2010 - 2019
“Enantioselective Iridium-Catalyzed Allylation of Acetylenic Ketones via 2-Propanol-Mediated Reductive Coupling of Allyl Acetate: C14-C23 of Pladienolide D,” Brito, G. A.; Jung, W.-O.; Yoo, M.; Krische, M. J. Angew. Chem. Int. Ed. 2019, 58, 18803.
“Inversion of Enantioselectivity in Allene Gas vs Allyl Acetate Reductive Aldehyde Allylation Mediated by 2-Propanol Guided by Metal-Centered Stereogenicity: An Experimental and Computational Study,” Kim, S. W.; Meyer, C. C.; Mai, B. K.; Liu, P.; Krische, M. J. ACS Catalysis, 2019, 9, 9158.
“Direct Conversion of Primary Alcohols to 1,2-Amino Alcohols: Enantioselective Iridium-Catalyzed Carbonyl Reductive Coupling of Phthalimido-Allene via Hydrogen Auto-Transfer,” Spielmann, K.; Xiang, M.; Schwartz, L. A.; Krische, M. J. J. Am. Chem. Soc. 2019, 141, 14136.
"Vinyl Triflate-Aldehyde Reductive Coupling-Redox Isomerization Mediated by Formate: Rhodium-Catalyzed Ketone Synthesis in the Absence of Stoichiometric Metals," Shuler, W. G.; Swyka, R. A.; Schempp, T. T.; Spinello, B. J.; Krische, M. J. Chem. Eur. J. 2019, 25, 12517.
"Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis," Doerksen, R. S.; Meyer, C. C.; Krische, M. J. Angew. Chem. Int. Ed. 2019, 58, 14055.
"Conversion of Aldehydes to Branched or Linear Ketones via Regiodivergent Rhodium-Catalyzed Vinyl Bromide Reductive Coupling-Redox Isomerization Mediated by Formate," Swyka, R. A.; Shuler, W. G.; Spinello, B. J.; Zhang, W.; Lan, C.; Krische, M. J. J. Am. Chem. Soc. 2019, 141, 6864.
"Regio- and Enantioselective Iridium-Catalyzed N-Allylation of Indoles and Related Azoles with Racemic Branched Alkyl-Substituted Allylic Acetates," Kim, S. W.; Schempp, T. T.; Zbieg, J. R.; Stivala, C. E.; Krische, M. J. Angew. Chem. Int. Ed. 2019, 58, 7762.
"Catalytic Enantioselective Synthesis of Chiral Organofluorine Compounds: Alcohol-Mediated Hydrogen Transfer for Catalytic Carbonyl Reductive Coupling," Tauber, J.; Schwartz, L.A..; Krische, M. J. Org. Proc. Res. Devel. 2019, 23, 730.
"Successive Nucleophilic and Electrophilic Allylation for The Catalytic Enantioselective Synthesis of 2,4-Disubstituted Pyrrolidines," Luo, G.; Xiang, M.; Krische, M. J. Org. Lett. 2019, 21, 2493.
"Rhodium-Catalyzed Aldehyde Arylation via Formate-Mediated Transfer Hydrogenation: Beyond Metallic Reductants in Grignard-NHK-Type Addition," Swyka, R. A.; Zhang, W.; Richardson, J.; Ruble, J. C.; Krische, M. J. J. Am. Chem. Soc. 2019, 141, 1828.
"Cyclometallated Iridium-PhanePhos Complexes Are Active Catalysts in Enantioselective Allene-Fluoral Reductive Coupling and Related Alcohol-Mediated Carbonyl Additions that Form Acyclic Quaternary Carbon Stereocenters," Schwartz, L. A.; Holmes, M. T.; Brito, G. A.; Goncalves, T. P.; Richardson, J.; Ruble, J. C.; Huang, K. -W.; Krische, M. J. J. Am. Chem. Soc. 2019, 141. 2087.
