We are often expected to know who everyone is
Try to early on at least know the Heads of Department or which department the crew belong to.
The cast are a little easier as there is usually less of them
You'll soon get to know about peoples medical conditions and history
If you need to interact with cast, high profile members will usually have a PA
Be visible (but stay hidden)
People need to know you are there, and where you are based
On larger sets or locations, take a walk around every hour or so
Stay well away from the Camera line or technical work area, don't go into indoor sets unless your asked