buretea, T. D. Tilley.  Inorg. Chim. Acta 1999, 287, 152.

147.

Dendrimers as Building Blocks for Nanostructured Materials:  Micro- and Mesoporosity in Dendrimer-Based Xerogels.  J. Kriesel and T. D. Tilley.  Chem. Mater. 1999, 11, 1190.

1998

146.

Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5-C5Me5)(Me3P)2Ru=SiR2]+.  S. K. Grumbine, G. P. Mitchell, D. A. Straus, T. D. Tilley, and A. L. Rheingold.  Organometallics 1998, 17, 5607.

145.

Synthesis of Highly Charged Organometallic Dendrimers and their Characterization by Electrospray Mass Spectrometry and Single Crystal X-ray Diffraction.  J. W. Kriesel, S. König, M. A. Freitas, A. G. Marshall, J. A. Leary, and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 12207.

144.

Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate Complex in Organic Solvents.  C. G. Lugmair and T. D. Tilley.  Inorg. Chem. 1998, 37, 6304.

143.

Isolation and Characterization of Neutral Platinum Silylene Complexes of the Type (R3P)2Pt=SiMes2 (Mes = 2,4,6-Trimethylphenyl).  J. Feldman, G. P. Mitchell, J.-O. Nolte, and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 11184.

142.

A Molecular Precursor Route to Active and Selective Vanadia-Silica-Zirconia Heterogeneous Catalysts for the Oxidative Dehydrogenation of Propane.  R. Rulkens and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 9959.

141.

Generation of a Silylene Complex via the 1,2-Migration of Hydrogen from Silicon to Platinum.  G. P. Mitchell and T. D. Tilley.  Angew. Chem. Int. Ed. Engl. 1998, 37, 2524.

140.

Zirconocene-Coupling Routes to Conjugated Polymers: Soluble Poly(arylenedienylene)s.  B. L. Lucht and T. D. Tilley.  Chem. Commun. 1998, 1645.

139.

η5-Silolyl and η5-Germolyl Complexes of d0 Hafnium.  Structural Characterization of an η5-Silolyl Complex.  J. M. Dysard and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 8245.

138.

Reversible 1,2-Migration of Hydrogen between Platinum and Silicon via Intermediate Silylene Complexes.  G. P. Mitchell and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 7635.

137.

Hydrogen Migrations in Rhodium Silyl Complexes:  Silylene Intermediates vs. Oxidative Addition/Reductive Elimination.  G. P. Mitchell and T. D. Tilley.  Organometallics 1998, 17, 2912.

136.

A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s:  Bandgap Tuning via Conformational Control.  B. L. Lucht, S. S. H. Mao, and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 4354.

135.

Bipyridine-Containing Cyclophanes via Zirconocene-Coupling.  J. Nitschke and T. D. Tilley.  J. Org. Chem. 1998, 63, 3673.

134.

A Simple, Efficient Route to Cage Compounds via Zirconocene-Coupling.  F.-Q. Liu, G. Harder, and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 3271.

133.

Di-tert-buyl Phosphate Complexes of Titanium.  C. G. Lugmair and T. D. Tilley.  Inorg. Chem. 1998, 37, 1821.

132.

Alkoxy(siloxy) complexes of tin, lead, and bismuth.  K. W. Terry, K. Su, T. D. Tilley and A. L. Rheingold.  Polyhedron 1998, 17, 891.

131.

Hydrolysis of Zirconium and Hafnium Siloxide Complexes.  Isolation and Characterization of Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n (M = Zr, Hf; n = 1, 2).  C. G. Lugmair and T. D. Tilley.  Inorg. Chem. 1998, 37, 764.

130.

Efficient Zirconocene-Coupling of Silicon-Substituted Diynes to Polymers and Macrocycles.  S. S. H. Mao, F.-Q. Liu and T. D. Tilley.  J. Am. Chem. Soc. 1998, 120, 1193.

129.

A coordination network based on d0 transition-metal centers: synthesis and structure of the [4,2]-connected layered compound [(TiCl4)2Si(p-C6H4CN)4]•1.5C7H8.  F.-Q. Liu and T. D. Tilley.  J. Chem. Soc., Chem. Commun. 1998, 103.

1997

128.

Structure and Reactivity of Chelating Imido-Amido Complexes of Tantalum.  Mechanistic Studies on the Addition of Silanes to Ta-N Multiple Bonds.  T. I. Gountchev and T. D. Tilley.  J. Am. Chem. Soc. 1997, 119, 12831.

127.

Reversible Cycloaddition of Isocyanates to Ruthenium Silylene Complexes.  G. P. Mitchell and T. D. Tilley.  J. Am. Chem. Soc. 1997, 119, 11236.

126.

