Selection of the Alloy Steel
Before heat treatment, the type of alloy steel is chosen based on the required mechanical properties (e.g., hardness, toughness, wear resistance). Common alloying elements include:
Chromium (Cr) – Improves hardness and wear resistance
Nickel (Ni) – Enhances toughness
Molybdenum (Mo) – Strengthens the material and enhances heat resistance
Vanadium (V) – Refines grain size for better toughness
Cleaning: Remove contaminants like oil, dirt, or rust that could affect heating uniformity.
Fixturing: If necessary, use jigs or fixtures to prevent distortion.
Atmosphere Control: Use inert gas, vacuum, or controlled atmospheres (e.g., nitrogen, endothermic gas) to prevent oxidation and decarburization.
The steel is heated to a temperature where its structure transforms into austenite, typically 1500–1900°F (815–1038°C) depending on the alloy composition.
Rate of Heating: A gradual increase in temperature helps prevent thermal shock and cracking.
Soaking Time: The steel is held at the target temperature long enough for uniform transformation (~30 minutes per inch of thickness).
Quenching rapidly cools the steel to prevent the formation of soft microstructures. The choice of quenching medium depends on the desired hardness and the risk of cracking:
Water Quenching – Fastest cooling; high hardness but high risk of distortion/cracking.
Oil Quenching – Moderately fast; balances hardness and toughness.
Polymer Quenching – Intermediate cooling rate; used for complex geometries.
Air Cooling – Slowest; used for alloys that harden sufficiently without rapid quenching.
During quenching, the microstructure transforms into martensite (a very hard phase). However, as-quenched martensite is brittle and requires further treatment.
Normalizing
Annealing vs. Tempering
After quenching, the steel is reheated to a lower temperature (300–1300°F or 150–700°C) and held for a specific time to reduce brittleness while maintaining strength.
Low-Temperature Tempering (300–500°F / 150–260°C): Retains hardness, commonly used for tools.
Medium-Temperature Tempering (500–800°F / 260–427°C): Balances strength and toughness, suitable for structural steels.
High-Temperature Tempering (800–1300°F / 427–700°C): Maximizes toughness, often used for gears and shafts.
Depending on the application, the steel may undergo further treatments:
Cryogenic Treatment: Deep freezing to -300°F (-185°C) to transform retained austenite into martensite, improving wear resistance.
Surface Hardening: Methods like carburizing, nitriding, or induction hardening create a hard outer layer while keeping the core tough.
Stress Relieving: A lower-temperature heat treatment (900–1250°F or 480–675°C) used to reduce internal stresses without affecting hardness significantly.