Paint is a material or mixture that, after applied to a solid material and allowed to dry, adds a film-like layer. As art, this is used to create an image, known as a painting. Paint can be made in many colors and types. Most paints are either oil-based or water-based, and each has distinct characteristics.
It is illegal in most municipalities to discard oil-based paint down household drains or sewers.[citation needed] Clean-up solvents are also different for water-based paint than oil-based paint.[3] Water-based paints and oil-based paints will cure differently based on the outside ambient temperature of the object being painted (such as a house). Usually, the object being painted must be over 10 C (50 F), although some manufacturers of external paints/primers claim they can be applied when temperatures are as low as 2 C (35 F).[4]
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Paint was one of the earliest arts of humanity. Some cave paintings drawn with red or yellow ochre, hematite, manganese oxide, and charcoal may have been made by early Homo sapiens as long as 40,000 years ago.[5] Paint may be even older. In 2003 and 2004, South African archeologists reported finds in Blombos Cave of a 100,000-year-old human-made ochre-based mixture that could have been used like paint.[6][7] Further excavation in the same cave resulted in the 2011 report of a complete toolkit for grinding pigments and making a primitive paint-like substance.[7][8]
Interior walls at the 5,000-year-old Ness of Brodgar have been found to incorporate individual stones painted in yellows, reds, and oranges, using ochre pigment made of haematite mixed with animal fat, milk or eggs.[9][10]
Ancient colored walls at Dendera, Egypt, which were exposed for years to the elements, still possess their brilliant color, as vivid as when they were painted about 2,000 years ago. The Egyptians mixed their colors with a gummy substance and applied them separately from each other without any blending or mixture. They appear to have used six colors: white, black, blue, red, yellow, and green. They first covered the area entirely with white, then traced the design in black, leaving out the lights of the ground color. They used minium for red, generally of a dark tinge.[citation needed]
In the 13th century, oil was used to detail tempera paintings. In the 14th century, Cennino Cennini described a painting technique utilizing tempera painting covered by light layers of oil. The slow-drying properties of organic oils were commonly known to early European painters. However, the difficulty in acquiring and working the materials meant that they were rarely used (and indeed, the slow drying was seen as a disadvantage[12]). The paint was made with the yolk of eggs, and therefore, the substance would harden and adhere to the surface it was applied to. The pigment was made from plants, sand, and different soils. Most paints use either oil or water as a base (the diluent, solvent, or vehicle for the pigment).
The Flemish-trained or influenced Antonello da Messina, who Vasari wrongly credited with the introduction of oil paint to Italy,[13] does seem to have improved the formula by adding litharge, or lead (II) oxide. A still extant example of 17th-century house oil painting is Ham House in Surrey, England, where a primer was used along with several undercoats and an elaborate decorative overcoat; the pigment and oil mixture would have been ground into a paste with a mortar and pestle. The painters did the process by hand, which exposed them to lead poisoning due to the white-lead powder.
In 1718, Marshall Smith invented a "Machine or Engine for the Grinding of Colours" in England. It is not known precisely how it operated, but it was a device that dramatically increased the efficiency of pigment grinding. Soon, a company called Emerton and Manby was advertising exceptionally low-priced paints that had been ground with labor-saving technology:
By the proper onset of the Industrial Revolution, in the mid-18th century, paint was being ground in steam-powered mills, and an alternative to lead-based pigments had been found in a white derivative of zinc oxide. Interior house painting increasingly became the norm as the 19th century progressed, both for decorative reasons and because the paint was effective in preventing the walls rotting from damp. Linseed oil was also increasingly used as an inexpensive binder.
In the 21st century, "paints" that used structural color were created. Aluminum flakes dotted with smaller aluminum nanoparticles could be tuned to produce arbitrary colors by adjusting the nanoparticle sizes rather than picking/mixing minerals to do so. These paints weighed a tiny fraction of the weight of conventional paints, a particular advantage in air and road vehicles. They reflect heat from sunlight and do not break down outdoors. Preliminary experiments suggest it can reduce temperatures by 20 to 30 degrees Fahrenheit vs conventional paint. Its constituents are also less toxic.[15]
The vehicle is composed of binder; if it is necessary to thin it with a diluent like solvent or water, it is a combination of binder and diluent.[16][17] In this case, once the paint has dried or cured very nearly all of the diluent has evaporated and only the binder is left on the coated surface. Thus, an important quantity in coatings formulation is the "vehicle solids", sometimes called the "resin solids" of the formula. This is the proportion of the wet coating weight that is binder, i.e., the polymer backbone of the film that will remain after drying or curing is complete. The volume of paint after it has dried, therefore only leaving the solids, is expressed as the volume solid.