Zirconocene Molecular Zippers:  Implements for Construction of Well-Defined Polymers and Macrocycles. In Modular Chemistry, NATO ASI Series C: Vol. 499,J. Michl, Ed.; Kluwer Academic Publisher: Dordrecht, The Netherlands, 1997.  S. S. H. Mao and T. D. Tilley, pp 623-635.

125.

Coordination Networks Based on Tetrahedral Silane Building Blocks:  Influence of the Anion on Structures Adopted by Ag+-Si(p-C6H4CN)4 Arrays.  F.-Q. Liu and T. D. Tilley.  Inorg. Chem. 1997, 36, 5090.

124.

Synthesis and Reactivity of d0 Bis(imido) Silyl and Germyl Complexes of Molybdenum and Tungsten.  G. L. Casty, T. D. Tilley, G. A. P. Yap and A. L. Rheingold.  Organometallics 1997, 16, 4746.

123.

Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous Zirconia- and Hafnia-Silica Materials.  An Alternative to the Sol-Gel Method.  K. W. Terry, C. G. Lugmair and T. D. Tilley.  J. Am. Chem. Soc. 1997, 119, 9745.

122.

Osmium Alkyl and Silyl Derivatives with Cyclopentadienyl(phosphine) and Pentamethylcyclopentadienyl(phosphine) Ligand Sets.  P. W. Wanandi and T. D. Tilley.  Organometallics  1997, 16, 4299.

121.

A Versatile, Transition Metal-Mediated Route to Blue-Light Emitting Polymers with Chemically Tunable Luminescent Properties.  S. S. H. Mao and T. D. Tilley.  Macromolecules 1997, 30, 5566.

120.

Zirconium Bent Sandwich Complex of a Dicarbahexaborate Ligand:  [Li(THF)3]{[η5-C2B4H4(SiMe3)2](η5-C5Me5)ZrCl2.  S. S. H. Mao, T. D. Tilley, A. L. Rheingold, and N. S. Hosmane.  J. Organomet. Chem. 1997, 533, 257.

119.

Poly(ferrocenylenevinylene) from Ring Opening Metathesis Polymerization of ansa-(Vinylene)ferrocene.  M. A. Buretea and T. D. Tilley.  Organometallics 1997, 16, 1507.

118.

Molecular Routes to Metal Oxides and Metal Silicates.  Synthesis and Thermal Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3 and W2(NHMe2)2[O2Si(OtBu)2]2-[OSi(OH)(OtBu)2]2.  K. Su and T. D. Tilley.  Chem. Mater. 1997, 9, 588.

117.

Zinc Di(tert-butyl)phosphate Complexes as Precursors to Zinc Phosphates.  Manipulation of Zincophosphate Structures.  C. G. Lugmair, T. D. Tilley, and A. L. Rheingold.  Chem. Mater. 1997, 9, 339.

116.

Synthesis and Reactivity of 16-Electron Hafnocene Silyl Hydride Complexes.  G. L. Casty, C. G. Lugmair, N. S. Radu, T. D. Tilley, J. F. Walzer, and D. Zargarian.  Organometallics 1997, 16, 8.

1996

115.

Tris(trimethylstannyl)silyl Complexes of Ruthenium and Platinum.  R. H. Heyn and T. D. Tilley.  Main Group Chem. 1996, 1, 415.

114.

Samarium-Mediated Redistribution of Silanes and formation of Trinuclear Samarium-Silicon Clusters.  N. S. Radu, F. J. Hollander, T. D. Tilley, and A. L. Rheingold.  J. Chem. Soc., Chem. Commun. 1996, 2459.

113.

Synthesis and Study of Cyclic π-Systems Containing Silicon and Germanium.  The Question of Aromaticity in Cyclopentadienyl Analogues.  W. P. Freeman, T. D. Tilley, L. M. Liable-Sands, and A. L. Rheingold.  J. Am. Chem. Soc. 1996, 118, 10457.

112.

Cross-Conjugated Polymers via Condensation of a Zirconocene Alkynyl(benzyne) Derivative Generated by Thermolysis of Cp2ZrMe(C6H4C≡CSiMe3).  S. S. H. Mao and T. D. Tilley.  J. Organomet. Chem. 1996, 521, 425.

111.

Polymers with Linked Macrocyclic Rings in the Main Chain.  Zirconocene Coupling of 1,8-Cyclotetradecadiyne.  S. S. H. Mao and T. D. Tilley.  Macromolecules 1996, 29, 6362.

110.

Low Band-Gap, σ-Conjugated Polymers: Poly(diarylstannanes).  V. Lu and T. D. Tilley. Macromolecules 1996, 29, 5763.

109.

Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Tanatalum.  X-ray Structure of (η5-C5Me5)[o-C6H4(NSiiPr3)2]TaCl2.  K. Aoyagi, P. K. Gantzel, and T. D. Tilley.  Polyhedron 1996, 15, 4299.

108.

