Characterize solid/liquid materials by terahertz time-domain spectroscopy (THz-TDS)
Characterize solid/sheet/liquid materials by network analyzer in frequency domain, including
Waveguide systems (X band, Ka band, W band) with transmission/reflection method
Coaxial systems with transmission/reflection method
Open-type probing systems with reflection methods
Develop algorithms for retrieving isotropic refractive index, permittivity and permeability
Develop algorithms for retrieving anisotropic permeability tensor, saturation magnetization, and magnetic linewidth
During 2009-2016 (my B.S.-Ph.D. student life) and 2018-2022 (my postdoc career) in National Tsing Hua University, I cooperated with Prof. Tsun-Hsu Change to develop a series of microwave/THz spectroscopic systems (listed above) for characterizing high-frequency electric and magnetic properties of samples in different phases. Firstly, we built up three rectangular waveguide systems (X, Ka, and W bands) for characterizing the complex permittivity of bulky materials at 8-12.5 GHz, 26.5-40 GHz, and 75-110 GHz, respectively. Since the retrieval algorithm based on the measured scattering parameters have well developed, those systems promise very stable and accurate data that are important for device designs for 5G-6G communication. Those systems therefore show great opportunity of industry-academy cooperation (ex: MediaTek Inc. and JSR Corporation, etc.). In additional to the commercial/industrial applications, we also employed these techniques to characterize the electrical properties of newly-developed functional nanocomposites, such as high-index BaTiO3-epoxy nanocomposites, superparamagnetic ferrite-epoxy nanocomposites, and diamagnetic Ag-epoxy nanocomposites. Those works have been respectively published in “Polymers” (Polymers 13, 1391 (2021)), “Scientific Reports” (Sci. Rep. 11, 3288 (2021)), and “Applied Physics Letters” (Appl. Phys. Lett. 116, 202904 (2020)).
During 2018-2020, we modified the traditional three-section rectangular waveguide system for characterizing the anisotropic ferrimagnetism of magnetite at microwave regime. A rigorous retrieval procedure was proposed, which utilizes both the advantages of transmission/reflection method (broadband) and resonant method (sensitive) to accurately determine the permittivity, saturation magnetization, and magnetic linewidth of ferrite materials. The theoretical model and experimental results were respectively published in “Progress in Electromagnetics Research C” (Prog. Electromagn. Res. C 90, 195-208 (2019)) and “The Journal of Magnetism and Magnetic Materials” (J. Magn. Magn. Mater. 505, 166712 (2020)).
Since the aforementioned dielectric characterization schemes all suffer from the difficulties in sample preparation and loading for measurement. Those troublesome processes lead to low-efficiency and high-uncertainty characterization and might even raise the risk of sample damage. In 2020-2021, we developed a fast and non-destructive dielectric characterization system at 31-35 GHz. By the aid of the highly-confined nature of the fringing field of the TE01 mode at a cylindrical waveguide open end, we can directly probe the sheeted samples and retrieve their local complex permittivity. The retrieved data of near ten kinds of polymers (such as Teflon, PP, PE, FR4, etc.) have been reported in “Polymers” (Polymers 12, 1891 (2020).). Unimicron Technology Corporation is highly interested in this technique for the quality control in their PCB production.
In addition to the waveguide systems whose allowed bandwidth is usually limited by the operating mode’s cutoff, since 2020, we tried to develop several coaxial-type systems for broadband characterization from 0.1-20 GHz and 0.1-40 GHz. Very different from the commercial coaxial probe, a full-coaxial scheme and a coaxial-to-circular cutoff junction were designed, which can greatly reduce the required amount of sample. Broadband dielectric data of liquids can facilitate the investigation their underlying molecular relaxation processes and the interaction/correlation between molecules. In 2021, we used this system to characterize the broadband dielectric spectrums of common alcohols, acids, and their binary mixtures. By fitting with proper relaxation models, we clearly observed different types of the heterogeneous dipole-dipole interaction between ethanol and four acid molecules. In 2022, these findings have been published in a high-impact journal: “Journal of Molecular Liquids” (J. Mol. Liq. 353, 118755 (2022)).