"Enantioselective Iridium-Catalyzed Carbonyl Isoprenylation via Alcohol-Mediated Hydrogen Transfer," Xiang, M.; Luo, G.; Wang, Y.; Krische, M. J. Chem. Comm. 2019, 55, 981.
"Regio- and Enantioselective Iridium-Catalyzed Amination of Racemic Branched Alkyl-Substituted Allylic Acetates with Primary and Secondary Aromatic and Heteroaromatic Amines," Kim, S. W.; Schwartz, L. A.; Zbieg, J. R.; Stivala, C. E.; Krische, M. J. J. Am. Chem. Soc. 2019, 141, 671.
"Catalytic Enantioselective Carbonyl Propargylation Beyond Preformed Carbanions: Reductive Coupling and Hydrogen Auto-Transfer," Ambler, B. R.; Woo, S. K.; Krische, M. J. ChemCatChem 2018, 11, 324.
"Selection between Diastereomeric Kinetic vs Thermodynamic Carbonyl Binding Modes Enables Enantioselective Iridium-Catalyzed anti-(α-Aryl)allylation of Aqueous Fluoral Hydrate and Difluoroacetaldehyde Ethyl Hemiacetal," Cabrera, J. M.; Tauber, J.; Zhang, W.; Xiang, M.; Krische, M. J. J. Am. Chem. Soc. 2018, 140, 9392.
"Hydroamination versus Allylic Amination in Iridium Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity," Kim, S. W.; Wurm, T.; Brito, G. A.; Jung, W.-O.; Zbieg, J. R.; Stivala, C. E.; Krische, M. J. J. Am. Chem. Soc. 2018, 140, 9087.
"Enantioselective Ruthenium Catalyzed Benzocyclobutenone-Ketol Cycloaddition: Merging C-C Bond Activation and Transfer Hydrogenative Coupling for Type II Polyketide Construction," Ambler, B. R.; Turnbull, B. W. H.;Suravarapu, S. R.; Uteuliyev, M. M.; Huynh, N. O.; Krische, M. J. J. Am. Chem. Soc. 2018, 140, 9091.
"Catalytic Enantioselective Allylation of Acetylenic Aldehydes via 2-Propanol-Mediated Reductive Coupling," Brito, G. A.; Della-Felice, F.; Luo, G.; Burns, A. S.; Philli, R.; Rychnovsky, S. D.; Krische, M. J. Org. Lett. 2018, 20, 4144.
"Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes and Enynes with Carbonyl Compounds and Imines," Holmes, M.; Schwartz, L. A. Chem. Rev. 2018, 118, 6026.
"Amphiphilic π-Allyliridium C, O-Benzoates Enable Regio- and Enantioselective Amination of Branched Allylic Acetates Bearing Linear Alkyl Groups," Meza, A. T.; Wurm, T.; Smith, L.; Kim, S. W.; Zbieg, J. R.; Stivala, C. E.; Krische, M. J. J. Am. Chem. Soc. 2018, 140, 1275.
"Enantioselective Iridium Catalyzed Phthalide Formation via Internal Redox Allylation of Phthalaldehydes," Cabrera, J. M.; Tauber, J.; Krische, M. J. Angew. Chem. Int. Ed. 2018, 57, 1390.
"Ruthenium(0) Catalyzed Cycloaddition of 1,2-Diols, Ketols or Diones via Alcohol-Mediated Hydrogen Transfer," Sato, H.; Turnbull, B. W. H.; Fukaya, K.; Krische, M. J. Angew. Chem. Int. Ed. 2018, 57, 3012.
"Ruthenium-Catalyzed Insertion of Adjacent Diol Carbon Atoms into C-C Bonds: Entry to Type II Polyketides," Bender, M.; Turnbull, B. W. H.; Ambler, B. R.; Krische, M. J. Science, 2017, 779.