Migrations in a Polysilyl Complex of Rhodium.  Trapping of an Apparent Silylene Intermediate and Observation of Reversible Si-Si Bond Reductive Elimination.  G. P. Mitchell and T. D. Tilley.  Organometallics 1996, 15, 3477.

107.

Neutral Lanthanide Silyl Complexes via σ-Bond Metathesis Reactions.  N. S. Radu, T. D. Tilley, and A. L. Rheingold.  J. Organomet. Chem. 1996, 516, 41.

106.

Silolyl Anions and Silole Dianions:  X-ray Structure of [K(18-Crown-6)+]2[C4Me4Si2-].  W. P. Freeman, T. D. Tilley, G. A. P. Yap, and A. L. Rheingold.  Angew. Chem. Int. Ed. Engl. 1996, 35, 882.

105.

Zirconocene Coupling of 1,8-Cyclotetradecadiyne to Polymers Containing Macrocyclic Rings in the Main Chain.  S. S. H. Mao and T. D. Tilley.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1996, 37(1), 443.

104.

Molecular and Polymer Precursor Routes to Manganese-Doped Zinc Orthosilicate Phosphors.  K. Su, T. D. Tilley, and M. J. Sailor.  J. Am. Chem. Soc. 1996, 118, 3459.

103.

Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium and Zirconium:  Investigation of a New Ancillary Ligand.  K. Aoyagi, P. K. Gantzel, K. Kalai, and T. D. Tilley.  Organometallics 1996, 15, 923.

102.

Cuprous Tris(tert-butoxy)siloxy Complexes and their Thermolytic Conversion to Copper-Silica and Copper Oxide-Silica Nanocomposites.  K. W. Terry, C. G. Lugmair, P. K. Gantzel, and T. D. Tilley.  Chem. Mater. 1996, 8, 274.

1995

101.

Polysilyl Group Isomerization via Migrations in Rhodium and Iridium Derivatives (Me3P)3MSi(SiMe3)3.  G. P. Mitchell, T. D. Tilley, G. P. A. Yap, and A. L. Rheingold.  Organometallics 1995, 14, 5472.

100.

Metal-Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular Weight Polystannanes.  T. Imori, V. Lu, H. Cai and T. D. Tilley.  J. Am. Chem. Soc. 1995, 117, 9931.

99.

Synthesis and Structure of a Free Germacyclopentadienide Anion: [Li(12-Crown-4)2]+[C4Me4GeSi(SiMe3)3]-.  W. P. Freeman, T. D. Tilley, F. P. Arnold, A. L. Rheingold and P. K. Gantzel.  Angew. Chem., Int. Ed. Engl. 1995, 34, 1887.

98.

Efficient, Zirconocene-Mediated Cyclotrimerization and Cyclotetramerization of Me3SiC≡CC6H4C6H4C≡CSiMe3 to Unsaturated Macrocycles.  S. S. H. Mao and T. Don Tilley.  J. Am. Chem. Soc. 1995, 117, 7031.

97.

Autocatalytic Mechanism for σ-Bond Metathesis Reactions of (η5-C5Me5)2SmCH(SiMe3)2 with Silicon-Hydrogen Bonds.  N. S. Radu and T. D. Tilley.  J. Am. Chem. Soc. 1995, 117, 5863.

96.

New Route to Unsaturated Organosilicon Polymers and Macrocycles Based on Zirconocene-Coupling of 1,4-MeC≡C(Me2Si)C6H4(SiMe2)C≡CMe.  S. S. H. Mao and T. Don Tilley.  J. Am. Chem. Soc. 1995, 117, 5365.

95.

Isolation of the First d0 Metalloxy Ketene Complexes via Double Insertion of Carbon Monoxide into Thorium-Silicon Bonds.  N. S. Radu, M. P. Engeler, C. P. Gerlach, and T. D. Tilley.  J. Am. Chem. Soc. 1995, 117, 3621.

94.

Synthetic, Structural, and Reactivity Studies with New Group 4 Transition-Metal Silyl Complexes. T. Imori, R. H. Heyn, T. D. Tilley, and A. L. Rheingold.  J. Organomet. Chem. 1995, 493, 83.

93.

Synthesis, Structure and Dynamic Studies on Base-Stabilized Silylene Complexes [(η5-C5Me5)(PMe3)2RuSiX2(NCMe)+]. S. K. Grumbine, D. A. Straus, T. D. Tilley, and A. L. Rheingold.  Polyhedron 1995, 14, 127.

1994

92.

Synthesis and Characterization of Transition Metal Silylene and Silylyne Complexes In Progress in Organosilicon Chemistry, B. Marciniec and J. Chojnowski, Eds.; Gordon and Breach Science Publishers: Langhorne, PA, 1994.  S. K. Grumbine and T. D. Tilley, p 133.

91.

The Influence of Catalyst Structure on the Dehydropolymerization of Phenylsilane. T. Imori and T. D. Tilley.  Polyhedron 1994, 13, 2231.

