不飽和チオン炭酸エステルのカスケード反応

研究に携わった方々は以下のとおりである．

三好浩一郎，大泉憲秀，三坂 恵祐，衛藤 仁，小野菊馬，西本光宏，上村 敏啓、久保田 昌嗣、清水範子， 藤井牧子，池田 千里、田尻 興保 ，山城 茂，芦村耕介，金城雄一，清永秀雄，横手千秋，濱田貴美子，秋葉悦子，寺田直子，頼藤 忍，溝口千秋

β-Cyclodextrin包接体における[3,3]-sigmatropy反応（不斉誘起） 清永秀雄，朝長 充則H8，古庄 晃H5，丸山 格H10，本多 教稔H11，秋吉 隆幸 H12，日高伸之介H14，多田隈景子 調査中

触媒による Xantahteの thion-thiol 転位に関する研究 篠原郁夫，村瀬元治，杉本慎一郎，野中美鈴，久保田昌嗣，中川秀稔

投稿論文

50. Catalytic Rearrangement of O-Cholesteryl S-Alkyl Dithiocarbonates to S-Alkyl S-Cholesteryl Dithiocarbonates by Phenols

K. Harano, K. Miyoshi and T. Hisano

Chem. Pharm. Bull., 1985, 33(5), 1861-1868). ⭕

52. A Convenient and Stereoselective Synthesis of Allylic Sulfides

K. Harano, N. Ohizumi and T. Hisano

Tetrahedron Lett., 1985, 26(35), 4203-4206.

58. Solvolytic Behavior of O-(1-Cycopropylethyl) S-Methyl Dithiocarbonate and Related Compounds

K. Harano, H. Kiyonaga and T. Hisano

Chem. Pharm. Bull., 1987, 35(4), 1388-1396. ⭕

59. Pyridine N-Oxides as Catalyst for Thione-Thiol Rearrangement

K. Harano, I. Shinohara, M. Murase and T. Hisano

Heterocycles, 1987, 26(10), 2583-2586.

60. 4-Dimethylaminopyridine N-Oxide as an Excellent Catalyst for Thione to Thiol Rearrangement of Xanthates

K. Harano, H. Kiyonaga, S. Sugimoto, T. Matsuoka and T. Hisano

Heterocycles, 1988, 27(10), 2327-2330.

62. Catalytic Rearrangement of O,S-Dialkyl Dithiocarbonates to S,S-Dithiocarbonates by Pyridine N-Oxides. The Reaction Mechanism

K. Harano, I. Shinihara, S. Sugimoto, T. Matsuoka and T. Hisano

Chem. Pharm. Bull., 1989, 37(3), 576-581. ⭕

66. Stereoselective Formation of Allylic Sulfide via Two Sequential [3,3]-Sigmatropic Rearrangements of Allylic Xanthates and Its Mechanistic Aspects

K. Harano, N. Ohizumi, K. Misaka, S. Yamashiro and T. Hisano

(1990 ･ Chem. Phram. Bull. ･ 38(3) ･ (619-624)). ⭕

68. Catalytic Behavior of Phenols in Pyrolytic Conversion of Allylic Dithiolcarbonates to Allylic Sulfides

K. Harano, S. Yamashiro, K. Misaka and T. Hisano

(1990 ･ Chem. Pharm. Bull. ･ 38(11) ･ (2956-2959)). ⭕

71. Linear Correlation of the Solvolysis Rates of Xanthates with the Grunwald-Winstein Y Values.

K. Harano, H. Kiyonaga, C. Yokote and T. Hisano

Chem. Pharm. Bull., 1991, 39(8), 1952-1957. ⭕

72. A Simple One-Pot Synthesis of Hydroisobenzothiophenes via Three-Step Sequential Pericyclic Reactions of Xanthates

K. Harano, K. Ono, M. Nishimoto, M. Eto and T. Hisano

Tetrahedron Lett., 1991, 32(21), 2387-2390.

73. [3,3]-Sigmatropic Rearrangement of Allylic Xanthates in β-Cyclodextrin Complexes

K. Harano, H. Kiyonaga and T. Hisano

Tetrahedron Lett., 1991, 32(51), 7557-7558.

76. Thione-Thiol Rearrangement of Xanthates Catalyzed by Pyridine N-Oxides. Remarkably Enhanced Reactivity of 4-Dialkylaminopyridne N-Oxides

K. Harano, H. Nakagawa, K. Kamei, H. Kiyonaga and T. Hisano

Chem. Pharm. Bull., 1992, 40(7), 1675-1682. ⭕

77. 4-Piperidinopyridine as an Effective Catalyst for Thione-Thiol Rearrangement of Xanthates

K. Harano, H. Nakagawa, H. Kiyonaga and T. Hisano

Org. Prep. Procd. Int., 1992, 24(2), 200-204.