"Diols as Dienophiles: Bridged Carbocycls via Ruthenium(0) Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene," Sato, H.; Fukaya, K.; Poudel, B. S.; Krische, M. J. Angew. Chem. Int. Ed. 2017, 56, 14667.
"Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis," Feng, J.; Holmes, M.; Krische, M. J. Chem. Rev. 2017, 117, 12564.
"Carbonyl anti-(α-Amino)allylation via Ruthenium Catalyzed Hydrogen Auto-Transfer: Use of an Acetylenic Pyrrole as an Allylmetal Pronucleophile," Zhang, W.; Chen, W.; Xiao, H.; Krische, M. J. Org. Lett. 2017, 19, 4876.
"Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier," Kim, S. W.; Zhang, W.; Krische, M. J. Acc. Chem. Res. 2017, 50, 2371.
“Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition Metal Catalysis,” Haydl, A. M.; Breit, B.; Liang, T.; Krische, M. J. Angew. Chem. Int. Ed. 2017, 56, 11312.
"Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation," Holmes, M. T.; Nguyen, K. D.; Schwartz, L. A.; Luong, T.; Krische, M. J. J. Am. Chem. Soc. 2017, 139, 8114.
"Nickel Catalyzed Cross-Coupling of Vinyl-Dioxanones to Form Enantiomerically Enriched Cyclopropanes," Guo, Y.-A.; Liang, T.; Kim, S. W.; Xiao, H.; Krische, M. J. J. Am. Chem. Soc. 2017, 139, 6847.
"Asymmetric Allylation of Glycidols Mediated by Allyl Acetate via Iridium Catalyzed Hydrogen Transfer," Kim, S. W.; Lee, W.; Krische, M. J. Org. Lett. 2017, 19, 1252.
"Ruthenium(0) Catalyzed C-C Coupling of Alkynes and 3-Hydroxy-2-oxindoles: Direct C-H Vinylaion of Alcohols," Luong, T.; Chen, S.; Qu, K.; McInturff, E. L.; Krische, M. J. Org. Lett. 2017, 19, 966.
"Diastereo- and Enantioselective Synthesis of Oxetanes Bearing All-Carbon Quaternary Stereocenters via Iridium Catalyzed Alcohol-Vinyl Epoxide C-C Coupling," Guo, Y.-A.; Lee, W.; Krische, M. J. Chem. Eur. J. 2017, 2557.
"Diols, α-Ketols and Diones as 22π Components in [2+2+2] Cycloadditions of 1,6-Diynes via Ruthenium(0) Catalyzed Transfer Hydrogenation," Sato, H.; Bender, M.; Chen, W.; Krische, M. J. J. Am. Chem. Soc. 2016, 138, 16244.
"Metal-Catalyzed Reductive Coupling of Olefin-Derived Nucleophiles: Reinventing Carbonyl Addition," Nguyen, K. D.; Park, B. Y.; Luong, T.; Sato, H.; Garza, V. J.; Krische, M. J. Science 2016, 354, 300.
"Regioselective Hydrohydroxy of Styrene with Primary Alcohols or Aldehydes via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation," Xiao, H.; Wang, G.; Krische, M. J. Angew. Chem. Int. Ed. 2016, 55, 16119.
"Osmium(0) Catalyzed C-C Coupling of Ethylene and α-Olefins with Diols, Ketols or Hydroxy Esters via Transfer Hydrogenation," Park, B. Y.; Luong, T.; Sato, H.; Krische, M. J. J. Org. Chem. 2016, 81, 8585.
"Enantioselective Formation of All-Carbon Quaternary Centers via C-H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation," Nguyen, K. D.; Herkommer, D.; Krische, M. J. J. Am. Chem. Soc. 2016, 138, 14210.
"C-Propargylation Overrides O-Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium Catalyzed Transfer Hydrogenation," Liang, T.; Woo, S. K.; Krische, M. J. Angew. Chem. Int. Ed. 2016, 55, 9207.