90.

Stable Silacyclopentadienyl Complexes of Ruthenium: (η5-C5Me5)Ru[η5-Me4C4Si-Si(SiMe3)3] and X-ray Structure of its Protonated Form. W. P. Freeman, T. D. Tilley, and A. L. Rheingold.  J. Am. Chem. Soc. 1994, 116, 8428.

89.

Transition Metal-Mediated Redistribution at Silicon: A Bimolecular Mechanism Involving Silylene Complexes. S. K. Grumbine and T. D. Tilley.  J. Am. Chem. Soc. 1994, 116, 6951.

88.

Base-Free Silylene Complexes Without π-Donor Stabilization.  Molecular Structure of [Cp*(PMe3)2Ru=SiMe2][B(C6F5)4]. S. K. Grumbine, T. D. Tilley, F. P. Arnold, and A. L. Rheingold.  J. Am. Chem. Soc. 1994, 116, 5495.

87.

Lanthanide-Tungsten Heterobimetallic Complexes via σ-Bond Metathesis. N. S. Radu, P. K. Gantzel, and T. D. Tilley.  J. Chem. Soc., Chem. Commun. 1994, 1175.

86.

Sigma-Bond Metathesis Reactions Involving Lanthanide-Silicon and Lanthanide-Hydrogen Bonds.  N. S. Radu and T. D. Tilley.  Phosphorus, Sulfur, and Silicon 1994, 87, 209.

85.

New Chemistry for Reactive Transition-Metal-Silicon Bonds In Organosilicon Chemistry: From Molecules to Materials, N. Auner and J. Weis, Eds.; VCH Publishers:  New York, 1994.  T. D. Tilley, p 225.

1993

84.

A Stable η5-Germacyclopentadienyl Complex: (η5-C5Me5)Ru[η5-C4Me4GeSi(SiMe3)3].  W. P. Freeman, T. D. Tilley, A. L. Rheingold and R. L. Ostrander.  Angew. Chem. Int. Ed. Engl. 1993, 32, 1744. 

83.

High Molecular Weight Polystannanes via Dehydropolymerization of Di(n-butyl)stannane.  T. Imori and T. D. Tilley.  J. Chem. Soc., Chem. Commun. 1993, 1607. 

82.

Disilanylenearylene Oligomers and Polymers from Dehydropolymerization of 1,4-RH2SiC6H4SiH2R (R = Methyl, Ethyl, and Hexyl).  T. Imori, H.-G. Woo, J. F. Walzer and T. D. Tilley.  Chem. Mater. 1993, 5, 1487. 

81.

A Fischer-Type Silylene Complex of Platinum:  [trans-(Cy3P)2(H)Pt=Si(SEt)2]BPh4.  S. D. Grumbine, T. D. Tilley, A. L. Rheingold, and F. P. Arnold.  J. Am. Chem. Soc. 1993, 115, 7884.

80.

Chromium(II) and Chromium(III) Tri-tert-butoxysiloxy Complexes.  K. W. Terry, P. K. Gantzel and T. D. Tilley.  Inorg. Chem. 1993, 32, 5402.

79.

Synthesis and Study of the Ruthenium Silene Complexes (η5-C5Me5)(PR3)RuH(η2-CH2=SiR'2) (R = iPr, Cy; R' = Me, Ph).  B. K. Campion, R. H. Heyn, T. D. Tilley and A. L. Rheingold.  J. Am. Chem. Soc. 1993, 115, 5527.

78.

Synthesis and Reactions of Silyl and Germyl Derivatives of Scandocene.  Structure of Cp2Sc[Si(SiMe3)3](THF).  B. K. Campion, R. H. Heyn and T. D. Tilley.  Organometallics 1993, 12, 2584.

77.

Synthesis and Structure of a Transition Metal-Substituted Silylene Complex, (CO)4OsSi(STol-p)[Ru(η5-C5Me5)(PMe3)2].  S. D. Grumbine, T. D. Tilley and A. L. Rheingold.  J. Am. Chem. Soc. 1993, 115, 358. 

76.

The Coordination Polymerization of Silanes to Polysilanes by a σ-Bond Metathesis Mechanism.  Implications for Linear Chain Growth.  T. D. Tilley.  Acc. Chem. Res. 1993, 26, 22. 

1992

75.

Low-Temperature Pyrolytic Transformations of Tri-tert-butoxysiloxy Derivatives of Aluminum to Aluminosilicate Materials.  K. W. Terry, P. K. Ganzel and T. D. Tilley.  Chem. Mater. 1992, 4, 1290.

74.

Silylene-Bridged Ruthenium Dimers via Reactions of [(η5-C5Me5)Ru(μ-OMe)]2 with Silanes.  Structure of {[(η5-C5Me5)Ru]2(μ-SiPhOMe)(μ-OMe)(μ-H)]}.  B. K. Campion, R. H. Heyn and T. D. Tilley.  Organometallics 1992, 11, 3918.

