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A battery is a source of electric power consisting of one or more electrochemical cells with external connections[1] for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode.[2] The terminal marked negative is the source of electrons that will flow through an external electric circuit to the positive terminal. When a battery is connected to an external electric load, a redox reaction converts high-energy reactants to lower-energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell.[3]

Batteries come in many shapes and sizes, from miniature cells used to power hearing aids and wristwatches to, at the largest extreme, huge battery banks the size of rooms that provide standby or emergency power for telephone exchanges and computer data centers. Batteries have much lower specific energy (energy per unit mass) than common fuels such as gasoline. In automobiles, this is somewhat offset by the higher efficiency of electric motors in converting electrical energy to mechanical work, compared to combustion engines.

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Benjamin Franklin first used the term "battery" in 1749 when he was doing experiments with electricity using a set of linked Leyden jar capacitors. [4] Franklin grouped a number of the jars into what he described as a "battery", using the military term for weapons functioning together. [5] By multiplying the number of holding vessels, a stronger charge could be stored, and more power would be available on discharge.

Italian physicist Alessandro Volta built and described the first electrochemical battery, the voltaic pile, in 1800.[6] This was a stack of copper and zinc plates, separated by brine-soaked paper disks, that could produce a steady current for a considerable length of time. Volta did not understand that the voltage was due to chemical reactions. He thought that his cells were an inexhaustible source of energy,[7] and that the associated corrosion effects at the electrodes were a mere nuisance, rather than an unavoidable consequence of their operation, as Michael Faraday showed in 1834.[8]

Batteries in vacuum tube devices historically used a wet cell for the "A" battery (to provide power to the filament) and a dry cell for the "B" battery (to provide the plate voltage).[citation needed]

Between 2010 and 2018, annual battery demand grew by 30%, reaching a total of 180 GWh in 2018. Conservatively, the growth rate is expected to be maintained at an estimated 25%, culminating in demand reaching 2600 GWh in 2030. In addition, cost reductions are expected to further increase the demand to as much as 3562 GWh.[13]

Important reasons for this high rate of growth of the electric battery industry include the electrification of transport,[13] and large-scale deployment in electricity grids,[13] supported by anthropogenic climate change-driven moves away from fossil-fuel combusted energy sources to cleaner, renewable sources, and more stringent emission regimes.

A battery consists of some number of voltaic cells. Each cell consists of two half-cells connected in series by a conductive electrolyte containing metal cations. One half-cell includes electrolyte and the negative electrode, the electrode to which anions (negatively charged ions) migrate; the other half-cell includes electrolyte and the positive electrode, to which cations (positively charged ions) migrate. Cations are reduced (electrons are added) at the cathode, while metal atoms are oxidized (electrons are removed) at the anode.[18] Some cells use different electrolytes for each half-cell; then a separator is used to prevent mixing of the electrolytes while allowing ions to flow between half-cells to complete the electrical circuit.

A reserve battery can be stored unassembled (unactivated and supplying no power) for a long period (perhaps years). When the battery is needed, then it is assembled (e.g., by adding electrolyte); once assembled, the battery is charged and ready to work. For example, a battery for an electronic artillery fuze might be activated by the impact of firing a gun. The acceleration breaks a capsule of electrolyte that activates the battery and powers the fuze's circuits. Reserve batteries are usually designed for a short service life (seconds or minutes) after long storage (years). A water-activated battery for oceanographic instruments or military applications becomes activated on immersion in water.

On 28 February 2017, the University of Texas at Austin issued a press release about a new type of solid-state battery, developed by a team led by lithium-ion battery inventor John Goodenough, "that could lead to safer, faster-charging, longer-lasting rechargeable batteries for handheld mobile devices, electric cars and stationary energy storage".[35] The solid-state battery is also said to have "three times the energy density", increasing its useful life in electric vehicles, for example. It should also be more ecologically sound since the technology uses less expensive, earth-friendly materials such as sodium extracted from seawater. They also have much longer life.[36]

Sony has developed a biological battery that generates electricity from sugar in a way that is similar to the processes observed in living organisms. The battery generates electricity through the use of enzymes that break down carbohydrates.[37]

In the 2000s, developments include batteries with embedded electronics such as USBCELL, which allows charging an AA battery through a USB connector, nanoball batteries that allow for a discharge rate about 100x greater than current batteries, and smart battery packs with state-of-charge monitors and battery protection circuits that prevent damage on over-discharge. Low self-discharge (LSD) allows secondary cells to be charged prior to shipping.

Standard-format batteries are inserted into battery holder in the device that uses them. When a device does not uses standard-format batteries, they are typically combined into a custom battery pack which holds multiple batteries in addition to features such as a battery management system and battery isolator which ensure that the batteries within are charged and discharged evenly.

A battery's characteristics may vary over load cycle, over charge cycle, and over lifetime due to many factors including internal chemistry, current drain, and temperature. At low temperatures, a battery cannot deliver as much power. As such, in cold climates, some car owners install battery warmers, which are small electric heating pads that keep the car battery warm.

A battery's capacity is the amount of electric charge it can deliver at the rated voltage. The more electrode material contained in the cell the greater its capacity. A small cell has less capacity than a larger cell with the same chemistry, although they develop the same open-circuit voltage.[49] Capacity is measured in units such as amp-hour (Ah). The rated capacity of a battery is usually expressed as the product of 20 hours multiplied by the current that a new battery can consistently supply for 20 hours at 68 F (20 C), while remaining above a specified terminal voltage per cell. For example, a battery rated at 100 Ah can deliver 5 A over a 20-hour period at room temperature. The fraction of the stored charge that a battery can deliver depends on multiple factors, including battery chemistry, the rate at which the charge is delivered (current), the required terminal voltage, the storage period, ambient temperature and other factors.[49]

The higher the discharge rate, the lower the capacity.[50] The relationship between current, discharge time and capacity for a lead acid battery is approximated (over a typical range of current values) by Peukert's law:

Batteries that are stored for a long period or that are discharged at a small fraction of the capacity lose capacity due to the presence of generally irreversible side reactions that consume charge carriers without producing current. This phenomenon is known as internal self-discharge. Further, when batteries are recharged, additional side reactions can occur, reducing capacity for subsequent discharges. After enough recharges, in essence all capacity is lost and the battery stops producing power. Internal energy losses and limitations on the rate that ions pass through the electrolyte cause battery efficiency to vary. Above a minimum threshold, discharging at a low rate delivers more of the battery's capacity than at a higher rate. Installing batteries with varying Ah ratings does not affect device operation (although it may affect the operation interval) rated for a specific voltage unless load limits are exceeded. High-drain loads such as digital cameras can reduce total capacity, as happens with alkaline batteries. For example, a battery rated at 2 Ah for a 10- or 20-hour discharge would not sustain a current of 1 A for a full two hours as its stated capacity implies.

Battery life (and its synonym battery lifetime) has two meanings for rechargeable batteries but only one for non-chargeables. For rechargeables, it can mean either the length of time a device can run on a fully charged battery or the number of charge/discharge cycles possible before the cells fail to operate satisfactorily. For a non-rechargeable these two lives are equal since the cells last for only one cycle by definition. The term shelf life is used to describe how long a battery will retain its performance between manufacture and use. Available capacity of all batteries drops with decreasing temperature. In contrast to most of today's batteries, the Zamboni pile, invented in 1812, offers a very long service life without refurbishment or recharge, although it supplies current only in the nanoamp range. The Oxford Electric Bell has been ringing almost continuously since 1840 on its original pair of batteries, thought to be Zamboni piles.[citation needed] ff782bc1db