"Ruthenium-BINAP Catalyzed Alcohol C-H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation," Nguyen, K. D.; Herkommer, D.; Krische, M. J. J. Am. Chem. Soc. 2016, 138, 5238.
”Hydroxymethylation beyond Carbonylation: Enantioselectvie Iridium Catalyzed Reductive Coupling of Formaldehyde with Allylic Acetates via Enantiotopic π-Facial Discrimination,” Garza, V. J.; Krische, M. J. J. Am. Chem. Soc. 2016, 138, 3655.
"Ruthenium(0)-Catalyzed [4+2] Cycloaddition of Acetylenic Aldehydes with α-Ketols: Convergent Construction of Angucycline Ring Systems," Saxena, A.; Perez, F.; Krische, M. J. Angew. Chem. Int. Ed. 2016, 55, 1493.
“Diene Hydroaminomethylation via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation: Beyond Carbonylation,” Oda, S.; Franke, J.; Krische, M. J. Chem. Sci. 2016, 7, 136.
"Iridium Catalyzed C-C Coupling of a Simple Propargyl Ether with Primary Alcohols: Enantioselective Homoaldol Addition via Redox-Triggered (Z)-Siloxyallylation," Liang, T.; Zhang, W.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 16024.
"Ruthenium Catalyzed Diastereo- and Enantioselevtive Couping of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls," Liang, T.; Zhang, W.; Chen, T.-Y.; Nguyen, K. D.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 13066.
"Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation," Tsutsumi, R.; Hong, S.; Krische, M. J. Chem. Eur. J. 2015, 21, 12903.
Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control,” Grayson, M. N.; Krische, M. J.; Houk, K. N. J. Am. Chem. Soc. 2015, 137, 8838.
"Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines and Alcohols: SIte-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines," Wang, G.; Franke, J.; Ngo, C. Q.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 7915.
"A Metallacycle Fragmentation Strategy for Vinyl Transfer from Enol Carboxylates to Secondary Alcohol C-H Bonds via Osmium or Ruthenium Catalyzed Transfer Hydrogenation," Park, B. Y.; Luong, T.; Sato, H.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 7652.
"Ruthenium(0) Catalyzed Endiyne-α-Ketol [4+2] Cycloaddition: Convergent Assembly of Type II Polyketide Substructures," Saxena, A.; Perez, F.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 5883.
“Enantioselective Ruthenium Catalyzed Carbonyl Allylation via Alkyne-Alcohol C-C Bond Forming Transfer Hydrogenation: Allene Hydrometallation vs. Oxidative Coupling,” Liang, T.; Nguyen, K. D.; Zhang, W.; Krische, M. J. J. Am. Chem. Soc. 2015, 137, 3161.
"Hydroaminomethylation Beyond Carbonylation: Allene-Imine Reductive Coupling by Ruthenium-Catalyzed Transfer Hydrogenation," Oda, S.; Sam, B.; Krische, M. J. Angew. Chem. Int. Ed. 2015, 54, 8525.
“Ruthenium Catalyzed C-C Coupling of Fluorinated Alcohols with Allenes to Form All-Carbon Quaternary Centers: Dehydrogenation at the Energetic Limit of β-Hydride Elimination,” Sam, B.; Luong, T.; Krische, M. J. Angew. Chem. Int. Ed. 2015, 54, 5465.
“Paraformaldehyde and Methanol as C1-Feedstocks in Metal Catalyzed C-C Couplings of π-Unsaturated Reactants: Beyond Hydroformylation,” Sam, B.; Breit, B.; Krische, M. J. Angew. Chem. Int. Ed. 2015, 54, 3267.
“Ruthenium Catalyzed C-C Coupling of Amino Alcohols with Dienes via Transfer Hydrogenation: Redox-Triggered Imine Addition and Related Hydroaminoalkylations,” Chen, T.-Y.; Tsutsumi, R.; Montgomery, T. P.; Volchkov, I. Krische, M. J. J. Am. Chem. Soc. 2015, 137, 1798.