73.

Synthesis and Characterization of the Neutral Lanthanide Silyl Complexes (η5-C5Me5)2LnSiH(SiMe3)2 (Ln = Nd, Sm).  N. S. Radu, T. D. Tilley and A. L. Rheingold.  J. Am. Chem. Soc. 1992, 114, 8293.

72.

Transition Metal-Catalyzed Routes to Polysilane Polymers In Ultrastructure Processing of Advanced Materials, D. R. Uhlmann and D. R. Ulrich, Eds.; Wiley:  New York, 1992.  H.-G. Woo and T. D. Tilley.  Chap 56, p. 651-665.

71.

Ruthenium(IV) Silyl Hydride Complexes via Reaction of Silanes with 16-Electron (η5-C5Me5)Ru(PPri3)X (X = Cl, CH2SiHPh2, SiMePh2) Complexes.  Hydride Migrations to an η2-Silene Ligand.  B. K. Campion, R. H. Heyn and T. D. Tilley.  J. Chem. Soc., Chem. Commun. 1992, 1201.

70.

A σ-Bond Metathesis Mechanism for Dehydropolymerization of Silanes to Polysilanes by d0 Metal Catalysts.  H.-G. Woo, J. F. Walzer and T. D. Tilley.  J. Am. Chem. Soc. 1992, 114, 7047.

69.

σ-Bond Metathesis Reactions for d0 Metal-Silicon Bonds that Produce Zirconocene and Hafnocene Hydrosilyl Complexes.  H.-G. Woo, R. H. Heyn, and T. D. Tilley.  J. Am. Chem. Soc.1992, 114, 5698.

68.

Synthesis, Characterization and Reactivity of Triphenylsilyl, Triphenylgermyl, and Triphenylstannyl Derivatives of Zirconium and Hafnium.  H.-G. Woo, W. P. Freeman and T. D. Tilley.  Organometallics 1992, 11, 2198.

67.

Synthesis and Structure of [(η5-C5Me5)Ru(μ-NHPh)]2, an Electron-Deficient Ruthenium Amide Complex.  R. E. Blake, Jr., R. H. Heyn and T. D. Tilley. Polyhedron 1992, 11, 709.

66.

Design of Catalysts for the Dehydropolymerization of Silanes to Polysilanes.  T. D. Tilley, N. S. Radu, J. F. Walzer and H.-G. Woo.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1992, 33, 1237.

65.

Platinum-Mediated Reactions of Hydrosilanes.  Isolation of a Complex with Bridging Disilene and Silylene Ligands.  R. H. Heyn and T. D. Tilley.  J. Am. Chem. Soc. 1992, 114, 1917.

64.

Transition-Metal Complexes Containing Donor-Stabilized Silylyne Ligands.  Reductive Dimerization to a Silylene Complex.  S. D. Grumbine, R. K. Chadha and T. D. Tilley.  J. Am. Chem. Soc. 1992, 114, 1518. 

1991

63.

Dehydropolymerization of Bis- and Tris(silyl)arenes to Highly Cross-Linked Disilanylenearylene Polymers, Catalyzed by [(η5-C5H5)(η5-C5Me5)ZrH2]2.  H.-G. Woo, J. F. Walzer and T. D. Tilley.  Macromolecules 1991, 24, 6863.

62.

Trialkoxysiloxy Complexes as Precursors to MO2·4SiO2 (M = Ti, Zr, Hf) Materials.  K. W. Terry and T. D. Tilley.  Chem. Mater. 1991, 3, 1001.

61.

Transition-Metal Silyl Derivatives.  In The Silicon-Heteroatom Bond, S. Patai and Z. Rappoport, Eds.; Wiley:  New York, 1991.  T. D. Tilley.  Chaps 9 and 10, pp. 245 and 309. 

60.

Reactions of the Ruthenium Silylene Derivative [(η5-C5Me5)(PMe3)2RuSiPh2-(NCMe)]BPh4 with Alcohols, Ketones, and Acetic Acid.  C. Zhang, S. D. Grumbine and T. D. Tilley.  Polyhedron 1991, 10, 1173.

59.

Transition-Metal Complexes of Reactive Silicon Intermediates.  In Frontiers of Organosilicon Chemistry, A. R. Bassindale and P. P. Gaspar, Eds.; The Royal Society of Chemistry, Thomas Graham House:  Cambridge, 1991.  T. D. Tilley, B. K. Campion, S. D. Grumbine, D. A. Straus and R. H. Heyn, p. 295. 

58.

