2013-01-04. Hydrogen-Nitrogen Greenhouse Warming in Earth's Early Atmosphere | Robin Wordsworth and Raymond Pierrehumbert, Science Vol. 339 no. 6115 pp. 64-67. Excerpt: One of the most durable questions about Earth’s early climate arises from the faint young Sun effect: Because progressive accumulation of He in a star’s core causes its luminosity to increase with age, the solar energy incident on Earth was significantly lower [∼75% of present-day values 3.8 billion years ago (Ga)] during the Hadean and Archean eras. Because geological evidence shows that Earth was not in a globally glaciated, snowball state throughout this time, additional mechanisms must have been present to warm the climate. Previous explanations for this altered climate have included increased atmospheric ammonia or CH4, a decreased surface albedo, and changes in the distribution of clouds. However, all of these mechanisms have subsequently been shown to suffer important defects. … on the pre-biotic/early Archean Earth, the atmospheric N2 content was around two to three times the present-day value. Hydrogen, the most abundant gas in the solar system, has previously been ignored in the Archean climate budget, presumably because it was long thought to be a minor constituent even in the early atmosphere. …It was long believed that the escape of H2 in the Archean was rapid, … However, recent numerical calculations imply that the rate of hydrodynamic H2 escape on the early Earth was more strongly constrained by the adiabatic cooling of the escaping gas, given a limited extreme ultraviolet (XUV) energy input. As a result, H2 could have been a major constituent (up to ∼30% by volume) of the Archean atmosphere unless surface or ocean biogeochemistry continuously removed it. …molecular hydrogen interacts strongly with infrared radiation via collision-induced absorption (CIA), the strength of which scales with the product of the densities of the two interacting gases. CIA has been well studied for the gas giant planets and Titan, where it dominates radiative transfer in the middle and lower portions of the atmosphere. On early Earth, N2 and H2 may both have been abundant in the atmosphere, so interacting pairs of N2-N2, H2-N2, and H2-H2 should all be considered as potential contributors to greenhouse warming. …CH4 greenhouse was believed necessary to solve the faint young Sun problem. In contrast, our results show that an early climate dominated by abiotic H2-N2 and CO2 warming is consistent with both observational and theoretical limits on atmospheric CO2 levels…. H2-N2 warming is also likely to be important in the search for biosignatures on super-Earth exoplanets, whose higher masses imply lower energy-limited hydrogen escape rates and larger typical atmospheric N2 inventories. Because incident XUV flux is a function of orbital distance, H2-N2 warming may be of particular importance to the habitability of terrestrial exoplanets that are far from their host stars. …. Read the full article: http://www.sciencemag.org/content/339/6115/64.full See also "How Was Early Earth Kept Warm?" by James F. Kasting, http://www.sciencemag.org/content/339/6115/44.full
2012-03-30. Ancient raindrop fossils shed light on early atmosphere | By Amina Khan, Los Angeles Times. Excerpt: Fossilized imprints of raindrops that were sealed into stone 2.7 billion years ago indicate that Earth's early atmosphere could have been packed with greenhouse gases, according to new research that addresses a long-standing paradox of the planet's early history.
About 2 billion years ago, the young sun was far less bright, emitting less than 85% of the light and heat it puts out today…. How did Earth manage to stay so warm?
To get at the answer, a team of scientists from the University of Washington in Seattle adopted an unusual method employed in 1851 by a 19th-century geologist named Charles Lyell… Lyell suggested that the thickness of the ancient atmosphere could be pinned down by measuring the size of fossil raindrops….
2009 Dec 10. Our
Atmosphere Came From Space Gases, Study Says. By
Ker Than, for
National Geographic News. Excerpt:
that make up Earth's atmosphere came from a
swarm of comets, not from bubbling volcanoes
as long thought, a new study says. The new theory
came about after scientists discovered that
pristine samples of the elements krypton and
xenon, recently collected from deep within the
Earth, have the same chemical makeup as ancient
It's still true that volcanoes spewed out some
gases, "but [that] contribution was insignificant" for
the creation of Earth's atmosphere," Ballentine
... most of Earth's krypton has remained unchanged
since its arrival on our planet—allowing
scientists to precisely study the conditions
of early Earth.
Based on their research, Ballentine and colleagues
claim that our atmosphere likely formed when
gas and water-rich comets bombarded Earth, shortly
after its formation 4.54 billion years ago.
...Scientists have already discovered that the
comet barrage likely formed Earth's oceans....
2003 September 17. Ancient
Relatives of Algae Yield New Insights into
Role of CO2 in Earth's Early Atmosphere. NASA's
Earth Observatory. Greenhouse gas has been
playing a critical role in warming our planet
for billions of years, according to a new
study that looks at the photosynthetic cycle
by which plants convert light energy and CO2
into cellular tissue.