CONSULTANCY  —  SOLUTION AND SOLID-STATE NMR

20 years of experience in both Academia and Industry

NEWS!

New Homonuclear Decoupling Processing Method

Simplify your proton spectra for easier interpretation  

If you have access to two NMR spectrometers at different fields, you can try the processing method described in https://doi.org/10.26434/chemrxiv-2024-r9tgw  

US Copyright Office Registration Number: TXu 2-432-842 

Request a Python script and a GUI to perform synthetic homonuclear decoupling yourself!

pilotnmr@gmail.com

Publications

On Bloch-Siegert effects in MAS NMR of spin-3/2 nuclei: quasi-isotropic 1D spectra. DOI: 10.26434/chemrxiv-2025-st1bt 

Equivalence between synthetic decoupling and 2-field autocorrelation NMR spectroscopy. DOI: 10.26434/chemrxiv-2025-g4pqn 

Bloch-Siegert shifted correlations in solution NMR spectroscopy. DOI: 10.26434/chemrxiv-2024-xfn7g.

Picking and sorting single-transition NMR lines at two fields: unveiling the pure-shift information. DOI: https://doi.org/10.26434/chemrxiv-2024-r9tgw.

Effects of Microwave Gating on Transverse Relaxation Rates Monitored by Nuclear Spin Echoes in Dynamic Nuclear Polarization. J. Phys. Chem. Lett. 2022, 13, 175–182; DOI: 10.1021/acs.jpclett.1c03436.

Nitrogen-14 NMR Spectroscopy, Book Chapter: Comprehensive Inorganic Chemistry III ­– Elsevier. DOI: 10.1016/B978-0-12-823144-9.00019-4.

Natural Abundance Oxygen-17 Solid-State NMR of Metal Organic Frameworks Enhanced by Dynamic Nuclear Polarization, Phys. Chem. Chem. Phys. 2021, 23, 2245–2251; DOI: 10.1039/d0cp06064j.

Spin Thermometry: A Straightforward Measure of Millikelvin Deuterium Spin Temperatures Achieved by Dynamic Nuclear Polarization, J. Phys. Chem. Lett. 2020, 11, 9, 3219–3225; DOI: 10.1021/acs.jpclett.0c00713.

Self‐Assembly of DNA and RNA Building Blocks Explored by Nitrogen‐14 NMR Crystallography: Structure and Dynamics. Chem. Phys. Chem. 2020, 21, 10, 1044–1051; DOI: 10.1002/cphc.201901214.

Orientation-dependent proton relaxation of water molecules trapped in solids: crystallites with long-lived magnetization. J. Phys. Chem. A 2019, 123, 9763−9769; DOI: 10.1021/acs.jpca.9b07303.

Cross-term Splittings Due to the Orientational Inequivalence of Proton Magnetic Shielding Tensors: Do protons of trapped water molecules hop or tunnel? J. Phys. Chem. Lett. 2019, 10, 3224–3231; DOI: 10.1021/acs.jpclett.9b00914.

Dipolar couplings in solid polypeptides probed by 14N NMR spectroscopy. Commun. Chem. 2018, 1:73; DOI: 10.1038/s42004-018-0072-5.

Double cross polarization for the indirect detection of nitrogen-14 nuclei in magic angle spinning NMR spectroscopy. J. Chem. Phys. 2017, 147, 18421; DOI: 10.1063/1.5000689.

Columnar self-assembly of benzene-1,3,5-tricarboxamides investigated by means of NMR spectroscopy and computational methods in solution and solid state. Phys. Chem. Chem. Phys. 2017, 19, 5525–5539; DOI: 10.1039/c6cp05598b.

Exciting wide NMR spectra of static solid samples with weak radiofrequency fields. Zeitschrift für Physikalische Chemie 2017, 231, 3, 527–543; DOI: 10.1515/zpch-2016-0808.

 Homonuclear decoupling for spectral simplification of carbon-13 enriched molecules in solution-state NMR enhanced by dissolution DNP. Phys. Chem. Chem. Phys. 2016, 18, 11480–11487; DOI: 10.1039/c5cp07884a.

NMR Spectroscopy and DFT Calculations of a Self-Assembled Arene Ruthenium Rectangle Obtained from a Combination of Coordination and Hydrogen Bonds. Dalton Trans. 2016, 45, 1410–1421; DOI: 10.1039/C5DT04179A.

Solid-state NMR measurements and DFT calculations of the magnetic shielding tensors of protons of water trapped in barium chlorate monohydrate. RSC Adv. 2014, 4, 56248–56258; DOI: 10.1039/c4ra09992c.

Solid-state carbon-13 NMR and computational characterization of the N719 ruthenium sensitizer adsorbed on TiO2 nanoparticles. Dalton Trans. 2014, 43, 6389–6395; DOI:10.1039/C3DT52543K.

Solid-state proton NMR of paramagnetic metal complexes: DANTE spin echoes for selective excitation in inhomogeneously broadened lines. Chem. Phys. Lett. 2013, 580, 172–178; dx.doi.org/10.1016/j.cplett.2013.06.052.

Broadband Excitation in Solid-State NMR of Paramagnetic Samples using Delays Alternating with Nutation for Tailored Excitation. Chem. Phys. Lett. 2012, 553, 68–76; DOI: 10.1016/j.cplett.2012.09.056.

Polychromatic Decoupling of a Manifold of Homonuclear Scalar Interactions in Solution-State NMR. Chem. Eur. J. 2012, 18, 11573–11576; DOI: 10.1002/chem.201200481.

Composite pulses for efficient excitation of the central transition of half-integer quadrupolar nuclei in NMR of static and spinning solid samples. Chem. Phys. Lett. 2012, 530, 120–125; DOI: 10.1016/j.cplett.2012.01.058.