Catalytic Dehydrogenative Polymerization of Silanes to Polysilanes by Zirconocene and Hafnocene Catalysts.  A New Polymerization Mechanism.  In Inorganic and Organometallic Oligomers and Polymers, Proceedings of the 33rd IUPAC Symposium on Macromolecules, J. F. Harrod, R. M. Laine, Eds.; Kluwer Publishers, Amsterdam, Netherlands, 1991.  T. D. Tilley and H.-G. Woo, p 3.

57.

Approaches to High Molecular Weight Polysilanes via Dehydrogenative Coupling of Silanes.  J. F. Walzer, H.-G. Woo and T. D. Tilley.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1991, 32, 441.

56.

Structure of trans-{Pt[P(c-C6H11)3]2(H)(NCCH3)}[BPh4].  R. H. Heyn, S. D. Grumbine and T. D. Tilley.  Acta Cryst. Sect. C 1991, C47, 313. 

1990

55.

Silicon-Based Ligands. In 1991 McGraw-Hill Yearbook of Science and Technology; McGraw-Hill:  New York, 1990.  T. D. Tilley.  pp. 80-83.

54.

Carbon Dioxide Activation by a Transition Metal-Silicon Bond.  Formation of Silanecarboxylate Complexes [Cp2Sc(μ-O2CSiR3)]2.  B. K. Campion, R. H. Heyn and T. D. Tilley.  Inorg. Chem. 1990, 29, 4355.

53.

Base-Free Silylene Complexes [(η5-C5Me5)(PMe3)2Ru=Si(SR)2]BPh4 (R = Et, p-MeC6H4).  D. A. Straus, S. D. Grumbine and T. D. Tilley.  J. Am. Chem. Soc. 1990, 112, 7801.

52.

Preparation and Properties of Tris(trimethylstannyl)silyl Complexes of Chromium, Molybdenum, and Tungsten.  X-ray Structure of [NEt4][(CO)5WSi(SnMe3)3].  R. H. Heyn and T. D. Tilley.  Inorg. Chem. 1990, 29, 4051.

51.

Insertion of Nitriles and Pyridine into the Zr-Si Bond of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]Me.  H.-G. Woo and T. D. Tilley.  J. Organomet. Chem. 1990, 393, C6.

50.

Dehydrogenative Polymerization of Silanes by Sigma-Bond Metathesis.  T. D. Tilley and H.-G. Woo.  Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1990, 31, 228.

49.

Bis[bis(trimethylsilyl)amido]bis(diethyl ether)ytterbium and (Diethyl ether)bis(η5-pentamethylcyclopentadienyl)ytterbium.  T. D. Tilley, J. M. Boncella, D. J. Berg, C. J. Burns and R. A. Andersen.  Inorg. Synth. 1990, 27, 146. 

48.

Trialkoxysiloxy Complexes of Nickel.  Crystal and Molecular Structures of Na3(μ3-I){Ni[μ3-OSi(OtBu)3]3I}0.5THF·0.5C5H12 and {(η3-C3H5)Ni[μ2-OSi(OtBu)3]}2.  A. K. McMullen, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Inorg. Chem. 1990, 29, 2228.

47.

A Stable η2-Silene Complex of Iridium: (η5-C5Me5)(PMe3)Ir(η2-CH2=SiPh2).  B. K. Campion, R. H. Heyn and T. D. Tilley.  J. Am. Chem. Soc. 1990, 112, 4079. 

46.

Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions.  T. D. Tilley.  Comments Inorg. Chem. 1990, 10, 37. 

45.

Silyl and Diphenylsilylene Derivatives of (η5-C5Me5)(PMe3)2Ru.  Evidence for the Base-Free Silylene Complex [(η5-C5Me5)(PMe3)2Ru=SiPh2]+.  D. Straus, C. Zhang, G. E. Quimbita, S. D. Grumbine, R. H. Heyn, T. D. Tilley, A. L. Rheingold and S. J. Geib.  J. Am. Chem. Soc. 1990, 112, 2673. 

44.

Reactions of Alkynes with Coordinatively Unsaturated (η5-C5Me5)Ru Derivatives.  X-ray Crystal Structures of (η5-C5Me5)Cl2Ru(η2:η4-μ2-C4H4)Ru(η5-C5Me5) and (η5-C5Me5)3Ru3(μ2-Cl)2(μ3-Cl)(η2-μ2-HC≡CSiMe3).  B. K. Campion, R. H. Heyn and T. D. Tilley.  Organometallics  1990, 9, 1106. 

43.

Reactivity of a Sc-Si Bond Toward CO and CN(2,6-Me2C6H3).  Generation and Reactivity of an Apparent Silene Intermediate Resulting From Isocyanide Coupling at Scandium.  B. K. Campion, R. H. Heyn and T. D. Tilley.  J. Am. Chem. Soc. 1990, 112, 2011. 

1989

42.

Preparation and Characterization of the Monomeric Copper(II) Siloxide Complex Cu[OSi(OCMe3)3]2(pyr)2.  A. K. McMullen, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Inorg. Chem. 1989, 28, 3772. 