"Palladium Catalyzed Reductive Cyclization of N-Acyl ortho-Bromoanilides to Form 3-Hydroxy-2-Oxindoles: A Hydrogen-Mediated Grignard Addition," Shin, I.; Ramgren, S. D.; Krische, M. J. Tetrahedron 2015, 71, 5776.
“Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting Group-Free Synthesis of 4-Hydroxy-2,6-cis- or trans-Pyrans,” Shin, I.; Wang, G.; Krische, M. J. Chem. Eur. J. 2014, 13382.
“Alkynes as Allylmetal Equivalents in Redox-Triggered C-C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium Catalyzed Propargyl C-H Activation,” Park, B. Y.; Nguyen, K. D.; Chaulagain, M. R.; Komanduri, V.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 11902.
“Redox-Triggered C-C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation,” Feng, J.; Garza, V. J.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 8911.
“Benzannulation via Ruthenium Catalyzed Diol-Diene [4+2] Cycloaddition: One- and Two-Directional Syntheses of Fluoranthenes and Acenes,” Geary, L. M.; Chen T.-Y.; Montgomery, T. P.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 5920.
“Redox-Triggered C-C Coupling of Diols and Alkynes: Synthesis of β,γ-Unsaturated α-Hydroxyketones and Furans via Ruthenium Catalyzed Hydrohydroxyalkylation,” McInturff, E. L.; Nguyen, K. D.; Krische, M. J. Angew. Chem. Int. Ed. 2014, 53, 3232.
"Ring Expansion of Cyclic 1,2-Diols to Form Medium Sized Rings via Ruthenium Catalyzed Transfer Hydrogenative Cycloaddition," Kasun, Z. A.; Geary, L. M.; Krische, M. J. Chem. Comm. 2014, 7545.
“Ruthenium Catalyzed Hydrohydroxyalkylation of Acrylates with Diols and α-Hydroxycarbonyl Compounds to Form Spiro- and α-Methylene-γ-Butyrolactones,” McInturff, E. L.; Mowat, J.; Waldeck, A. R.; Krische, M. J. J. Am. Chem. Soc. 2013, 135, 17230.
“Ruthenium Catalyzed Hydrohydroxyalkylation of Isoprene Employing Heteroaromatic Secondary Alcohols: Isolation and Reversible Formation of the Putative Metallacycle Intermediate,” Park, B. Y.; Montgomery, T. P.; Garza, V.; Krische, M. J. J. Am. Chem. Soc. 2013, 135, 16320.
“Direct C-C Coupling of α-Olefins and Styrenes to 3-Hydroxy-2-oxindoles by Ruthenium Catalyzed Hydrohydroxyalkylation: Byproduct-Free Conversion of Secondary to Tertiary Alcohols,” Yamaguchi, E.; Mowat, J.; Luong, T.; Krische, M. J. Angew. Chem. Int. Ed. 2013, 52, 8428.
“Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF3-Bearing All-Carbon Quaternary Centers,” Sam, B.; Montgomery, T. P. Krische, M. J. Org. Lett. 2013, 15, 3790.
“Ruthenium Catalyzed Hydroaminoalkylation of Isoprene via Transfer Hydrogenation: Byproduct-free Prenylation of Hydantoins,” Schmitt, D. C.; Lee, J.; Dechert-Schmitt, A.-M. R. Yamaguchi, E.; Krische, M. J. Chem. Comm. 2013, 6096.
“Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4+2] Cycloaddition across the Diol, Hydroxycarbonyl or Dione Oxidation Levels,” Geary, L. M.; Glasspoole, B. W.; Kim, M. M. Krische, M. J. J. Am. Chem. Soc. 2013, 135, 3796.
