2017 Spring Solid State Chemistry (고체화학공학)

2017 Spring [ECH2022-42] Solid State Chemistry (고체화학공학)

Text: Tarr Inorganic Chemistry 5e

Class Meeting: Mon 09:00-10:15, Wed 10:30-11:45 (Rm 26505)

Office Hours: Tue 10:00-11:30 am (Rm 25317A)

TA: Myong-Joo NAM (남명주, Rm 25416)

go to icampus for lecture slides

[2017.6.19.] HW#14

Describe your understanding on the MO of H2O molecule after reading followings.

* http://butane.chem.uiuc.edu/pshapley/Enlist/Labs/WaterStruc/Teachers.html

* http://www1.lsbu.ac.uk/water/h2o_orbitals.html

* https://en.wikipedia.org/wiki/Molecular_orbital_diagram

* http://www.ch.ic.ac.uk/vchemlib/course/mo_theory/

* http://pubs.acs.org/doi/pdf/10.1021/ed064p124 (in case you cannot see this file, the pdf file was uploaded on icampus>과목자료실.

- 1 page (either in English or in Korean)

- Email to kimjaeyun@skku.edu before 6/23 6 pm

[2017.6.7.] HW#13

Problems in Chapter 9

9.2 / 9.3 / 9.8 / 9.12(a-e)

- Due: Class meeting (6.12.)

[2017.5.31.]  Final Exam

6/5 (Mon): No class meeting (학부생 예비군 훈련일)

6/19 (Mon): Final Exam (26505, 8:30~10:15 am, please come to classroom by 8:20 am)

[2017.5.29.] HW#12

(1) Research on Blomstrand's chain theory vs. Werner's coordination theory.

(2) Draw the structure of EDTA and [Ca(EDTA)]2-. Research on the applications (uses) of EDTA.

- Due: Next class meeting (5.31.)

[2017.5.24.] HW#11

(1) Derive c/a value in HCP unit cell.

(2) Derive radius of tetrahedral site and octahedral site in close-packed structure.

(3) Derive the equation of lattice spacing (dhkl) related with Miller index (h,k,l) for cubic structure.

(4) What is coordination number for the following structures.

- Diamond structure

- NaCl structure

- CsCl structure

- Zinc Blend Structure

- Wurtzite structure

- Fluorite structure

- Rutile structure

- Due: Next class meeting (5.29.)

[2017.5.22.] HW#10

(1) Derive APF of BCC and FCC structure.

(2) When silver crystallizes, it forms face-centered cubic cells. The unit cell edge length is 408.7 pm. Calculate the density of silver.

- Due: Next class meeting (5.24.)

[2017.5.11.] HW#9

Construct MO of the following molecules.

(1) NO, (2) N3- ion

- Due: Class meeting (5.15.)

[2017.4.12.] HW#8

Problems in Chapter 4

4.21 / 4.23 / 4.26 / 4.28 / 4.29

- Due: Class meeting (4.26.)

[2017.4.12.]  Mid-term Exam

4/19 (Wed): No class meeting

4/24 (Mon): Mid-term Exam (26505, 9:00~10:15 am, please come to classroom by 8:50 am)

4/26 (Wed): Make-up class meeting (10:30 am)

[2017.4.12.] HW#7

(1) Problems in Chapter 3: 3.3 / 3.9 / 3.41

(2) Complete the character table of C3v point group (Tarr 5th ed. 96-99)

- Due: Class meeting (4.17.)

[2017.4.10.] HW#6

Determine the point group for the following molecules.