The first He-Ne lasers emitted infrared at 1150 nm, and were the first gas lasers and the first lasers with continuous wave output. However, a laser that operated at visible wavelengths was much more in demand, and a number of other neon transitions were investigated to identify ones in which a population inversion can be achieved. The 633 nm line was found to have the highest gain in the visible spectrum, making this the wavelength of choice for most He-Ne lasers. However, other visible and infrared stimulated-emission wavelengths are possible, and by using mirror coatings with their peak reflectance at these other wavelengths; He-Ne lasers could be engineered to employ those transitions, including visible lasers appearing red, orange, yellow, and green.[1] Stimulated emissions are known from over 100 μm in the far infrared to 540 nm in the visible.

Because visible transitions have somewhat lower gain, these lasers generally have lower output efficiencies and are more costly. The 3.39 μm transition has a very high gain, but is prevented from use in an ordinary He-Ne laser (of a different intended wavelength) because the cavity and mirrors are lossy at that wavelength. However, in high-power He-Ne lasers having a particularly long cavity, superluminescence at 3.39 μm can become a nuisance, robbing power from the stimulated emission medium, often requiring additional suppression.




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