41.

Dehydrogenative Polymerization of Silanes to Polysilanes by Zirconocene and Hafnocene Catalysts.  A New Polymerization Mechanism.  H.-G. Woo and T. D. Tilley.  J. Am. Chem. Soc. 1989, 111, 8043.

40.

Insertion of Ethylene into Zr-Si and Hf-Si Bonds.  J. Arnold, M. P. Engeler, F. H. Elsner,  R. H. Heyn and T. D. Tilley.  Organometallics 1989, 8, 2284. 

39.

Trityl Tetraphenylborate as a Reagent in Organometallic Chemistry.  D. A. Straus, C. Zhang and T. D. Tilley.  J. Organomet. Chem. 1989, 369, C13. 

38.

Alkoxy and Aryloxy Derivatives of (Pentamethylcyclopentadienyl)ruthenium.  X-ray Crystal Structures of [(η5-C5Me5)Ru(μ-OMe)]2, [(η5-C5Me5)(CO)Ru(μ-OEt)]2, and (η5-C5Me5)Ru(η5-2,6-tBu2C6H3O), and Molecular Orbital Analysis of [(η5-C5H5)Ru(μ-OMe)]2.  S. D. Loren, B. K. Campion, R. H. Heyn, T. D. Tilley, B. E. Bursten and K. W. Luth.  J. Am. Chem. Soc. 1989, 111, 4712. 

37.

Tris(trimethylsilyl)silyl Derivatives of Tri(tert-butoxy)zirconium and -Hafnium.  X-ray Crystal Structure of (Me3CO)3ZrSi(SiMe3)3.  R. H. Heyn and T. D. Tilley.  Inorg. Chem. 1989, 28, 1768.

36.

σ-Bond Metathesis Reactions of Si-H and M-Si Bonds.  New Routes to d0 Metal Silyl Complexes.  H.-G. Woo and T. D. Tilley.  J. Am. Chem. Soc. 1989, 111, 3757.

35.

Dimesitylsilyl Derivatives of Zirconium.  D. M. Roddick, R. H. Heyn and T. D. Tilley.  Organometallics 1989, 8, 324.

34.

Carbonylation Chemistry of the Tantalum Silyl (η5-C5Me5)Cl3TaSiMe3.  Synthesis, Characterization, and Reaction Chemistry of (η5-C5Me5)Cl3Ta(η2-COSiMe3) and Derivatives.  J. Arnold, T. D. Tilley, A. L. Rheingold, S. J. Geib and A. M. Arif.  J. Am. Chem. Soc. 1989, 111, 149. 

33.

Transition-Metal Silyl Derivatives.  In The Chemistry of Organic Silicon Compounds, S. Patai and Z. Rappoport, Eds.; Wiley: New York, 1989.  T. D. Tilley.  Chap 24, p. 1415.

1988

32.

Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X = Cl, Me) Complexes with Carbon Monoxide and the Isocyanide 2,6-Me2C6H3NC.  Crystal Structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl.  F. H. Elsner, T. D. Tilley, A. L. Rheingold and S. J. Geib.  J. Organomet. Chem. 1988, 358, 169. 

31.

Preparation, Isolation and Characterization of Transition-Metal η2-Silene Complexes.  X-ray Crystal Structure of (η5-C5Me5)[P(i-Pr)3]Ru(H)(η2-CH2SiPh2).  B. K. Campion, R. H. Heyn and T. D. Tilley.  J. Am. Chem. Soc. 1988, 110, 7558.

30.

Preparation and Characterization of Tris(trimethylsilyl)silyl and Tris(trimethylsilyl)germyl Derivatives of Zirconium and Hafnium.  X-ray Crystal Structures of (η5-C5Me5)Cl2HfSi(SiMe3)3 and (η5-C5Me5)Cl2HfGe(SiMe3)3.  J. Arnold, D. M. Roddick, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Inorg. Chem. 1988, 27, 3510.

29.

Surface Modification of Matrix Materials for Oxidation-Resistant Carbon-Carbon Composites.  In Ultrastructure Processing of Advanced Ceramics, J. A. Mackenzie and D. R. Ulrich, Eds.; Wiley: New York, 1988. H. Streckert, F. Montgomery, T. D. Tilley, B. K. Campion and R. H. Heyn.  Chap 79, p. 963. 

28.

Reaction of an Early Transition-Metal η2-Silaacyl Complex with Pyridine.  Diastereoselectivity in the Formation of a (2-Pyridyl)(silyl)methoxy Ligand.  J. Arnold, H.-G. Woo, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Organometallics 1988, 7, 2045. 

27.

Preparation and Reactivity of 16-Electron Half-Sandwich Ruthenium Complexes; X-ray Crystal Structure of (η5-C5Me5)Ru(PiPr3)Cl.  B. K. Campion, R. H. Heyn and T. D. Tilley.  J. Chem. Soc., Chem. Commun. 1988, 278. 