The binder is the film-forming component of paint.[18] It is the only component that is always present among all the various types of formulations. Many binders must be thick enough to be applied and thinned. The type of thinner, if present, varies with the binder.
The paint type known as Emulsion in the UK and Latex in the United States is a water-borne dispersion of sub-micrometer polymer particles. These terms in their respective countries cover all paints that use synthetic polymers such as acrylic, vinyl acrylic (PVA), styrene acrylic, etc. as binders.[21] The term "latex" in the context of paint in the United States simply means an aqueous dispersion; latex rubber from the rubber tree is not an ingredient. These dispersions are prepared by emulsion polymerization. Such paints cure by a process called coalescence where first the water and then the trace, or coalescing, solvent, evaporate and draw together and soften the binder particles and fuse them together into irreversibly bound networked structures, so that the paint cannot redissolve in the solvent/water that originally carried it. The residual surfactants in paint, as well as hydrolytic effects with some polymers cause the paint to remain susceptible to softening and, over time, degradation by water. The general term of latex paint is usually used in the United States, while the term emulsion paint is used for the same products in the UK, and the term latex paint is not used at all.
Recent environmental requirements restrict the use of volatile organic compounds (VOCs), and alternative means of curing have been developed, generally for industrial purposes. UV curing paints, for example, enable formulation with very low amounts of solvent, or even none at all. This can be achieved because of the monomers and oligomers used in the coating have relatively very low molecular weight, and are therefore low enough in viscosity to enable good fluid flow without the need for additional thinner. If solvent is present in significant amounts, generally it is mostly evaporated first and then crosslinking is initiated by ultraviolet light. Similarly, powder coatings contain no solvent. Flow and cure are produced by the heating of the substrate after electrostatic application of the dry powder.[24]
So-called "catalyzed" lacquers" or "crosslinking latex" coatings are designed to form films by a combination of methods: classic drying plus a curing reaction that benefits from the catalyst. There are paints called plastisols/organosols, which are made by blending PVC granules with a plasticiser. These are stoved and the mix coalesces.
Solvent-borne, also called oil-based, paints can have various combinations of organic solvents as the diluent, including aliphatics, aromatics, alcohols, ketones and white spirit. Specific examples are organic solvents such as petroleum distillate, esters, glycol ethers, and the like. Sometimes volatile low-molecular weight synthetic resins also serve as diluents.
Pigments are solid particles or flakes incorporated in the paint, usually to contribute color to the paint film. Pigments impart color by selective absorption of certain wavelengths of light and/or by scattering or reflecting light. The particle size of the pigment is critical to the light-scattering mechanism. The size of such particles can be measured with a Hegman gauge. Dyes, on the other hand, are dissolve in the paint and impart color only by the selective absorption mechanism. [25] Paints can be formulated with only pigments, only dyes, both, or neither.
Pigments can also be used to give the paint special physical or optical properties, as opposed to imparting color, in which case they are called functional pigments.[26] Fillers or extenders are an important class of the functional pigments. These are typically used to build film thickness and/or reduce the cost of the paint, or they can impart toughness and texture to the film. [27] Fillers are usually cheap and inert materials, such as diatomaceous earth, talc, lime, barytes, clay, etc. Floor paints that must resist abrasion may contain fine quartz sand as a filler.
Sometimes, a single pigment can serve both decorative and functional purposes. For example some decorative pigments protect the substrate from the harmful effects of ultraviolet light by making the paint opaque to these wavelengths, i.e. by selectively absorbing them. These hiding pigments include titanium dioxide, phthalo blue, red iron oxide, and many others. 0852c4b9a8
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