80. Phenol-Catalyzed Thione-Thiol Rearrangement of Xanthates and MINDO/3 Analysis of the Reaction Mechanism

K. Harano, H. Kiyonaga and T. Hisano

Chem. Pharm. Bull., 1992, 40(10), 2654-2662. ⭕

84. An Improved Preparation of 2,4-Dinitrophenyl Thioethers from Thiolcarbonates

K. Harano, M. Eto, S. Kubota and T. Hisano

(1993 ･ Org. Prep. Proced. Int. ･ 25(1) ･ (130-133))

85. Sequential Pericyclic Reactions of Unsaturated Xanthates. One-Pot Synthesis of Hydroisobenzothiophenes

K. Harano, M. Eto, K. Ono, K. Misaka and T. Hisano

J. Chem. Soc. Perkin Trans. 1, 1993, 299-307.

95. Simple Synthesis of Furfuryl Sulfids via Extrusion of COS from the Xanthates and Its Mechanistic Aspects,

M. Eto, M. Nishimoto, T. Uemura, T. Hisano and K. Harano

J. Chem. Soc. Perkin Trans. 2, 1155-1162, 1995.

99. Retro-Ene Type Fragmentation of Allylic Dithiolcarbonates（AOX）

M. Eto, M. Nishimoto, S. Kubota, T. Matsuoka and K. Harano

Tetrahedron Lett., 1996, 37, 2445-2448.

謝辞 藤井牧子

101. Sequential Pericyclic Reaction of Unsaturated Xanthates. Intramolecular Cycloaddition Selectivity of the 2,4-Alkadienyl 2-Alkenyl Sulfides（AOX）

M. Eto, T. Uemura, N. Shimizu and K. Harano

Tetrahedron, 1996, 52, 13909-13918.

謝辞なし

109. Correlation of Thione-to-thiol Rearrangement Rates of Xanthates with Solvent Scales. Analysis of the Reaction Behavior by the Kamlet-Taft Parameters, π*, alpha and beta（Xan-Taft）

M. Eto, O. Tajiri, H. Nakagawa and K. Harano

Tetrahedron, 1998, 54, 8009-8014.

謝辞 池田 千里

110. Pyridine N-Oxide Catalyzed Thione-to-Thiol Rearrangement of Xanthates. MO Analysis of thr Reaction Mechanism (PyNO-Xan)

H. Nakagawa, M. Eto and K. Harano

Tetrahedron, 1998, 54, 9333-9340.

謝辞 なし

114. CATALYTIC THIONE-TO-THIOL REARRANGEMENT OF XANTHATES BY 4-DIALKYLAMINOPYRIDINE. MO ANALYSIS OF THE CATALYTIC BEHAVIOR (DAP-Xan)

H. Nakagawa, M. Eto and K. Harano

Heterocycles, 1999, 51, 51-59.

121. A X-ray Crystallographic and Computational Study of Intermolecular Edge-to-Face Aromatic Interaction in Crystal Structure of Exo [4+2]π Cycloadduct of Phencyclone and S-Allyl S-Methyl Dithiocarbonate（ASY CP DA 弱結合）

Yasuyuki Yoshitake, Hidetoshi Nakagawa, Masashi Eto and Kazunobu Harano

Tetrahedron, 2000, 56, 6015-6021.

123. Molecular Orbital Studies on Pericyclic Reactions of Cinnamyl Xanthates in b-Cyclodextrin Cavities（COX b-CyD MO)

Masashi Eto, Shoji Kubota, Hidetoshi Nakagawa, Yasuyuki Yoshitake and Kazunobu Harano

Chem. Pharm. Bull., 2000, 48(11), 1652-1659.

謝辞 朝長充則，溝口千秋

124. Theoretical Study of Neighboring-group Participation in Thione-to-Thiol Rearrangement of Xanthates. Molecular Orbital Calculations using Conductor like Screening (COSMO) Models (ROX MO COSMO)

Yasuyuki Yoshitake, Hidetoshi Nakagawa and Kazunobu Harano

Chem. Pharm. Bull., 2001, 49, 1433-1439. ⭕

134. A Cascade Reactions of Unsaturated Xanthates and Related Reactions: Computer-assisted Molecular Design and Analysis of Reaction Mechanisms

Kazunobu Harano

YAKUGAKU ZASSHI, 2005, 125(6), 469-489. ⭕

150. New Formation Mechanism of Allylic Trithiocarbonates from Sodium O-(2-Alkenyl) Dithiocarbonates via Sequential Pericyclic Reactions: Density Functional Theory Study

Masashi ETO, Koki YAMAGUCHI, Yasuyuki YOSHITAKE, Kazunobu HARANO*

Chem. Pharm. Bull., 2010, 58, 1517-1520. ⭕

151. Formation Mechanism of Furfuryl Sulfides from O-Furfuryl Dithiocarbonates: Density Functional Theory Study for Aromatic [3,3]-Sigmatropic Rearrangement

Masashi ETO, Koki YAMAGUCHI, Yasuyuki YOSHITAKE, Kazunobu HARANO*

Chem. Pharm. Bull., 2011, 59 (6), 681-685. ⭕

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