“Site-Selective Primary Alcohol Dehydrogenation Enables Protecting Group-Free Diastereoselective C-C Coupling of 1,3-Glycols and Allyl Acetate,” Dechert-Schmitt, A.-M. R.; Schmitt, D. C.; Krische, M. J. Angew. Chem. Int. Ed. 2013, 52, 3195.
"Regioselective Ruthenium Catalyzed Hydrohydorxyalkylation of Dienes with 3-Hydorxy-2-Oxindoles: Prenylation, Geranylation and Beyond," Chen, T.-Y.; Krische, M. J. Org. Lett. 2013, 15, 2994.
“Regiodivergent Reductive Coupling of 2-Substituted Dienes to Formaldehyde Employing Ruthenium or Nickel Catalysts: Hydrohydroxymethylation via Transfer Hydrogenation,” Köpfer, A.; Sam, B.; Breit, B.; Krische, M. J. Chem. Sci. 2012, 4, 1876.
“Chiral Anion Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium Catalyzed Butadiene Hydrohydroxyalkylation,” McInturff, E. L.; Yamaguchi, E.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 20628.
“Iridium-Catalyzed Allylation of Chiral β-Stereogenic Alcohols: Bypassing Discrete Formation of Epimerizable Aldehydes,” Org. Lett. Schmitt, D. C.; Dechert-Schmitt, A.-M. R.; Krische, M. J. Org. Lett. 2012, 14, 6302.
“Direct, Redox Neutral Prenylation and Geranylation of Secondary Carbinol C-H Bonds: C4 Regioselectivity in Ruthenium Catalyzed C-C Couplings of Dienes to α-Hydroxy Esters,” Leung, J. C.; Geary, L. M.; Chen, T.-Y.; Zbieg, J. R.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 15700.
“Ruthenium Catalyzed Reductive Coupling of 1,3-Enynes and Aldehydes via Transfer Hydrogenation: anti-Diastereoselective Carbonyl Propargylation,” Geary, L. M.; Leung, J. C.; Krische, M. J. Chem. Eur. J. 2012, 18, 16823.
“Enantioselective Conversion of Primary Alcohols to α-Methylene Butyrolactones via Iridium Catalyzed C-C Bond Forming Transfer Hydrogenation: 2-(Alkoxycarbonyl)allylation,” Montgomery, T. P.; Hassan, A.; Park, B. Y.; Krische, M. J. J. Am. Chem. Soc. 2012, 134, 11100.
“Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides,” Woo, S. K.; Geary, L. M.; Krische, M. J. Angew. Chem. Int. Ed. 2012, 51, 7830.
“Consecutive Iridium Catalyzed C-C and C-H Bond Forming Hydrogenations for the Diastereo- and Enantioselective Synthesis of syn-3-Fluoro-1-Alcohols: C-H (2-Fluoro)allylation of Primary Alcohols,” Hassan, A.; Montgomery, T. P.; Krische, M. J. Chem. Comm. 2012, 4692.
“Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene,” Zbieg, J. R.; Yamaguchi, E.; McInturff, E. L.; Krische, M. J. Science 2012, 336, 324.
“Diastereo- and Enantioselective Iridium Catalyzed Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level: 1,3-Enynes as Allenylmetal Equivalents,” Geary, L. M.; Woo, S. K.; Leung, J. C. Krische, M. J. Angew. Chem. Int. Ed. 2012, 51, 2972.
“Polarity Inversion of Donor-Acceptor Cyclopropanes: Disubstituted -Lactones via Enantioselective Iridium Catalysis,” Moran, J.; Smith, A. G.; Carris, R. M.; Johnson, J. S.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 18618.
“Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction,” Gao, X.; Han, H.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 12795.