26.

Preparation of the First Stable Formylsilane, (Me3Si)3SiCHO, from a Zirconium η2-Silaacyl Complex.  F. H. Elsner, H.-G. Woo and T. D. Tilley.  J. Am. Chem. Soc. 1988, 110, 313.

1987

25.

Preparation, Characterization and X-ray Crystal Structure of an Acetonitrile-Complexed Ruthenium Silylene.  D. A. Straus, T. D. Tilley, A. L. Rheingold and S. J. Geib.  J. Am. Chem. Soc. 1987, 109, 5872.

24.

An Arbuzov-like Reaction in the Trimethylphosphite-η2-Silaacyl Adduct (η5-C5Me5)Cl3Ta{η2-OC(SiMe3)[P(OMe)3]}.  J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Inorg. Chem. 1987, 26, 2556.

23.

Preparation and Characterization of Tris(trimethylsilyl)silyl Derivatives of Zinc, Cadmium and Mercury.  X-ray Crystal Structure of Zn[Si(SiMe3)3]2.  J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Inorg. Chem. 1987, 26, 2106.

22.

Formation of the Novel Benzophenone Sila-acylhydrazonato Complex (η5-C5Me5)Cl3Ta[OC(SiMe3)NNCPh2] Following Addition of Diphenyldiazomethane to an η2-Sila-acyl Ligand.  J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib.  J. Chem. Soc., Chem. Commun. 1987, 793.

21.

Insertion of Organic Carbonyls into the Tantalum-Silicon Bond of (η5-C5Me5)Cl3TaSiMe3.  Preparation and Characterization of the α-Silylalkoxides (η5-C5Me5)Cl3TaOCRR'SiMe3.  J. Arnold and T. D. Tilley.  J. Am. Chem. Soc. 1987, 109, 3318.

20.

Reactions of Carbon Monoxide with Trimethylsilyl and Tris(trimethylsilyl)silyl Derivatives of Group 4 Metals.  Synthesis, Characterization, and Reactivity of Silaacyl Complexes.  B. K. Campion, J. Falk and T. D. Tilley.  J. Am. Chem. Soc. 1987, 109, 2049.

19.

Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Niobium.  Redox Chemistry of (η5-C5H5)2Nb(SiMe3)Cl and X-ray Structures of (η5-C5H5)2Nb(SiMe3)(η2-C2H4) and [(η5-C5H5)2Nb(CH2SiMe3)Cl]PF6.  J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib.  Organometallics  1987, 6, 473.

18.

Coordinatively Unsaturated Tris(trimethylsilyl)silyl Complexes of Chromium, Manganese and Iron.  D. M. Roddick, T. D. Tilley, A. L. Rheingold and S. J. Geib.  J. Am. Chem. Soc. 1987, 109, 945.

1986

17.

Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum.  X-ray Structures of d0 (η5-C5Me5)Ta(SiMe3)Cl3 and d1 (η5-C5Me5)Ta(SiMe3)(PMe3)Cl2.  J. Arnold, D. N. Shina, T. D. Tilley and A. M. Arif.  Organometallics 1986, 5, 2037.

16.

Tetrahedral Lewis Base Adducts of an Acyl.  Preparation and X-ray Structure of the Pyridine Adduct (η5-C5Me5)Cl3Ta[η2-OC(SiMe3)(NC5H5)].  J. Arnold, T. D. Tilley and A. L. Rheingold.  J. Am. Chem. Soc. 1986, 108, 5355.

1985

15.

Ether Cleavage Following Insertion of Carbon Monoxide into the Tantalum-Silicon Bond of (η5-C5Me5)Ta(SiMe3)Cl3.  J. Arnold and T. D. Tilley.  J. Am. Chem. Soc. 1985, 107, 6409.

14.

Trimethylsilyl Derivatives of Bis(cyclopentadienyl)zirconium and -hafnium.  Crystal Structure of (η5-C5H5)2Zr(SiMe3)(S2CNEt2).  T. D. Tilley.  Organometallics 1985, 4, 1452.

13.

Insertion of Carbon Monoxide into a Transition-Metal-Silicon Bond.  X-ray Structure of the Silaacyl (η5-C5H5)2Zr(η2-COSiMe3)Cl.  T. D. Tilley.  J. Am. Chem. Soc. 1985, 107, 4084.

1984

12.

Divalent Lanthanide Chemistry.  Preparation and Crystal Structures of Sodium Tris[bis(trimethylsilyl)amido]europate(II) and Sodium Tris[bis(trimethylsilyl)amido]-ytterbate(II), NaM[N(SiMe3)2]3.  T. D. Tilley, R. A. Andersen and A. Zalkin.  Inorg. Chem. 1984, 23, 2271.