“Alkyne-Aldehyde Reductive C-C Coupling via Ruthenium Catalyzed Transfer Hydrogenation: Regio- and Stereoselective Carbonyl Vinylation to Form Trisubstituted Allylic Alcohols in the Absence of Vinylmetal Reagents,” Leung, J. C.; Patman, R. L.; Sam, B.; Krische, M. J. Chem. Eur. J. 2011, 17, 12437.
“Catalytic Enantioselective Grignard Nozaki-Hiyama Methallylation from the Alcohol Oxidation Level: Chloride Compensates for π-Complex Instability,” Hassan, A.; Townsend, I. A.; Krische, M. J. Chem. Comm. 2011, 10028.
“Diastereo- and Enantioselective Ruthenium Catalyzed Hydrohydroxyalkylation of 2-Silyl-Butadienes: Carbonyl syn-Crotylation from the Alcohol Oxidation Level,” Zbieg, J. R.; Moran, J.; Krische M. J. J. Am. Chem. Soc. 2011, 133 (27), 10582.
"Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydroxymethylation with Formaldehyde," Bausch, C. C.; Patman, R. L.; Breit, B.; Krische, M. J. Angew. Chem. Int. Ed. 2011, 50, 5687.
“Iridium Catalyzed anti-Diastereo- and Enantioselective Carbonyl (α-Trifluoromethyl)allylation from the Alcohol or Aldehyde Oxidation Level,” Gao, X.; Zhang, Y. J.; Krische, M. J. Angew. Chem. Int. Ed. 2011, 50, 4173.
“Enantioselective Iridium Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates,” Zbieg, J. R.; Hassan, A.; Kim, I.-S.; Krische, M. J. Angew. Chem. Int. Ed. 2011, 50, 3493.
“Amplification of anti-Diastereoselectivity via Curtin-Hammett Effects in Ruthenium Catalyzed Hydrohydroxyalkylation of 1,1-Disubstituted Allenes: Diastereoselective Formation of All-Carbon Quaternary Centers,” Zbieg, J. R.; McIntuff, E. L.; Leung, J. C.; Krische, M. J. J. Am. Chem. Soc. 2011, 133, 1141.
"Direct Catalytic C-C Coupling of Methanol Employing a Homogeneous Iridium Complex: Hydrohydroxymethylation of Allenes," Moran, J.; Preetz, A.; Mesch, R. A.; Krische, M. J. Nature Chem. 2011, 3, 287.
"Enhanced anti-Diastereo- and Enantioselectivity in Alcohol Mediated Carbonyl Crotylation Using an Isolable Single Component Iridium Catalyst," Gao, X.; Townsend, I. A.; Krische, M. J. J. Org. Chem. 2011, 76, 2350.
“Total Synthesis of (+)-Roxaticin via C-C Bond Forming Transfer Hydrogenation: A Departure from Stoichiometric Chiral Reagents, Auxiliaries and Premetallated Nucleophiles in Polyketide Construction,” Han, S. B.; Hassan, A.; Kim, I. S.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 15559.
"Iridium Catalyzed anti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level" Han, S. B.; Gao, X.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 9153.
"Direct Ruthenium Catalyzed C-C Coupling of Ethanol: Diene Hydro-Hydroxyethylation to Form All Carbon Quaternary Center" Han, H.; Krische, M. J. Org. Lett. 2010, 12, 2844.
"Allenamide Hydro-Hydroxyalkylation: 1,2-Aminoalcohols via Ruthenium Catalyzed Carbonyl anti-Aminoallylation" Zbieg, J. R.; McInturff, E.; Krische, M. J. Org. Lett. 2010, 12, 2514.
"anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates" Zhang, Y. J.; Yang, J. H.; Kim, S. H.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 4562.
"Diastereo- and Enantioselective anti-Alkoxyallylation Employing Allylicgem-Dicarboxylate as Ally Donors via Iridium Catalyzed Transfer Hydrogenation." Han, S. B.; Han, H.; Krische, M. J. J. Am. Chem. Soc. 2010, 132, 1760.
